• 대한치과기공학회지
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• 제26권1호
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• pp.35-40
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• 2004

In order to understand alloying effects on the corrosion resistance of Ti-(10$\sim$20)%Zr-(2$\sim$8%)Nb-0.2%Pd alloys, Polarization curves were measured at 5%HCI solution. The results were interpreted in terms of two parameters obtained by the molecular orbital calculation ; one is the bond order($B_{\circ}$) and the other is the metal d-orbital level($M_{d}$). $B_{\circ}$ is a measure of the strength of covalent bonds between titanium and alloying elements. $M_{d}$ is correlative with the electronegativity of elements. It was found that increasing of Zr and Nb with higher $B_{\circ}$ values showed a lower critical anodic current density in the polarization curve and hence higher corrosion resistance. On the other hand, increasing of Zr and Nb with higher $M_{d}$ values showed a higher corrosion resistance.

• Bulletin of the Korean Chemical Society
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• 제35권2호
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• pp.383-391
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• 2014

Biotin-S-S-Phosphine was designed and synthesized as a potential tool for a proteomic study of O-GlcNAcmodified proteins. This reagent features a disulfide linker between a triarylphosphine moiety, which allows selective conjugation to azide-containing proteins, and a biotin moiety that can allow easy isolation through its strong affinity toward avidin-coated solid beads. The disulfide linkage within this reagent can allow the easy release of the bound molecules of interest, which is difficult to achieve when a biotin:avidin pair is used alone, by reducing the disulfide bond of the reagent with DTT. Preliminary in vitro biological assays with azidelabeled and unlabeled cell lysates and a pure protein Nup62 showed that the Biotin-S-S-Phosphine reagent is highly reactive toward the free thiol groups of proteins. When a molecular tool with a disulfide linker is applied to the enrichment of the molecules of interest from other species, it is important to block the free-thiols of the sample using exhaustive alkylation prior to the Staudinger ligation reactions to restore the bioorthogonal nature of this reaction.

• 한국표면공학회지
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• 제46권1호
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• pp.22-28
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• 2013

$WS_2$ particles were added to micro-diamond blades with Cu/Sn binding metal as lubricants to improve cutting efficiency. It was found in previous works that the added $WS_2$ lubricant could reduce remarkably the momentary energy consumption during dicing tests but increased wear rate slightly owing to weak bonding between lubricant particles and bond metals. In the present work, the surface of $WS_2$ lubricant particles were etched for activating the surface of $WS_2$ particles that provide even distribution of particles during powder mixing process and improvement of wetting at the interfaces between $WS_2$ particles and molten Cu/Sn bond metals during pressurized sintering so that could provide the improved strength of micro-blades and result in extended life. Chipping behavior of workpiece with the types of micro-blades including $WS_2$ were compared because it is important in semiconductor and micro-packaging industries to control average roughness and straightness of sliced surface which is closely related with quality.

• 콘크리트학회논문집
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• 제11권4호
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• pp.43-54
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• 1999

Shear tests are performed on four full-scale 12.5 m proto-type models, "least depth double tee," which are resulted from the optimization process. Domestic superimposed live load regulation, domestic material properties which is available to product. Korean building code requirements, construction environments and economy are considered as the main factors to establish the process. All of the specimens tested fully comply with the shear strength requirements as specified by ACI 318-95. The research has shown following results. 1) The development length requirement of ACI 318-95 does not seem a good predictor for the estimation of bond failure in a beam with the strands below the supports. 2) The load required for the first initial coner cracking in the dap end and first web shear cracking does not seem to have any relation with the dimension and shear strength of the section in the test beams. 3) The strand slip has a direct relationship with the web shear cracking. However, the coner cracking in the dap end does not give any help for the slip in anchorage. 4) Use of whole area for bearing steel at the bottom of dap end is desired for safe bearing pressure design in the precast prestressed double tee beams. 5) The deflection of beam influences directly on the amount of strand slip at the anchorage after initiation of it, and relationship between them are very linear.

• 한국구조물진단유지관리공학회 논문집
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• 제15권6호
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• pp.201-211
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• 2011

우리나라는 삼면이 바다로 이루어져 있으며 많은 철근콘크리트 구조물이 위치해 있다. 만약 철근콘크리트 구조물이 염해의 노출이 장기화 된다면 철근의 부식으로 인하여 철근-콘크리트 부착성능이 감소될 뿐만 아니라, RC 구조물의 성능저하가 우려되고 있다. 따라서 본 연구에서는 부착성능이 상실된 RC 보-기둥 접합부에 대한 기초자료를 확보하기 위해 연구를 수행하였다. 철근-콘크리트 부착이 상실된 보-기둥 접합부를 제작하여 부착 및 비부착 특성 여부에 따라 반복 횡하중 실험 및 해석적 연구를 수행하여 접합부의 성능을 평가 및 고찰하였다.

