• Title/Summary/Keyword: buffering

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Factors affecting the chloride threshold level for steel corrosion in concrete

  • Moon, Han-Young;Ann, Ki-Yong;Kim, Hong-Sam
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.205-208
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    • 2005
  • The present study surveys the concrete properties-concerned factors influencing the chloride threshold level for steel corrosion in concrete, altogether with supporting experimental works, in particular, chloride binding capacity, buffering capacity, condition of steel-concrete interface and cement replacement. It concluded that the order of the dominance on CTL is such that chloride binding < buffering capacity of cement matrix < physical condition of steel-concrete interface. This is attributed to the fact that calcium hydroxide does not form a continuous layer on the steel surface and that bound chlorides are released at the stage of corrosion initiation.

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Resistance of Cementitious Binders to Chloride Induced Corrosion of Embedded Steel by Electrochemical and Microstructural Studies

  • Song, Ha-Won;Ann, Ki-Yong;Kim, Tae-Sang
    • Corrosion Science and Technology
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    • v.8 no.2
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    • pp.74-80
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    • 2009
  • The high alkaline property in the concrete pore solution protects the embedded steel in concrete from corrosion due to aggressive ions attack. However, a continuous supply of those ions, in particular, chlorides altogether with a pH fall in electrochemical reaction on the steel surface eventually depassivate the steel to corrode. To mitigate chloride-induced corrosion in concrete structures, finely grained mineral admixtures, for example, pulverized fuel ash (PFA), ground granulated blast furnace slag (GGBS) and silica fume (SF) have been often advised to replace ordinary Portland cement (OPC) partially as binder. A consistent assessment of those partial replacements has been rarely performed with respect to the resistance of each binder to corrosion, although the studies for each binder were extensively looked into in a way of measuring the corrosion rate, influence of microstructure or chemistry of chlorides ions with cement hydrations. The paper studies the behavior of steel corrosion, chloride transport, pore structure and buffering capacity of those cementitious binders. The corrosion rate of steel in mortars of OPC, 30% PFA, 60% GGBS and 10% SF respectively, with chloride in cast ranging from 0.0 to 3.0% by weight of binder was measured at 7, 28 and 150 days to determine the chloride threshold level and the rate of corrosion propagation, using the anodic polarization technique. Mercury intrusion porosimetry was also applied to cement pastes of each binder at 7 and 28 days to ensure the development of pore structure. Finally, the release rate of bound chlorides (i.e. buffering capacity) was measured at 150 days. The chloride threshold level was determined assuming that the corrosion rate is beyond 1-2 mA/$m^3$ at corrosion and the order of the level was OPC > 10% SF > 60% GGBS > 30% PFA. Mercury intrusion porosimetry showed that 10% SF paste produced the most dense pore structure, followed by 60% GGBS, 30% PFA and OPC pastes, respectively. It was found that OPC itself is beneficial in resisting to corrosion initiation, but use of pozzolanic materials as binders shows more resistance to chloride transport into concrete, thus delay the onset of corrosion.

Chemical Indices of Soil Quality: Effects of Heavy Metal Additions

  • Yang, Jae-E.;Choi, Moon-Heon;Lee, Wi-Young;Kim, Jeong-Je;Jung, Yeong-Sang
    • Applied Biological Chemistry
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    • v.41 no.8
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    • pp.587-594
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    • 1998
  • The objective of this research was to characterize effects of Cu or Cd additions on chemistry of soil quality indices, such as pH, EC, cation distribution and buffering capacity. Metals were added at rates ranging from 0 to 400 mg $kg^{-1}$ of soil. Soil solution was sequentially extracted from saturated pastes using vacuum. Concentrations of Cu or Cd remaining in soil solutions were very low as compared to those added to the soils, warranting that most of the added metals were recovered as nonavailable fractions. Adsorption of the added metals released cations into soil solution causing increases of ionic strength of soil solution. At metal additions of $200{\sim}400\;mg\;kg^{-1}$, EC of soil solution increased to as much as $2{\sim}4\;m^{-1}$; salinity levels considered high enough to cause detrimental effects on plant production. More divalent cations than monovalent cations were exchanged by Cu or Cd adsorption. The nutrient buffering capacity of soils was decreased due to the metal adsorption and release of cations. pH of soil solution decreased linearly with increasing metal loading rates, with a decrement of up to 1.3 units at 400 mg Cu $kg^{-1}$ addition. Influences of Cu on each of these soil quality parameters were consistently greater than those of Cd. These effects were of a detrimental nature and large enough in most cases to significantly impact soil productivity. It is clear that new protocols are needed for evaluating potential effects of heavy metal loading of soils.

