• Title/Summary/Keyword: carbide behavior

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Silicon Melt Infiltration of Reaction-Bonded Silicon Carbide (반응소결 탄화규소에서 실리콘의 침윤향상)

  • 신현익;김주선;이종호;김긍호;송휴섭;이해원
    • Journal of the Korean Ceramic Society
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    • v.39 no.7
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    • pp.693-698
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    • 2002
  • Reaction-Bonded Silicon Carbide (RBSC) Ceramics were fabricated which satisfies the maximum packing density of silicon carbide skeleton in the green compacts. Such a high packing density induced incomplete infiltration during reaction-sintering; forms linear void around the interface of large alpha silicon carbide powders. During reaction-sintering, the limited extraction and entrapped gas induced by residue oxide was considered to be a reason of linear void formation. In order to improve infiltration behavior in the highly packed preform, the pre-treatment methods for residue oxide removal were proposed.

Precipitation Behavior of Laves Phase and Mechanical Properties of 10%Cr Ferritic Heat-resistant Steel Applied to the Power Plants (발전플렌트용 10Cr페라이트 내열강의 라베스상 석출거동 및 기계적 성질)

  • Kang, C.Y.;Nam, K.W.;Kim, H.J.;Kim, C.G.;Bae, D.S.;Lee, J.M.
    • Journal of Power System Engineering
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    • v.5 no.1
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    • pp.97-103
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    • 2001
  • The present study was investigated changes of precipitation behaviour of laves phase in ferrite single phase and ferrite-martensite dual phase and the mechanical properties of 10%Cr ferritic alloys. In the ferrite phase, laves phase was mainly precipitated, whereas in the martensite phase, carbide was preferentially formed during the initial stage of aging and with increasing aging time. Laves phase and carbide were simultaneously precipitated by precipitation of laves phase at around carbide. Strength and toughness were lowered by the disk-type precipitator in the initial stage of aging and toughness was recovered with increasing of aging time and then, decreasing by precipitation of laves phase.

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Tribological Behavior of Silicon Carbide Ceramics - A Review

  • Sharma, Sandan Kumar;Kumar, B. Venkata Manoj;Kim, Young-Wook
    • Journal of the Korean Ceramic Society
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    • v.53 no.6
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    • pp.581-596
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    • 2016
  • A comprehensive review on sliding and solid particle erosion wear characteristics of silicon carbide (SiC) ceramics and SiC composites is provided. Sliding or erosion wear behavior of ceramics is dependent on various material characteristics as well as test parameters. Effects of microstructural and mechanical properties of SiC ceramics are particularly focused to understand tribological performance of SiC ceramics. Results obtained between varieties of pairs of SiC ceramics indicate complexity in understanding dominant mechanisms of material removal. Wear mechanisms during sliding are mainly divided in two groups as mechanical and tribochemical. In solid particle erosion conditions, wear mechanisms of SiC ceramics are explained by elastic-plastic deformation controlled micro-fracture on the surface followed by radial-lateral crack propagation beneath the plastic zone.

Sliding Wear Behavior of Plasma-Sprayed $Al_2$O$_3$-TiO$_2$ Coating against Cemented Carbide (Al$_2$O$_3$-TiO$_2$ 플라즈마 세라믹 코팅과 초경합금간의 미끄럼 마멸특성)

  • 이병섭;채영훈;김석삼
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2001.06a
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    • pp.313-318
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    • 2001
  • The sliding wear behavior of Plasma-Sprayed Al$_2$O$_3$-TiO$_2$ Coating against Cemented Carbide were Investigated using a pin on disk type tester. The experiment was conducted using Al$_2$O$_3$-TiO$_2$ Coaling as pin material and Cemented Carbide as disk material and different operating conditions, at room temperature under a dry conditions. The results showed that the type B(250kw power) appeared average wear rate Is lowed than type A(80kw power). The specific wear rate of Specimen A1 Increased with normal load. But The specific wear rate of Specimen B1 decreased with normal load. Average wear rate of specimen A3, B3 are lowed than other but the sliding wear mechanism of edge were rough.

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Estimation of Tribological Properties on Surface Modified SiC by Chlorine Gas Reaction at Various Temperatures (다양한 온도에서 염소가스 반응에 의해 표면 개질된 SiC의 트라이볼로지 특성평가)

  • Bae, Heung-Taek;Jeong, Ji-Hoon;Choi, Hyun-Ju;Lim, Dae-Soon
    • Journal of the Korean Ceramic Society
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    • v.46 no.5
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    • pp.515-519
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    • 2009
  • Carbon layers were fabricated on silicon carbide by chlorination reaction at temperatures between $1000^{\circ}C$ and $1500^{\circ}C$ with $Cl_2/H_2$ gas mixtures. The effect of reaction temperature on the micro-structures and tribological behavior of SiC derived carbon layer was investigated. Tribological tests were carried out ball-on-disk type wear tester. Carbon layers were characterized by X-ray diffractometer, Raman spectroscopy and surface profilometer. Both friction coefficients and wear rates were maintained low values at reaction temperature up to $1300^{\circ}C$ but increased suddenly above this temperature. Variation of surface roughness as a function of reaction temperature was dominant factor affecting tribological transition behavior of carbon layer derived from silicon carbide at high temperature.

