• Title/Summary/Keyword: calibration equation

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Measurement of lipid content of compost fermentation using near-infrared spectroscopy

  • Daisuke Masui;Suehara, Ken-ichiro;Yasuhisa Nakano;Takuo Yano
    • Near Infrared Analysis
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    • v.2 no.1
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    • pp.37-42
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    • 2001
  • Near infrared spectroscopy (NIRS) was applied to determination of the lipid content of the compost during the compost fermentation of tofu (soybean0curd) refuse. The absorption of lipid observed at 5 wavelengths, 1208, 1712, 1772, 2312 and 2352 nm on the second derivative spectra. To formulated a calibration equation, a multiple linear regression analysis was carried out between the near-infrared spectral data and on the lipid content in the calibration sample set (sample number, n=60) obtained using Soxhlet extraction method. The value of the multiple correlation coefficient (R) was 0.975 when using the wavelengths of 1208 and 1712 nm were used in the calibration equation. To validate the calibration equation obtained, the lipid content in the validation sample set (n=35) not used for formulating the calibration equation was calculated using the calibration equation, and compared with the value obtained using the Soxhlet extraction method. Good agreement was observed between the results of the Soxhlet extraction method and those values of the NIRS method. The simple correlation coefficient (r) and standard error of prediction (SEP) were 0.964 and 0.815 %, respectively. suitability of the lipid content as an indicator of the compost fermentation of tofu refuse was also studied. The decrease of the lipid content in the compost corresponded to the decrease of the total dry weight of the compost in the composter. The lipid content was a significant indicator of the compost fermentation. The NIRS method was applied to measure the time course of the lipid content in the compost fermentation and good results were obtained. The study indicates that NIRS is a useful method for process management of the compost fermentation of tofu refuse.

Determination of Calibration Curve for Total Nitrogen Contents Analysis in Fresh Rice Leaves Using Visible and Near Infrared Spectroscopy (벼 생체엽신 질소함량 측정을 위한 근적외선분광분석의 검량식 작성)

  • Kwon Young-Rip;Baek Mi-Hwa;Choi Dong-Chil;Choi Joung-Sik;Choi Yeong-Geun
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.50 no.6
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    • pp.394-399
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    • 2005
  • Near Infrared Spectroscopy (NIRS) has been used as a tool for the rapid, accurate and nondestructive assay of the fresh rice leaf in nitrogen content. NIRS used in this study was visible and near infrared spectroscopy type instrument, Foss model 6500. To obtain a useful calibration equation, standard regression between the data was analyzed by chemical analysis and by NIRS method. Accuracy of calibration equation for nitrogen content on fresh leaf of rice were 0.879, 0.858 and 0.819, respectively. Accuracy of calibration equation after outlier treatment increased as 0.017, 0.02 and 0.061 improved each with 0.896, 0.878 and 0.880, respectively. Calibration equation combined using merge function after accuracy of calibration equation more increased by 0.911. Difference analysis value between calibration equation and lab value by kjeldahl showed $0.001\%$. With this as same result is the possibility of closing the deterioration of the sample in order to omit a construction and pulverization process it is judged with the fact that the nitrogen content measurement of the fresh rice leaf which the possibility of reducing an hour and an expense is by a near infrared spectroscopy technique will be possible.

Hand/Eye calibration of Robot arms with a 3D visual sensing system (3차원 시각 센서를 탑재한로봇의 Hand/Eye 캘리브레이션)

  • 김민영;노영준;조형석;김재훈
    • 제어로봇시스템학회:학술대회논문집
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    • 2000.10a
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    • pp.76-76
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    • 2000
  • The calibration of the robot system with a visual sensor consists of robot, hand-to-eye, and sensor calibration. This paper describe a new technique for computing 3D position and orientation of a 3D sensor system relative to the end effect of a robot manipulator in an eye-on-hand robot configuration. When the 3D coordinates of the feature points at each robot movement and the relative robot motion between two robot movements are known, a homogeneous equation of the form AX : XB is derived. To solve for X uniquely, it is necessary to make two robot arm movements and form a system of two equation of the form: A$_1$X : XB$_1$ and A$_2$X = XB$_2$. A closed-form solution to this system of equations is developed and the constraints for solution existence are described in detail. Test results through a series of simulation show that this technique is simple, efficient, and accurate fur hand/eye calibration.

