• Title/Summary/Keyword: bismuth nitrate

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Protective Mechanism of Bismuth Nitrate Against Gentamicin Nephrotoxicity (질산비스마스의 겐타마이신 신독성 경감기전)

  • Kim, Jung-Sun;Chung, Hae-Young;Rho, Young-Jae;Lee, Sang-Rok
    • YAKHAK HOEJI
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    • v.36 no.6
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    • pp.570-576
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    • 1992
  • The treatment with gentamicin in the presence of pretreatment with bismuth nitrate significantly reduced blood urea nitrogen compared with given gentamicin alone. But the amelioration of gentamicin-induced nephrotoxicity by bismuth nitrate was abolished by pretreatment with indomethacin that is cyclooxygenase inhibitor, which significantly decreased renal glutathione S-transferase activity and thiobarbituric acid reactive substance compared with mice of given gentamicin and bismuth nitrate. On the other hand, treatment with bismuth nitrate significantly increased prostaglandin $E_2$ production in rat kidney slice. These results suggest that bismuth nitrate might ameliorate the nephrotoxicity of gentamicin via prostaglandin $E_2$ production.

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질산염이 Saccharomyces cerevisiae의 발효작용에 미치는 영향

  • 김상준
    • Proceedings of the Korean Society for Applied Microbiology Conference
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    • 1979.04a
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    • pp.115.3-115
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    • 1979
  • 중금속을 함유한 13종의 질산염을 명 농도별로 첨가하여 주정효모 Saccharomyces cerevisine의 주정생산과 발효작용에 미치는 영향을 조사하였다. 1. 일반적으로 중금속을 함유한 질산염은 그 첨가량이 0.0001mo1. 보다 고농도일수록 Saccharo-myces cerevisiae의 발효작용을 점차 억제하였다. 2. Nickel nitrate, chromium nitrate들의 0.0001 moi.의 첨가는 Saccharomyces cerevisiae의 alcohol 발효작용을 약간촉진시켰다. 3. Cadmium nitrate 0.001mo1. 이상, cupric nit-rate, nickel nitrate, cobalt nitrate 0.01mo1. 이상, 그리고 silver nitrate, mercurous nitrate, manganese nitrate, zinc nitrate, lead nitrate, chromiun nitrate, ferric nitrate, bismuth nitrate 0.1mol. 의 농도에서 Saccharomyces cerevisiae 의 발효작용은 완전히 조지되었다.

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Preparation of Bismuth Vanadate Pigment from Aqueous Solutions (습식법에 의한 Bismuth Vanadate 안료의 제조)

  • Kim, Jung-Teag;Kim, Tae-Won;Heo, Jea-Jun;Na, Seog-Eun;Joo, Jung-Pyo;Chun, Jae-Ki;Ju, Chang-Sik
    • Korean Chemical Engineering Research
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    • v.44 no.2
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    • pp.114-120
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    • 2006
  • Bismuth vanadate is one of the environmentally benign substitutes for conventional inorganic pigments composed of heavy metals. The effect of process parameters on the physical properties of bismuth vanadate pigment prepared from aqueous solutions of potassium vanadate and bismuth nitrate were experimentally examined. Two aqueous solutions were fed into precipitation chamber at the same flow rate, and precipitates were formed at primary pH of 4.5 and secondary pH of 7.0~7.5. After aging for 3 hours in reaction mixture, 3 hours' calcination at $400^{\circ}C$ gave bismuth vanadate pigment with a good color and hiding power. Increase in molybdenum concentration in reaction mixture increased the hiding power of the pigment, but the other minor constituents had minor effect on the physical properties of the pigment.

Study on preparation and characterization of uniform bismuth nanospheres

  • Ji, Nianjing;Li, Ziqing;Chen, Yang;Wang, Jiyang;Duan, Xiulan;Jiang, Huaidong
    • Journal of Ceramic Processing Research
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    • v.19 no.5
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    • pp.369-371
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    • 2018
  • The uniform and monodisperse bismuth nanospheres were successfully prepared by simple and convenient solvothermal method. The bismuth nitrate was reduced by ethylene glycol at $150-200^{\circ}C$ for 20-30 hrs. The nanospheres were characterized by powder X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The dispersivity of bismuth nanospheres was investigated using optical microscope. The optimum reaction conditions to prepare the uniform bismuth nanospheres with a narrow diameter range was investigated. The results indicate that the monodisperse bismuth nanospheres prepared at $200^{\circ}C$ possess sizes ranging from 100-200 nm. The formation mechanism of the bismuth nanospheres was hypothesized.

Photocatalytic study of Zinc Oxide with bismuth doping prepared by spray pyrolysis

  • Lin, Tzu-Yang;Hsu, Yu-Ting;Lan, Wen-How;Huang, Chien-Jung;Chen, Lung-Chien;Huang, Yu-Hsuan;Lin, Jia-Ching;Chang, Kuo-Jen;Lin, Wen-Jen;Huang, Kai-Feng
    • Advances in nano research
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    • v.3 no.3
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    • pp.123-131
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    • 2015
  • The unintentionally doped and bismuth (Bi) doped zinc oxide (ZnO) films were prepared by spray pyrolysis at $450^{\circ}C$ with zinc acetate and bismuth nitrate precursor. The n-type conduction with concentration $6.13{\times}10^{16}cm^{-3}$ can be observed for the unintentionally doped ZnO. With the increasing of bismuth nitrate concentration in precursor, the p-type conduction can be observed. The p-type concentration $4.44{\times}10^{17}cm^{-3}$ can be achieved for the film with the Bi/Zn atomic ratio 5% in the precursor. The photoluminescence spectroscopy with HeCd laser light source was studied for films with different Bi doping. The photocatalytic activity for the unintentionally doped and Bi-doped ZnO films was studied through the photodegradation of Congo red under UV light illumination. The effects of different Bi contents on photocatalytic activity are studied and discussed. Results show that appropriate Bi doping in ZnO can increase photocatalytic activity.

