• Title/Summary/Keyword: blue pigment

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Synthesis and Characteristic of ${\epsilon}$-type Copper Phthalocyanine Used as Color Filter in LCD Panel (입실론 프탈로시아닌의 합성 및 특성에 대한 연구)

  • Kim, Jae Hwan;Kim, Song Hyuk;Kim, Seong Jin;Hong, Seong-Soo;Lee, Gun-Dae;Park, Seong Soo
    • Applied Chemistry for Engineering
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    • v.23 no.2
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    • pp.138-142
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    • 2012
  • The ${\epsilon}$ type copper phthalocyanine (${\epsilon}$-CuPc), called as a pigment blue 15 : 6, is a significant material to produce a blue pixel in LCD (Liquid Crystal Display) panel. In this study, ${\epsilon}$-CuPc sample was synthesized at various reaction conditions by applying the seed method using ${\epsilon}$-CuPc nanoparticles as a seed. Adequate synthetic conditions of the samples were selected by analyzing and comparing crystalline structure, crystalline purity, microstructure, and synthetic yield of the samples with ${\alpha}$ and ${\beta}$ crystalline CuPc samples. The chemical and crystalline structure of the samples were tested using FT-IR spectrometer and X-ray diffractometry, respectively. The shape of the particle was examined using field emission scanning electiron microscope while the thermal property was tested utilizing thermogravimetric analysis.

Interpretation of Coloring Materials Recorded in Ceremonial Writing of the Hanging Painting of Chiljangsa Temple (Five Buddhas) (칠장사 오불회 괘불탱 화기에 기록된 채색 재료의 해석)

  • Lee, Eun Woo;Yoon, Ji Hyeon;Kwon, Yoon Mi;Shin, Tae Ho
    • Journal of Conservation Science
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    • v.36 no.6
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    • pp.519-532
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    • 2020
  • This study aimed to interpret the coloring materials recorded in the ceremonial writing with the scientific investigation results of the Hanging Painting of the Chiljangsa Temple (Five Buddhas). The results confirm that the Jinboon, Joohong, Hwangdan, Hwanggeum and Seokjahwang are clearly connected to lead white, cinnabar, minium, gold, and orpiment, respectively. Danghayeop and samrok are related to Copper trihydroxychloride, while Daecheong and Joongcheong are azurite, and they seems to be classified by the particle size. Yeonji and Chunghwa are organic dyes in red and blue, respectively, with blue confirming the existence of the side, but Yeonji differs from the names of the ancient texts and Chinese characters; it is unclear whether it is a commonly used Yeonji because of differences in the names of the ancient texts. The presence of Sootohwang has not been confirmed in the gwaebultaeng, but it can be extracted from the soil as a yellow-colored material but the possibility of Deunghwang cannot be ruled out.

Conjugal Transfer of Plasmid DNA from Escherichia coli to Streptomyces lavendulae RFI-5

  • KITANI, SHIGERU;BIBB, MERVYN J.;NIHIRA, TAKUYA;YAMADA, YASUHIRO
    • Journal of Microbiology and Biotechnology
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    • v.10 no.4
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    • pp.535-538
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    • 2000
  • Streptomyces lavendulae FRI-5 produces the ${\gamma}$-butyrolactone autoregulator IM-2, which is required for nucleoside antibiotic producetion. We have developed a system for introducing DNA into S. lavendule FRI-5 via conjugal transfer from Esherichia cole. Conditions were established for conjugation of the oriT-and attP-containing plasmid pSET152 from E. coli ET12567 (pUZ8002) to FRI-5. Conjugation resulted in integration of the plasmid at the chromosomal C31 attB site. The frequency of intergeneric conjugation varied with the medium used. The highest frequency ($1.6\times10-5$ per recipient) was obtained on ISP medium 2 containing 10mM MgCl2. Southern blot and phenotypic analyses of exconjugants revealed that S. lavendulae FRI-5 contains a unique C31 attB site, and that integration of heterologous DNA into the attB site did not interfere with morphological differentiation or IM-2-dependent signal transduction, including the production of a blue pigment. This system will now enable detailed genetic analysis of the regulation of antibiotic production in S. lavendulae FRI-5.

