Selective Production of Monomeric Phenols from Lignin via Two-step Catalytic Cracking Process
![]() |
Kim, Jae-Young
(Institute of Green-Bio Science and Technology, Seoul National University)
Heo, Sujung (Graduate School of International Agricultural Technology, Seoul National University) Park, Shin Young (Department of Forest Sciences, CALS, Seoul National University) Choi, In-Gyu (Department of Forest Sciences, CALS, Seoul National University) Choi, Joon Weon (Institute of Green-Bio Science and Technology, Seoul National University) |
1 | Saidi, M., Samimi, F., Karimipourfard, D., Nimmanwudipong, T., Gates, B.C., Rahimpour, M.R. 2014. Upgrading of lignin-derived bio-oils by catalytic hydrodeoxygenation. Energy & Environmental Science 7(1): 103-129. DOI |
2 | Song, Q., Wang, F., Cai, J., Wang, Y., Zhang, J., Yu, W., Xu, J. 2013. Lignin depolymerization (LDP) in alcohol over nickel-based catalysts via a fragmentation-hydrogenolysis process. Energy & Environmental Science 6(3): 994-1007. DOI |
3 | Wang, Y.-Y., Ling, L.-L., Jiang, H. 2016. Selective hydrogenation of lignin to produce chemical commodities by using a biochar supported Ni-Mo 2 C catalyst obtained from biomass. Green Chemistry 18(14): 4032-4041. DOI |
4 | Ye, Y., Zhang, Y., Fan, J., Chang, J. 2012. Selective production of 4-ethylphenolics from lignin via mild hydrogenolysis. Bioresource Technology 118: 648-651. DOI |
5 | Alonso, F., Riente, P., Rodriguez-Reinoso, F., Ruiz-Martinez, J., Sepulveda-Escribano, A., Yus, M. 2009. A Highly Reusable Carbon-Supported Platinum Catalyst for the Hydrogen-Transfer Reduction of Ketones. ChemCatChem 1(1): 75-77. DOI |
6 | Bouxin, F.P., McVeigh, A., Tran, F., Westwood, N.J., Jarvis, M.C., Jackson, S.D. 2015. Catalytic depolymerisation of isolated lignins to fine chemicals using a Pt/alumina catalyst: part 1-impact of the lignin structure. Green Chemistry 17(2): 1235-1242. DOI |
7 | Brunow, G., Lundquist, K. 2010. Functional groups and bonding patterns in lignin (including the lignin-carbohydrate complexes). CRC Press, Boca Raton, USA. |
8 | Chaudhary, R., Dhepe, P.L. 2017. Solid base catalyzed depolymerization of lignin into low molecular weight products. Green Chemistry 19: 778-788. DOI |
9 | Das, J., Halgeri, A.B. 2000. Selective synthesis of para-ethylphenol over pore size tailored zeolite. Applied Catalysis A: General 194: 359-363. |
10 | Fang, B., Binder, L. 2006. A modified activated carbon aerogel for high-energy storage in electric double layer capacitors. Journal of Power Sources 163(1): 616-622. DOI |
11 | Hanzawa, Y., Kaneko, K., Pekala, R., Dresselhaus, M. 1996. Activated carbon aerogels. Langmuir 12(26): 6167-6169. DOI |
12 | Fang, Z., Sato, T., Smith, R.L., Inomata, H., Arai, K., Kozinski, J.A. 2008. Reaction chemistry and phase behavior of lignin in high-temperature and supercritical water. Bioresource Technology 99(9): 3424-3430. DOI |
13 | Farag, S., Kouisni, L., Chaouki, J. 2014. Lumped approach in kinetic modeling of microwave pyrolysis of kraft lignin. Energy & Fuels 28(2): 1406-1417. DOI |
