• Journal of the Korean Wood Science and Technology
• /
• v.45 no.3
• /
• pp.278-287
• /
• 2017

In this study, lignin was efficiently degraded via two-step catalytic cracking process and lignin-oil, char, and gas was produced as lignin degraded products. Three kinds of catalysts (MgO, CaO, and Pt/C) were used in first catalytic cracking step and the highest lignin-oil yield (76.2 wt%) was obtained in Pt/C catalyst with the smallest char formation (4.1 wt%). GC-MS/FID analysis revealed that 18 kinds of monomeric phenols existed in lignin-oil and sum of them was the highest in Pt/C condition (97.8 mg/g lignin). Meanwhile, relatively lower yield of monomeric phenols was produced in MgO and CaO condition because of their absorption on catalysts. Lignin-oil produced over Pt/C was introduced to second catalytic cracking process with porous Pd/activated carbon aerogel catalyst. From this process, four kinds of monomeric phenols such as 4-ethylguaiacol, 4-propylguaiacol, 4-ethylsyringol, 4-propylsyringol were selectively produced at 0.89 - 1.82 wt% level.

• Journal of Bio-Environment Control
• /
• v.11 no.3
• /
• pp.101-107
• /
• 2002

This study was carried out to improve the performance of heat recovery device attached to exhaust gas flue connected to combustion chamber of greenhouse heating system. Three different units were prepared far the comparison of heat recovery performance; A-type is exactly the same with the typical one fabricated for previous study of analyzing heat recovery performance in greenhouse heating system, other two types (B-type and C-type) modified from the control unit are different in the aspects of airflow direction (U-turn airflow) and pipe arrangement. The results are summarized as follows ; 1. In the case of Type-A, when considering the initial cost and current electricity fee required for system operation, it was expected that one or two years at most would be enough to return the whole cost invested. 2. Type-B and Type-C, basically different with Type-A in the aspect of airflow pattern, are not sensitive to the change of blower capacity with higher than 25m$^3$.min$^{-1}$ . Therefore, heat recovery performance was not improved so significantly with the increment of blower capacity. This was assumed to be that air flow resistance in high air capacity reduced the heat exchange rate as well. Never the less, compared with control unit, resultant heat recovery rate of Type-B and Type-C was improved by about 5％ and 13％, respectively 3. Desirable blower capacity of these heat recovery units experimented were expected to be about 25m$^3$.min$^{-1}$ , and at the proper blower capacity, U-turn airflow units showed better heat recovery performance than control unit. But, without regard to the type of heat recovery unit, it was recommended that comprehensive consideration of system's physical factors such as pipe arrangement density, unit pipe length and pipe thickness, etc., was required for the optimization of heat recovery system in the aspects of not only energy conservation but economic system design.

• Journal of Bio-Environment Control
• /
• v.16 no.1
• /
• pp.67-71
• /
• 2007

This study was conducted to find out the influence of cultivation season for fresh parsley in modified atmosphere storage. As the qualities of fresh parsley grown in different seasons; autumn, winter, summer were compared, the chlorophyll and vitamin C showed the highest content in autumn and winter cultivation, respectively, but the firmness was the highest in summer cultivation treatment. These fresh parsleys grown in different seasons packaged with 0.04mm ceramic film and stored at $0^{\circ}C$. The shelf life of these parsleys were 84 days in winter cultivation treatment, while parsleys cultivated in autumn and summer were able to be stored for 77 days and 56 days, respectively. The fresh weight loss of parsley was much more higher in summer than in both autumn and winter cultivation treatments. The carbon dioxide and ethylene contents in packages in summer were more than twice as high in autumn and winter cultivation treatment. There were not different between autumn and winter cultivation treatment in the two kinds of gas contents. This result should be caused by higher field heat that increased a respiration remarkably during the early storage. The highest field heat produced by summer cultivation resulted in remarkable decreases of firmness, chlorophyll and vitamin C during MA storage. As the results, the fresh parsley showed highest storability in winter cultivation treatment. The field heat of fresh parsley should be eliminated just after harvest for a long term storage.

