• Journal of Environmental Policy
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• v.12 no.4
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• pp.119-132
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• 2013

Hosta longipes is one of the most popular ornamental perennials in use in Korea today, and is mainly used as a groundcover plant in urban shaded places. In this study, the pytoremediation effect of Hosta longipes was tested using four concentrations (Control, 100, 250 and $500mg{\cdot}kg^{-1}$) of Cd, Pb and Zn in soil. The plants were planted in $300mm{\times}200mm{\times}250mm$ drainless-containers, which were filled with a artificial amended soil for 7 months. The results showed that the contents of heavy metals cadmium and lead in the shoot of Hosta longipes increased with increasing heavy metal concentration levels exception of zinc. The amount of zinc, cadmium, and lead accumulated in roots were increased with heavy metal concentration levels up in soil. The shoot/root ratios(TF; translocation factor) values were found to be more than 80% of total Zn, Cd, and Pb take up by Hosta longipes. These results indicated that root is the major part for accumulation of heavy metal. The removal contents of zinc, cadmium, and lead increased significantly with the increasing heavy metal concentration in the soil, which was planted with Hosta longipes. The heavy metal concentration accumulation in plant/soil ratios (BF; bioaccumulation factor) values for three metals were found to be more than 30% in cadmium and lead, but lower in zinc treatments. The different responses of Hosta longipes suggest that in heavy metal contaminated soils the plant adsorbs available metals depending on the concentration soils in which they are present. Therefore, this species can be an efficient phytoremediator for soils contaminated with cadmium and lead in urban shaded places.

• Journal of Environmental Health Sciences
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• v.44 no.5
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• pp.491-501
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• 2018

Objectives: The aims of this study were to compare concentrations and the correspondence of human blood cadmium by using graphite furnace atomic absorption spectrometry (GF-AAS) and inductively coupled plasma-mass spectrometry (ICP-MS), which are representative methods of heavy metal analysis. Methods: We randomly selected 79 people who agreed to participate in the research project. After confirming the linearity of the calibration curves for GF-AAS and ICP-MS, the concentrations of cadmium in a quality control standard material and blood samples were measured, and the correlation and the degree of agreement were compared. Results: The detection limit of ICP-MS (IDL: $0.000{\mu}g/L$, MDL: $0.06{\mu}g/L$) was lower than that of GF-AAS (IDL: $0.085{\mu}g/L$, MDL: $0.327{\mu}g/L$). The coefficient of variation of the quality control standard material showed stable values for both ICP-MS (clinchek-1: 5.35%, clinchek-2: 6.22%) and GF-AAS (clinchek-1: 7.92%, clinchek-2: 5.22%). Recovery was relatively high for both ICP-MS (clinchek-1: 95.1%, clinchek-2: 92.8%) and GF-AAS (clinchek-1: 91.4%, clinchek-2: 98.8%), with more than 90%. The geometric mean, median, and percentile of blood samples were all similar. The agreement of the two instruments compared with the bias of the analytical values found that about 81% of the analytical values were within ${\pm}30%$ of the deviation from the ideal reference line (y=0). As a result of the agreement limit, the value included in the confidence interval was about 94%, which shows high agreement. Conclusion: In this study, we confirmed there was no significant difference in concentrations of a quality control standard material and blood samples. Since ICP-MS showed lower concentrations than GF-AAS at concentrations below the method detection limit of GF-AAS, it is expected that more precise results will be obtained by analyzing blood cadmium with ICP-MS.

• Journal of Soil and Groundwater Environment
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• v.6 no.3
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• pp.21-29
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• 2001

Organobentonite modified with hexadecyltrimethylammonium (HDTMA) was used to quantify adsorption of heavy metals. Adsorption of cadmium and lead increased with increasing pH and soil/solution ratio. Based on these experiments, an optimal soil/solution ratio and an optimal pH was selected. Adsorption experiments with cadmium and lead were conducted to quantify adsorption selectivity on bentonite and organobentonite. Adsorption of heavy metals on organobentonite was slightly reduced relative to bentonite. Because of competition between cadmium and lead, adsorption of each metal was reduced due to the presence of the other. Adsorption selectivity of cadmium was higher than lead. This study used the principle of hard soft-acid-base (HSAB) to interpret adsorption.

