• Restorative Dentistry and Endodontics
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• 제16권2호
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• pp.126-142
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• 1991

The purpose of this study was to evaluate the effect of various dentin surface treatments on shear bond strength, microhardness and fracture mode before and after thermocycling. Recently extracted 75 human molars were used. The teeth were sagittal sectioned faciolingually to obtain 150 specimens. They were randomly divided into six groups. Mesial and distal dentinal surfaces of specimens were exposed by grinding and treated respectively with GC-DENTIN CONDITIONER. 10-3 solution of 4-Meta, Cleansar and Primer of GLUMA, Scotchprep of Scotchbond 2, DENTIN CONDITIONER and PRIMER A, B of ALL BOND according to the manufacturers directions. Specimens of one group were not treated. Adhesive agent of Scotchbond 2, were applied and cured on the treated dentin surfaces. After P-50 were cured on them, specimens were stored in 31c water for 24 hours before shear bond strength measurement Shear bond strength was measured in 10 specimens of each group. 10 specimens of each group were thermocycled in $20^{\circ}C$, $60^{\circ}C$,$20^{\circ}C$, $4^{\circ}C$, $20^{\circ}C$ water in order, for 30 seconds respectively, 100 times a day for 7 days. After thermocycling shear bond strength was measured. Microhardness was checked on treated dentin surface and fractured dentin surface in 10 specimens respectievly. Francture modes were observed with SEM The following results were obtained. 1. Before thermocycling. shear bond strengths in the specimens treated with DENTIN CONDITIONER and PRIMER A, B of ALL BOND were significantly higher than those in other specimens(P<0.01). 2. After thermocycling. shear bond strengths in the specimens treated with Cleanser and Primer of GLUMA, Scotchprep of Scotchbond 2 and DENTIN CONDITIONER and PRIMER A, B of AIL BOND were significantly higher than those in specimens not: treated, treated with GC-DENTIN CONDITIONER and 10-3 solution of 4-Meta(P<0.01). Shear bond strengths in the specimens treated with GC-DENTIN CONDITIONER and PRIMER A, B of ALL BOND were significantly higher than those in other specimens except those treated with Scotchprep of Srotchbond 2(P<0.01). 3. Shear bond strengths after thermocycling were reduced in the specimens not treated, treated with GC-DENTIN CONDITIONER and 10-3 solution of 4-Meta and were increased in the specimens treated with Cleanser and Primer of GLUMA, Scotchprep of Scotchbond 2, without significance, compared with those before thermocycling. In the specimens treated with DENTIN CONDITIONER and PRIMER A, B of ALL BOND, shear bond strengths after thermocycling were significantly increased, compared with those before thermocycling(P<0.01). 4. Microhardnesses in the fractured surfaces after shear bond strength measurement were significantly increased in the specimens treated with 10-3 solution of 4-Meta and significantly decreased in the specimens treated with DENTIN CONDITIONER and PRIMER A, B of ALL BOND, compared with those in the treated dentin surfaces(P<0.01). 5. In the specimens treated with Cleanser and Primer of GLUMA, Scotchprep of Scotchbond 2 and DENTIN CONDITIONER and PRIMER A, B of ALL BOND, cohesive fracture modes were observed more than adhesive fracture modes.

• 대한치과기공학회지
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• 제26권1호
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• pp.35-40
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• 2004

In order to understand alloying effects on the corrosion resistance of Ti-(10$\sim$20)%Zr-(2$\sim$8%)Nb-0.2%Pd alloys, Polarization curves were measured at 5%HCI solution. The results were interpreted in terms of two parameters obtained by the molecular orbital calculation ; one is the bond order($B_{\circ}$) and the other is the metal d-orbital level($M_{d}$). $B_{\circ}$ is a measure of the strength of covalent bonds between titanium and alloying elements. $M_{d}$ is correlative with the electronegativity of elements. It was found that increasing of Zr and Nb with higher $B_{\circ}$ values showed a lower critical anodic current density in the polarization curve and hence higher corrosion resistance. On the other hand, increasing of Zr and Nb with higher $M_{d}$ values showed a higher corrosion resistance.

