• Bulletin of the Korean Chemical Society
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• v.31 no.4
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• pp.953-958
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• 2010

A laser ablation-molecular beam/reflectron time-of-flight mass spectrometric technique was used to investigate the ion-molecule reactions that proceed within $Ti^+(CH_3COCH_3)_n$ heterocluster ions. The reactions of $Ti^+$ with $CH_3COCH_3$ clusters were found to be dominated exclusively by an oxidation reaction, which produced $TiO^+(CH_3COCH_3)_n$ clusters. These ions were attributed to the insertion of a $Ti^+$ ion into the C=O bond of the acetone molecule within the heteroclusters, followed by $C_3H_6$ elimination. The mass spectra also indicated the formation of minor sequences of heterocluster ions with the formulas $Ti^+(C_3H_4O)(CH_3COCH_3)_n$ and $TiO^+(OH)(CH_3COCH_3)_n$, which could be attributed to C-H bond insertion followed by $H_2$ elimination and to the sequential OH abstraction by the $TiO^+$ ion, respectively. Density functional theory calculations were carried out to model the structures and binding energies of both the association complexes and the relevant reaction products. The reaction pathways and energetics of the $TiO^+\;+\;CH_2CHCH_3$ product channel are presented.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.27 no.6
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• pp.589-596
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• 2014

Joints, fasteners or connected parts frequently have a significant effect on the dynamical behavior of assembled mechanical structures. Therefore, the analytical prediction of structural responses depends on the accuracy of joint modeling. This paper deals with the formulation and analysis of dynamic mechanism for joint flexibilities whose relevant magnitudes of stiffnesses are investigated by using linear and torsional springs. The equation of motion is derived by using a generic joint in the middle of clamped-clamped beam. A reanalysis due to changes in magnitudes of joint stiffnesses is based on the reduced analysis where the binomial series terms are used as basis vectors. The solution procedures are straightforward and the method can be readily used with a general finite element method. The computational effort needed by this approach is usually much smaller than the effort needed for complete vibration analysis. Two numerical examples show that accurate results are obtained efficiently by reducing the number of degree in the reduced model.

• Structural Engineering and Mechanics
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• v.56 no.6
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• pp.899-916
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• 2015

Upgrading or strengthening of existing reinforced concrete (RC) infrastructure is an emerging demand nowadays. Near Surface Mounted (NSM) technique is very promising approach for flexural strengthening of RC members. However, premature failure such as concrete cover separation failure have been a main concern in utilizing this technique. In this study, U-wrap end anchorage with carbon fiber reinforced polymer (CFRP) fabrics is proposed to eliminate the concrete cover separation failure. Experimental programs were conducted to the consequence of U-wrap end anchorage on the flexurally strengthened RC beams with NSM-steel. A total of eight RC rectangular beam specimens were tested. One specimen was kept unstrengthened as a reference; three specimens were strengthened with NSM-steel bars and the remaining four specimens were strengthened with NSM-steel bars and U-wrap end anchorage using CFRP fabrics. A 3D non-linear finite element model (FEM) was developed to simulate the flexural response of the tested specimens. It is revealed that NSM-steel (with and without end-anchors) significantly improved the flexural strength; moreover decreased deflection and strains compared with reference specimen. Furthermore, NSM-steel with end anchorage strengthened specimens revealed the greater flexural strength and improve failure modes (premature to flexure) compared with the NSM-steel without end anchorage specimens. The results also ensured that the U-wrap end anchorage completely eliminate the concrete cover separation failure.

• Structural Engineering and Mechanics
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• v.31 no.2
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• pp.163-180
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• 2009

In the design of tall reinforced concrete (R/C) buildings, the serviceability stiffness criteria in terms of maximum lateral displacement and inter-story drift must be satisfied to prevent large second-order P-delta effects. To accurately assess the lateral deflection and stiffness of tall R/C structures, cracked members in these structures need to be identified and their effective member flexural stiffness determined. In addition, the implementation of the geometric nonlinearity in the analysis can be significant for an accurate prediction of lateral deflection of the structure, particularly in the case of tall R/C building under lateral loading. It can therefore be important to consider the cracking effect together with the geometric nonlinearity in the analysis in order to obtain more accurate results. In the present study, a computer program based on the iterative procedure has been developed for the three dimensional analysis of reinforced concrete frames with cracked beam and column elements. Probability-based effective stiffness model is used for the effective flexural stiffness of a cracked member. In the analysis, the geometric nonlinearity due to the interaction of axial force and bending moment and the displacements of joints are also taken into account. The analytical procedure has been demonstrated through the application of R/C frame examples in which its accuracy and efficiency in comparison with experimental and other analytical results are verified. The effectiveness of the analytical procedure is also illustrated through a practical four story R/C frame example. The iterative procedure provides equally good and consistent prediction of lateral deflection and effective flexural member stiffness. The proposed analytical procedure is efficient from the viewpoints of computational effort and convergence rate.

