• 제목/요약/키워드: bonding network

검색결과 134건 처리시간 0.025초

Proton Conductivity of Niobium Phosphate Glass Thin Films

  • Kim, Dae Ho;Park, Sung Bum;Park, Yong-il
    • 한국재료학회지
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    • 제28권5호
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    • pp.308-314
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    • 2018
  • Among the fuel cell electrolyte candidates in the intermediate temperature range, glass materials show stable physical properties and are also expected to have higher ion conductivity than crystalline materials. In particular, phosphate glass has a high mobility of protons since such a structure maintains a hydrogen bond network that leads to high proton conductivity. Recently, defects like volatilization of phosphorus and destruction of the bonding structure have remarkably improved with introduction of cations, such as Zr4+ and Nb5+, into phosphate. In particular, niobium has proton conductivity on the surface because of higher surface acidity. It can also retain phosphorus content during heat treatment and improve chemical stability by bonding with phosphorus. In this study, we fabricate niobium phosphate glass thin films through sol-gel processing, and we report the chemical stability and electrical properties. The existence of the hydroxyl group in the phosphate is confirmed and found to be preserved at the intermediate temperature region of $150-450^{\circ}C$.

Sol-Gel Transition in Di-(2-ethylhexyl) phthalate-Plasticized Poly(vinyl chloride)

  • Lee, Chang-Hyung;Nah, Jae-Woon;Cho, Kil-Won;Kim, Seong-Hun;Hahn, Ai-Ran
    • Bulletin of the Korean Chemical Society
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    • 제24권10호
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    • pp.1485-1489
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    • 2003
  • The gelation for di-(2-ethylhexyl) phthalate (DEHP)-plasticized poly(vinyl chloride) was studied by measuring time-resolved small-angle X-ray scattering (SAXS) and a flow of the solutions in test tube. It was found that for the gelation there were three regimes. At Regime I, the solution rapidly changed to a gel, and the SAXS intensity showed a peak and the peak intensity increased, keeping the peak angle constant. Applying the SAXS intensity to the kinetic analysis of the liquid-liquid phase separation, it was revealed that the spinodal decomposition proceeded to develop a periodic length of 29.9 nanometer in size, a hydrogen-bonding-type association in polymer rich phase followed, and then it induced fast gelation rate. At Regime II, the gelation slowly occurred and the SAXS intensity was not observed, suggesting that a homogeneous gel network was formed by a hydrogen-bonding. At regime III, the solution was a homogeneous sol.

Social Networking Site Usage, Social Capital and Entrepreneurial Intention: An Empirical Study from Saudi Arabia

  • HODA, Najmul;FALLATAH, Mahmoud
    • The Journal of Asian Finance, Economics and Business
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    • 제9권5호
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    • pp.421-429
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    • 2022
  • Entrepreneurship research has focused on several factors that might affect the intention of an individual to start an enterprise. Using principles from social network theory and the entrepreneurial intention model (EI), the current research intends to investigate how social capital is formed on Social Networking Sites (SNS) and how the resulting social capital influences entrepreneurial intention. Using an online survey, 151 valid responses were received from university students. Applying partial least square structural equation modeling, positive and significant relationship was found between the SNS usage and bonding and bridging social capital. Further, it was also found that online-bonding social capital does not impact any of the three antecedents of entrepreneurial intention. On the other hand, online-bridging social capital significantly influences personal attitudes and subjective norms. It was also found that both personal attitude and perceived behavioral control significantly relate to EI, while the subjective norms do not relate significantly to EI. The paper contributes to the literature on technology-based human behavior and entrepreneurship in emerging countries, opening some areas for future research, while also providing some managerial insights. It also should be beneficial to educational institutions in understanding how the use of SNS use by students may be optimized.

DOCSIS 3.0 기반 케이블망에서의 경쟁구간 설정 알고리즘에 관한 연구 (A Study on the Contention Area Establish of Algorithm from Cable Network based on DOCSIS 3.0)

  • 김영성;송재준;노선식
    • 한국정보통신학회:학술대회논문집
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    • 한국해양정보통신학회 2007년도 춘계종합학술대회
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    • pp.69-72
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    • 2007
  • 최근 광대역 가입자망으로서 HFC 망을 고도화 할 수 있는 DOCSIS 3.0이 표준화되고 있다. DOCSIS 3.0에서는 상향 스트림 프레임에서 경쟁구간의 크기에 따라 프레임의 크기와 예약 구간의 크기에 영향을 받는다. 또한 경쟁구간을 통해 Request를 전송하려는 CM들의 Request 성공률에도 밀접한 관계가 있다. 이 때 다수의 CM들이 경쟁구간을 통해 대역 할당을 요청하기 때문에 발생하는 충돌을 최소화할 수 있는 경쟁구간 설정 알고리즘이 필요하다. 따라서 본 논문에서는 DOCSIS 3.0에서 사용하는 채널-결합 방식을 고려하여 경쟁구간 설정 알고리즘을 제안하였다. 성능 평가를 통해 기존 알고리즘 보다 경쟁구간의 이용률과 절약율에 있어서 더 좋은 성능을 나타냄을 확인하였다.