• 한국건축시공학회지
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• 제15권5호
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• pp.465-471
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• 2015

철근콘크리트 기둥에서 횡 보강근의 시공성 및 구속효과를 향상시키기 위하여 본 연구에서는 내부 크로스타이의 대체로서 V형 띠철근의 배근방법을 제시하였다. 제시된 V형 띠철근의 부착응력-미끄러짐 관계를 파악하기 위하여 콘크리트 강도 및 V형 띠철근의 절곡각도와 묻힘길이를 주요변수로 35개의 직접인발 실험체를 제작하였다. V형 띠철근의 부착강도는 절곡각도가 $60^{\circ}$ 이하에서 CEB-FIP 기준 식보다 높게 있었다. V형 띠철근의 시공성 및 부착거동을 고려하면, V형 띠철근의 최적 절곡각도 및 묻힘길이는 각각 $45^{\circ}$와 $6d_b$ 이상으로 제시될 수 있었는데, 여기서 $d_b$는 띠철근 직경이다.

• 대한치과교정학회지
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• 제30권4호
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• pp.483-490
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• 2000

치과용 금합금에 브라켓을 부착하는 경우 자연치에 비하여 낮은 결합강도를 보이며, 잦은 브라켓 탈락이 나타나고 있는 바, 본 연구는 여러 가지 금합금 표면처리 방법이 교정용 레진 접착제와 금합금 간의 전단결합강도에 미치는 영향을 평가하여 금합금과 브라켓 간의 부착강도 증진방법을 모색하고자 시행하였다. 치과용 금합금으로 주조된 240개의 시편을 표면처리 유무 및 방법에 따라 무처리, 샌드블라스팅 단독처리, 샌드블라스팅과 주석도금 병용처리, 그리고 샌드블라스팅과 중간접착제 병용처리의 4가지 경우와, Ortho-one, Panavia 21, Superbond C&B의 3가지 레진접착제의 조합에 의해 12군으로 나누어 브라켓을 부착하였다. 시편을 증류수에 담아 $37^{\circ}C$ 항온 수조 속에서 24시간 동안 보관한 후, 만능물성 시험기를 이용하여 전단결합강도를 측정한 후 다음과 같은 결과를 얻었다. 1. 치과용 금합금의 표면을 처리하지 않은 경우에 비하여 표면처리한 군에서 통계적으로 유의하게 높은 전단결합강도가 나타났다. 2. 샌드블라스팅 단독처리에 비하여 주석도금 병용처리를 시행한 경우 Panavia 21에서만 유의한 결합강도 증가가 나타났다. 3. 샌드블라스팅 단독처리에 비하여 중간접착제 병용처리를 시행한 경우 모든 접착제에서 유의한 결합강도 증가가 나타났다. 4. 사용된 레진접착제에 따른 전단결합강도를 비교한 결과 Superbond C&B가 가장 높고 그 다음으로 Panavia 21, Ortho-one 순으로 나타나는 양상을 보였다. 이상의 결과는 금합금 표면에서 브라켓 부착강도를 증가시키기 위해서는 레진접착제 종류에 관계없이 샌드블라스팅과 중간접착제 병용처리가 필요함을 시사하였다.