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Physical and Chemical Properties of Soluble Sodium Silicate (수용성 규산나트륨의 물리 · 화학적 특성)

  • Ha, Youn Shick;Park, Kyeong Il;Seo, Moo Lyong
    • Journal of the Korean Chemical Society
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    • v.43 no.2
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    • pp.172-181
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    • 1999
  • To develop the manufacturing technique for the powder builder of amorphous solid types, the water glass mixed with caustic soda dispersed into the methanol. Thus soluble sodium silicate was made a form of amorphous solid powder. In order to examine characteristics of water soluble sodium silicate $SiO_2/Na_2O$ mol ratio, we investigated solubility, thermogram, SEM, and BET analysis. pH buffering capacity, calcium-ion binding capacity as temperature change, and surfactant loading capacity were examined for characteristics as laundry detergent builder. $SiO_2/Na_2O$ molar ratio of soluble sodium silicate was 1.0, 2.4, 2.8, and zeolite was used in order to investigate basic characteristics of laundry detergent builder. Silicate used with laundry detergent was good for pH buffering capacity and solubility. But calcium-ion binding capacity and surfactant adsorption ability were lower. $SiO_2/Na_2O$ mol ratio became higher, pH buffering capacity and ion exchange ability were lower and surfactant adsorption ability was a little higher.

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Detergency of Soluble Sodium Silicate (수용성 규산나트륨의 세정성)

  • Ha, Youn-Shick;Park, Kyeong-Il;Seo, Moo-Lyong
    • Analytical Science and Technology
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    • v.12 no.1
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    • pp.13-21
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    • 1999
  • Silicate used as laundry detergent builder was good for pH buffering capacity and solubility but calcium-ion binding capacity and surfactant adsorption ability were lower. As $SiO_2/Na_2O$ molar ratio became higher, pH buffering capacity and ion exchange ability were lower and surfactant adsorption ability was little higher. Anionic surfactant LAS (linear alkylbenzene sulphonate), nonionic surfactant LA-9 (lauryl alcohol EO-9) were used to investigate the detergency performance. Zeolite was better than sodium silicate in detergency performance. In case of LAS, detergency performance was good when $SiO_2/Na_2O$ molar ratio was lower. In case of LA-9, detergency performance was similar without discrimination of molar ratio of $SiO_2/Na_2O$.

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Spatial Analysis Modeling for the Development of Evaluating Model for Hospital Location (공간분석모델링을 이용한 병원의 적지평가 모형 개발)

  • Lee, Kwang-Soo;Lee, Jung-Soo
    • The Journal of the Korea Contents Association
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    • v.9 no.10
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    • pp.258-267
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    • 2009
  • This study purposed to develop GIS model for evaluating hospital location in a metropolitan city. Secondly, the suitability score of hospital was compared with the number of outpatient/inpatients of hospitals. This study used administrative data collected from the annual report of the 5 ward offices from Daejeon in Korea in 2004. 7 Acute care hospitals operated in Daejeon in 2004 were selected for the analysis. The suitability of hospitals in a metropolitan city was evaluated by the economic factors which were assumed to influence the health care demand. Each criterion was measured from each Dong. Correlation coefficients between the suitability score of hospital and the number of patients were varied depending on the buffering size. The relationship showed positive relationship with the number of inpatient (0.15) and outpatients (0.10) on the 0.5km buffering size. However, the correlation coefficients were changed to a negative direction or decreased when the buffering size was increased to 1.0km, 1.5km, and 2.0km.

Improved Real-time Video Conferencing System with Memory Buffer Control Management (메모리 버퍼 제어 관리 기능을 갖춘 향상된 실시간 영상회의 시스템)

  • Yoo, Woo Jong;Kim, Sang Hyong
    • KIPS Transactions on Computer and Communication Systems
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    • v.6 no.6
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    • pp.255-260
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    • 2017
  • The limitation of real-time video conferencing system is that the delay of network and buffering and the transmission of user information are not efficiently performed between systems, so real - time performance is not guaranteed completely. In order to overcome this problem, the study on the extension of the network infrastructure and the jitter delay is actively carried out, but the study on the buffering delay is insufficient. In this paper, we propose a frame-rate control buffer management (FRCB) scheme to solve the problem caused by buffering delay. The FRCB is used to prevent overflow and underflow of the buffer by adopting the two-stage buffer threshold of Fast-play THreshold (FTH) and Slow-play THreshold (STH). Therefore, it showed better performance than jitter buffer even under high CPU load, and showed that it is suitable for high quality real time video conferencing.