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Radiometric Calibration Method with Compensation of Nonlinearity of Detector for Hyper-Spectral Camera

  • Yang, Ji-Hyeon;Choi, Byung-In;Park, Hee Duk;Kim, Sohyun;Park, Yong Chan
    • Journal of the Korea Society of Computer and Information
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    • v.22 no.10
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    • pp.27-34
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    • 2017
  • In this paper, we propose a novel radiometric calibration method which can effectively compensate the nonlinearity of the detector for hyper-spectral camera. In general, the detector of hyper-spectral camera can produce nonlinear output depending on radiance and integral time. The conventional radiometric calibration methods extract the imprecise radiance profile from the spectral profile of the target due to this nonlinearity. In our proposed method, we use a quadratic equation instead of a linear equation to describe the relation between output of detector and radiance. Then, we use a fractional function to compensate variation of integration time. Thus, our proposed method can extract more precise spectral profile of radiance than conventional radiometric calibration method.

Measurement of Lipid Content of Compost in the fermentation Process using Near-Infrared Spectroscopy

  • Suehara, Ken-Ichiro;Masui, Daisuke;Nakano, Yasuhisa;Yano, Takuo
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1254-1254
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    • 2001
  • Near infrared spectroscopy (NIRS) was applied to determination of the lipid content of compost during compost fermentation of tofu(soybean-curd) refuse. The reflected rays in the wavelength range between 800 and 2500 nm were measured at 2 nm intervals. The absorption of lipid observed at 4 wavelengths, 1208, 1712, 2312 and 2352 nm on the second derivative spectra. To formulate a calibration equation, a multiple linear regression analysis was carried out between the near-infrared spectral data and on the lipid content in the calibration sample set (sample number, n=60) obtained using a Soxhlet extraction method. The calibration equation for prediction of lipid, the value of the multiple correlation coefficient (R) was 0.975 when using the wavelengths of 1208 and 1712nm. To validate the calibration equation obtained, the lipid content in the validation sample set (n=35) not used for formulating the calibration equation were calculated using the calibration equations, and compared with the values obtained using the Soxhlet extraction method. Good agreement were observed between the results of the Soxhlet extraction method and those values of the NIRS method. The simple correlation coefficient (r) and standard error of prediction (SEP) were 0.964 and 0.815 %, respectively. Then, the NIRS method was applied to a compost fermentation in which the time course the lipid content were measured and good results were obtained. The study indicates that NIRS is a useful method for process management of the compost fermentation of tofu refuse.

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Relationship between porcine carcass grades and estimated traits based on conventional and non-destructive inspection methods

  • Lim, Seok-Won;Hwang, Doyon;Kim, Sangwook;Kim, Jun-Mo
    • Journal of Animal Science and Technology
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    • v.64 no.1
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    • pp.155-165
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    • 2022
  • As pork consumption increases, rapid and accurate determination of porcine carcass grades at abattoirs has become important. Non-destructive, automated inspection methods have improved slaughter efficiency in abattoirs. Furthermore, the development of a calibration equation suitable for non-destructive inspection of domestic pig breeds may lead to rapid determination of pig carcass and more objective pork grading judgement. In order to increase the efficiency of pig slaughter, the correct estimation of the automated-method that can accommodate the existing pig carcass judgement should be made. In this study, the previously developed calibration equation was verified to confirm whether the estimated traits accord with the actual measured traits of pig carcass. A total of 1,069,019 pigs, to which the developed calibration equation, was applied were used in the study and the optimal estimated regression equation for actual measured two traits (backfat thickness and hot carcass weight) was proposed using the estimated traits. The accuracy of backfat thickness and hot carcass weight traits in the estimated regression models through stepwise regression analysis was 0.840 (R2) and 0.980 (R2), respectively. By comparing the actually measured traits with the estimated traits, we proposed optimal estimated regression equation for the two measured traits, which we expect will be a cornerstone for the Korean porcine carcass grading system.

