• Applied Chemistry for Engineering
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• v.7 no.1
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• pp.177-185
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• 1996

The optimum conditions for the removal of hydrogen sulfide by Fe-EDTA complex in the bubble column reactor were investigated. As the concentrations of the complex increased, the conversion rate of hydrogen sulfide increased, while Fe concentration and pH were stably decreased and the amount of elemental sulfur produced was also increased. Hydrogen sulfide was removed efficiently when the concentration of Fe-EDTA complex was maintained more than 0.05M. pH acts as an important factor for the stability of complex in the oxidation of hydrogen sulfide and optimum pH range was 8.5~9.5. As the molar ratio of EDTA : Fe was increased, the conversion rate of hydrogen sulfide became stable. However, the rate was decreased due to the precipitation of FeS when the concentration of EDTA was decreased. As the concentration of EDTA increased, the conversion rate of hydrogen sulfide increased due to the high stability of Fe-EDTA complex.

• KSBB Journal
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• v.13 no.1
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• pp.101-107
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• 1998

Carbon dioxide is estimated to be responsible for 60% of the global warming effect, and this percentage is tending upward. Studies on removal and fixation of $CO_2$ in the flue gas are recognized as one of the important roles of the future biotechnology. Photobiological systems have considerably higher photosynthetic efficiency than conventional biomass system. The experiment for the photosynthetic fixation of $CO_2$ and the biomass production was performed with various initial cell concentration in a tubular photobioreactor and a bubble column $CO_2$ contactor with a gas sparger of $CO_2$ -enriched air(0.03~20%). Synechocystis PCC 6803 could grow at 10~20% $CO_2$ content under pH control. The highest specific growth rate, 0.0258 $h^{-1}$ , was obtained at 5% $CO_2$-air mixture. The maximum cell production rate, 0.2784 g/L.day, was obtained when the initial cell concentration was 0.45 g/L at 5% $CO_2$ -air mixture. The maximum cell concentration was 2.03 g/L in the tubular photobioreactor when the light intensity was $45.5{\mu}$ $E/m^2$ . s. This system showed 0.482 g $CO_2$ /L . day of the $CO_2$ fixation.

• Journal of Microbiology and Biotechnology
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• v.11 no.3
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• pp.369-375
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• 2001

Urushiol, a natural monomeric oil, was used to prepare a detergentless micro-emulsion with water and 2-propanol The formation of micro-emulsion was verified by conductivity measurements and dynamic light scattering. The conductivity data showed phase change dynamics, a characteristics of micro-emulsions, and subsequent dynamic light scattering study further confirmed the phenomenon. Average water droplet diameter was 10 nm to 500 nm when the molar ratio of 2-propanol ranged from 0.40 to 0.44 . Earlier studies were performed on toluene and hexane, in which the insoluble substrate in water phase was added to the solvents to be reacted on by enzymes. However, in the present urushiol system, urushiol was used as both solvent and substrate in the laccase polymerization of urushiol. The laccase activity in the system was examined using polymerization of urushiol. The laccase activity in the system was examined using syringaldezine as a substrate, and the activity increased rapidly near the molar ratio of 2-propanol at 0.4, where micro-emulsion started. The activity rose until 0.46 and fell dramatically thereafter. The study of laccase activity in differing mole fractions of 2-propanol showed the existence of an ‘optimal zone’, where the activity of laccase was significantly higher. In order to analyze urushiol polymerization by laccase, a bubble column reactor using a detergentless micro-emulsion system was constructed. Comparative study using other organic solvents systems were conducted and the 2-propanol system was shown to yield the highest polymerization level. The study of laccase activity at a differing mole fraction of 2-propanol showed the existence of an ‘optimal zone’ where the activity was significantly higher. Also, 3,000 cP viscosity was achieved in actual urushi processing, using only 1/100 level of laccase present in urushi.

• The Bulletin of The Korean Astronomical Society
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• v.39 no.1
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• pp.61.1-61.1
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• 2014