• 비파괴검사학회지
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• 제21권2호
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• pp.163-168
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• 2001

접착제와 리벳으로 접합된 항공기 판재의 접합부는 접합 불량, 크랙, 피로 결함이나 부식등에 의해 손상되고 열화될 수 있으며 이런 결함을 전 영역에 걸쳐서 신속하고도 신뢰성 있게 검사하는 것은 항공기 안전을 위해 매우 중요하다. 본 연구에서는 이를 위해 항공기용 알루미늄 판재의 랩 스플라이스 접합 연결부의 접합 품질을 비접촉 방식으로 수행할 수 있는 초음파 비파괴 평가법을 제안한다. 여기서는 레이저를 이용해 램파를 발생시키고 비접촉식 트랜스듀서 (공기정합 용량형 트랜스듀서)를 이용해 피치-캐치 방식으로 검사한다. 레이저 소스로는 Q-스위치된 Nd:YAG 레이저가 이용되며 배열 형태의 직선 슬릿을 갖는 마스크를 이용해 특정 모드의 램파를 발생시켜 이용하였다. 접합부의 한 쪽에서 발생된 레이저 여기 초음파는 판을 따라 전파하여 접합부를 지나 반대편에서 수신되고 수신된 신호의 특성과 접합부의 품질과의 관련성을 조사하였다.

• 한국도로학회논문집
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• 제19권6호
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• pp.129-137
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• 2017

PURPOSES : The purpose of this study is to develop bridge deck concrete materials based on ordinary Portland cement concrete, and to evaluate the applicability of the developed materials through material properties tests. METHODS : For field implementation, raw material (cement, fine aggregate, and coarse aggregate) properties, fresh concrete properties (slump and air content), strength (compressive, flexural and bond strength) gain, and durability (freeze-thaw resistance, scaling resistance, and rapid chloride penetrating resistance) performance were evaluated in the laboratory. RESULTS : For the selected binder content of $410kg/m^3$, W/B = 0.42, and S/a = 0.48, the following material performance results were obtained. Considering the capacity of the deck finisher, a minimum slump of 150 mm was required. At least 6 % of air content was obtained to resist freeze-thaw damage. In terms of strength, 51.28 MPa of compressive strength, 7.41 MPa of flexural strength, and 2.56 MPa of bond strength at 28 days after construction were obtained. A total of 94.9 % of the relative dynamic modulus of elasticity after 300 cycles of freeze-thaw resistance testing and $0.0056kg/m^2$ of weight loss in a scaling resistance test were measured. However, in a chloride ion penetration resistance test, the result of 3,356 Coulomb, which exceeds the threshold value of the standard specification (1000 Coulomb at 56 days) was observed. CONCLUSIONS : Instead of using high-performance modified bridge deck materials such as latex or silica fume, we developed an optimum mix design based on ordinary Portland cement concrete. A test construction was carried out at ramp bridge B (bridge length = 111 m) in Gim Jai City. Immediately after the concrete was poured, the curing compound was applied, and then wet mat curing was applied for 28 days. Considering the fact that cracks did not occur during the monitoring period, the applicability of the developed material is considered to be high.

• 마이크로전자및패키징학회지
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• 제26권4호
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• pp.89-94
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• 2019

전력저장용 전기에너지 저장장치의 일종인 NaS 전지 단위 셀을 개발함에 있어서 알파-알루미나 절연세라믹 캡과 베타-알루미나 전해질 튜브 간의 세라믹-세라믹 상호 접합을 위하여 글라스 기반의 실링소재가 필요하다. 본고에서는 이 세라믹-세라믹 접합용 글라스 실링 페이스트를 제조함에 있어서, 열간 칭법에 의한 글라스 프릿 제조와 상분석, 분말입도 분석 및 글라스 조성에 따른 열팽창계수 변화 및 표면거칠기를 분석하였다. 또한 글라스 실란트의 접합력 평가를 위해 종래 솔더 볼 조인트의 접합력 평가용 분석장비인 Dage bond tester를 이용하여 세라믹-세라믹 컴포넌트의 작은 접합면에 대한 접합력 측정 방법을 제안하였다.

• Computers and Concrete
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• 제14권4호
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• pp.387-403
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• 2014

The aim of this study is to assess the structural performance of deteriorated reinforced concrete bridge piers, and to provide method for developing improved evaluation method. For a deteriorated bridge piers, once the cover spalls off and bond between the reinforcement and concrete has been lost, compressed reinforcements are likely to buckle. By using a sophisticated nonlinear finite element analysis program, the accuracy and objectivity of the assessment process can be enhanced. A computer program, RCAHEST (Reinforced Concrete Analysis in Higher Evaluation System Technology), is used to analyze reinforced concrete structures. Material nonlinearity is taken into account by comprising tensile, compressive and shear models of cracked concrete and a model of reinforcing steel. Advanced deteriorated material models are developed to predict behaviors of deteriorated reinforced concrete. The proposed numerical method for the structural performance assessment of deteriorated reinforced concrete bridge piers is verified by comparing it with reliable experimental results. Additionally, the studies and discussions presented in this investigation provide an insight into the key behavioral aspects of deteriorated reinforced concrete bridge piers.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2004년도 춘계 학술발표회 제16권1호
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• pp.240-243
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• 2004

A new shear connection for the application of precast decks to PSC girders was proposed and push-off tests were conducted to evaluate the horizontal shear strength of the shear connection. Major parameters of the tests were connector type, shank area, vertical load, surface condition and bedding height. Judging from the test results, shear strength of the suggested shear connection was proportional to the shank area and yield strength of the connectors and was in inverse proportion to the bedding height. Shear connection with shear key at the surface showed better performance. An empirical equation for the evaluation of the shear strength of the shear connection without considering bond strength was proposed and it showed good correlation with the test results.