• Elastomers and Composites
• /
• v.46 no.3
• /
• pp.195-203
• /
• 2011

Eco-friendly materials or bio-composites were made with poly(lactic acid) (PLA) as matrix polymer and kenaf fibers as filler. Also, acetylated kenaf fibers and compatibilizer were adopted in order to improve the interfacial adhesion between fiber and polymer. In this study, the effect of chemical modification and compatibilizer on the mechanical-viscoelastic and morphology properties of the bio-composites was discussed. The hydrophobic fibers by acetylation were known to show better interfacial bonding with the matrix polymer and resulted in improved performance and morphology. Viscoelastic property and glass transition temperature, however, were not nearly enhanced.

• Tribology and Lubricants
• /
• v.31 no.5
• /
• pp.195-204
• /
• 2015

Several researches are focused on improving the value of fine chemicals based on biomass resources due to environmental and other concerns associated with the use of petroleum-based products. Therefore, the synthesis and application of estolides derived from plant-based waste oil materials and their application as lubricants and as processing oil for butyl rubber products have been studied. Four kinds of estolide were prepared with conversions of 71~92% over 24h using various vegetable oils, as determined by size exclusion chromatography (SEC) and nuclear magnetic resonance (NMR) spectroscopy. FT-IR spectroscopy determines the esterification of estolides using 2-ethylhexyl alcohol. The estolides have iodine values of 35~90, α-ester/α-acid ratios of 0.45~0.55, and total acid number of 114~134 mg KOH g^–1. Four ball wear tests show that the wear scar diameters (WSDs) of estolides as base oil significantly decreased to 0.328~0.494 mm, compared to WSDs of 0.735 and 0.810 mm of WSD for 150N and Yubase 6, respectively, as general base oil. Thus, the estolides have better wear resistance and satisfying design objectives for the engineering of a variety of lubricant base oils.

• Journal of Adhesion and Interface
• /
• v.11 no.2
• /
• pp.57-62
• /
• 2010

Photo-curable material can be crosslinked among molecules by light source such as UV and visible light materials. Material properties are controlled by crosslink reaction. Shrinkage is occured during the curing reaction of material structure. Phenomenon of shrinkage stress occurs inside the product and reduce the stability of the product causes problems. Heat shrink the evaluation of the phenomenon has been formalized. But the evaluation of photo shrink is not enough. In this experiment, real-time contract with shrinkage tester phenomena and analysis degree of shrinkage of the material differences. According to the research, experimental results and theoretical analysis of the results were big differences. Shrinkage, especially for a number of different functional groups that were very different theory. These differences are occurred by the molecular structure different and not enough reaction.

• Elastomers and Composites
• /
• v.59 no.2
• /
• pp.51-63
• /
• 2024

Polypropylene (PP) is a commodity plastic that is widely used owing to its cost-effectiveness, lightweight nature, easy processability, and outstanding chemical and thermomechanical characteristics. However, the imperative to address energy and environmental crises has spurred global initiatives toward a circular economy, necessitating sustainable alternatives to traditional fossil-fuel-derived plastics. In this study, we conducted a series of comparative investigations of bio-based polypropylene (bio-PP) blends with current PP of the same and different grades. An extrusion-based processing methodology was employed for the bio-PP composites. Talc was used as an active filler for the preparation of the composites. A comparative analysis with the current petroleum-based PP indicated that the thermal properties and tensile characteristics of the bio-PP blends and composites remained largely unaltered, signifying the feasibility of bio-PP as a potential substitute for the current PP. To achieve a higher Young's modulus, elongation at break (EAB), and melt flow index (MFI), we prepared different composites of PP of different grades and bio-PP with varying talc contents. Interestingly, at higher biomass contents, the composites exhibited higher MFI and EAB values with comparable Young's moduli. Notably, the impact strengths of the composites with various biomass and talc contents remained unaltered. In-depth investigations through surface analysis confirmed the uniform dispersion of talc within the composite matrix. Furthermore, the moldability of the bio-PP composites was substantiated by comprehensive rheological property assessments encompassing shear rate and shear viscosity. Thus, from these outcomes, the fabricated bio-PP-based composites could be an alternative to petroleum-based PP composites for sustainable automobile applications.

