• Bulletin of the Korean Chemical Society
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• v.24 no.8
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• pp.1135-1140
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• 2003

The kinetics and mechanism of the pyridinolysis $(XC_5H_4N)$ of Y-aryl phenyl isothiocyanophosphates (1;$(YC_6H_4O)\;(C_6H_5O)$P(=O)NCS) are investigated in acetonitrile at 55.0 ℃. The Hammett plots for substituent (Y) variations in the substrate (log k₂ vs σY) exhibit a convex upward biphasic type with breaks at Y = H. For electron-donating Y groups the Hammett coefficients, ρY, are positive and cross-interaction constant ρXY is negative, while those for electron-withdrawing Y groups ρY values are negative with a positive ρXY. These results are interpreted to indicate mechanistic change at the breakpoint (σY = 0) from a concerted to a stepwise mechanism with rate-limiting expulsion of the $^-NCS$ group from a trigonal bipyramidal pentacoordinated (TBP-5C) intermediate. Biphasic plots of log k₂ vs σX or $pK_a$(X) with steeper slopes for the more basic nucleophiles are obtained suggesting an equatorial nucleophilic attack in contrast to an apical attack for the less basic nucleophiles with smaller magnitude of ρX or βx.

• ETRI Journal
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• v.34 no.1
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• pp.44-54
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• 2012

Because of the intrinsic lack of internal-system observability and controllability in highly integrated multicore processors, very restricted access is allowed for the debugging of erroneous chip behavior. Therefore, the building of an efficient debug function is an important consideration in the design of multicore processors. In this paper, we propose a flexible on-chip debug architecture that embeds a special logic supporting the debug functionality in the multicore processor. It is designed to support run-stop-type debug functions that can halt and control the execution of the multicore processor at breakpoint events and inspect the possible causes of any errors. The debug architecture consists of the following three functional components: the core debug support block, the multicore debug support block, and the debug interface and control block. By embedding this debug infrastructure, the embedded processor cores within the multicore processor can be debugged simultaneously as well as independently. The debug control is performed by employing a JTAG-based scanning operation. We apply this on-chip debug architecture to build a debugger for a prototype multicore processor and demonstrate the validity and scalability of our approach.

• Neonatal Medicine
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• v.15 no.2
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• pp.200-206
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• 2008

Human chromosome 9 is characterized by a high degree of morphologic heteromorphisms, including variation in the size of the heterochromatin. We present a case of a de novo short arm addition of chromosome 9, [46, XY, add(9)(p13)], associated with multiple anomalies, including trigonocephaly, upward slant of the palpebral fissures, patent ductus arteriosus, pulmonary hypertension, hypertrophic cardiomyopathy, umbilical hernia, ambiguous genitalia, and sensorineural hearing and visual loss. This mutation affects the pericentric region of the heterochromatin. This patient exhibited a clinically important breakpoint of the heterochromatic region of chromosome 9 short arm and the associated anomalies.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2008.05a
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• pp.183-186
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• 2008

Carbonation is measured as Phenolphthalein Solution, it is possible to confirm the scope of alkali through acid and basic reaction. Then, Concrete Basic Reaction is decided according to alkali concentration depending on Potassium Hydroxide Now that Carbonation is gradually produced toward inner side from outer side, with time going by, it doesnt work, to some adequate depth, in as fast time as compulsory facilitating test. Thus, this research thesis made a comparative analysis on concrete phenomenal discoloration borderline following Phenolphthalein Solution, as part of a bid to measure Carbonation. Also, the thesis measured Concrete Alkali Concentration. The result showed that concrete coloring is classified into red and scarlet according to alkali concentration, and into borderline breakpoint of the speckle of scarlet and carbonation reaction. The higher chroma becomes with concrete decolorizing, the higher alkali concentration becomes.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.18 no.2
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• pp.166-177
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• 2006

The accuracy impact of using high-order Boussinesq-type model as compared to the typical order model is examined in this paper. The multi-layer model developed by Lynett and Liu(2004a) is used for simulating of wave breaking over a shelf region. The nonlinearity of the waves tested, ${k_0}{A_0}$, ranges from 0.029 to 0.180. The overall agreement between the two-layer model and the hydraulic experiments are quite good. The one-layer model overshoals the wave near the breakpoint, while the two-layer model shoals at a rate more consistent with the experimental data.