• Journal of environmental and Sanitary engineering
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• v.6 no.1
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• pp.83-93
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• 1991

For the survey of water pollution, several heavy metals were analyzed in the sediment of the Han River from March 20 to April 22, 1989. The results were as follows : 1. The respective ranges of heavy metal concentrations of Cadimium, Lead, Copper, Zinc and Manganese found in the sediments of the Han River were 0.32!2.41 $\mu g/g$, 15.80~129.64 $\mu g/g$, 13.82~372.36 $\mu g/g$, 58.40~925.40 $\mu g/g$, 271.50~668.30 $\mu g/g$. 2. In the sediment of inflow site Jung Rang Chon the contents of Lead, Copper, Zinc were the highest among other sampling points and An Yang Chon, the contents of Cadmium, was the highest among other sampling points and Wang Sook Chon, the contents of Manganese, was the highest among other sampling points. 3. Through all sampling points general trend of heavy metal contamination showed the highest in Zinc, the next Manganese, Copper, Lead and Cadmium respectively. 4. The higher amount of heavy metal was found in the finer particles of sediment. 5. The amount of Cadmium and Lead of the Han River water was below the standard of environment.

• Journal of Environmental Science International
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• v.17 no.9
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• pp.943-947
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• 2008

For the purpose of safety identification, the concentrations of heavy metals in seaweeds collected from Busan Gijang coastal area were investigated. The average concentration of metals had a level of as high as the order of manganese (2.76 ppm)>zinc(2.11 ppm)>copper(0.59 ppm)>arsenic (0.092 ppm)>lead(0.06 ppm)> mercury(0.03 ppm)>cadmium(0.026 ppm). The contents of manganese and zinc were highly detected from P. elliptica, copper and mercury from agar, cadmium from sea mustard and arsenic from wild sea mustard, respectively. The metal contents of seaweeds varied with kinds of samples, but high level for the safety can be found in these samples. Because P. elliptica had shown a clear selectivity for both manganese and zinc, this seaweed could be useful as a bioindicator for these two metal pollution.

• Journal of Preventive Medicine and Public Health
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• v.22 no.2 s.26
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• pp.215-222
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• 1989

The relationship between cadmium level and mental retardation was investigated. The 297 subjects with mental retardation were drawn from two schools providing special educational services, one, consisted of children living in an orphan home, another, children with parents. The 117 control subjects were drawn from whom had got average or above average academic achivement in a general elementary school. Hair sample was taken from the nape of the neck and the cadmium and zinc analysis were carried out on an atomic absorption spectrophotometer (IL 551). Children in the retarded group had significantly higher cadmium levels compared with control but not in zinc levels. There was no relationship between metal concentrations and age except control male group, which showed significant positive linear relationship in zinc, and there was no difference between sex in both metal except the male orphan group in cadmium. In the orphan group, there was relationship between severity of retardation and cadmium concentration in both sex but not in retarded children with parents. No difference in cadmium levels between the group with Down's syndrome, one of causes of mental retardation, and the control group suggested the cadmium as a possible cause of mental retardation. In the case of accompanying autism, zinc level was significantly lower than that of other accompanying diseases. Although not establishing an etiologic relationship, findings of this study suggest that there are some influeces of cadmium on mental retardation, and call for a continuing study.

• Journal of Microbiology and Biotechnology
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• v.4 no.1
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• pp.20-23
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• 1994

The polymerase chain reaction was used to study the genes inducible under stress from the heavy metal cadmium. Schizosaccharomyces pombe, grown in the presence or absence of sublethal concentration of cadmium, was isolated to purify the total RNAs. The Induced RNA Random Fishing (IRRF) method in which random oligonucleotides were used as primers was applied to the identification of cadmium-induced gene expressions. A PCR-DNA product of 400-bp was cloned and sequenced. Computer analysis showed that this DNA has no homology with any known DNA sequences in GenBank or EMBL databases. The induction of this gene was confirmed by Northern blot analysis of total RNAs isolated from both cadmium-treated and untreated yeast cells.

