• Elastomers and Composites
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• v.48 no.1
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• pp.61-66
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• 2013

A family of Cr(III) complexes supported on tridentate dibenzimidazolyl ligands having a general formula: $[N(CH_3)(CH_2)_2(Bm-R)_2]CrCl_3$ [where Bm = benzimidazolyl, R = H (3a); -Me(3b); -Bn (3c)] have been synthesized and utilized them for the trans-1,4-specific polymerizations of 1,3-butadiene (BD), activated with methylalumoxane (MAO). The activity of BD polymerizations was sensitive to the type of ligand on the Cr metal, so that the activity decreases in the order of 3a > 3c > 3b. All the catalysts combined with MAO yielded polybutadienes with perfect trans-1,4 structure with moderate molecular weight.

• Korean Journal of Materials Research
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• v.24 no.11
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• pp.632-638
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• 2014

We investigated the effects of DMAB (Borane dimethylamine complex, C2H10BN) in electroless Ni-B film with addition of DMAB as reducing agent for electroless Ni plating. The electroless Ni-B films were formed by electroless plating of near neutral pH (pH 6.5 and pH 7) at $50^{\circ}C$. The electroless plated Ni-B films were coated on screen printed Ag pattern/PET (polyethylene terephthalate). According to the increase of DMAB (from 0 to 1 mole), the deposition rate and the grain size of electroless Ni-B film increased and the boron (B) content also increased. In crystallinity of electroless Ni-B films, an amorphization reaction was enhanced in the formation of Ni-B film with an increasing content of DMAB; the Ni-B film with < 1 B at.% had a weak fcc structure with a nano crystalline size, and the Ni-B films with > 5 B at.% had an amorphous structure. In addition, the Ni-B film was selectively grown on the printed Ag paste layer without damage to the PET surface. From this result, we concluded that formation of electroless Ni-B film is possible by a neutral process (~green process) at a low temperature of $50^{\circ}C$.

• Journal of the Korean Society for Heat Treatment
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• v.12 no.2
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• pp.99-107
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• 1999

The graphitization is affected by the addition of small amount of the elements(such as Si, Al, Ni, B, Cr and Mn etc.) and the pre-treatment(such as cold rolling). Boron is well known element to accelerate the graphitization of cementite in high carbon steels. Also, cold rolling is known to accelerate the graphitization. But the graphitization nucleation mechanism by cold rolling is few reported. Therefore the effect of cold rolling in Fe-0.5%C-1.0%Si-0.47%Mn-0.005%B steel on the graphitization is investigated quantitatively using hardness test, optical microscope and scanning electron microscope, neutron induced microscopic radiography. The nucleation of graphite in cold-rolled Fe-0.5%C-1.0%Si-0.47%Mn-0.005%B steel is formed at void which is formed at pearlite/pearlite boundary by cold rolling. But the effect of cold rolling on graphitization in boron addition steel is more effective than that of no boron addition steel due to segregation of BN at void in boron addition steel.

• Information Systems Review
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• v.19 no.3
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• pp.47-67
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• 2017

The sharing economy has emerged as a new form of consumption pattern along with the advancement of information technology and the changes in the consumers' desires for economic spending. In a C2C-sharing economy platform, the user side and supplier side share the same assets, thereby making both sides of the market closely related. However, an information asymmetry exists within the platform that makes the players from one side reluctant to participate. This information asymmetry warrants a strategic approach for solving the fundamental "chicken and egg" problem for platform development. Motivated by this phenomenon, this study aims to analyze how the participation intentions from both sides of the platform are influenced by certain anteceding factors, such as trust, perceived risk, and perceived economic profit. Our findings show that the anteceding factors affect the participation intentions in different paths for both sides of the platform. As a managerial implication, these findings highlight the necessity of employing different approaches for each side of market development.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 1993.10a
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• pp.161-165
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• 1993

최근 산업의 발달과 함께 제품의 고정도화,다양화,생산성 향상등의 요구에 의해 연삭가공에 있어서도 고능률.고정도가공이 주목되고 있다. 특히 반도체산업,광산업 등에 넓게 응용되고 있는 광학소자 가공에서는 가공정도와 가공능률이 동시에 달성되는 것에 대한 요구가 많지만, 이러한 광학소자의 가공에 있어서 기존의 연마방법은 가공정도와 가공능률에 한계가 있었다. 그런데 연삭가공에서 고능률,고정도가공의 한가지 방법으로 "전해 인프로세스드레싱(Electrolytic In-Process Dressing;ELID)연삭법"이 개발되어 고강도 메탈본드숫돌에 의한 초경합금,세라믹재료등의 경취성재료를 고품위 가공하고 있다. ELID연석법이란 숫돌의 다이아몬드나 cBN등의 연삭입자를 결합하고 있는 금속결합재를 전기분해에 의해 적당량 제거하여 일반적인 연삭과 같이 연삭입자를 연속적으로 돌출시켜 가공이 유지되도록 하는 연삭방법이다. 본 연구는 ELID연삭기술을 이용하여 원통연삭에서 철갈재료 및 세라믹재료의 고능률.고정도 가공특성을 살펴보았다. 원통연삭에서의 주철파이바본드숫돌 및 코발트본드숫돌에 의한 ELID연삭과 비트리파이드본드숫돌에 의한 일반연삭과의 고능률 가공특성을 비교하였다.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.61 no.4
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• pp.585-589
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• 2012