• 대한치과보철학회지
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• 제39권2호
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• pp.157-170
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• 2001

The bond strength is the most important factor in establishing long-term success of resin-retained fixed prostheses. So, various surface treatment methods have been introduced to improve the bond strength of metal surface and bonding resin till now This study was performed to compare the effect of silicoating with that of metal primer and analyze the correlation between treatment time of sandblasting and the bond strength, so that meant to find more effective surface treatment method that could enhance the bond strength of resin-retained fixed prostheses. The surfaces of all specimens made of $Verabond^{(R)}$ alloys were air abraded with $250{\mu}m\;Al_2O_3$ according to treatment time of sandblasting and they were subdivided to be treated with only sandblasting(S group), silicoating following sandblasting(SS group) and metal primer application after sandblasting(SM group). Then pairs of metal specimens (${\phi}10mm{\times}h\;2mm,\;{\phi}6{\times}h\;2mm$) were bonded with Super bond $C&B^{(R)}$. The specimens were stored in $38^{\circ}C$ water for 48 hours and shear bond strength was measured using the universal testing machine. The results were as follows, 1. In the comparison of shear bond strength according to treatment time of sandblasting, bond strength was increased in the order of 0', 15', 30', 45', 60' group. 0' group had significantly lower value than any other, while 0', 15' group were significantly different with 30', 45', 60' group(p<0.05). 2. In the comparison of shear bond strength according surface treatment methods, bond strength was increased in the order of S group. SS group and SM group. S group was significantly different with SS group and SM group(p<0.05). 3. Observing the mode of bond failure. 0', 15' group showed only adhesive failure, and 30', 45', 60' group did mostly adhesive & cohesive failure in S group. In SS group and SM group, all other groups except 0', 15' group showed mostly cohesive failure. From the above results, it is considered that sandblasting should be treated for more than 30 seconds, and metal primer be more effective and available clinically than silicoater system which is complicate, technique-sensitive and time-consuming method, when nonprecious metal surface is planning be treated with in order enhance the bond strength of resin-retained fixed prostheses.

• 콘크리트학회논문집
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• 제26권5호
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• pp.651-660
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• 2014

강섬유로 보강되어 SF-RPC (Steel-Fiber reinforced Reactive Powder Concrete)로 불리는 초고성능 콘크리트의 설계는 이에 대한 연구결과를 기반으로 한 가이드라인을 통해 수행되고 있으나, 명확한 설계기준은 확립되지 않은 상태이다. 특히 SF-RPC 일반적으로 고온($90^{\circ}C$)의 증기양생을 필요로 하므로 프리캐스트 부재 형태로 사용되고 있어 부재간 접합 방법이 중요한 설계 요소로 간주됨에도 불구하고 명확한 설계기준이 존재하지 않음에 따라 현재 안전성 및 경제성 측면에서 많은 의문이 있는 상태이다. 본 연구에서는 SF-RPC의 명확한 정착 설계를 위한 기반으로 SF-RPC와 철근 사이의 부착강도를 실험적으로 파악하고, 기존에 사용하였던 평가 방법의 적용성을 검토하고자 한다. 이를 위해, 콘크리트의 압축강도, 피복두께, 섬유의 혼입량을 변수로 가진 직접 뽑힘 실험을 계획 및 수행하였다. 실험 결과 SF-RPC의 부착강도는 압축강도의 증가량에 따라 증가하고 있으나 그 증가율은 크게 나타나지 않음을 확인할 수 있으며, 피복두께의 증가에 따라 부착강도가 증가하며 $5.2d_b$ 이상의 피복을 가질 경우 매우 짧은 매입깊이인 $3d_b$의 매입깊이에서도 철근을 항복시킬 수 있는 것을 확인하였다. 또한, 섬유의 보강에 의해 부착강도가 두배 이상 증가하는 것을 확인하였다. 안전하고 경제적인 설계를 위해서는 SF-RPC의 부착강도를 추정할 수 있어야 하나, 현재까지는 이에 대한 추정식이 제시되고 있지 않으며, SF-RPC의 거동이 압축응력하에서는 큰 탄성 거동을 하며, 인장응력하에서는 소성거동을 함에 기인하여 Tepfers의 응력 해석 방법을 적용한 결과 실험 결과와 유사한 추정치를 기대할 수 있는 것을 확인하였다.