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게임 이용자의 사회자본과 자기해석이 행동적 적응을 통해 SNG재이용의도 및 유료아이템 구매의도에 미치는 영향 (The Effects of Game User's Social Capital and Self-Construal on SNG Reuse Intention and Charge Item Purchasing Intention Through Behavioral Adaptation)

  • 이지현;김한구
    • 한국정보시스템학회지:정보시스템연구
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    • 제27권2호
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    • pp.135-155
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    • 2018
  • Purpose Recently, with the enhancement of mobile technologies, people have formed various relationships and spreaded networks on social network service(SNS). In addition, although people make a decision based on the thoughts and emotions about self, there is little empirical research on social relations and self-construal of users in social network game (SNG). Design/methodology/approach This study was designed to examine the structural relationships among SNG users' social capital, self-construal, behavioral adaptation, SNG reuse intention and charged item purchasing intention. Findings The results from this study are as follow. First of all, the bonding social capital did not have a significant impact on behavioral adaptation to SNG, but bridging social capital had a positive impact on behavioral adaptation. Second, independent self-construal did not have a significant impact on behavioral adaptation to SNG, but interdependent self-construal had a positive impact on behavioral adaptation. Lastly, the behavioral adaptation to SNG had a positive impact reuse intention and charged item purchasing intention. Also, SNG reuse intention had a positive impact on charged item purchasing intention.

Structure-Function of the TNF Receptor-like Cysteine-rich Domain of Osteoprotegerin

  • Shin, Joon;Kim, Young-Mee;Li, Song-Zhe;Lim, Sung-Kil;Lee, Weontae
    • Molecules and Cells
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    • 제25권3호
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    • pp.352-357
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    • 2008
  • Osteoprotegerin (OPG) is a soluble decoy receptor that inhibits osteoclastogenesis and is closely associated with bone resorption processes. We have designed and determined the solution structures of potent OPG analogue peptides, derived from sequences of the cysteine-rich domain of OPG. The inhibitory effects of the peptides on osteoclastogenesis are dose-dependent ($10^{-6}M-10^{-4}M$), and the activity of the linear peptide at $10^{-4}M$ is ten-fold higher than that of the cyclic OPG peptide. Both linear and cyclic peptides have a ${\beta}$-turn-like conformation and the cyclic peptide has a rigid conformation, suggesting that structural flexibility is an important factor for receptor binding. Based on structural and biochemical information about RANKL and the OPG peptides, we suggest that complex formation between the peptide and RANKL is mediated by both hydrophobic and hydrogen bonding interactions. These results provide structural insights that should aid in the design of peptidyl-mimetic inhibitors for treating metabolic bone diseases caused by abnormal osteoclast recruitment.

초분자 네트워크를 이용한 열가역성 가교 탄성체 (Thermo-reversible Crosslinking Elastomer through Supramolecular Networks)

  • 배종우;오상택;김구니;백현종;김원호;최성신
    • Elastomers and Composites
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    • 제45권3호
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    • pp.165-169
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    • 2010
  • 최근에 기존 고무의 장점인 유연성과 충전제에 의한 다양한 기능성과 열가소성 고무의 장점인 리싸이틀 및 성형의 용이성을 동시에 갖춘 초분자 네트워크형 열가역성 가교 탄성체가 소개되고 있다. 수소 결합과 이온 클러스터간의 결합력과 같은 열가역성 결합은 1990년부터 소개되었지만, 초분자 네트워크에서 가교 구조의 결합과 절단을 조절할 수 있는 기술이 시도된 것은 최근의 기술적 성과이다. 본 보문에서는 열가소성 탄성체의 용융 특성과 가교 탄성체의 보강 거동을 가지는 열가역성 가교 탄성체의 특징들을 정리하였다.

침엽수, 활엽수 펄프섬유의 혼합비에 따른 종이의 강도발현 기작 구명 (Paper Strength Mechanism Depending on Mixing Ratio of Softwood and Hardwood Fibers)

  • 이진호;박종문
    • 펄프종이기술
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    • 제33권3호
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    • pp.1-8
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    • 2001
  • Paper consists of fiber network and paper properties were highly affected by fiber characteristics. Many researchers have tried to relate fiber and paper properties. Softwood and hardwood fiber's are quite different in their properties. Generally, softwood fiber's are longer and more flexible than hardwood fibers. At present, many paper mills make mixed paper with softwood and hardwood fibers except for special grade. During fracture some fiber's are broken and others are pulled out. In this paper, the number of broken and pulled out fiber's during fracture is analyzed depending on the mixing ratio of softwood and hardwood fiber's. Fiber length, curl, kink, coarseness, WRV and formation index were measured. Double-edged strength samples were prepared to observe the number of broken and pulled out fiber's. Mixed paper strength was decreased with increasing hardwood fibers ratio. During fracture, softwood fiber's were more likely broken and hardwood fibers were more likely pulled out. The strength of paper which consists of softwood fibers was determined by fiber's broken strength and that of hardwood fibers by fiber's debonding strength. Paper strength was changed depending on the fiber's bonding capability. If the fiber is longer and more flexible, the fiber network becomes stronger and stiffer.

