• Title/Summary/Keyword: bio-composites

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Viscoelastic and Acoustic Characterization of Coatings for Stringed Instruments (현악기용 음향기능성 도료의 점탄성적 성질과 음향적 성질)

  • Choi, Jae-Hoon;Lee, Byoung-Hoo;Kim, Hyun-Joong;Chung, Woo-Yang
    • Journal of the Korean Wood Science and Technology
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    • v.33 no.4 s.132
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    • pp.15-22
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    • 2005
  • The acoustic properties of various coatings for stringed musical instruments made were investigated. The applied coatings were urethane topcoat, oil stain, natural varnish, cashew and UV-curable epoxy coating. Acoustic properties of coatings inferred from a resonance frequency and a damping measured by FFT analyzer and tan ${\delta}$ measured by DMTA. Acoustic properties from resonance frequency and damping were analyzed. Optimum coating for stringed instruments was determined by viscoelastic properties and acoustic properties of coating.

Comparison of Formaldehyde Emission of Wood-based Panels with Different Adhesive-hardener Combinations by Gas Chromatography and Standard Methods

  • Eom, Young Geun;Kim, Sumin;Baek, In-Chan;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.33 no.2 s.130
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    • pp.29-39
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    • 2005
  • Formaldehyde emissions from wood-based panels bonded with pine and wattle tannin-based adhesives, urea-formaldehyde resin (UF), melamine-formaldehyde resin (MF), and co-polycondensed resin of urea-melamine-formaldehyde (UMF) were measured by the Japanese standard method using a desiccator (JIS A 1460) and the EN 120 (European Committee For Standardization, 1991) method using the perforator value. In formaldehyde emission, all particleboards made using the wattle tannin-based adhesive with three different hardeners, paraformaldehyde, hexamethylenetetramine, and tris(hydroxyl)nitromethan (TN), satisfied the requirements of grade $E_1$. But only those made using the pine tannin-based adhesive with the hexamine as hardener met the grade $E_1$ requirements. Hexamine was effective in reducing formaldehyde emission in tannin-based adhesives when used as the hardener. While the UF resin showed a desiccator value of $7.1mg/{\ell}$ and a perforator value of 12.1 mg/100 g, the MF resin exhibited a desiccator value of $0.6mg/{\ell}$ and a perforator value of 2.9 mg/100 g. According to the Japanese Industrial Standard and the European Standard, the formaldehyde emission level of the MDF panels made with UF resin in this study came under grade $E_2$. The formaldehyde emission level was dramatically reduced by the addition of MF resin. The desiccator and perforator methods produced proportionally equivalent results. Gas chromatography, a more sensitive and advanced method, was also used. The samples for gas chromatography were gathered during the experiment involving the perforator method. The formaldehyde contents measured by gas chromatography were directly proportional to the perforator values.

Pressure Sensitive Adhesion Performances of SIS/SBS based UV-curable Pressure Sensitive Adhesives using Thiol-ene Reaction (Thiol-ene 반응을 이용한 UV경화형 SIS/SBS계 점착제의 점착물성)

  • Lim, Dong-Hyuk;Do, Hyun-Sung;Kim, Hyun-Joong;Yoon, Goan-Hee;Bang, Jung-Suk
    • Journal of Adhesion and Interface
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    • v.6 no.3
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    • pp.19-25
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    • 2005
  • Synthetic rubber based pressure-sensitive adhesives (PSAs) usually containing SIS or SBS block copolymer, tackifier, plasticizer, and other additives are now widely used on various applications. As these PSAs are physically crosslinked and can be applied without the use of solvent, they are thermally processable and environmentally friendly. However these PSAs cannot be used in high temperature applications and in applications where solvent and chemical resistance properties are required. We developed the PSA adding UV curable system, such as thiol-ene system, to increase adhesion properties at elevated temperature. The adhesion properties such as probe tack, peel strength, shear adhesion failure temperature (SAFT) were evaluated. The probe tack test was conducted with varying probe materials and coating thickness of PSAs. Using the contact angle, the surface property of the cured PSAs was also observed.