14 | Gosselink, R.J., Teunissen, W., Van Dam, J.E., De Jong, E., Gellerstedt, G., Scott, E.L., Sanders, J.P. 2012. Lignin depolymerisation in supercritical carbon dioxide/acetone/water fluid for the production of aromatic chemicals. Bioresource Technology 106: 173-177. DOI |
15 | Huang, X., Atay, C., Koranyi, T.I., Boot, M.D., Hensen, E.J. 2015. Role of Cu-Mg-Al mixed oxide catalysts in lignin depolymerization in supercritical ethanol. ACS Catalysis 5(12): 7359-7370. DOI |
16 | Huang, S., Mahmood, N., Tymchyshyn, M., Yuan, Z., Xu, C.C. 2014. Reductive de-polymerization of kraft lignin for chemicals and fuels using formic acid as an in-situ hydrogen source. Bioresource Technology 171: 95-102. DOI |
17 | Jegers, H.E., Klein, M.T. 1985. Primary and secondary lignin pyrolysis reaction pathways. Industrial & Engineering Chemistry Process Design and Development 24(1): 173-183. DOI |
18 | Kim, J.-Y., Oh, S., Hwang, H., Cho, T.-s., Choi, I.-G., Choi, J.W. 2013. Effects of various reaction parameters on solvolytical depolymerization of lignin in sub-and supercritical ethanol. Chemosphere 93(9): 1755-1764. DOI |
19 | Laskar, D.D., Tucker, M.P., Chen, X., Helms, G.L., Yang, B. 2014. Noble-metal catalyzed hydrodeoxygenation of biomass-derived lignin to aromatic hydrocarbons. Green Chemistry 16(2): 897-910. DOI |
20 | Kim, J.-Y., Park, J., Kim, U.-J., Choi, J.W. 2015. Conversion of lignin to phenol-rich oil fraction under supercritical alcohols in the presence of metal catalysts. Energy & Fuels 29(8): 5154-5163. DOI |
21 | Ling, S.K., Tian, H.-Y., Wang, S., Rufford, T., Zhu, Z., Buckley, C. 2011. KOH catalysed preparation of activated carbon aerogels for dye adsorption. Journal of Colloid and Interface Science 357(1): 157-162. DOI |
22 | Long, J., Zhang, Q., Wang, T., Zhang, X., Xu, Y., Ma, L. 2014. An efficient and economical process for lignin depolymerization in biomass-derived solvent tetrahydrofuran. Bioresource technology 154: 10-17. DOI |
23 | Lora, J.H., Glasser, W.G. 2002. Recent industrial applications of lignin: a sustainable alternative to nonrenewable materials. Journal of Polymers and the Environment 10(1-2): 39-48. DOI |
24 | Moreno-Castilla, C., Maldonado-Hodar, F. 2005. Carbon aerogels for catalysis applications: An overview. Carbon 43(3): 455-465. DOI |
25 | Namane, A., Mekarzia, A., Benrachedi, K., Belhaneche-Bensemra, N., Hellal, A. 2005. Determination of the adsorption capacity of activated carbon made from coffee grounds by chemical activation with ZnCl 2 and H 3 PO 4. Journal of Hazardous Materials 119(1): 189-194. DOI |
26 | Park, H.W., Hong, U.G., Lee, Y.J., Song, I.K. 2011. Decomposition of 4-phenoxyphenol to aromatics over palladium catalyst supported on activated carbon aerogel. Applied Catalysis A: General 409: 167-173. |
27 | Saha, B.C., Nichols, N.N., Qureshi, N., Kennedy, G.J., Iten, L.B., Cotta, M.A. 2015. Pilot scale conversion of wheat straw to ethanol via simultaneous saccharification and fermentation. Bioresource technology 175: 17-22. DOI |
28 | Park, J., Kim, J.Y., Choi, J.W. 2015. Degradation of Plant Lignin with The Supercritical Ethanol and Ru/C Catalyst Combination for Lignin-oil. Journal of The Korean Wood Science & Technology 43(3): 355-363. DOI |
![]() |