• Journal of Fashion Business
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• v.20 no.2
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• pp.1-15
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• 2016

Currently, a lot of people are aware of their health and well-being, so they are concerned about their healthcare. 'Taekwondo' is one of the popular sports that Korean people are passionate about Taekwondo has also become globalized. The uniform of Taekwondo is gaining importance. Taekwondo involves a lot of movement, hence the pattern should facilitate the movement. In addition Taekwondo uniform pattern should meet the demands of functionality, fit and consumer design preferences. This study aimed to provide the basic data for development of Taekwondo uniform pattern based on design preferences and functionality to wearer satisfaction. The result of this method indicated fit and design details. Also, the length of pants, top, and sleeve was too wide, which has to more fitted for both of genders. For females, the breakpoint was too low, which requires some increase to make females feel more secure. In conclusion, the results of this study indicated that in order to increase 'Takwondo' value, Taekwondo uniform is required to be more fashionable and comfortable to wear, which could influence other sports wear.

• Proceedings of the Korea Information Processing Society Conference
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• 2001.10a
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• pp.671-674
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• 2001

Q+P Esto는 정보가전용 RTOS인 Q+P를 위한 원격 개발 환경이다. 타겟에이전트는 타겟에서 실행되면서 호스트에 있는 디버거와 원격쉘, 그리고 자원모니터 같은 Q+P Esto 도구들이 원격 개발을 하는데 필요한 기본적인 기능들을 제공한다. 본 논문은 GNU gdb 5.0에 있는 gdbserver를 이용하여 타겟에서 실행 중인 응용 프로세스를 감시 및 제어하는 구조를 제안한다. 디버깅을 위하여 정지점(breakpoint)에 걸린 응용 프로세스를 continue 시켰을 때 응용 프로세스가 무한 루프에 빠지더라도 타겟에이전트는 다른 도구의 요청을 계속 처리할 수 있다. 응용 프로세스를 제어하는 자세한 메커니즘은 gdbserver가 담당한다. 따라서, 타겟에이전트는 단지 gdb remote protocol만 사용하여 gdbserver와 통신하면 되므로 구현이 용이하다.

• Journal of KIISE:Computing Practices and Letters
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• v.8 no.1
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• pp.9-16
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• 2002

Join operation exert a great effect on the performance of system in temporal database as in the relational database. Especially, as for the temporal join, the optimization of interval partition decides the performance of query processing. In this paper, to improve the efficiency of parallel join query in temporal database. I proposed Minimum Interval Partition(MIP) scheme that time interval partitioning. The validity of this MIP algorithm that decides minimum breakpoint of the partition is proved by example scenario and I confirmed improved efficiency as compared with existing partition algorithm.

• The Journal of Asian Finance, Economics and Business
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• v.8 no.10
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• pp.239-247
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• 2021

Central Bank authorities should carefully manage inflation rate uncertainties to achieve economic growth and development not only in the short-run but also in the long-run. Since inflation is a key macroeconomic variable, an increased understanding about its behavior is undoubtedly important. Thus, paper employs unit root with breakpoints to examine the mean reverting behavior of inflation rate in the Philippines using monthly data from 2002 to 2020. Empirically, the unit root breakpoint innovational and additive outlier tests favor the stationarity or mean reverting behavior of inflation in the Philippines. Also, results of standard unit root tests, ADF, PP, GLS-Dickey-Fuller, KPSS and NP, provide strong evidence of mean reverting processes. The mean reverting behavior of inflation rate reveals that the monetary policy using inflation targeting framework has succeeded in reducing chronic inflation persistence in the Philippines. Thus, this research supports inflation targeting policy that aims to maintain general price level stability for the Philippine economy's long-term growth and development prospects. The findings of this research remain important for the central bankers for not only providing them better understanding about the behavior of inflation rate, but also helping them formulate and implement policy reforms related to money, credit and banking.

• Annals of Rehabilitation Medicine
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• v.42 no.6
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• pp.884-887
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• 2018

We report a female proband carrying a de novo 5q34-q35.2 deletion breakpoint, and review the unique skeletal phenotype and possible genotype related to this mutation. The patient presented with a persistent head tilt and limited head rotation. Non-contrast-enhanced three-dimensional computed tomography of the cervical spine revealed several malformations including a bone cleft in the right pars interarticularis, a bone defect in both C5 lamina and the transverse foramen at C2-C3, agenesis of the right articular process of C5, bony fusion of C4-C5, and subluxation of the craniocervical joints. Several deformities of the cervical spine seen in this patient have not been associated with the 5q deletion. A review of 5q-related mutations suggests that abnormalities associated with MSX2 gene might cause cervical spine abnormalities.