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Effect of Formability of Physical Properties of Polyester/Melamine Cured Coating Using Polycarbonate Diol with Various Molecular Weight (폴리카보네이트 분자량이 폴리에스터/멜라민 경화형도료의 도막 성형성 및 물성에 미치는 영향)

  • Lee, Yong-Hee;Moon, Je-Ik;Kim, Hyun-Joong;Lee, Jae-Young;Noh, Seung Man;Nam, Joon Hyun
    • Journal of Adhesion and Interface
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    • v.12 no.4
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    • pp.105-110
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    • 2011
  • Polyester/melamine cured coatings had been used for pre-primed coatings and pre-coated metal coatings, because it has good mechanical,chemical properties, and mar resistance. But it has weak points such as stiffness and low formability for making automotive components. Polyester had been synthesized using polycarbonate diol of long alkyl chain which can improve flexibility and formability which is one of the important factors for pre-coated steel sheets (PCM). In this study, strain and tensile strength were examined by the tensile test and formability was examined by the drawing test. Also, Those polyester resins were also measured by DMA to verify flexibility of cured coatings.

Vibration behavior of partially bio-sourced sandwich panel with orthogonally stiffened core: Analytical and experiment study

  • Boussoufi, Aicha;Errouane, Lahouaria;Sereir, Zouaoui;Antunes, Jose V.;Debut, Vincent
    • Advances in aircraft and spacecraft science
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    • v.9 no.3
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    • pp.169-193
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    • 2022
  • By the present paper, both experimental and analytical models have been proposed to study the vibration behavior of partially bio-sourced sandwich panel with orthogonally stiffened core. For a variable mass fraction of Alfa fibers from 5% to 15%, impregnated in a Medapoxy STR resin, this panel were manufactured by molding the orthogonally stiffened core then attached it with both skins. Using simply supported boundary conditions, a free vibration test was carried out using an impact hammer for predicting the natural frequencies, the mode shapes and the damping coefficient versus the fibers content. In addition, an analytical model based on the Higher order Shear Deformation Theory (HSDT) was developed to predict natural frequencies and the mode shapes according to Navier's solution. From the experimental test, we have found that the frequency increases with the increase in the mass fraction of the fibers until 10%. Beyond this fraction, the frequencies give relatively lower values. For the analytical model, variation of the natural frequencies increased considerably with side-to-thickness ratio (a/H) and equivalent thickness of the core to thickness of the face (hs/h). We concluded that, the vibration behavior was significantly influenced by geometrical and mechanical properties of the partially bio-sourced sandwich panel.

Preparation and Properties of Celluose Diacetate/Starch Composite (Cellulose Diacetate/Starch 복합체의 제조 및 물성)

  • Lee, Sang-Yool;Lee, Seung-Kyung;Lim, Hwan-Kyu;Kye, Hyoung-San;Lee, Young-Kwan
    • Polymer(Korea)
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    • v.30 no.6
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    • pp.532-537
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    • 2006
  • In order to successfully meet the environmental and recycling problems, natural polymer and their derivatives are recognized as a promising biodegradable material. In this study, the biodegradable composites of cellulose diacetate and starch were prepared, and their physical and thermal properties were investigated. For the melting processing, triacetine was added as a plasticizer into the composites. The processability of cellulose diacetate was further enhanced by increasing the amount of starch in the composites. The tensile stress and Young's modulus were decreased and elongation was increased with increasing the amount of starch in them. A $T_g$ value was decreased with increasing the amount of starch in the composites. Also, the morphology of the composites were observed with the SEM.

Development of Simple Test Method using VOC Analyzer to Measure Volatile Organic Compounds Emission for Particleboards (VOC Analyzer를 이용한 파티클보드로부터 방산되는 휘발성유기화합물의 간이 측정방법 개발)

  • An, Jae-Yoon;Kim, Sumin;Kim, Jin-A;Kim, Hyun-Joong;Mun, Suck-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.4
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    • pp.22-30
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    • 2006
  • The volatile organic compound (VOC) Analyzer is a portable device to measure the four main aromatic hydrocarbon gases: toluene, ethylbenzene, xylene and styrene. With the VOC Analyzer, a semiconductor gas sensor eliminates the need for the carrier gas which is required for conventional gas chromatographs. In addition, since the semiconductor gas sensor is supersensitive to gas components, it is not necessary to use a conventional gas concentrator or other complicated equipment. Compared with other measurement methods, the VOC analyzer is useful for measuring toluene, ethylbenzene, xylene and styrene in wood-based panel because of its ease in obtaining field results and repeating the test. The VOC Analyzer primarily measures four VOC in the air. In this study, we designed a test method of VOC measurement for particle board. A specimen was sealed in 3L polyester bag, after 96hours we could measure maximum VOC emission level that is a stabilized VOC Value. For easy, fast and economic testing of TVOC emission from wood-based panel, we developed the test method with the VOC Analyzer. The VOC Analyzer is expected to gain widespread use in the manufacturing field where a quick and easy test for VOC emission from wood-based panel is required. Furthermore, the VOC Analyzer promises to become an easier, faster and more economic technique than the currently used standard methods.

