• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.22 no.4
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• pp.172-186
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• 2017

Current study is a part of the efforts to assess the estuarine barrage effects on the coastal ecosystem induced by the Si flux changes. Surface sediments from Seomjin and Nakdong estuary and sediment cores from Nakdong estuary was analysed to investigate the effect of estuarine barrage on the distribution of grain size, organic matter (loss on ignition: LOI) and biogenic silica (BSi). The samples of Seomjin estuary were collected in March, 2015 and those of Nakdong estuary were collected in November, 2014. Generally, the longitudinal distribution of grain size, LOI and BSi in Seomjin estuary, natural estuary, was gradually changed. However mud (silt and clay), LOI and BSi increased from station mid-estuary where tide reaches year-round. The distribution of grain size, LOI and BSi in Nakdong estuary, however, were entirely different between inside and outside of estuarine barrage. The mud percentage and LOI were low and consistent in inside of the barrage except R05, inside of right gate, yet those of outside of the barrage were higher and varied by adjacent sluices. Mud, LOI and BSi of ND1 and ND2 decreased immediately after the construction of Nakdong estuarine barrage due to disturbance of sediment and decrease of sediment supply. To exclude the physical effects by the barrage, BSi excess ($BSi_{exc}$) was calculated using regression equation of BSi-LOI and BSi-mud of Seomjin estuary. $BSi_{exc}$ of Seomjin estuary decreased gradually from upper estuary to lower estuary. $BSi_{exc}$ of Nakdong estuary were positive in inside of the barrage and negative in outside of the barrage. BSi retention and shift of species composition of diatom by the barrage would affect $BSi_{exc}$ distribution. Before the construction of Nakdong estuarine barrage, $BSi_{exc}$ of ND2 was negative and consistent owing to high mud sedimentation. After the construction, $BSi_{exc}$ of ND2, however, fluctuated due to continuous disturbance of sediment due to construction of Eulsuk bridge and East gate.

• Journal of the Korean earth science society
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• v.42 no.1
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• pp.1-10
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• 2021

Silicon (Si) is the second most abundant element in the crust and consists of three stable isotopes, 28Si (92.23%), 29Si (4.67%), and 30Si (3.10%). Si isotopes are widely studied worldwide as a proxy for the biogeochemical cycle of Si to reconstruct the paleoenvironment and paleoclimate. However, in Korea, there have been no studies on biogenic silica using Si isotopes. In this study, we carried out Si isotope measurements of giant diatoms, summarizing the previously reported alkali fusion methods and establishing the best Si separation method for biogenic silica. Samples were completely digested using alkali fusion at high temperatures, effectively separating Si using an AG® 50W-X8 cation exchange resin. To evaluate the precision and accuracy of our measurements, Si isotope standard material (NBS-28) and USGS reference materials (AGV-2, GSP-2, BHVO-2) were analyzed. The results are in excellent agreement with the reported values within the acceptable error. The Si isotope measurement method developed in this study is expected to help in understanding the paleoclimate and paleoenvironment by tracing the Si cycle.

• Ocean and Polar Research
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• v.24 no.3
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• pp.301-311
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• 2002

We used diatom and porewater data of two piston cores from the central subbasin and one from the western subbasin in the Bransfield Strait in the northern Antarctic Peninsula to elucidate the depositional mechanism of the layered diatom ooze. The layered diatom ooze is characterized by an abundance of organic carbon, biogenic silica, sulfde sulfur, and lower porewater sulfate concentration. This lack of pore-water sulfate concentration in the diatom ooze interval may reflect development of reducing micro-environment in which bacterially mediated sulfate reduction occurred. The negative relationship between the total organic carbon and sulfate contents, however, indicates that sulfate reduction was partly taking place but does not control organic carbon preservation in this unit. Rather, well-preserved Chaetoceros resting spores in the layered diatom ooze indicate a rapid sedimentation of the diatom as a result of repetitive iceedge blooms on the Bransfield shelf during the cold period (around 2500 yrs BP) when the permanent seaice existed on the shelf, During this period, it is expected that the downslope-flowing cold and dense water was also formed on the Bransfield shelf as a result of sea ice formation, playing an important role for the formation of layered diatom ooze in the Bransfield subbasins.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.26 no.2
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• pp.173-181
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• 1993