Loading Rate Effects During Static Indentation and Impact on Silicon Carbide with Small Sphere (탄화규소에 구형입자의 정적압입 및 충격시 부하속도의 영향)

  • Shin, Hyung-Seop
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.20 no.12
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    • pp.3847-3855
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    • 1996
  • In order to study the relationship between static and cynamic behaviors of silion caride, both quasi-static indentaiton and impact experiments of spherical particle have been conducted. The difference inmaterial behavior when using the two mehtods suggests a loading rate difference in the damate pattrern and fracture strength of silicon carbide. This investigation showed some difference in damage pattern according to particla property, especially inthe case of particle impact. There was no differences in deformation behaviors according to the loading rate when the crater profiles were compared with each other at the same contact radius. From the result of residual strength evaluation, it was found that the strength degradation began at the initiation of ring crack and its behavior was colsely related to morphologies of the damage developed which was also dependent upon the extent of deformation atthe loaidng point. In the case of static indentation, there didnot exist the particle property effects onthe strength degradation behavior.

Precipitation Behavior of Laves Phase in 10%Cr Ferrite System Alloy (10%Cr 페라이트계 합금에서 라베스상의 석출거동에 관한 연구)

  • Kim, I.S.;Kang, C.Y.;Bae, D.S.
    • Journal of the Korean Society for Heat Treatment
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    • v.12 no.1
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    • pp.21-30
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    • 1999
  • The present study were investigated changes of precipitation behaviour of laves phase in ferrite single phase and ferrite-martensite dual phase and precipitation of laves phase under stress. Hardness changes in ferrite phase appeared two hardness peaks by precipitation of initial fine precipitator and laves phase in 3Mo-0.3Si and 3Mo-0.3Si-C specimens, respectively. Hardness changes in martensite phase of 3Mo-0.3Si-C specimen was lower in the initial stage of aging by carbide precipitation and after this, increased by re-hardening due to precipitation of laves phase. In the ferrite phase, laves phase was mainly precipitated, whereas in the martensite phase, carbide was preferentially formed during the initial stage of aging and with increasing aging time, laves phase and carbide were simultaneously precipitated by precipitation of laves phase at around carbide. In the ferrite-martensite interface, laves phase was mainly precipitated and carbide was mainly formed at boundary of lath martensite than grain boundary. Adding the stress in aging, fine precipitator of inital precipitation of laves phase precipitated in (100) of perpendicular to tensile direction and has grown to only followed<010>direction and also, volume fraction of laves phase increased. Consequently, the stress added was accelerated initial precipitation of laves phase.

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The Relationship Between Hydrogen Trapping Behavior and SSCC Suceptibility of API X60/65 Grade Steels

  • Lee, Jae Myung;Kim, Jin Suk;Kim, Kyoo Young
    • Corrosion Science and Technology
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    • v.2 no.3
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    • pp.109-116
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    • 2003
  • It is well known that SSCC (sulfide stress corrosion cracking) is caused by drastic ingression of hydrogen during the service and accumulation of hydrogen near the potential crack initiation site in the material. It is important to characterize the hydrogen trapping behavior to evaluate the service performance of the high strength pipeline steels. In this study. the relationship between the hydrogen trapping behavior and SSCC susceptibility is evaluated in terms of alloy composition, microstructure and carbide behavior. The hydrogen trapping behavior was measured by electrochemical hydrogen permeation test cell (Devanathan cell). The SSCC susceptibility is evaluated by constant extension rate test and constant strain lest method. The hydrogen trapping behavior is affected greatly by microstructure and nature of carbide particles. The fine TiC, and NbC in the matrix of ferritic structure acts as strong irreversible trap sites whereas the bainitic structure acts as reversible trap site. The SSCC susceptibility is closely related to not only the hydrogen trapping behavior but also the loading condition. As the activity of reversible trap site increases, SSCC susceptibility decreases under static loading condition below yield strength, whereas SSCC susceptibility increases under dynamic loading condition or above yield strength. As the activity of irreversible trap site increases. SSCC susceptibility increases regardless of loading condition. It is cased by the mixed effect of dislocation on hydrogen diffusion and trapping behavior.

Photoluminescence of Porous Silicon Carbide in Solvents

  • Lee, Ki-Hwan;Lee, Tae-Ho;Yoon, Seok-Won;Lee, Seung-Koo;Jeon, Hae-Kwon;Choi, Chang-Shik
    • Journal of Photoscience
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    • v.12 no.3
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    • pp.171-174
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    • 2005
  • The relationship between porous surfaces and photoluminescence (PL) behavior of porous silicon carbide (PSC) in various solvents has been studied. The porous surfaces of p-type silicon carbide can be fabricated by electrochemical anodization from the 6H, 15R, 4H-${\alpha}$-SiC substrates in dark-current mode (DCM) condition. We have been investigated the dependence of the PL spectra of PSC under the medium having the different dielectric constants. It has been found that PL depends sensitively on the environment surrounding the surface. The extent of chemically stability on the surface of PSC due to the various solvents was confirmed by reflectance Fourier transform infrared (FTIR) spectroscopy. Detailed IR experiments on the PSC samples were carried out before and after various solvents immersion. These results will be offered important information on the origin of PL in porous structure.

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Tribological Behaviors of Chromium Carbide Coatings by HVOF Thermal Spraying (HVOF 열용사에 의한 크롬 카바이드 코팅의 마모.마찰거동)

  • 김장엽;임대순;이상로;변응선;이구현
    • Journal of the Korean Ceramic Society
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    • v.32 no.11
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    • pp.1315-1321
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    • 1995
  • The optimal coating condition for chrominum carbide coating was selected by Taguchi method. The wear tests with coated specimens by HVOF method were performed in the temperature to 80$0^{\circ}C$. Applied normal loads were selected to be from 8N to 30N. The worn surfaces and subsurfaces were characterized by XRD, EPMA, AES and SEM. The wear track increased with increasing applied normal load, and in terms of the temperature range from 400 to $600^{\circ}C$, below that range, the wear track increased, and above that temperature ragne, the wear track decreased. The degree of oxidation caused by the test temperature and the frictional heating was responsible to the unique high temperature wear behavior chromium carbide coatings.

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