GSH 006-15+7 is a Milky Way supershell discovered by Moss et al. (2012). This supershell shows large shell-like structures in H I velocity maps. We have analyzed FUV emission for the supershell regions based on the FIMS and GALEX observations. Bright FUV flux at the boundaries of the supershell is mostly originated from dust scattering of FUV photons by dust clouds which was also observed at the boundaries of the supershell. We could find the distance to the supershell can be closer more than 30% compared with the distance of 1500 pc suggested by Moss et al. (2012) from the dust scattering simulation. And we also found the albedo and the phase function asymmetry factor of interstellar grains were 0.30 and 0.40, respectively. The confidence range for the albedo covers the theoretical value of 0.40, but g-factor is rather smaller than the theoretical value of 0.65. The small g-factor might mean the environment of turbulent ISM of the supershell. Meanwhile, the excess of C IV and X-ray emissions in the inside of the supershell can support the existence of hot gas and cooling in the supershell. And the C IV and X-ray emissions are monotonically decrease as away from the center of the SNR. This indicates the size of the hot bubble has considerably shrunk. We applied a simple simulation model to the PDR candidate region of the lower part of the supershell and obtained a H2 column density N(H2) = 1017.0-18.0 cm-2 and total hydrogen density nH ${\geq}$ 10 cm-3. This result shows the PDR candidate region represents a transition region from the warm phase to the cool phase in the PDR.

• The Transactions of the Korean Institute of Electrical Engineers P
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• v.63 no.4
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• pp.219-225
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• 2014

The purpose of this paper is to control of the low-speed, high-precision PMSM 2-axes pitch/turning. In this paper, apply the PAM-PWM inverter for it. However, The PAM-PWM inverter, control algorithms and hardware is complex. But it is possible to improve the performance in the low-speed operation can reduce the effect of the PWM ripple and Dead Time of inverter by applying suitable DC-bus voltage control. The direct driver PMSM(Permanent Magnet Synchronous Motor) configured to vector control part, PAM control part and the other controller. The vector control part includes PI current, speed control, additional space vector modulation. PAM control part has to have PI voltage controller and P current controller for DC-bus voltage control. Besides, the motor position estimator, the speed estimator and the counter electromotive force and Dead Time Compensation are added. With this arrangement, PMSM was driven with a low pole pitch/turning by performing the current control to the current command or torque command is the paper. As a result, it was possible to minimize the disturbance component that appears in the drive in proportion to the DC voltage magnitude. The use of a hydraulic drive method for a two-axis bubble column is a typical tank. When using the PWM PAM inverter driver is in the turret can be driven by high-precision, low vibration, low noise compared to the hydraulic drive may contribute to the computerization of the turret.

• The Journal of the Petrological Society of Korea
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• v.1 no.2
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• pp.91-103
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• 1992

Eruptive mechanisms and processes at Udo tuff cone can be inferred from indicative characters of products, bedforms and lithofacies, and ring faults. In terms of bedforms and lithofa-cies in particular, massive lapilli tuff beds and chaotic lapilli tuff beds are derived from subaerial falls of aggregated tephra of wet tephra finger jets, occurring dominantly at the lower sequences of proximal part at the tuff cone. Crudely stratified lapilli tuff are derived from subaerial falls of slightly aggregated tephra of less wet tephra finger jets, whereas reversely graded lapilli tuff beds are from slightly disaggregated subaerial falls of continuous uprush. Both beds frequently occur in the middle sequences at proximal and near medial part of the tuff cone. Block and lapilli tephra lenses, ash-coated lapilli tephra beds(lenses) and thin-bedded tuff beds are derived from extremely disaggregated subaerial falls of dry tephra in the continuous uprush, frequently occurring at the upper sequences of medial part at the tuff cone. Udo tuff cone is a basaltic volcano emergent through the sea water surface while water could flood across or into the vent area. Emergence of the tuff cone was from the type-Surtseyan eruption characterized by earlier tephra finger jets and later continuous uprush columns of tephra with copious volumes of steam. Explosions began when boiling of wter produced a bubble column reducing the hydrostatic pres-sure, allowing exsolution of gases from the magma. This expansion of magma into a vesiculating froth fragmented the magma and permitted mixing of magma and water so that a more vigorous generation of steam could proceed. Tephra finger jetting explosions continued to build the crater rims, then remove water from the vent that their deposits flowed like slsurries until the continuous uprush explosion ensued. Continuous uprush explosions were associated with most rapid accumula-tion of tephra. The increasing volume rate led to partial removal of water from the vent area by the newly tephra ring so that more vigorous activity could be attended by a reducing water supply. This might restrain surplus of cold water entering the vent and thus enhance the vigour of the eruption by allowing optimal heat exchange. Eventually the crater became so deep and unsuported that piecemeal sliding, or massive subsidence on indipping ring faults, filled and closed the vent, and the cycle of explosions and collapse began anew.