• Journal of the Korean Wood Science and Technology
• /
• v.43 no.1
• /
• pp.86-95
• /
• 2015

This study was performed to study physical and mechanical properties of hybrid cross laminated timber (HCLT) with plywood as core layer in order to improve its mechanical properties for wooden housing. MOE, MOR, and dimensional stability of the HCLT were determined, depending on plywood composition and lamination direction. MOR value of the HCLT was improved as much as that of the glued laminated timber, which was 59.6% stronger than that of the cross laminated timber (CLT) control group. All MOE values of the HCLT were similar to glued laminated timber structure control group regardless of plywood composition and lamination directions. The dimensional stability of the HCLT was better than those of the glued laminated timber and CLT control group, owing to the use of plywood in the core.

• Journal of Magnetics
• /
• v.11 no.4
• /
• pp.189-194
• /
• 2006

The recent development of bio-conjugated magnetic nanoparticles offers many opportunities for applications in the field of biomedicine. In particular, the use of magnetic nanoparticles for biosensing has generated widespread research efforts following the progress of various magnetic field sensors. Here we demonstrate substrate-free biosensing approaches based on the Brownian rotation of ferromagnetic nanoparticles suspended in liquids. The signal transduction is through the measurement of the magnetic ac susceptibility as a function of frequency, whose peak position changes due to the modification of the hydrodynamic radius of bio-conjugated magnetic nanoparticles upon binding to target bio-molecules. The advantage of this approach includes its relative simplicity and integrity compared to methods that use substrate-based stray-field detectors.

• Journal of the Korea Furniture Society
• /
• v.28 no.2
• /
• pp.111-117
• /
• 2017

Recently, as people's interest in wood has increased, the use of wood as household and landscape decking materials has increased. As the deck material, imported wood such as synthetic wood, Ipe, and Malas was used in addition to the existing preserved wood, but recently deck use has been activated as part of the activation of domestic materials. As an important quality factor in the selection of such decking materials, various durability along with weatherability for long - term use is required for maintenance. Generally used tropical hardwoods have excellent weatherability and durability without additional preservative treatment. However, the domestic larch is a wood species with a higher specific gravity and durability than ordinary conifers. However, it has not yet been used as a deck material due to lack of comparative studies on its characteristics. Therefore, hardness and durability of wood were measured using six specimens of Ipe, Massaranduba, Malas, Douglas-fir, Larch and Torrefied-Larch. Density Profile was used to measure the density, and Brinell hardness test and resistance test against momentary impact were carried out for the test of resistance to static load. Also, The hardness and durability of wood were measured by castor test with resistance test against dynamic load, as well as, nail down test by experiment on surface hardness and durability. As a result of the experiment, the hardness was increased in proportion to the density, and it was confirmed that the imported lumber was harder and durable than the domestic larch.

• Journal of the Korean Wood Science and Technology
• /
• v.37 no.2
• /
• pp.155-163
• /
• 2009

This study examined the thermal stability of PLA-WF bio-composites. Wood flour (WF)-filled PLA bio-composites were reinforced with the flame retardants, Melamine pyrophosphate (MPP), resorcinol bis (diphenyl phosphate) (RDP) and zinc borate (ZB). The flame retardant was compounded with PLA and natural biodegradable filler. The thermal properties of the biodegradable polymer and bio-composites reinforced with the flame retardant were measured and analyzed by DSC, DMA and TGA. The results showed that the flame retardant-reinforced biodegradable bio-composite exhibited improved thermal properties.

• Journal of Adhesion and Interface
• /
• v.8 no.4
• /
• pp.32-40
• /
• 2007

• Tribology and Lubricants
• /
• v.30 no.6
• /
• pp.323-329
• /
• 2014

The friction-reducing properties of lubricants containing ionic liquids based on ammonium dithiocarbamate are studied. The ionic liquids are produced through the following two steps: the synthesis of sodium alkyl dithiocarbamates via the substitution reaction of dialkylamine and carbon disulfide and their subsequent conversion into ammonium dithiocarbamate-based ionic liquids through an ion-exchange reaction with a quaternary alkyl ammonium halide salt. The structures of the ionic liquids are characterized by NMR spectroscopy and Fourier transform infrared spectroscopy. The isolated yields of the ionic liquids, which are viscous and pale yellow, are approximately 92%. The Brookfield viscosities and pour points of the ionic liquids are determined. Further, their wear resistances are measured through the four-ball wear test and the Schwingung Reibung Ver-schleiss (oscillation, friction, wear) test. The wear scar diameter of the lubricants containing 1 wt of the quaternary alkyl ammonium dithiocarbamate-based ionic liquids (0.475-0.631 mm) is significantly lower than that of the base oil (0.825 mm), proving that the ammonium dithiocarbamate-based ionic liquids have good friction-reducing characteristics. However, these friction-reducing characteristics fade significantly after long-term storage, owing to the degradation of the ionic liquids.