• Title/Summary/Keyword: binder paste

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Effect of Blast Furnace Slag on Rheological Properties of Fresh Mortar (고로슬래그미분말의 치환율 변화에 따른 굳지않은 모르타르의 레올로지 특성 검토)

  • Lim, Ji-Hee;Lee, Gun-Cheol
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.4
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    • pp.285-291
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    • 2014
  • Partial replacement of cement with blast furnace slag has many advantages such as the reduction of construction fee, the decrease of hydration heat and the increase of long-term strength. Hence, slag is widely used in practice. This study investigates the effect of slag on the rheological properties of cement paste and mortar. Three different types of slag (BS1, BS2 and BS3) with five different contents (0, 20, 40, 60 and 80 wt.%) were used to replace the cement. Each type of slag has different fineness. Water to binder ratio was 0.5. Test results showed that the partial replacement of BS1 and BS2 decreased flow and increased O-lot flow time, whereas that of BS3 caused an opposite effect, i.e., increased flow and decreased O-lot flow time. It was found that there was a good corelation between the values of yield stress and flow.

Characteristics of Hydraulic Lime using Low-grade Dolomitic Limestone

  • Moon, Ki-Yeon;Choi, Moon-Kwan;Cho, Jin-Sang;Cho, Kye-Hong;Ahn, Ji-Whan
    • Journal of the Korean Ceramic Society
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    • v.53 no.2
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    • pp.206-214
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    • 2016
  • This study aims to produce dolomitic hydraulic lime (D-NHL) using domestic low grade dolomitic limestone and to determine the effect of adding blast furnace slag (BFS) and gypsum as part of an investigation of the hydration properties of D-NHL to increase the mechanical properties. The main mineral phases of D-NHL as a hydraulic lime binder were $Ca(OH)_2$, $Mg(OH)_2$, $C_2S$, $C_3S$, and MgO residues. $Ca(OH)_2$ transformed into $CaCO_3$ in D-NHL paste over the period of 28 days, but the carbonation of $Mg(OH)_2$ and the hydration of $C_2S$ did not occur until hydration, after 28 days. Through an investigation of the hydration properties of D-NHL pastes mixed with BFS and gypsum, Al-based compounds such as calcium aluminate hydrates ($C_4AH_{13}$) and ettringite were observed at early hydration time. The compressive strength was improved due to the increased quantities of these hydration products. These results show that good performance results from the application of dolomitic hydraulic lime and that a high value product can be made from domestic waste materials.

Adsorption of residual gases on carbon nanotubes and their field emission properties

  • Lee, Han-Sung;Jang, Eun-Soo;Goak, Jeung-Choon;Kim, Jin-Hee;Lee, Nae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.51-51
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    • 2008
  • Carbon nanotubes (CNTs) have long been reported as an ideal material due to their excellent electrical conductivity and chemical and mechanical stability as well as their high aspect ratios for field emission devices. CNT emitters made by screen printing the organic binder-based CNT paste may act as a source to release gases inside a vacuum panel. These residual gases may cause a catastrophic damage by electrical arcing or ion bombardment to the vacuum microelectronic devices and may change their physical or electrical properties by adsorbing on the CNT emitter surface. In this study, we analyzed the composition of residual gases inside the vacuum-sealed panel by residual gas analyzer (RGA), investigating the effects of individual gases of different kinds at several pressures on the field emission characteristics of CNT emitters. The residual gases included $H_2$, CO, $CO_2$, $N_2$, $CH_4$, $H_2O$, $C_2H_6$, and Ar. Effect of residual gases on the field emission was studied by observing the variation of the pulse voltages with the duty ratio of3.3% to keep the constant emission current of $28{\mu}A$. Each gas species was introduced to a vacuum chamber up to three different pressures ($5\times10^{-7}$, $5\times10^{-6}$, and $5\times10^{-5}$ torr) each for 1 h while electron emission was continued. The three different pressure regions were separated by keeping a high vacuum of $\sim10^{-8}$ torr for a 1 h. The emission was terminated 6 h after the third gas exposure was completed. Field emission characteristics under residual gases will be discussed in terms of their adsorption and desorption on the surface of CNTs and the resultant change of work function.