• Journal of Ginseng Research
• /
• v.32 no.4
• /
• pp.305-310
• /
• 2008

The volatile constituents of the fresh roots of Panax ginseng C.A. Meyer have been investigated after treatment with artificial saliva and analysed by gas chromatography-mass spectrometry (GC-MS) using solid phase microextraction (SPME) fiber. Twenty peaks were detected in fresh ginseng, 5 of them were unknown peak, and mainly hydrocarbon components (${\alpha}$-pinene, ${\beta}$-pinene, myrcene, limonene, ${\beta}$-panasinsene, ${\beta}$-elemene, ${\beta}$-gurjunene, trans-caryophyllene, ${\alpha}$-gurjunene, ${\alpha}$-panasinsene, ${\alpha}$-neoclovene, trans-${\beta}$-farnasene, ${\alpha}$-humulene, ${\beta}$-neoclovene, ${\alpha}$-selinene, ${\beta}$-selinene, bicyclogermacrene) were detected. It's area percentage was increased about 10% in the fresh ginseng added artificial saliva during 40 minutes.

• Journal of Energy Engineering
• /
• v.18 no.2
• /
• pp.132-135
• /
• 2009

Development of biofuels like ethanol and biodiesel for commercial uses is a recent phenomenon. However, the growth of ethanol and biodiesel has been impressive during the period 2000-2007yr. Globally, production of biodiesel stands around 8.3 billion liters. Europe leads the world in biodiesel production with 80% share of the global biodiesel production total. Today biodiesel fuels have been in commercial use in many countries and recently the world-wide biodiesel market has experienced considerable growth, which is partly due to various tax concession programs and other financial incentives. In Korea, biodiesel has already been used for transportation fuel, but not used for power generation fuel yet. Korean government has a strategy for renewable energy propagation, especially the goal of power generation amount by renewable energy is 3% of total power production by 2012. This paper focuses on the estimation study for effect of using biodiesel as power generation fuel. The study also has the plan to replace the fuel of thermal power plant, gas turbine and distributed power generation system. As the increase of biodiesel fuel, I look forward to environment-friendly power generation and the strategy of Renewable Portfolio Standards(RPS).

• Journal of Bio-Environment Control
• /
• v.10 no.4
• /
• pp.207-212
• /
• 2001

The environmental characteristics, absorption rate of NO$_2$, physiological response, and quality of lettuces were examined in a semi-closed plant production system consisted of human and plant modules. Leaf lettuces were transplanted to 10-cm diameter pots at 4-to 5-leaf stage, and grown in a gas-fumigated plant module. Air containing NO$_2$was circulated 10 min-ON/ 20 min-OFF between the human and plant modules by a diaphragm. At 0.13, 0.30, and 0.45 $\mu$mol.mol$^{-1}$ NO$_2$, NO$_2$ decrements in the chamber during the 10 min were 0.040, 0.109, and 0.149 $\mu$mol.mol$^{-1}$ , respectively. The NO$_2$absorption rate of the plants was estimated to be 0.078 $\mu$mol.mol$^{-1}$ .m$^{-2}$ .min$^{-1}$ at 0.45 $\mu$mol.mol$^{-1}$ NO$_2$ was less than that of the control plant at 4th and 5th days, whereas the respiration rate was the same. The lettuce grown at 0.45 $\mu$mol.mol$^{-1}$ NO$_2$ had similar leaf length, leaf area, dry and fresh weights, and quality to that grown without NO$_2$.

• KSBB Journal
• /
• v.21 no.4
• /
• pp.255-259
• /
• 2006

The biodegradable hyaluronic acid(HA) membranes cross-linked with lactide using the crosslinking agent, 1-ethyl-3(3-dimethyl aminopropyl) carbodiimide(EDC) were prepared as a potential biocompatible material for tissue engineering. HA membranes having different mechanical properties were synthesised by varying degree of the mole ratio of lactide to HA, EDC concentration, and crosslinking temperature. HA membranes were degradable in water solution and the degradation became slower with the increasing mole ratio of lactide to HA. HA membranes were sterilized using ethylene oxide gas and extracted with cell culture medium for 24 h at $37^{\circ}C$ and 200 rpm. Cytotoxicity of the extract was tested using NIH/3T3 mouse embryo fibroblast as a model cell. Growth inhibition was not observed in the extracts of HA membranes with the mole ratios of lactide to HA, 5 or 10, and 10% EDC concentration, however 11% of growth inhibition was observed in the extract with the mole ratio of 13. Growth inhibition was not observed in the extracts of HA membranes prepared with 5% EDC or 10% EDC and the mole ratio of lactide to HA, 10, however 12% of growth inhibition was observed in the extract with 20% EDC. Cytotoxicity was not observed in the extracts of HA membranes prepared at varying crosslinking temperatures, $15^{\circ}C,\;25^{\circ}C,\;and\;28^{\circ}C$ with the mole ratio of lactide to HA, 10 and 10% EDC.