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Enhancement of Mucosal Immune Functions by Dietary Spirulina platensis in Human and Animals

  • Osamu Hayashi;Kyoko Ishii;Chinami Kawamura;Hei, Shi-Yen;Bao, Ning-Ye;Tomohiro Hirahashi;Toshimitsu Katoh
    • Nutritional Sciences
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    • v.7 no.1
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    • pp.31-34
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    • 2004
  • This paper reviews the effects of Spirulina platensis and its extracts and phycocyanin, a blue photosynthetic pigment protein in Spirulina on the mucosal immune functions in humans and animals as follows: TEX>$\bullet$ IgA antibody response and other classes in mucosal immunity of mice treated with Spirulina platensis and its extract. $\bullet$ Effect of Spirulina phycocyanin ingestion on the mucosal antibody responses in mice. - Distinct effects of phycocyanin on secretory IgA and allergic IgE antibody responses in mice following oral immunization with antigen-entrapped biodegradable microparticles. $\bullet$ Influence of dietary Spirulina platensis on IgA level in human saliva. $\bullet$ A study on enhancement of bone-marrow cell-proliferation and differentiation by Spirulina platensis in mice: in vivo and in vitro study

Design of Optical Biological Sensor for Phycocyanin Parameters Measurement using Fluorescence Technique

  • Lee, Sung Hwa;Mariappan, Vinayagam;Won, Dong Chan;Ann, Myungsuk;Yang, Seungyoun
    • International journal of advanced smart convergence
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    • v.5 no.2
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    • pp.73-79
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    • 2016
  • Remote sensing and measurement are of paramount importance of providing information on the state of water quality in water bodies. The formation and growth of cyanobacteria is of serious concern to in land aquatic life forms and human life. The main cause of water quality deterioration stems from anthropogenic induced eutrophication. The goal of this research to quantify and determine the spatial distribution of cyanobacteria concentration in the water using remote sensing technique. The standard approach to measure water quality based on the direct measurement of the fluorescence of the chlorophyll a in the living algal cells and the same approach used to detect the phycobilin pigments found in blue-green algae (a.k.a. cyanobacteria), phycocyanin and phycoerythrin. This paper propose the emerging sensor design to measure the water quality based on the optical analysis by fluorescence of the phycocyanin pigment. In this research, we developed an method to sense and quantify to derive phycocyanin intensity index for estimating cyanobacteria concentrations. The development of the index was based on the reflectance difference between visible light band 620nm and 665nm. As a result of research this paper presents, an optical biological sensor design information to measure the Phycocyanin parameters in water content.

Suspension Stability of Pigments in Aqueous Solution of Anionic Oligo-Type Surfactants(part 3);Synthesis of Anionic Oligo Surfactant having Fluorescent Intensity and Their Properties (올리고머형 음이온성계면활성제 수용액에서 안료의 분산안정성(제 3보);형광성이 큰 올리고머 계면활성제의 합성 및 그의 계면성)

  • Lee, H.W.;Lee, J.H.;Ju, M.J.;Nam, K.D.
    • Journal of the Korean Applied Science and Technology
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    • v.14 no.1
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    • pp.109-115
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    • 1997
  • Fluorescent anionic oligo surfactants were synthesized by the condensing products of long chain alkylvinylether-maleic anhydride cooligomers and resorcinol including dye structures. Their various surface activities and dispersing action were studied on the aqueous solution. These oligo surfactants exhibited a remarkable surface tension lowering property, lower foaming and a large dispersing action for the particles of ${\alpha}-copper$ phthalocyanine blue. Further it was ascertained that the binding of oligo surfactant onto the pigment surface caused the deviation towards lower wavelengths at the maximum fluorescent intensity as compared with aqueous oligo surfactant solutions, These surface active properties of the oligo surfactants may be attributed to rigid and hydrophobic structure of dye groups, besides surface-active groups of alkylether groups and carboxylic group of the anionic oligo surfactants.