• Environmental Engineering Research
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• v.24 no.3
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• pp.389-396
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• 2019

The electrical energy consumption (EEC) in removal of NO by a $UV/H_2O_2$ oxidation process was introduced and related to removal efficiency of this gas. The absorption-reaction of NO was conducted in a bubble column reactor in the presence of $SO_2$. The variation in NO removal efficiency was investigated for various process parameters including NO and $SO_2$ inlet concentrations, initial concentration of $H_2O_2$ solution and gas flow rate. EEC values were obtained in these different conditions. The removal efficiency was increased from about 22% to 54.7% when $H_2O_2$ concentration increased from 0.1 to 1.5 M, while EEC decreased by about 70%. However, further increase in $H_2O_2$ concentration, from 1.5 to 2, had no significant effect on NO absorption and EEC. An increase in NO inlet concentration, from 200 to 500 ppm, decreased its removal efficiency by about 10%. However, EEC increased from $2.9{\times}10^{-2}$ to $3.9{\times}10^{-2}kWh/m^3$. Results also revealed that the presence of $SO_2$ had negative effect on NO removal percentage and EEC values. Some experiments were conducted to investigate the effect of $H_2O_2$ solution pH. The changing of pH of oxidation-absorption medium in the ranges between 3 to 10, had positive and negative effects on removal efficiency depending on pH value.

• Applied Chemistry for Engineering
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• v.33 no.6
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• pp.606-612
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• 2022

The purpose of this study is to convert hydrophobic dyestuff to hydrophilic dyestuff by reacting cationic collector with anionic dyestuff and reaction anionic collector with cationic dyestuff. The removal of colors from aqueous solutions and/or dispersions has been studied by dispersed-air flotation in a batch column. In this studies used generated micro bubble by ceramic gas diffuser having micro pore size for air flotation process. In this study, a ceramic gas diffuser with micro pore size was used to generate micro bubbles for the air flotation process. Two colours were used for the experiments: Basic Yellow 1 (cationic dyestuff) and Direct Orange 10 (anionic dyestuff). All two were effectively removed by flotation within 8 mins. Sodium dodecyl sulfate, sodium oleate (an anionic collector), and amines (a cationic collector) were found to be effective as collectors in the removal of color, which was found to be related to the pH of the solution and the amount of collector added to it, with high collector dosages causing the process to become pH-independent.

• Nuclear Engineering and Technology
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• v.55 no.1
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• pp.169-179
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• 2023

Filtered containment system is a passive safety system that controls the over-pressurization of containment in case of a design-based accidents by venting high pressure gaseous mixture, consisting of air, steam and radioactive particulate and gases like iodine, via a scrubbing system. An indigenous lab scale facility was developed for research on iodine removal by venturi scrubber by simulating the accidental scenario. A mixture of 0.2 % sodium thiosulphate and 0.5 % sodium hydroxide, was used in scrubbing column. A modified mathematical model was presented for iodine removal in venturi scrubber. Improvement in model was made by addition of important parameters like jet penetration length, bubble rise velocity and gas holdup which were not considered previously. Experiments were performed by varying hydrodynamic parameters like liquid level height and gas flow rates to see their effect on removal efficiency of iodine. Gas holdup was also measured for various liquid level heights and gas flowrates. Removal efficiency increased with increase in liquid level height and gas flowrate up to an optimum point beyond that efficiency was decreased. Experimental results of removal efficiency were compared with the predicted results, and they were found to be in good agreement. Maximum removal efficiency of 99.8% was obtained.

• Korean Chemical Engineering Research
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• v.49 no.5
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• pp.605-610
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• 2011

Phase holdup characteristics of relatively large and small bubbles were investigated in a three-phase(gasliquid-solid) fluidized bed of which diameter was 0.105 m(ID) and 2.5 m in height, respectively. Effects of gas(0.01~0.07 m/s) and liquid velocities(0.01~0.07 m/s) and particle size($0.5{\sim}3.0{\times}10^{-3}m$) on the holdups of relatively large and small bubbles were determined. The holdups of two kinds of bubbles in three phase fluidized beds were estimated by means of static pressure drop method with the knowledge of pressure drops corresponding to each kind of bubble, respectively, which were obtained by dynamic gas disengagement method. Dried and filtered air which was regulated by gas regulator, tap water and glass bead of which density was $2500kg/m^3$ were served as a gas, a liquid and a fluidized solid phase, respectively. The two kinds of bubbles in three-phase fluidized beds, relatively large and small bubbles, were effectively detected and distinguished by measuring the pressure drop variation after stopping the gas and liquid flow into the column as a step function: The increase slope of pressure drop with a variation of elapsed time was quite different from each other. It was found that the holdup of relatively large bubbles increased with increasing gas velocity but decreased with liquid velocity. However, the holdup showed a local minimum with a variation of size of fluidized solid particles. The holdup of relatively small bubbles increased with an increase in the gas velocity or solid particle size, while it decreased slightly with an increase in the liquid velocity. The holdups of two kinds of bubbles were well correlated in terms of operating variables within this experimental conditions, respectively.