Quality Characteristics of Soybean Paste Added with Krill (크릴이 첨가된 된장의 품질 특성)

  • Kim, Ji-Sang;Moon, Gap-Soon;Lee, Young-Soon
    • Journal of the East Asian Society of Dietary Life
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    • v.19 no.5
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    • pp.776-782
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    • 2009
  • This study was conducted to develop functional soybean paste with krill (Euphausiacea) as compared to a conventional soybean paste (S1). Soybean containing 10%, 20% and 30% (w/w) krill (S2~S4, respectively) was prepared and quality characteristics (moisture, crude fat, crude protein, ash, reducing sugar, pH, titratable acidity, total acidity and buffering power) were assessed during fermentation for 150 days. As well, antioxidative activities of krill soybean paste were compared to those of control soybean paste based on total phenolic compound content and free radical scavenging activity, including the 1,1-diphenyl-2-picryl-hydrazil (DPPH) scavenging activity and the thiobarbituric acid value (TBA value). The moisture content of all samples decreased to 41.91~53.47% during fermentation, while the crude fat increased to 1.98~5.21% with increasing addition of krill. Additionally, crude protein increased slightly to 8.24~14.08% with increasing addition of krill after 120 days of fermentation. Ash content was 15.96~18.92%. The reducing sugar content of S2, S3 and S4 was higher than those of S1 with increasing length of fermentation. S2, S3, and S4 displayed progressive decreases in pH and progressive increases in titratable acidity compared to S1. The total acidity of all samples was increased, while the buffering power was decreased with increasing fermentation. Especially, the buffering power of S1 was lower than that of S2, S3 and S4. DPPH radical scavenging activity of lipophilic extracts from S2, S3 and S4 was slightly higher than those of S1. However, the radical scavenging activity of hydrophilic extracts from all samples had similar tendencies, regardless of the krill content or fermentation period. Total phenolics increased with increasing fermentation time and TBA value increased with increasing fermentation time and krill content.

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Effect of Fiber Content, Yarn Size and Construction of Knit Fabrics on the Buffering Capacity against Water Vapor (편성물의 섬유의 종류, 실의 굵기 및 니트타입에 따른 투습완충능력)

  • Yoo, Hwa-Sook;Hu, Yoon-Sook;Kim, Eun-Ae
    • Journal of the Korean Society of Clothing and Textiles
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    • v.20 no.1
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    • pp.228-238
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    • 1996
  • The purpose of this study was to evaluate the effect of chacteristics of knit fabrics on the microclimate of the skin simulating system. To determine the effect of characteristics of knit fabrics, vapor state of sweat pulse was simulated in the closed system. Different contents of fibers such as cotton, wool and polyester with different yarn size and knit types were chosen for specimens. The changes of humidity and temperature of air layer in the simulated systems were measured. Buffering indices, $K_d$ and $\beta_r$, were determined by considering $\alpha_p, \DeltaP_{max}, t_{max}, and tan\beta$. Physical properties of knit fabrics such as thickness, porosity, air resistance and moisture vapor transport were measured. Results showed that vapor pressure of wool was lower than cotton or polyester This was attributed to the hydrophilicity of wool which absorbed moisture rather quickly and retained in the knit fabric. The time to decrease vapor pressure was faster for polyester than cotton or wool. As a result, $K_d$ was in the order of wool> polye, item> cotton. $\beta_r$ of wool was rower than cotton or polyester due to its lowers porosity and slower desorption rate. For the yarn size, $K_d$ was in the order of 80's> 60's> 30's; thinner and lighter yarn showed better water vapor transport property. For knit type, buffering capacity of single jersey was better than interlock knit fabric. Statistical analysis showed that the air permeability was the most influential factor far the water vapor transport properties.

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An Integrated Prefetching/Caching Scheme for P2P Live Streaming (P2P 라이브 스트리밍 시스템을 위한 프리패칭/캐싱 통합 기법)

  • Kim, Taeyoung;Kim, Eunsam
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.14 no.1
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    • pp.69-76
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    • 2014
  • In this paper, we propose a buffering scheme to improve the performance in P2P live streaming systems by adjusting the ratio of caching and prefetching portion of each peer. To this end, we assign all the peers into many groups depending on their playback periods. We then determine the ratio of caching and prefetching portion in each peer depending on its playback time position relative to those of other peers within the same group. In other words, as the playback position of a peer gets later, we increase the ratio of its caching portion. On the contrary, as the playback position of a peer gets eariler, we increase the ratio of its prefetching portion. This can significantly increase the degree of data duplication among peers that belong to each specific group. By simulation experiments, we show that our proposed an integrated prefetching/caching scheme can improve the performance considerably in terms of jitter ratio, initial playback delay and shared buffermap ratio when compared to the existing fixed portion buffering scheme.