Investigation on the Photooxidation of Pigment in Leaf-Burning Disease of Panax ginseng 1. Phenomenological observation and analysis on the chlorophyll bleaching phenomenon (인삼 엽소병에서 색소의 광산화작용에 관한 연구 1. Chlorophyll bleaching의 현상학적 연구)

  • Yang, Deok-Jo;Yu, Hui-Su;Yun, Jae-Jun
    • Journal of Ginseng Research
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    • v.11 no.2
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    • pp.91-100
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    • 1987
  • This study was investigated and analyzed the side of phenomenological of the chlorophyll bleaching phenomenon on the leaf burning-disease of the Ginseng (Panax ginseng C.A. Meyer) leaf. Red light (660-700 nm) was confirmed as one which induced the bleaching phenomenon and blue light (400-500 nm) did not at all. Temperature as 1 environmental factor had not any influence on chlorophyll bleaching phenomenon at all. Therefore, simple burning (thermal damage) hypothesis was perfectly ruled out by the result of this study. And, low pH accelerated chlorophyll bleaching velocity. A primary factor of chlorophyll bleaching phenomenon may be peculiar structural difference of the Ginseng leaf compared with other plant.

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Scientific Analysis of the Historical Characteristics and Painting Pigments of Gwaebultaeng in Boeun Beopjusa Temple (보은 법주사 <괘불탱>의 미술사적 특징과 채색 안료의 과학적 분석 연구)

  • Lee, Jang-jon;Gyeong, Yu-jin;Lee, Jong-su;Seo, Min-seok
    • Korean Journal of Heritage: History & Science
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    • v.52 no.4
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    • pp.226-245
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    • 2019
  • Beopjusa Gwaebultaeng (Large Buddhist Painting), designated as Treasure No. 1259, was painted in 1766 and featured Yeorae (Buddha) at the center in the style of a single figure. It is the longest existing buddhist painting and was created by Duhun, a painter who was representative of 18th century Korean artists. His other remaining work is Seokgayeorae Gwaebultaeng (1767) in Tongdosa Temple. Considering their same iconography, they are assumed to have used the same underdrawing. Duhun had a superb ability to maintain a consistent underdrawing, while most painters changed theirs within a year. The Beopjusa painting carries significance because it was not only painted earlier than the one in Tongdosa, but also indicates possible relevance to the royal family through its records. Beopjusa Temple is also the site of Seonhuigung Wondang, a shrine housing the spirit tablet of Lady Yi Youngbin, also known as Lady Seonhui. Having been built only a year before Beopjusa Gwaebultaeng was painted, it served as a basis for the presumption that it has a connection to the royal family. In particular, a group of unmarried women is noticeable in the record of Beopjusa painting. The names of some people, including Ms. Lee, born in the year of Gyengjin, are recorded on the Bonginsa Temple Building, the construction of which Lady Yi Youngbin and Princess Hwawan donated money to. In this regard, they are probably court ladies related to Lady Yi Youngbin. The connection of Beopjusa Gwaebultaeng with the royal family is also verified by a prayer at the bottom of the painting, reading "JusangJusamJeonhaSumanse (主上主三殿下壽萬歲, May the king live forever)." While looking into the historical characteristics of this art, this study took an approach based on scientific analysis. Damages to Beopjusa Gwaebultaeng include: bending, folding, wrinkles, stains due to moisture, pigment spalling, point-shaped pigment spalling, and pigment penetration to the lining paper at the back. According to the results of an analysis of the painting pigments, white lead was used as a white pigment, while an ink stick and indigo were used for black. For red, cinnabar and minium were used independently or were combined. For purple, organic pigments seem to have been used. For yellow, white lead and gamboge were mixed, or gamboge was painted over white lead, and gold foil was adopted for storage. As a green pigment, atacamite or a mixture of atacamite and malachite was used. Azurite and smalt were used separately or together as blue pigments.

