• Carbon letters
• /
• 제9권4호
• /
• pp.298-302
• /
• 2008

Carbon blacks could be used as the filler for the electromagnetic interference (EMI) shielding. The poly vinyl alcohol (PVA) and polyvinylidene fluoride (PVDF) were used as the matrix for the carbon black fillers. Porous carbon blacks were prepared by $CO_2$ activation. The activation was performed by treating the carbon blacks in $CO_2$ to different degrees of burnoff. During the activation, the enlargement of pore diameters, and development of microporous and mesoporous structures were introduced in the carbon blacks, resulting in an increase of extremely large specific surface areas. The porosity of carbon blacks was an increasing function of the degree of burn-off. The surface area increased from $80\;m^2/g$ to $1142\;m^2/g$ and the total pore volume increased from $0.14073\;cc{\cdot}g^{-1}$ to $0.9343\;cc{\cdot}g^{-1}$. Also, the C=O functional group characterized by aldehydes, ketones, carboxylic acids and esters was enhanced during the activation process. The EMI shielding effectiveness (SE) of raw N330 carbon blacks filled with PVA was about 1 dB and those of the activated carbon blacks increased to the values between 6 and 9 dB. The EMI SE of raw N330 carbon blacks filled with PVDF was about 7 dB and the EMI SE increased to the range from 11 to 15 dB by the activation.

• 한국재료학회지
• /
• 제13권12호
• /
• pp.825-830
• /
• 2003

Structural changes during oxidation of anisotopic mesophase carbon fiber(AMCFs) have been observed with TEM and XRD. It was shown that the AMCFs are three dimensionally stacked structure of turbostratic layers, and are non-homogeneous structure which consist of the highly ordered areas and the random areas. The $d_{ 002}$, Lc, and La of AMCFs which were measured by XRD were 3.44, 146, and $135\AA$, respectively. It was observed that the oxidation initiated at the random areas, because the $d_{002}$ / decreased to the value of 3.41 $\AA$ during initial oxidation stage. It was also observed that the La of the oxidized AMCFs increased up to 182 $\AA$ during the whole oxidation process, and the $d_{002}$ of that increases up to 9.44 $\AA$ when the burn-off is over the degree of 20%. Therefore, it was suggested that the micro-crystalline grew up by heat treatment effects during the fibers were oxidized, In addition, it was shown that there was difference in the measured value of La by XRD and TEM, in case of 39% oxidized fibers for example, the measured La was $ 165\AA$ by XRD and in the range of 180∼220 $\AA$ by TEM.

• 한국재료학회지
• /
• 제13권12호
• /
• pp.831-838
• /
• 2003

Anisotropic mesophase carbon fiber(AMCFs) was exposed to isothermal oxidation in air and $CO_2$atmosphere, and burn-off rates have measured by TGA. The microstructure changes of oxidized carbon fibers, were observed by SEM. It was observed that oxidation rate in the air is over 100 times faster than that in $CO_2$atmosphere. The activation energy obtained in air was about 43.4 Kcal/mole in the temperature range of $600∼800^{\circ}C$, and in $CO_2$was about 55.2 Kcal/mole in the temperature range of $950∼1200^{\circ}C$. Therefore, the oxidation reaction in both atmospheres was under chemical reaction regime in the above temperature ranges. It was shown that the oxidation of the AMCFs is initiated at the end of fibers at high temperature($1100^{\circ}C$) with developing the large pores, and the small pores are developed on the fiber surface at low temperature($900^{\circ}C$). In conclusion, the oxidation of the AMCFs is progressed through the imperfection.

• Journal of Radiation Protection and Research
• /
• 제36권4호
• /
• pp.174-182
• /
• 2011

With the reactor operation conditions - 4.3 wt% $^{235}U$ initial enrichment, burn-up 55,000 MWd/MTU, average power 34 MW/MTU for three periods burned time for 539.2 days per period and cooling time for 100 hours after shut down, to set up the condition to determine the minimum height (depth) of spent fuel storage pool to shut off the radiation out of the spent fuel storage pool and to store spent fuels safely, the dose rate on the specific position directed to the surface of spent fuel storage pool induced by the neutron and gamma-ray from spent fuels are evaluated. The length of spent fuel is 381 cm, and as the result of evaluation on each position from the top of spent fuel to the surface of spent fuel storage pool, it is difficult for neutrons from spent fuels to pass through the water layer of maximum 219 cm (600 cm from the floor of spent fuel storage pool) and 419 cm (800 cm from the floor of spent fuel storage pool) for gamma-ray. Therefore, neutron and gamma-ray from spent fuels can pass through below 419 cm (800 cm from the floor) water layer directed to the surface of spent fuel storage pool.

• Carbon letters
• /
• 제4권4호
• /
• pp.168-174
• /
• 2003

Silver nitrate ($AgNO_3$) powder was mixed into a reformed pitch precursor. Then, the silver-containing pitch was melt spun to form round and "C" shape fibers. A wire mesh was inserted prior to the nozzle to improve the spinnability of the silvercontaining precursor pitch. Silver particles in the carbon fibers (CFs) were detected by XRD and TEM. These tests showed that silver particles were uniformly distributed and the total amount of silver remained constant during stabilization and carbonization. Next, the silver-containing CFs were activated by steam diluted in nitrogen gas. Silver particles accelerated the activation rate, but the specific surface areas of the silver-containing ACFs were similar to those of non-silver containing ACFs at the same burn-off levels. The specific surface area of the C-shaped activated carbon fibers was larger than that of the round activated carbon fibers. The likely reason is that the surface area of a C-shaped CF is about two times larger than that of a round CF when equivalent cross-sectional areas are compared. A small amount of silver particles in the periphery of the CFs was removed during the activation, but the remainder of silver was stayed within the ACFs.