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Design and Fabrication of Semi-cylindrical Radar Absorbing Structure using Fiber-reinforced Composites (섬유강화 복합재료를 이용한 반원통형 전자파 흡수구조의 설계 및 제작)

  • Jang, Hong-Kyu;Shin, Jae-Hwan;Kim, Chun-Gon;Shin, Sang-Hun;Kim, Jin-Bong
    • Composites Research
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    • v.23 no.2
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    • pp.17-23
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    • 2010
  • The stealth technology can increase the survivability of aircrafts or warships and enhance the capability of mission completion in hostile territory. The purpose of this paper is to present the low observable structure with curved surfaces made by fiber-reinforced composites and to show the possibility of developing omnidirectional stealth platforms for military applications. In this study, we developed a radar absorbing structures(RAS) based on a circuit analog absorber to reduce the radar cross section(RCS) of an object with curved surfaces. Firstly, the RAS with a periodic square patterned conducting polymer layer was designed and simulated using a commercial 3-D electromagnetic field analysis program. Secondly, the designed semi-cylindrical structure with low RCS was fabricated using fiber-reinforced composites and conducting polymer. To make the periodic pattern layer, acts as resistive sheet, the intrinsic conducting polymer paste containing PEDOT with a polyurethane binder was used. Finally, the radar cross section was measured to evaluate the radar absorbing performances of the fabricated RAS by the compact range facility in POSTECH.

Optimization of Printing Process for the Development of Metal-oxide Resistivity Sensor (전기저항형 금속산화물 센서의 인쇄공정 최적화에 관한 연구)

  • Lee, Seokhwan;Koo, Jieun;Lee, Moonjin;Jung, Jung-Yeul;Chang, Jiho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.6
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    • pp.353-358
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    • 2016
  • In this paper, we have studied about the optimum fabrication condition of the printed Indium Tin Oxide (ITO) layers for the electrical resistance-type sensor application. We have investigated on the substrates surface treatments, mixing ratio of organic binder/ITO powder, and viscosity of the printing paste to determine the optimum condition of the screen printed ITO layer. Also, we found that the printing condition is closely related with the sensor performance. To know the feasibility of printed ITO layer as an electrical resistance-type sensor, we have fabricated the ITO sensors with a printed and sputtered ITO layers. The printed ITO films revealed $10^2$ times higher sensitivity than the sputtered ITO layer. Also, the sputtered ITO layer exhibited an operating temperature of $127^{\circ}C$ at the operating voltage of 5 V. While, in case of the printed ITO layer showed the operating temperature of $27.6^{\circ}C$ in high operating voltage of 30 V. We found that the printed ITO layer is suitable for the various sensor applications.

A Study on the Fabrication of Multi-Walled Nanotubes (MWCNT) Based Thin Film and Chemical Sensor Operation Characteristics (Multi-Walled Carbon Nanotubes (MWCNT) 인쇄박막의 제작과 화학센서 동작 특성에 관한 연구)

  • Noh, Jae Ha;Choi, Junseck;Ko, Dongwan;Seo, Joonyoung;Lee, Sangtae;Jung, Jung-Yeul;Chang, Jiho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.3
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    • pp.181-185
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    • 2020
  • Hazardous and noxious substance (HNS) detection sensors were fabricated using multi-walled carbon nanotubes (MWCNTs) and various binder materials for ion batteries. To obtain uniformly printed films, the printing precision according to the substrate cleaning method was monitored, and the printing paste mixing ratio was investigated. Binders were prepared using styrene butadiene rubber + carboxymethyl cellulose (SBR+CMC), polyvinylidene fluoride + n-methyl-2-pyrrolidene (PVDF+NMP), and mixed with MWCNTs. The surface morphology of the printed films was examined using an optical microscope and a scanning electron microscope, and their electrical properties are investigated using an I-V sourcemeter. Finally, sensing properties of MWCNT printed films were measured according to changes in the concentration of the chemical under the various applied voltages. In conclusion, the MWCNT printed films made of (SBR+CMC) were found to be feasible for application to the detection of hazardous and noxious chemicals spilled in seawater.

Fundamental Characteristics of Activated Fly Ash-Slag Cement Exposed to 5℃ Seawater (5℃ 해수에 노출된 알칼리 활성 플라이애시-슬래그 시멘트의 기초 특성)

  • Kim, Taewan;Jun, Yubin
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.302-309
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    • 2019
  • This paper shows an experimental study for fundamental characteristics of alkali activated fly ash-slag cement paste exposed to seawater of 5℃. Fly ash and slag were blended in three different ratios; 6:4, 7:3, and 8:2. Activators (NaOH and Na2SiO3) used 5% of the binder weight. It was shown that as the fly ash substitution rate in creased, compressive strength and density decreased, and water absorption rate increased. The results of X-ray diffraction and thermogravimetry showed that hydration reactants formed in samples did not differ significantly, however, C-S-H gel increased as the slag substitution rate increased. It showed that mechanical properties of fly ash-slag cement pastes under 5℃ seawater condition were affected by the slag substitution rate rather than fly ash.