• 콘크리트학회논문집
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• 제16권3호
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• pp.327-334
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• 2004

본 연구에서는 초기재령에서 고강도콘크리트의 압축강도 발현 특성 검토 및 해석 그리고 콘크리트와 거푸집간의 부착강도 특성을 분석하며, P형 슈미트해머를 이용한 반발도와 압축강도간의 상관관계를 검토하므로서 실무의 고강도콘크리트 측면 거푸집 탈형과 연관한 관련규정의 적합성을 재검토하고, 아울러 거푸집제거와 연관한 효율적인 품질관리 방법에 대하여 제안하고자 한다. 연구결과에 따르면, W/B가 증가할수록 응결시간은 감소하는 것으로 나타났으며, 본 연구의 범위에서 로지스틱 모델에 의한 강도증진 해석 결과 압축강도 8MPa를 발휘하는 시간과 적산온도는 17${\~}$20시간, $21{\~}25^{\circ}D{\cdot}D$ 정도로 나타났다. 거푸집과 콘크리트의 부착강도는 종결시점에서 가장 크게 나타났으며 그 이후에는 감소함을 보였고, 거푸집에 부착되어 박리되는 콘크리트의 양은 응결이전에 크게 나타났으며, 그 이후에는 점차적으로 감소하는 경향을 보였다. P형 슈미트해머에 의한 반발도 실험결과 압축강도 발현시점보다 약 2${\~}$3시간 정도 빠르게 측정할 수 있으며, 반발도가 32 이상이면 측면 거푸집을 탈형 할 수 있는 시기로 품질관리가 가능할 것으로 판단되었다.

• 대한치과보철학회지
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• 제41권3호
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• pp.369-378
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• 2003

Statement of Problem: Recently, resin cements have become more widely used and have been accepted as prominent luting cements. Current resin cements exhibit less microleakage than conventional luting cements. However, the constant contact with water and exposure to occlusal forces increase microleakage even in resin cements inevitably. Most bonding resins have been modified to contain a hydrophilic resin such as 2-hydroxyethylmethacrylate (HEMA) to overcome some of the problems associated with the hydrophobic nature of bonding resins. By virtue of these modifications, bonding resins absorb a significant amount of water, and there may also be significant stresses at bonding interfaces, which may adversely affect the longevity of restorations. Therefore the reinforcement of water stability of resin cement is indispensable in future study. Purpose: This study was conducted to examine the influence of water retention on microleakage of two resin cements over the period of 6 months. Materials and Methods: 32 extracted human teeth were used to test the microleakage of a single full veneer crown. Two resin cements with different components and adhesive properties - Panavia F (Kuraray Co., Osaka, Japan) and Super-Bond C&B (Sun Medical Co., Kyoto, Japan)- were investigated. The storage medium was the physiological saline solution changed every week for 1 month, 3 months, and 6 months. One group was tested after storage for 1 day. At the end of the each storage period, all specimens were exposed to thermocycling from $5^{\circ}C$ to $55^{\circ}C$ of 500 cycles and chewing simulation of 50,000 cycles, and then stained with 50% silver nitrate solution. The linear penetration of microleakage was measured using a stereoscopic microscope at ${\times}40$ magnification and a digital traveling micrometer with an accuracy of ${\pm}3{\mu}m$. Values were analyzed using two-way ANOVA test, Duncan's multiple range tests (DMRT). Results : Statistically significant difference of microleakage was shown in the 3-month group compared with the1-day or 1-month group in both systems (p<0.05) and there were statistically significant differences in microleakage between the 3-month group and the 6-month group in both systems (p<0.05). The two systems showed different tendency in the course of increased microleakage during 3 months. In Panavia F, microleakage increased slowly throughout the periods. In Super-Bond C&B, there was no significant increase of microleakage for 1 month, but there was statistically significant increase of microleakage for the next 2 months. For the mean microleakage for each period, in the 3-month group, microleakage of Super-Bond C&B was significantly greater than that of Panavia F. On the other hand, in the 6-month group, microleakage of Panavia F was significantly greater than that of Super-Bond C&B (p<0.05). Conclusion: Within the limitation of this study, water retention of two different bonding systems influence microleakage of resin cements. Further studies with the longer observation periods in viro are required in order to investigate water stability and the bonding durability of the resin cement. CLINICAL IMPLICATIONS Microleakage at the Cement-tooth interfaces did not necessarily result in the failure of the crowns. But it is considered to be a major factor influening the longerity of restorations. Further clinical approaches for decreasing the amount of microleakage are required.