Effects of the in-process calibration from IR detector for thermal diffusivity measurement by laser flash method (레이저 섬광법에 의한 열확산계수 측정시 적외검출소자에서 실시간 온도보정이 미치는 영향)

  • 이원식;배신철
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.10 no.6
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    • pp.795-802
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    • 1998
  • For measuring the thermal diffusivity by laser flash method, raw data have to be calibrated using temperature data. We have developed in-process calibration method and polynomial calibration in which thermal diffusivity can be calibrated during measuring, This method is different from existing temperature pre-process calibration method and exponential calibration having various source of error. Using this new calibration method, measurement accuracy was improved about 1∼2% compare to the value by the existing method. We also studied more accurate fitting curve as in Figure 4 was shown the result of measuring output characteristics of IR radiometer with temperature. As illustrated in data, in-process calibration method and polynomial calibration equation is proper than pre-process calibration method and exponential calibration.

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Quantification of Tocopherol and Tocotrienol Content in Rice Bran by Near Infrated Reflectance Spectroscopy (근적외선분광분석기를 이용한 미강의 Tocopherol과 Tocotrienol 함량 분석)

  • 김용호;강창성;이영상
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.49 no.3
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    • pp.211-215
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    • 2004
  • Near infrared reflectance spectroscopy (NIRS) is a rapid and accurate analytical method for determining the composition of agricultural products and feeds. This study was conducted to determine tocopherol and tocotrienol contents in rice bran by using NIRS system. Total 80 rice bran samples previously analyzed by HPLC were scanned by NIRS and over 60 samples were selected for calibration and validation equation. A calibration equation calculated by MPLS(modified partial least squares) regression technique was developed and coefficient of determination for tocopheyol and tocotyienol content were 0.975 and 0.984, respectively, in calibration sets. Each calibration equation was fitted to validation set that was performed with the remaining samples not included is the calibration set, which showed high positive correlation both in tocopherol and tocotrienol content file. This results demonstrate that the developed NIRS equation can be practically used as a rapid screening method for quantification of tocopherol and tocotrienol contents in rice bran.

Discrimination of Korean Domestic and Foreign Soybeans using Near Infrared Reflectance Spectroscopy (근적외선분광광도계(NIRS)를 이용한 국내산 콩과 수입콩의 판별분석)

  • Ahn, Hyung-Gyun;Kim, Yong-Ho
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.57 no.3
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    • pp.296-300
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    • 2012
  • Discrimination of geographic origin of agricultural products is a important issue in Korea because the price difference between Korean domestic and imported cereals is a key among some reasons. NIRS (Near Infrared Reflectance Spectroscopy) has been applied to classify the geographical origin of soybeans. Total 135 samples (Korean domestic 92 and foreign 43) were used to obtain calibration equation through 400~2,500 nm wavelength. The math treatment with 1st derivative and 4 nm gap and the modified partial least squares(MPLS)regression was outstanding for calibration equation. The standard error of calibration and determination coefficient in calibration set(n=115) was 6.65 and 0.98, respectively. And it showed that the extra 20 samples for validation equation were identified their authentication correctly. This study describes that the application of NIRS would be possible for discrimination of geographical origin between Korean domestic and imported soybeans.

Studies on pharmaceutical assay method using Near Infrared Spectroscopy (NIRS) (II)

  • Kang, Shin-Jung;Yun, Mi-Ok;Lee, Su-Jung;Choi, Hyun-Chul;Kim, Ho-Jeong;Kim, Ji-Yeon
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.4113-4113
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    • 2001
  • This study developed effective assay method of pharmaceutical quality control was developed by near-infrared spectroscopy (NIRS). The calibration equation model of assay was developed by 2nd deriviative PLS(Partial Least Squares) regression method with NIRS over the wavelength range from 1100 to 1400nm using diazepam tablets (2mg, 5mg). Although diazepam tablets are made by 5-different manufacture, they have similar formulation. When the correlation was compared with values by NIRS and HPLC, the R-2s and standard error of calibration (SEC) for 2mg were 0.9300 and 0.98%, the R-2s and SEC for 5mg were 0.9165 and 0.63%. The validation of the calibration equation model yield that the R-2s and standard error of prediction (SEP) for 2mg were 0.9611 and 0.995%, the R-2s and SEP for 5mg were 0.9114 and 0.842%. The method was validated on assay method for diazepam tablets by the calibration equation.

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