Seasonal distributions of nutrients and particulate organic matter were investigated in Asan Bay, Korea. Most of nutrients were high in August and low in February. The atomic ratios of inorganic nitrogen to phosphorous were close to Redfield ratio except in May when the ratio was 24.8. In May, nutrient concentrations except phosphorous decreased with salinity until $31.5{\sim}32.0%0$, but the concentrations increased again with salinity, impling that there were nutrient input sources within the estuary. Howerer, significant inverse relationships between nutrients and salinity in August suggest that nutrient sources were river discharge. Maximum chlorophyll a concentrations occurred in May. Relatively low ratios of $R_b$ to $R_a$($R_b$: fluorescence before acidification; $R_a$: fluorescence after acidification) during the study periods indicate that phytoplankton were not in good physiological condition. Relatively low ratio of particulate biogenic silica(PBSi) to particulate organic carbon(POC) and high ratios of PBSi and POC to chlorophyll a during the study periods suggest input of non-living detrital PBSi and POC from bottom in Asan Bay, where strong tidal mixing occurs.

• Journal of the korean society of oceanography
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• v.33 no.4
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• pp.185-195
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• 1998

Two piston cores (94PC-2 and 95PC-4) taken from the East Sea (Sea of Japan) are studied to evaluate the paleoceanographic changes and its interaction with climatic variation. The bulk geochemistry of the non-biogenic fractions of 54 sediment samples is determined using X-ray fluorescence. Four geochemical stratigraphic units at both core sediments are recognized based on the variations in major element concentration. These chemical stratigraphic units correspond well with the sedimentological and paleontological facies. Source materials are considered as basic and/or intermediate rocks judging from silica content. A distinctive boundary around 11 kyr may correspond to Younger Dryas event. The switch of most major elements at this level and the distinctive changes in concentration of typical terrigenous elements (TiO$_2$ and Al$_2$O$_3$) are the strong evidence for the difference in sources of terrigenous materials. The weathering indices exhibit high degree in Core 94PC-2 and low degree in Core 95PC-4. The changes in weathering degree can be distinguished by the lowest value occurred at 11 kyr in Core 94PC-2 and by a gradual decrease from top to bottom in Core 95PC-4. The profiles of potassium and sodium exhibit specific excursions between the Holocene and the late Pleistocene. This implies that sediments of the two cores originating from different sources with different weathering degrees. The distinct two-group distributions in K$_2$O/CaO vs. Na$_2$O/K$_2$O also support the difference in provenance of aluminosilicate materials at the boundary of 11 kyr. Thus, supply patterns of terrigenous materials are stable in Holocene and more complicated in the last glacial period.

• Ocean and Polar Research
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• v.24 no.2
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• pp.153-166
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• 2002

Particle fluxes were measured by using time-series sediment traps in the Bransfield Strait from December 27th, 1999 to December 26th, 2000. Total mass fluxes showed distinct seasonal variations with high fluxes in the austral summer and low fluxes in the austral winter at a 678m water depth in the eastern Bransfield Strait, while they were high only in January and fairly low in other months at a 960m water depth in the central Bransfield Strait. The reason that total mass fluxes occurred only in January at a 960m water depth in the central Bransfield Strait seems to be the strong current in the surface waters, which leads to a substantial amount of terrestrial materials and locally produced organic matter being advected away from the mooring site. Total mass fluxes were very high from January to October at a 1678m water depth in the eastern Bransfield Strait, while they were high only in January and February at a 1860m water depth in the central Bransfield Strait. The fact that total mass fluxes were higher at the deep water in the both sites than at the intermediate water depth may reflect that a substantial amount of terrestrial and organic materials are laterally transported by strong tidal current from the shallow environments to the deep basins.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.20 no.4
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• pp.355-359
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• 1987