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치과용 복합레진으로 수리된 CAD-CAM hybrid 수복물의 전단결합강도 (Shear bond strength of dental CAD-CAM hybrid restorative materials repaired with composite resin)

  • 문윤희;이종혁;이명구
    • 대한치과보철학회지
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    • 제54권3호
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    • pp.193-202
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    • 2016
  • 목적: 본 연구에서는 치과용 CAD-CAM (computer aided design-computer aided manufacturing) hybrid 수복재료인 LAVA Ultimate와 VITA ENAMIC을 광중합 복합레진을 사용하여 수리할 때 표면처리방법(grinding, air abrasion with aluminum oxide, HF acid)과 접착재료(Adper Single Bond 2, Single Bond Universal)의 종류가 두 재료 사이의 전단결합강도에 어떠한 영향을 미치는지 알아보고자 하였다. 재료 및 방법: LAVA Ultimate와 VITA ENAMIC 시편을 30일간 $37^{\circ}C$의 인공타액(Xerova solution)에 보관하여 시효처리를 실시한 후 각각 SiC paper grinding한 것, grinding 후 air abrasion처리를 추가한 것, grinding 후 HF 처리한 것으로 분류하고 각각 no bonding, Adper Single Bond 2, 또는, Single Bond Universal 도포로 세분하여 9개의 group, 총 18개의 subgroup으로 나누어 실험을 실시하였다(N=10). HF 처리group에서는 도재시편을 대조군으로 추가하였다(N=10). 표면 처리 후 광중합 복합레진(Filtek Z250)을 각각의 시편에 부착하고 이를 1주일간 실온의 물에 침적시켰고 이후 전단결합강도를 측정하고 파절양상 및 표면처리 효과를 SEM으로 확인하였다. One-way ANOVA를 이용하여 group 간의 유의성을 분석하였고 사후 분석으로 Scheffe test를 실시하였다(${\alpha}=.05$). 결과: 실험 결과 접착재료 처리를 한 group들이 접착재료 처리를 하지 않은 group에 비해 모든 표면처리에서 더 높은 전단결합력을 나타내었으며, 표면처리만 시행한 group에서는 aluminum oxide air abrasion이 전단결합력의 증가에 약간의 영향을 미치는 것으로 나타났으나 통계적 유의성은 보이지 않았다. 결론: LAVA Ultimate와 VITA ENAMIC의 두 재료를 광중합 복합레진을 이용하여 수리를 실시할 경우 각각의 재료에 적합한 표면처리방법과 접착재료의 선택에 대한 연구가 더 필요할 것으로 사료된다. 특히 LAVA Ultimate의 경우 접착재료의 사용은 추천된다고 사료되었다.

다중 무선랜 인터페이스 전송을 위한 결합 방식의 성능 연구 (A Comparative Study of Aggregation Schemes for Concurrent Transmission over Multiple WLAN Interfaces)

  • 유리스;황환웅;윤지훈
    • 전자공학회논문지
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    • 제51권7호
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    • pp.18-25
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    • 2014
  • 무선 전송 용량의 향상을 위해 다른 주파수 대역을 사용하는 복수 개의 무선 인터페이스를 결합하여 동시에 사용하는 것을 고려할 수 있다. 본 논문에서는 복수 개의 Wi-Fi 인터페이스를 갖는 시스템을 대상으로, 인터페이스 결합 사용을 위한 링크 결합과 다중경로 TCP(MPTCP)의 두 기법을 실험을 통해 성능을 비교, 분석한다. 실험은 트래픽 종류, 네트워크 지연 시간, 무선 채널 품질, 인터페이스 장애 등의 다양한 조건이 고려되었다. 실험 결과, 인터페이스 결합을 통한 다중 전송은 큰 수율 이득이 있었다. 하지만, 링크 결합 기법은 패킷 전달 순서의 변경으로 중복 TCP 응답이 발생하여 MPTCP보다 낮은 수율을 보였고, 이의 개선을 위해 응답 필터링이 적용될 경우 이득이 있음을 확인하였다. 또, 링크 결합 기법에서 스케줄링 가중치의 조합에 따른 성능 차이가 있으므로 시공간에 따라 적응적으로 가중치를 조절할 필요가 있음을 보였다. 한편, 링크 결합 기법은 MPTCP 대비 빠른 반응으로 인해 긴 네트워크 지연 시간 및 인터페이스 장애 시 더 나은 성능을 보였다. 끝으로, 평균 소비 전력 계산을 위한 수학 모델을 제시하고, 이를 통해 각 기법의 소비 전력을 비교, 분석하였다.