• Journal of Microbiology
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• v.33 no.4
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• pp.302-306
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• 1995

E. coli was tested for their ability to uptake cadmium intracellularly, and the effect of zinc and calcium on cadmium toxicity to E. coli was observed. In addition, the effect of zinc and calcium on the uptake of cadimium was also studied. This study showed that living E. coli cells took up more cadmium than the dead cells. E. coli in the log phase uptake cadimiumm more actively than E. coli in the stationary phase. These results suggested that there may be metabolic reactions or compounds which encourage the uptake of cadimium. This study also showed that cadimium was sequestered by cell components of which molecular weight is about 30,000. Adding of zinc and calcium chloride reduced cadmium toxicity in E. coli and encouraged intracellular uptake by E coli. However adding of heavy metal solutions helped the microorganisms to adsorb more cadmium. Extremely high or low concentrations of zinc, however, did not affect cell viability.

• Journal of Life Science
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• v.13 no.4
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• pp.421-427
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• 2003

A natural habit at bacterium, Enterobacter intermedious KH410 was isolated from freshwater plant root and identified. Adsorption of heavy metals such as lead, cadmium, and copper by this strain was examined. The minimal inhibitory concentrations(MIC) for each metal were 1.78 mM for lead, 0.17 mM for cadmium and 1.39 mM for lopper, respectively. Maximum production of dried cell was 2.56 g/$\ell$ in LB medium containing 0.5% NaCl, 1% yeast extract and 1% of lactose. Optimal conditions for adsorption were 0.6 dry g-biomass, at pH 4.0 and the temperature of $20^{\circ}C$. Adsorption equilibrium reached maximum after 30 min in 400 mg/$\ell$ metal solution. The adsorption capacity (K) of copper was 1.5 times higher than that of cadmium and lead was 1.1 times higher than that of cadmium. from the results obtained in this study, Freundlich adsorption model was applicable for all metals. Adsorption strength (1/n) of heavy metal ions were in the order of cadmium>copper>lead. The adsorption of dried cell for lead, cadmium, and copper was 56.2, 58.0, 55.8 mg/g-biomass, respectively. Pretreatment to increase ion strength was the most effective with 0.1 M NaOH whereas slight difference was found both KOH and $CaCl_2$ upon same concentration. Effective desorption was induced by 0.1 M EDTA for lead and 0.1 M $HNO_2$ for cadmium and copper.

• Journal of Environmental Health Sciences
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• v.8 no.1
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• pp.31-43
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• 1982

Seventy-seven Mugil cephalus of spinal deformation, living in Hanam, Nogsan, and Myeongji area, the downstreams of the Nagdong River, were collected in order to determine their forms and the levels of heavy metal contamination between March and October, 1981. The specimens were examined by X-ray and content of cadmium, lead, copper, and zinc by atomic absorption spectrophotometer. The results were summarized as follows: 1. The rate of appearance of deformational fish to the total Mugil cephflus were 4.3% (13 fish), 5.7% (17 fish), relatively high in May and June (dry season). Meanwhile during March and October they were low by 1.0% (3 fish), 2.0% (6 fish). As far as the research areas are concerned, they appeared in larger numbers in downstreams than in upper streams Myeongji (39), Nogsan (25), and Hanam (13). 2. Concerning with fractured parts of vertebraes,86 percent (66 out of 77) had their caudal regions fractured and 72 percent (55) their first to seventh caudal regions fractured. 3. The average levels of cadmium, lead, copper, zinc detected from flesh were 0.26ppm, 2.06ppm, 6.35ppm, 0.85ppm on the other hand, they were 0.22ppm, 1.84ppm, 5.03ppm, 0.93ppm in normal fish. 4. The average levels of cadmium, lead, copper, zinc measured in the bones were 0.39ppm, 2.55ppm, 8.97ppm, 2.73ppm. Meanwhile, from normal fish they were 0.33ppm, 2.25ppm, 7.24ppm, 2.42ppm. 5. Compared with regional heavy metal contamination such as cadium, lead, zinc, Myeongji area had higher contamination content than Nogsan area Nogsan area than Hanam area. 6. Compared with heavy metal contamination level in their tissues, cadmium was highly found in bones Lead and copper were highly detected in viscera. Particularly in skeleton cadmium was 560 times, zinc 160 times in proportion to those in the downstreams of the Nagdong River.