The Effect of Blue Light Interception and SPF Boosting of Sunscreen Prepared with Bandgap-controlled TiO2 (밴드갭이 제어된 TiO2 를 이용한 자외선 차단제의 블루라이트 차단 및 SPF 부스팅 효과)

  • Sung Eun Wang;Jung Kyung Yoon;Gui Su Chung;Sung Bong Kye;Ho Sik Rho;Dae Soo Jung
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.49 no.2
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    • pp.159-167
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    • 2023
  • Titanium dioxide (TiO2) is commonly used in sunscreen formulations to protect the skin surface and prevent the penetration of harmful ultraviolet (UV) rays by the physical scattering action of light. However, a disadvantage of using TiO2 is that it can cause white turbidity when used on skin due to its inactive mineral ingredient. In addition, when TiO2 particles are reduced to nanosize to eliminate opacity, they can increase the transmittance of visible light and reduce whitening, but may lead to serious skin problems, such as allergic inflammation. To overcome these issues, the bandgap of TiO2 was controlled by adjusting the amount of oxygen defect and nitrogen amount, resulting in color TiO2 tailored to the skin. This innovative technology can reduce the whitening phenomenon and effectively block blue light, which is known to cause skin aging by inducing active oxygen. The bandgap controlled TiO2 compounds proposed in this study are hypoallergenic, broad-spectrum, and environmentally friendly. Furthermore, these compounds have been shown to significantly enhance sun protection factor (SPF) of sunscreens, demonstrating their compatibility with blue light blocking products.

Metal Concentrations Analysed in the Inorganic Bulk Pigment Samples by ICP-AES and the Provision Rate of MSDS and Agreement Rate with MSDS (우리 나라에서 제조/사용하는 일부 무기 안료중 ICP-AES를 이용한 주요 중금속 농도와 MSDS 비치율 및 일치율 비교)

  • Kim, Hyoung-Ah;Lee, Kyoung-Joo;Kim, Yong-Woo;Kim, Hyun Wook
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.8 no.2
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    • pp.196-208
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    • 1998
  • To improve the quality of environmental measurements and evaluation of the workplace air in the pigment manufacturing industries, we analyzed metal(chromium, cadmium, lead, iron, cobalt, manganese, antimony, titanium, arsenic, and selenium) concentrations by ICP-AES in sixty seven samples of inorganic bulk pigments which are produced and/or used in Korea. We also collected MSDS which has to be supplied by manufacturer and/or supplier and posted in the workplace according to the Hazard Communication Standards, and compared the number of metals listed in each MSDS with the number of metals determined by ICP-AES. Results were as followed; 1. Among seventeen yellowish-colored samples, chromium(2~19%) and lead(0.1~61%) were the two major metals. In thirteen reddish-colored samples, iron was the major component with 37~81%. Cobalt and manganese were detected in blue-colored samples with less than 1%, while antimony and titanium were the major two metals in white-colored pigments with 178~300 ppm and with 36~65%, respectively. 2. In area samples collected in workplace air(one pigments producing factory and five retailer stores), iron and manganese were detected but the concentrations not exceeded the TLVs(1 and $5mg/m^3$, respectively). In three of fifteen samples, the concentrations of lead exceeded the TLV ($0.05mg/m^3$). 3. Two out of seven companies provided MSDS, and the average provision rate was 22.4%. And the coincidence rate of the number of metals referenced in MSDS and determined by ICP-AES mostly accorded, but in one sample, different metal was detected from MSDS. In summary, metals have to be concerned in evaluation of the workplace air dealing with compounds of inorganic pigments dust are cobalt, chromium, iron, manganese, lead and antimony, and these are simultaneously determined by ICP-AES. Taking this opportunity, it is needed to reinforce that the personnel is to be concerned about prevention of workers' ill health regarding to provision of MSDS.

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