Texture and mineralogy of different microlayers of deep-sea manganese nodules are investigted to reveal the environmental changes of nodules during a nodule formation. Basically a nodule can have three types (A, B and C) of microlayer. Some nodules show only one or two types of microlayer. The classification is based primarily on the texture. The surface torture of type A is coarsely porous globular microstructure whereas type B and C are intermediate to finely porous textures. The type A is characterized by its highest Mn content $(30.6\%)$ and relatively well-crystallized todorokite as veil as the rapid growth rate. Smectite and biogenic silica (radiolaria) are also easily observed in the type A layer. It appears that the hydrothermal activity is one of the favorable mechanism of formation for the type A layer. The hydrothermal solution is possibly supplied from nearby fracture zone and spreading center.

• The Korean Journal of Quaternary Research
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• v.22 no.1
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• pp.28-36
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• 2008

The present study has focused on the environmental changes and evidences for sedimentation in the Lake Khuvsgul catchment during the Holocene period, inferred from short core sediment (BO03) from the eastern shore of Borsog Bay, which were analyzed in order to review records of the Holocene climatic evolution and Holocene history in Northern Mongolia. For the purpose of reconstruction of natural phenomenon that occurred in the lake catchment system during the Holocene, physical and chemical properties including HCl-soluble material, biogenic silica, organic matter and grain size distribution of minerals in the core sediments have been analyzed in this study. The vertical variations in composition for these properties show distinctly that five lines of paleoenvironmental evidence occurred in the lake catchment during the Holocene. A modified age model resulting from AMS carbon dating for the BO03 core sediment shows timings of these environmental events at 9.5 Kyr BP, 8.0 Kyr BP, 5.6 Kyr BP and 3.2 Kyr BP, respectively. Paleoenvironmental changes in the Lake Khuvsgul catchment system during the Holocene highlight distinctive features of the hydrological regime and geomorphologic evolution in the lake catchment due to regional landscape and global climatic changes corresponding with the Holocene optimum and thermal optimum. In particular, the change of hydrologic regime based on the sedimentological evidence has been caused by not only overland flow due to melting water, but also base flow due to thick permafrost around Khuvsgul region.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.35 no.1
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• pp.86-96
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• 2002

The distributions of suspended particulate matter (SPM), chlorophyll a, particulate organic carbon (POC) and nitrogen (PON) and particulate biogenic silica (PBSi) along the salinity gradient were investigated in the Seomjin River estuary from March 1999 to April 2001. Sampling sites were set based on the surface salinity during each cruise rather than geographic locations. Concentrations of SPM were less than 20 mg/L, suggesting relatively low input of terrestrial SPM despite large freshwater discharge through Seomiin River, Chlorophyll a peaks occurred at 5$\~$ 15 psu salinity zone (10$\~$20 km from Nan Cho Island) in November 1999, at 15$\~$25 psu (10$\~$20 km) salinity zone in April 2000 and at 1$\~$15 psu salinity zone (15$\~$20 km) in October 2000 (ca. 8$\~$58%\mu$g/L). Concentrations of POC, PON and PBSi were also high at the same zone. Relatively low ratios of POC to chlorophyll a in mid-salinity zone where POM peak occurred suggests high contribution of living phytoplankton to the total POC. On the other hand, relatively high ratios of POC to chlorophyll $\alpha$ in very low salinity zone and the mouth of estuary indicated relatively high portions of detrital POC. Consequently, the low concentrations of SPM in this estuary and the high concentrations of chlorophyll $\alpha$ and the low ratios of POC to chlorophyll $\alpha$ in the mid-salinity zone suggest that production of living phytoplankton is primary factor in controlling distribution of POM along the salinity gradients in the Seomjin River estuary.