• Title/Summary/Keyword: bipolar thermal conductivity

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Characterization of Lattice Thermal Conductivity in Semiconducting Materials (반도체 재료의 격자열전도도 분석)

  • Lim, Jong-Chan;Yang, Heesun;Kim, Hyun-Sik
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.4
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    • pp.61-65
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    • 2020
  • Suppressing lattice thermal conductivity of thermoelectric materials is one of the most popular approach to improve their thermoelectric performance. However, accurate characterization of suppressed lattice thermal conductivity is challenging as it can only be acquired by subtracting other contributions to thermal conductivity from the total thermal conductivity. Here we explain that electronic thermal conductivity (for all materials) and bipolar thermal conductivity (for narrow band gap materials) need to be determined accurately first to characterize the lattice thermal conductivity accurately. Methods to calculate Lorenz number for electronic thermal conductivity (via single parabolic model and using a simple equation) and bipolar thermal conductivity (via two-band model) are introduced. Accurate characterization of the lattice thermal conductivity provides a powerful tool to accurately evaluate effect of different defect engineering strategies.

The thermal conductivity analysis of the SOI LIGBT structure using $Al_2O_3$ ($Si/Al_2O_3/Si$ 형태의 SOI(SOS) LIGBT 구조에서의 열전도 특성 분석)

  • Kim, Je-Yoon;Kim, Jae-Wook;Sung, Man-Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.163-166
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    • 2003
  • The electrothermal simulation of high voltage LIGBT(Lateral Insulated Gate Bipolar Transistor) in thin Silicon on insulator (SOI) and Silicon on sapphire (SOS) for thermal conductivity and sink is performed by means of MEDICI. The finite element simulations demonstrate that the thermal conductivity of the buried oxide is an important parameter for the modeling of the thermal behavior of silicon-on-insulator (SOI) devices. In this paper, using for SOI LIGBT, we simulated electrothermal for device that insulator layer with $SiO_2\;and\;Al_2O_3$ at before and after latch up to measured the thermal conductivity and temperature distribution of whole device and verified that SOI LIGBT with $Al_2O_3$ insulator had good thermal conductivity and reliability

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The thermal conductivity analysis of the SOI/SOS LIGBT structure (Latch up 전후의 SOI(SOS) LIGBT 구조에서의 열전도 특성 분석)

  • Kim, Je-Yoon;Kim, Jae-Wook;Sung, Man-Young
    • 한국컴퓨터산업교육학회:학술대회논문집
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    • 2003.11a
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    • pp.79-82
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    • 2003
  • The electrothermal simulation of high voltage LIGBT(Lateral Insulated Gate Bipolar Transistor) in thin Silicon on insulator (SOI) and Silicon on sapphire (SOS) for thermal conductivity and sink is performed by means of MEDICI. The finite element simulations demonstrate that the thermal conductivity of the buried oxide is an important parameter for the modeling of the thermal behavior of silicon-on-insulator (SOI) devices. In this paper, using for SOI LIGBT, we simulated electrothermal for device that insulator layer with $SiO_2$ and $Al_2O_3$ at before and after latch up to measured the thermal conductivity and temperature distribution of whole device and verified that SOI LIGBT with $Al_2O_3$ insulator had good thermal conductivity and reliability.

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The Analysis of Electrothermal Conductivity Characteristics for SOI(SOS) LIGBT with latch-up

  • Kim, Je-Yoon;Hong, Seung-Woo;Park, Sang-Won;Sung, Man-Young;Kang, Ey-Goo
    • Transactions on Electrical and Electronic Materials
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    • v.5 no.4
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    • pp.129-132
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    • 2004
  • The electrothermal characteristics of a high voltage LIGBT(Lateral Insulated Gate Bipolar Transistor) using thin silicon on insulator (SOI) and silicon on sapphire (SOS) such as thermal conductivity and sink is analyzed by MEDICI. The device simulations demonstrate that the thermal conductivity of the buried oxide is an important parameter for modeling of the thermal behavior of SOI devices. In this paper we simulated the thermal conductivity and temperature distribution of a SOI LIGBT with an insulator layer of SiO$_2$ and $Al_2$O$_3$ at before and after latch-up and verified that the SOI LIGBT with the $Al_2$O$_3$ insulator had good thermal conductivity and reliability.

Forming of Metallic Bipolar Plates by Dynamic Loading (Dynamic Load를 이용한 박막 금속 분리판 성형기술)

  • Koo, J.Y.;Kang, C.G.
    • Transactions of Materials Processing
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    • v.21 no.1
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    • pp.5-12
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    • 2012
  • The weight of the bipolar plate is one of the crucial aspects of improving power density in PEMFC stacks. Aluminum alloys have good mechanical properties such as density, electrical resistivity, and thermal conductivity. Furthermore, using aluminum in a bipolar plate instead of graphite reduces the bipolar plate cost and makes machining easier. Therefore in this study, an aluminum alloy was selected as the appropriate material for a bipolar plate. Results from feasibility experiments with the aim of developing fuel cells consisting of Al bipolar plates with multiple channels are presented. Dynamic loading was applied and the formability of micro channels was estimated as a function of punch pressure and die radius. Sheets of Al5052 with a thickness of 0.3mm were used. For a die radius of 0.1mm the formability was optimized with a sine wave dynamic load of 90kN at maximum pressure and 5 cycles of a sine wave punch travel. The experimental results demonstrate the feasibility of the proposed manufacturing technique for producing bipolar plates.