• 한국응급구조학회지
• /
• 제14권1호
• /
• pp.19-29
• /
• 2010

Purpose : This study was conducted to examine the degree of recognition of safety education and its execution for child-care teachers at daycare center for the disabled children in Jeollanam-do. Ninety six child care teachers filled out the questionnaire and the results were as follows. Results : 1. The possibility of accident prevention by the day care teachers was a little higher in case of nearby education institution. The most appropriate period of safety education was within one month. 2. Majority of child care teachers had received safety and first-aid educations before and the education was done for less than 2 hours. 3. The best educational method was practice-centered education of off-duty time. The contents of first-aid education were bleeding, fall, shock, and burn. 4. The education material and book should be available to the teachers when they need the knowledge. 5. By the annual schedule, safety education should be conducted and provided to the parents. Conclusion : This study suggested that reinforcement of contents related to emergency situation and actual first-aid as well as theory education in the process of parent and teacher education should be conducted on the basis of information of general conditions related to safety and first-aid education at the daycare center for the disabled children.

• Carbon letters
• /
• 제7권1호
• /
• pp.1-8
• /
• 2006

The activated carbon "C" was obtained by carbonization followed by activation with steam at 40% of burn-off. Oxidized carbons C-N, C-P and C-H were obtained by oxidizing the activated carbon C with concentrated nitric acid, ammonium peroxysulfate and hydrogen peroxide, respectively. The textural properties of the carbons were determined from nitrogen adsorption at 77 K. The acidic surface functional groups were determined by pH titration, base neutralization capacity and electrophoretic mobility measurements. The cation exchange capacities of un-oxidized and oxidized carbons were determined by the removal of Cu(II) and Ni(II) from their aqueous solutions. The surface area and the total pore volume decreased but the pore radius increased by the treatment of activated carbon with oxidizing agents. These changes were more pronounced in case of oxidation with $HNO_3$. The surface pH of un-oxidized carbon was basic whereas those of the oxidized derivative were acidic. The removal of Cu(II) and Ni(II) was pH dependent and the maximum removal of the both ions was obtained at pH of 5-6. Cu(II) was more adsorbed, a phenomenon which was ascribed to its particular electronic configuration.

• Carbon letters
• /
• 제8권2호
• /
• pp.101-107
• /
• 2007

Activated carbons were prepared by impregnation of crushed clean date pits in concentrated solutions of phosphoric acid or zinc chloride followed by carbonization in absence of air at $600^{\circ}C$. Steam-activated carbon was prepared by gasifying $600^{\circ}C$-carbonization product at $950^{\circ}C$ to a burn-off = 50%. KOH- activated carbon was prepared by impregnating date pitscarbonization product obtained at $450^{\circ}C$ in concentrated KOH solution followed by carbonization at $840^{\circ}C$. Textural properties of these carbons were determined from nitrogen adsorption at $-196^{\circ}C$ and the chemistry of the carbon surface was investigated by determination and of the surface carbon-oxygen (C-O) groups using bases of variable strength and dilute HCl. The adsorption of endosulphan at $27^{\circ}C$ on all the carbons prepared was undertaken. Adsorption of this pesticide at 32 and $37^{\circ}C$ was also undertaken for steam-activated and KOH-activated carbons. Phosphoric acid-activated carbons and steamactivated carbons are mainly microporous and have high surface concentration of C-O groups of acidic nature. Steamactivated and KOH-activated carbons exhibited surface areas > 1000 $m^2/g$ and contain micro and non-micrpores. The adsorption of endosulphan was related to the surface area of non-micropores and was retarded by the high concentration of surface C-O groups. The thermodynamic properties indicated the feasibility of the adsorption process and the possible regeneration of the carbon for further use.

• 드라이브 ㆍ 컨트롤
• /
• 제15권2호
• /
• pp.32-37
• /
• 2018

The power plants use turbine output control devices to supply or shut off steam to high pressure and low-pressure steam turbines connected to generators. This turbine output control device is driven by a hydraulic servo actuator. The gas flows into the hydraulic servo actuator during periodic inspection or normal operation, and the resulting adiabatic compression of the gas raises the internal temperature of the actuator to $500^{\circ}C$. This temperature increase causes the seals to burn and show wear and tear, resulting in failure. In this study, an air vent valve was installed to allow gas inside the hydraulic servo actuator to flow large quantities of air at the beginning of the operation and after the periodic inspection. Gas was passed through for only minute flow during normal operation of the power plant. By applying the air vent valve, it improves the reliability of the hydraulic servo actuator by discharge the gas appropriately to improve the life of the seal.

• Journal of Magnetics
• /
• 제21권2호
• /
• pp.192-196
• /
• 2016

The Fe-Si-B-Nb-Cu alloys containing Ca and Al were rapidly solidified to thin ribbons by melt-spinning. The ribbons were ball-milled to make powders, and then mixed with 1 wt.% water glass and 1.5 wt.% lubricant. The mixed powders were burn-off, and then compacted to form toroidal-shaped cores, which were heat treated to crystallize the nano-grain structure and to remove residual stress of material. The characteristics of the powder cores were analyzed using a differential scanning calorimetry (DSC) and a B-H meter. The microstructures were observed using transmission electron microscope (TEM). The optimized soft magnetic properties (${\mu}_i$ and $P_{cv}$) of the powder cores were obtained from the Ca and Al containing alloys after annealing at $530^{\circ}C$ for 1 h. The core loss of Fe-Si-B-Nb-Cu-based powder cores was reduced by the addition of Ca element, and the initial permeability increased due to the addition of Al element.