Hydrothermal Synthesis of Metal-doped BiVO4 Powder and its Thermochromic Properties (금속이 도핑된 BiVO4 분말의 수열 합성 및 이의 열 변색 특성)

  • Wu, Guan Zhu;Son, Dae Hee;Jin, Young Eup;Lee, Gun-Dae;Park, Seong Soo
    • Applied Chemistry for Engineering
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    • v.26 no.6
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    • pp.681-685
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    • 2015
  • In this study, pure $BiVO_4$ powder and metal-doped $M-BiVO_4$ (M = Mg, Cu) powder, well known as thermochromic materials, were prepared from a mixed aqueous solution of bismuth nitrate ($Bi(NO_3)_3$) and ammonium vanadate ($NH_4VO_3$) in autoclave by hydrothermal method. The crystal structure, microstructure, and thermochromic property of samples were analyzed using FE-SEM, FT-IR, XRD, DSC, UV-Vis-NIR spectroscopy and colorimeter. When heating samples above phase transition temperature, the color of $M-BiVO_4$ (M = Mg, Cu) sample was thermally changed more clearly than that of using only pure $BiVO_4$ sample.

Properties of Bismuthoxynitrate as a Synthetic Pearl Pigment (인공 진주 안료로서 염기성 질산비스무트에 관한 연구)

  • 이계주;유병설
    • YAKHAK HOEJI
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    • v.22 no.1
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    • pp.22-26
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    • 1978
  • The purposes of this investigation were to study the characteristic properties of bismuthoxynitrate formed by hydrolysis of bismuthnitrate according to various reaction conditions and to propose the property difference between synthesized pearl pigment and bismuthsubnitrate as pharmaceuticals by means of X-ray diffraction, IR, DTA and TGA. The pearl pigment could be obtained by reaction of bismuth nitrate-diluted nitric acid solution with cold water (5.deg.) agitation at lower pH. The pearl pigment was BiO. NO$_{3}$. 2H$_{2}$O. in composition and crystalline form was thin plate of monoclinic system and its combination with water was assumed to be hydrated hydrous form between Bi-H$_{2}$O bond. On the other hand, bismuthsubnitrate was 5BiO.4NO$_{3}$.6H$_{2}$O in composition and crystalline form was pillar of rhombic system and the bond between Bi and H$_{2}$O molecules was assumed to be hydrous form. The different properties between two compounds in structure are presumed to be caused by the hydrolysing conditions of bismuthnitrate respectively.

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Fabrication and Characterization of BixCel-xO2-x/2 Electrolytes for IT-SOFC (중온형 고체산화물 연료전지BixCel-xO2-x/2 전해질의 제조 및 특성평가)

  • Han, Ju-Hyeng;Lee, In-Sung;Lee, Dokyol
    • Journal of the Korean Ceramic Society
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    • v.42 no.12 s.283
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    • pp.808-815
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    • 2005
  • [ $Bi_xCe_{l-x}O_{2-x/2}$ ](BD C : Bismuth Doped Ceria) powders with x = 0.1, 0.2, and 0.3 were synthesized using the Glycine Nitrate Process (GNP). They were then calcined at $500^{\circ}C$ for 2 hand sintered in a pellet or rod form at 900, 1000 or $1100^{\circ}C$ for 4 h for characterization as the alternative electrolyte material for intermediate temperature solid oxide fuel cells. The BDC powder consisted of a single phase of $CeO_2-Bi_2O_3$ solid solution in the as-synthesized state as well as in the as-calcined state with a mean powder size of 4.5nm in the former state and 6.5 - 10.1nm in the latter. On the contrary, the second phase of $\alpha-Bi_2O_3$ was observed to have been formed in the sinter with its amount increasing roughly with increasing temperature or $Bi_2O_3$ content. The BOC powder was superior in sinterability to other alternative electrolyte materials such as GDC, ScSZ, and LSGM with the minimum sintering temperature for a relative density of $95\%$ or larger as low as $1100^{\circ}C$. The ionic conductivity of BOC increased with $Bi_2O_3$ content and the maximum value of 0.119 S/cm was obtained at $800^{\circ}C$ for $Bi_{0.3}Ce_{0.7}O_{1.85}$.

Catalytic Activity of BiVO4-graphene Nanocomposites for the Reduction of Nitrophenols and the Photocatalytic Degradation of Organic Dyes

  • Li, Jiulong;Ko, Jeong Won;Ko, Weon Bae
    • Elastomers and Composites
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    • v.51 no.3
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    • pp.240-249
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    • 2016
  • $BiVO_4$ nanomaterial was synthesized from bismuth (III) nitrate pentahydrate [$Bi(NO_3)_3{\cdot}5H_2O$] and ammonium vanadate (V) [$NH_4VO_3$]. The $BiVO_4$-graphene nanocomposite was fabricated by calcining the $BiVO_4$ nanomaterial and graphene under an oxygen-free atmosphere at $700^{\circ}C$. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were employed to characterize structural and morphological properties of samples. The catalytic activity of the $BiVO_4$-graphene nanocomposite was studied for the reduction of 4-nitrophenol, 3-nitrophenol and 2-nitrophenol by sodium borohydride [$NaBH_4$]. The photocatalytic activity of the $BiVO_4$-graphene nanocomposite was demonstrated by the degradation of organic dyes like BG, MB, MO and RhB under irradiation at 365 nm. The catalytic and photocatalytic activity were studied by UV-vis spectrophotometry.