Development of high durable metallic bipolar plate for Polymer Electrolyte Membrane Fuel Cells (고분자 전해질 연료전지 금속분리판 코팅 내구성 평가)

  • Kim, Minsung;Seo, Hakyu;Han, In-Su;Jung, Jeehoon;Shin, Hyungil;Hur, Taeuk;Cho, Sungbaek
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.87.1-87.1
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    • 2010
  • Metallic bipolar plate is the one of the promising candidate material for PEMFC because of mechanical strength, low gas permeability, electrical and thermal conductivity. However, the corrosion is the main obstacle of metallic bipolar plate, and many investigations, especially coating on base metal, have been carried out to avoid corrosion. Gold is considered as the one of the best coating material because of its corrosion resistance and electrical conductivity. In this study, gold coated metallic bipolar plate was developed and evaluated. Due to our coating process, gold can be well-adhere to the base material, and hydrophobic material on its gold surface was coated by dipping method for better water management. To verify coating reliability, a single fuel cell(50cm2) was evaluated, and its durability over 4000hrs was demonstrated.

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Development of Composite Bipolar Plate for PEMFC (고분자 전해질 연료전지용 복합수지 분리판 개발)

  • Kang, Hyun-Min;Han, In-Su;Lim, Chan
    • New & Renewable Energy
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    • v.3 no.4
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    • pp.3-7
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    • 2007
  • Graphite/polymer composite bipolar plates for PEMFC are successfully developed, and their typical properties are superior to commercially available ones. Thermal property of the developed bipolar plate was evaluated by dynamic mechanical analyzer, and the results were compared to commercial ones. The specimens were immersed into the deionized water bath at $80^{\circ}$... for 1500hrs to evaluate dimensional stability and durability. Dimension, weight of the specimens as well as extraction conductivity was measured as each 500hrs. Fully molded bipolar plates without any machining or milling were also prepared using a specially developed mold, and they were applied to the fuel cell performance test. Results were compared to the machined commercial bipolar plate.

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Development of Composite Bipolar Plate for PEMFC (고분자 전해질 연료전지용 복합수지 분리판 개발)

  • Kang, Hyun-Min;Han, In-Su;Lim, Chan
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.5-7
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    • 2007
  • Graphite/polymer composite bipolar plates for PEMFC are successfully developed, and their typical properties are superior to commercially available ones. Thermal property of the developed bipolar plate was evaluated by dynamic mechanical analyzer, and the results were compared to commercial ones. The specimens were immersed into the deionized water bath at $80^{\circ}C$ for 1500hrs to evaluate dimensional stability and durability. Dimension, weight of the specimens as well as extraction conductivity was measured as each 500hrs. Fully molded bipolar plates without any machining or milling were also prepared using a specially developed mold, and they were applied to the fuel cell performance test. Results were compared to the machined commercial bipolar plate.

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Thermal Curing and Electrical Properties of Epoxy/Graphite/Expanded Graphite Composite for Bipolar Plate of Pemfc (PEMFC 바이폴라 플레이트 제조용 EPOXY/GRAPHITE/EXPANDED GRAPHITE 복합재료의 열경화 및 전기적 성질)

  • Lee, Jae-Young;Lee, Hong-Ki
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.6
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    • pp.827-834
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    • 2011
  • Epoxy/graphite/expanded graphite composites have been prepared in various weight ratios and thermal degradation and electrical properties were estimated in order to use for the bipolar plate materials in PEMFC. Thermogravimetric analysis (TGA) showed that the epoxy/graphite system cured by a curing agent GX-533 was most proper because its weight loss until $80^{\circ}C$ at which PEMFC would be operated was 0.3 wt%, and differential scanning calorimetry (DSC) analysis showed its cure temperature would be sufficient at $80^{\circ}C$. The activation energy for the cure reaction was 132.0 kJ/mol and the pre-exponential factor was $1.76{\times}10^{17}min^{-1}$. Electrical conductivity on the surface of the bipolar plate prepared under a pressure of 200 $kgf/cm^2$ was increased from 4 to 25 $S/cm^2$ by increasing expanded graphite (EG) content from 50 phr to 90 phr. The percolation threshold was initiated around 75 phr and the corrosion rate at 80 phr was 1.903 $uA/cm^2$.

Development and Evaluation of Bipolar Plates Coated with Noble Metals for Polymer Electrolyte Membrane Fuel Cells (Noble Metal이 코팅된 금속분리판 개발 및 성능 평가)

  • Seo, Hakyu;Han, In-Su;Jung, Jeehoon;Kim, Minsung;Shin, Hyungil;Hur, Taeuk;Cho, Sungbaek
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.90.2-90.2
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    • 2010
  • The coated metallic bipolar plates are getting attractive due to their good feasibility of mass production, low contact resistance, high electrical/thermal conductivity, low gas permeability and good mechanical strength comparing with graphite materials. Yet, metallic bipolar plates for polymer electrolyte membrane(PEM) fuel cells typically require coatings for corrosion protection. Other requirements for the corrosion protective coatings include low electrical contact resistance between metallic bipolar plate and gas diffusion layer, good mechanical robustness, low mechanical and fabrication cost. The authors have evaluated a number of protective coatings deposited on stainless steel substrate by electroplating. The coated metallic bipolar plates are investigated with an electrochemical polarization tests, salt dipping tests, adhesion tests for corrosion resistance and then the contact resistance was measured. The results showed that the selective samples electroplated with optimized method, satisfied the DOE target for corrosion resistance and contact resistance, and also were very stabilized in the typical fuel cell environments in the long-term.

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