• Journal of Applied Biological Chemistry
• /
• v.63 no.2
• /
• pp.153-159
• /
• 2020

The analytical method was established for simultaneous determination of fungicide prochloraz and its metabolites in several animal commodities using gas chromatography (GC) coupled with electron capture detector (ECD). Samples including beef meat, pork meat, chicken meat, milk, and egg were hydrolyzed with pyridine hydrochloride which converts prochloraz and its metabolites to 2,4,6-trichlorophenol (2,4,6-TCP) because residue definition for prochloraz was 'sum of prochloraz and its metabolites containing the 2,4,6-trichlorophenol moiety, expressed as prochloraz', for compliance with MRLs from animal commodities. Therefore, residual prochloraz was extracted with acetone, decomposed to 2,4,6-TCP, partitioned with dichloromethane, purified with aminopropyl SPE and quantified as 2,4,6-TCP with GC-ECD. The instrumental limit of quantitation and method LOQ (MLOQ) was 0.01 ㎍/mL and 0.02 mg/kg for prochloraz and 0.005 ㎍/mL and 0.01 mg/kg for 2,4,6-TCP, respectively. The linearity of the calibration curve was good with R² >0.995 in the range of 0.005-0.2 ㎍/mL. Fortification levels of prochloraz were 0.02 mg/kg (MLOQ) and 0.2 mg/kg (10MLOQ) for recovery tests. Overall recoveries of prochloraz were >90% with <10% of coefficient variation (C.V.). This established analytical method was fully validated and could be useful for quantification of prochloraz and its metabolites in animal commodities as official analytical method.

• Korean Journal of Environmental Agriculture
• /
• v.39 no.3
• /
• pp.171-177
• /
• 2020

BACKGROUND: Recently, biomass conversion from agricultural wastes to carbon-rich materials such as biochar has been recognized as a promising option to maintain or increase soil productivity, reduce nutrient losses, and mitigate greenhouse gas emissions from the agro-ecosystem. This experiment was conducted to select an optimum conditions for enhancing the NH₄-N adsorption capacity of rice hull activated biochar. METHODS AND RESULTS: For deciding the proper molarity of KOH for enhancing its porosity, biochars treated with different molarity of KOH (0, 1, 2, 4, 6, 8) were carbonized at 600℃ in the reactor. The maximum adsorption capacity was 1.464 mg g^-1, and an optimum molarity was selected to be 6 M KOH. For the effect of adsorption capacity to different carbonized temperatures, 6 M KOH-treated biochar was carbonized at 600℃ and 800℃ under the pyrolysis system. The result has shown that the maximum adsorption capacity was 1.76 mg g^-1 in the rice hull activated biochar treated with 6 M KOH at 600℃ of pyrolysis temperature, while its non-treated biochar was 1.17 mg g^-1. The adsorption rate in the rice hull activated biochar treated with 6 M KOH at 600℃ was increased at 62.18% compared to that of the control. Adsorption of NH₄-N in the rice hull activated biochar was well suited for the Langmuir model because it was observed that dimensionless constant (R_L) was 0.97 and 0.66 at 600℃ and 800℃ of pyrolysis temperatures, respectively. The maximum adsorption amount (q_m) and the bond strength constants (b) were 0.092 mg g^-1 and 0.001 mg L^-1, respectively, for the rice hull activated biochar treated with 6 M KOH at 600℃ of pyrolysis. CONCLUSION: Optimum condition of rice hull activated biochar was 6M KOH at 600℃ of pyrolysis temperature.

• Korean Journal of Soil Science and Fertilizer
• /
• v.41 no.1
• /
• pp.18-25
• /
• 2008

Pseudomonas sp. PRGB06, a bacterial strain isolated from diamondback moth (Plutella xylostella) gut, was examined for its plant growth promotion and biofertilizing traits. The bacteria growth was observed under various conditions of carbon sources, temperature, pH and salt concentrations. In addition, the mechanisms of antagonism and phosphate solubilization were investigated. The bacterial strain PRGB06, grew well using most of the tested carbon sources. The best growth was observed at $30^{\circ}C$ and pH 7. The inhibition of the pathogenic fungi was likely due to the volatile antifungal metabolite and ammonia gas produced by the bacteria. A significant positive relationship was found between the phosphate solubilization and acid production. When inoculated with PRGB06 in vitro and in gnotobiotic condition, red pepper and maize showed increase in root length, seedling vigor and dry bio-mass.