• Bulletin of the Korean Chemical Society
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• 제32권4호
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• pp.1253-1257
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• 2011

The surface structures, adsorption conditions, and thermal desorption behaviors of cyclopentanethiol (CPT) self-assembled monolayers (SAMs) on Au(111) were investigated by scanning tunneling microscopy (STM), X-ray photoelectron spectroscopy (XPS), and thermal desorption spectroscopy (TDS). STM imaging revealed that although the adsorption of CPT on Au(111) at room temperature generates disordered SAMs, CPT molecules at $50^{\circ}C$ formed well-ordered SAMs with a $(2{\surd}3{\times}{\surd}5)R41^{\circ}$ packing structure. XPS measurements showed that CPT SAMs at room temperature were formed via chemical reactions between the sulfur atoms and gold surfaces. TDS measurements showed two dominant TD peaks for the decomposed fragments ($C_5H_9^+$, m/e = 69) generated via C-S bond cleavage and the parent molecular species ($C_5H_9SH^+$, m/e = 102) derived from a recombination of the chemisorbed thiolates and hydrogen atoms near 440 K. Interestingly, dimerization of sulfur atoms in n-alkanethiol SAMs usually occurs during thermal desorption and the same reaction did not happen for CPT SAMs, which may be due to the steric hindrance of cyclic rings of the CPT molecules. In this study, we demonstrated that the alicyclic ring of organic thiols strongly affected the surface structure and thermal desorption behavior of SAMs, thus providing a good method for controlling chemical and physical properties of organic thiol SAMs.

• KSBB Journal
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• 제23권5호
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• pp.403-407
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• 2008

본 연구에서는 현재 산업적 응용이 활발하게 이루어지고 있고, 여러 장점을 지닌 효소인 Candida antarctica에서 유래된 lipase B (CalB)의 신속한 개질을 위해 취급이 용이한 E. coli를 이용하여 CalB 발현시스템을 구축하였다. E. coli 발현 시스템에서 효소활성을 지니지 못하는 내포체를 생성하는 단점을 지니고 있어, soluble한 형태의 CalB 생성을 위해 저온 발현이 가능한 pCold I vector와 단백질 접힘을 도와주는 chaperone을 사용하여 CalB를 발현하였다. Liu 등(17)은 E. coli Origami2와 B, 그리고 $DH5{\alpha}$를 실험한 결과, Origami 균주에서만 CalB에 의한 halo의 형성이 관찰되었으나, 동 연구에서는 실험한 3종의 균주와 5종의 chaperone plasmid중 Rosettagami와 $DH5{\alpha}$에서 groES/groEL chaperone이 CalB와 동시에 발현되면 soluble한 형태의 Cal B가 발현됨을 관찰할 수 있었다. 또한 신속한 CalB의 발현시스템을 구축하기 위해서는 유전자 조작의 용이성 및 안정성에서 우월한 $DH5{\alpha}$가 Rosettagami에 비해 soluble한 CalB의 발현에 더욱 적합한 균주임이 관찰되었다. 즉 재조합 pCold plasmid와 pGro7 plasmid (groES/groEL)로 형질이 전환된 $DH5{\alpha}$가 CalB 발현시스템에 가장 적합하다.