Loess(Yellow Soil) Finishing Materials Using Water-based Adhesive for Wooden Construction Indoor Wall (수성접착제를 이용한 목조주택 내벽용 황토 마감재의 물성 및 친환경성)

  • An, Jae-Yoon;Kim, Ki-Wook;Kim, Sumin;Oh, Jin-Kyoung;Kim, Hyun-Joong;Park, Moon-Jae
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.6
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    • pp.100-107
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    • 2007
  • People have spent lots of time inside building about 90% of these day. Industry has been developed rapidly after I960. Construction materials had changed from natural materials to chemical materials and confidentiality of building has been more higher than before by policy of saving energy. These have caused sick-building syndrome (SBS) for us. So people want environmental construction materials for their house. We designed a environmental loess (yellow soil) finishing material which was composed of loess, water, water-soluble resin, hardener and filler. The purposes of this study were that making an environmental loess finishing material with optimum ratio, evaluating the usability of loess finishing material for wall. Furthermore it was suitable for wall to evaluate mechanical properties that are impact test, cracking test, abrasion test and de-bonding test, environmental properties that were emission of VOCs, formaldehyde and far infrared radiation.

Curing Behavior and Tensile Strength of Elastomeric Polyester and Polyvinylidene Fluoride for Automotive Pre-primed Coatings (자동차용 Pre-primed 적용을 위한 Polyester 및 Polyvinylidene Fluoride 도료의 경화거동과 인장강도 특성)

  • Hwang, Hyeon-Deuk;Moon, Je-Ik;Lee, Yong-Ju;Kim, Hyun-Joong;Hyun, Jin-Ho;Noh, Seung Man;Kang, Choong Yeol;Lee, Jae-Woo;Nam, Joon Hyun;Park, Jong Myung
    • Journal of Adhesion and Interface
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    • v.10 no.4
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    • pp.155-161
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    • 2009
  • The most upcoming technical issue of automotive coating is the compact coating process. Pre-primed coating is the outstanding technology eliminating electro-deposition and primer coating process. The main properties of pre-primed coating for automotive are flexibility, corrosion resistance, and weldability. Therefore, we synthesized the conventional polyester, elastomeric polyester and polyvinylidene fluoride resins and evaluated their properties to use as weldable pre-primed automotive coatings. As the results of flexibility and curing behavior, the elastomeric polyester coating was most appropriate to use for the pre-primed automotive coatings.

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A Study on Adhesion of Mechanical Properties of Rubber by MgCl2 (투명 차폐 필름 구현을 위한 전도성 복합 바인더의 입자구조에 따른 성능 평가)

  • Park, Ji-won;Back, Jong-Ho;Lee, Tae-Hyung;Kim, Hyun-Joong
    • Journal of Adhesion and Interface
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    • v.18 no.2
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    • pp.59-67
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    • 2017
  • Recently, integration of parts is accelerating according to the growth of the smart mobile industry. The integration of these parts causes problems of interference phenomena between the parts, and the importance of electromagnetic wave shielding technology to solve this problem is highlighted. Electromagnetic wave shielding technology is implemented so as to reflect or absorb electromagnetic waves, and generally conductive materials are utilized for electromagnetic wave shielding. Transparent shielding technology is required according to recent industrial changes. In this research, we propose transparent the shielding film using imprint technology with conductive composite binder. Utilizing UV polymerized acrylic binder to produce a conductive composite binder. Spherical, plate and stacked silver particles were used for conductivity. The changes of the curing characteristics, conductivity and adhesion were observed according to the structural characteristics of the silver particles. The use of spherical particles was the most efficient in the curing process, and an additional curing system was required to complement the UV-shadowing structure. In the conductivity evaluation, the stacked structure showed excellent characteristics. The adhesion of spherical system was the best. It is evaluated as a result of irregularities on the surface. Ultimately, the patterned film using this showed excellent transparency characteristics.