Electrical Properties of Thick-Film Resistor Prepared by Using RuO2-Glass Composite Powder (RuO2-유리 복합분말을 이용하여 제조된 후막 저항의 전기적 특성 연구)

  • Kim, Min-Sik;Ryu, Sung-Soo
    • Journal of the Korean institute of surface engineering
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    • v.50 no.5
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    • pp.301-307
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    • 2017
  • The purpose of this study is to investigate the electrical properties of thick-film resistor (TFR) prepared from $CaO-ZnO-B_2O_3-Al_2O_3-SiO_2$ (CZBAS) glass containing $RuO_2$ particles. $RuO_2$-glass composite powder was made by mixing and melting oxide powders of constituents. For comparison, $RuO_2$ powder was simply mixed with glass powder. $RuO_2$-40wt% glass composite and mixture were dispersed in an organic binder to obtain printable resistor paste and then thick-film was formed by screen printing, followed by sintering at the range between $750^{\circ}C$ and $900^{\circ}C$ for 10 min with a heating rate of $50^{\circ}C/min$ in an ambient atmosphere. $RuO_2$-glass composite sample showed much higher resistance compared to the simple mixed sample. This could be attributed to the difference in conducting mechanism. After sintering at $850^{\circ}C$, temperature coefficient of resistance of composite sample was lower than that of simple-mixed sample. TFR with dense and homogeneous microstructure could be obtained by using $RuO_2$-glass composite powder.

Optimum Combination of Thermoplastic Formability and Electrical Conductivity in Al-Ni-Y Metallic Glass

  • Na, Min Young;Park, Sung Hyun;Kim, Kang Cheol;Kim, Won Tae;Kim, Do Hyang
    • Metals and materials international
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    • v.24 no.6
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    • pp.1256-1261
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    • 2018
  • Both thermoplastic formability and electrical conductivity of Al-Ni-Y metallic glass with 12 different compositions have been investigated in the present study with an aim to apply as a functional material, i.e. as a binder of Ag powders in Ag paste for silicon solar cell. The thermoplastic formability is basically influenced by thermal stability and fragility of supercooled liquid which can be reflected by the temperature range for the supercooled liquid region (${\Delta}T_x$) and the difference in specific heat between the frozen glass state and the supercooled liquid state (${\Delta}C_p$). The measured ${\Delta}T_x$ and ${\Delta}C_p$ values show a strong composition dependence. However, the composition showing the highest ${\Delta}T_x$ and ${\Delta}C_p$ does not correspond to the composition with the highest amount of Ni and Y. It is considered that higher ${\Delta}T_x$ and ${\Delta}C_p$ may be related to enhancement of icosahedral SRO near $T_g$ during cooling. On the other hand, electrical resistivity varies with the change of Al contents as well as with the change of the volume fraction of each phase after crystallization. The composition range with the optimum combination of thermoplastic formability and electrical conductivity in Al-Ni-Y system located inside the composition triangle whose vertices compositions are $Al_{87}Ni_3Y_{10}$, $Al_{85}Ni_5Y_{10}$, and $Al_{86}Ni_5Y_9$.

A Study on the Ozone Reduction of Plasma Devices by Catalyst Method (촉매법을 적용한 오존 저감형 플라즈마 기기)

  • Jeon, Sin Young;Kim, Dong Jun;Kim, Jong Yeop;Gwon, Jin Gu;Jeon, Young Min;Do, Gye Ryung;Lee, Seong Eui
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.34 no.1
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    • pp.56-62
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    • 2021
  • In this study, we created a DBD plasma device and a MnO2 catalyst mesh filter for evaluating ozone reduction of devices via the catalyst method. The DBD plasma device was manufactured by applying Ag paste to soda lime glass via the screen-printing method. The MnO2 catalyst mesh filter was manufactured by mixing MnO2 powder with binder with a 10% difference in concentration from 10% to 50% and then applying it using the dip-coating method. Finally, we sintered a MnO2 catalyst mesh filter in an electric furnace. We evaluated the characteristics of ozone generation according to the Ar gas flow of DBD plasma devices, the opening ratio, and ozone reduction performance of the MnO2 catalyst filters. Ozone reduction performance was approximately 20.4% at MnO2 10 wt%, 37.8% at MnO2 30 wt% and 50% at MnO2 50 wt%.