The characteristics of interface layer and the effect of mole fraction of inlet gas mixture($B_2H_6/H_2/N_2/TiCl_4$) on the microstructure of Ti(B,N) films were studied by microwave plasma hot filament CVD process. Ti(B,N) films were deposited on a substrate(STD-61) to develop a high performance of resistance wear coating tool. Ti(B,N) films were obtained at a gas pressure of 1 torr, bias voltage of 300 V and substrate temperature of $480^{\circ}C$ in $B_2H_6/H_2/N_2/TiCl_4$gas system. It was found that TiN, $TiB_2$, TiB and hexagonal boron nitride(h-BN) phases exist in thin layer on the STD-61.

• Journal of Powder Materials
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• v.5 no.4
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• pp.303-311
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• 1998

Hard materials such as hardmetal, coated hardmetal, cermet, ceramics and diamond or c-BN sintered compact are a kind of grain-dispersed alloy with high volume of hard particles. These are used for cutting tools, wear-resistant tools, rock bits, high pressure apparatus, etc. The annual production in Japan is about 1.7 billion dollars (200 billion yen). This is greatly owed to the development in science and technology which has been accomplished by applying new concepts such as fine or uniform grain microstructure, orientation of crystal grains, functionally graded material, artificial lattice and coherent bonding in recent years. In this review, the development in recent years in Japan is briefly summarized.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1995.11a
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• pp.44-47
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• 1995

In this study, dielectric and piezoelectric properties of 0.4[0.1Bi(Ni$\_$1/2/Ti$\_$1/2/)O$_3$0.9Pb(Ni$\_$1/3/Nb$\_$2/3/)O$_3$]-0.6(PbZr$\_$y/Ti$\_$1-y/)O$_3$ceramics with Zr/Ti ratio were observed. As a results, structure of the ceramics with ZrO$_2$(y) 0.425 and 0.45 was MPB. Electromechanical coupling coefficients k$\_$p/, k$\_$31/ of the BN$\_$162/ specimen were 57.2%, 35.6% and piezoelectric constants d$\_$33/, d$\_$31/ were 720, 298[x10$\_$-12/C/N).

• Journal of the Korean Ceramic Society
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• v.30 no.4
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• pp.309-315
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• 1993

Gas pressure sintering is a promising process in various densification methods of high strength Si3N4 ceramics. Environmental influences on gas pressure sintering of Si3N4 was investigated with the variationof packing powder, specimen container and N2 gas pressure. The specimens had higher density, larger weight loss and inhomogeneous color in graphite specimen container than in SN26 crucible. The variations of sintering densities in various packing powders (Si3N4, SN26, AlN, BN) were very small but SiC powder was synthesised in graphite crucible with Si3N4 packing powder, aluminium oxynitride compounds were synthesised in SN26 crucible with AlN packing power. Also N2 gas pressure over 20kg/$\textrm{cm}^2$ reduced the densification of Si3N4 in one step-gas pressure sintering. As the result of two step-gas pressure sintering at 700kg/$\textrm{cm}^2$ for 15min., relative density of 99.9% and 3-point bending strength of 1090MPa and dense microstructure of 3~4${\mu}{\textrm}{m}$ grain size were obtained.

• Journal of Welding and Joining
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• v.20 no.3
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• pp.91-97
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• 2002

Variation of HAZ toughness of Ti-containing steel with nitrogen content was investigated and interpreted in terms of its microstructure and the amount of soluble nitrogen present. The amounts of Ti and Al combined in TiN and AlN, respectively, in HAZ at $1400^{\circ}C$ peak temperature were less than those in base plate; 55~88% in TiN and 21~28% in AlN, indicating the dissolution of nitrifies in HAZ. The calculated amounts of soluble nitrogen using the thermodynamic analysis showed a good agreement with the measured values in other experiment. Therefore, the analysis can be used to estimate the amount of soluble nitrogen in HAZ. Simulated HAZ toughness was influenced not only by its microstructure but also by the amount of soluble nitrogen present after the formation of BN during the cooling cycle of welding. It showed maximum value when the nitrogen content is in stoichiometric ratio with titanium content, showing that soluble nitrogen in HAZ is detrimental to its toughness.