• Smart Structures and Systems
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• v.22 no.4
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• pp.413-424
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• 2018

The factors affecting the shear strength of the angle shear connectors in the steel-concrete composite beams can play an important role to estimate the efficacy of a composite beam. Therefore, the current study has aimed to verify the output of shear capacity of angle shear connector according to the input provided by Support Vector Machine (SVM) coupled with Firefly Algorithm (FFA). SVM parameters have been optimized through the use of FFA, while genetic programming (GP) and artificial neural networks (ANN) have been applied to estimate and predict the SVM-FFA models' results. Following these results, GP and ANN have been applied to develop the prediction accuracy and generalization capability of SVM-FFA. Therefore, SVM-FFA could be performed as a novel model with predictive strategy in the shear capacity estimation of angle shear connectors. According to the results, the Firefly algorithm has produced a generalized performance and be learnt faster than the conventional learning algorithms.

• The Journal of the Convergence on Culture Technology
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• v.6 no.4
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• pp.753-760
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• 2020

In this study, the structural safety of the bearing support was analysed by applying the vertical load (bearing design load) and horizontal load (horizontal force generated during an earthquake) using a precise three-dimensional numerical model. The results of stress and displacement of newly-poured concrete and welded rebars were confirmed numerically. Numerical results show that the increase in the horizontal force and the height of the beam causes the concrete cracking and the stress increase of the rebar connections due to the increase of the stress at the new concrete interface. Therefore, it was analyzed that the increase in the height of bearing support is directly related to the horizontal force and it is necessary to apply the bearing support height appropriate for the bearing support capacity. It was proposed that a method of setting the height of the bearing support suitable for the bearing capacity and determining the reinforcement by presenting the guideline with the correlation between the horizontal force acting on the bearing support and its height.

• Korean Journal of Optics and Photonics
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• v.25 no.4
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• pp.200-206
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• 2014

In this paper, using the value theoretically calculated to emit multidirectionally a beam coming into an optical fiber with diameter of $125{\mu}m$, we modeled and produced a cone-shaped structure at the distal end of the fiber. A numerical simulation was performed for an optical fiber tip in which all incident beams were totally reflected and emitted toward the side, as well as for an optical fiber tip from which the beams could be emitted forward and sideways simultaneously. We produced multidirectional-firing optical fiber tips based on the simulation result and model. Laser fabrication of the optical fiber was done by processing a cone-shaped structure at the distal end of an optical fiber with diameter of $125{\mu}m$ using a femtosecond pulsed laser and polishing the processed surface with a $CO_2$ laser. We also conducted an analysis to compare experimental and simulation results.

• Journal of Magnetics
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• v.14 no.1
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• pp.36-41
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• 2009

Magneto-optical Kerr effect (MOKE) magnetometry was used to investigate magnetization reversal dynamics in 30-nm NiFe/15-nm FeMn, 15-nm FeMn/30-nm CoFe bilayers, and 30-nm NiFe/(2,10)-nm FeMn/30-nm CoFe trilayers. The in-plane magnetization components of each ferromagnetic layer, both parallel and perpendicular to the applied field, were separately determined by measuring the longitudinal and transverse MOKE hysteresis loops from both the front and back sides of the film for an oblique incident s-polarized beam. The magnetization of the FeMn/CoFe bilayer was reversed abruptly and symmetrically through nucleation and domain wall propagation, while that of the NiFe/FeMn bilayer was reversed asymmetrically with a dominant rotation. In the NiFe/FeMn/CoFe trilayers, the magnetic reversal of the two ferromagnetic layers proceeded via nucleation and domain wall propagation for 2-nm FeMn, but via asymmetric rotation for 10-nm FeMn. The exchange-biased ferromagnetic layers showed the magnetization reversal along the same path in the film plane for the decreasing and increasing field branches from transverse MOKE hysteresis loops, which can be qualitatively explained by the theoretical model of the exchange-biased ferromagnetic/antiferromagnetic systems.

• Proceedings of the Korea Concrete Institute Conference
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• 2004.11a
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• pp.409-412
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• 2004

Over last decade extensive researches have been undertaken on the strength behaviour of Fiber Reinforced Concrete(FRC) structures. But the use of Ultra-High Strength Steel Fiber Cementitious Concrete Composites is in its infancy and there is a few experiments, analysis method and design criteria on the structural elements constructed with this new generation material which compressive strength is over 150 MPa and characteristic behaviour on the failure status is ductile. The objective of this paper is to investigate and analyze the behaviour of reinforced rectangular structural members constructed with ultra high performance cementitious composites (UHPCC). This material is known as reactive powder concrete (RPC) mixed with domestic materials and its compressive strength is over 150MP. The variables of test specimens were shear span ratio, reinforcement ratio and fiber quantity. Even if there were no shear stirrups in test specimens, most influential variable to determine the failure mode between shear and flexural action was proved to be shear span ratio. The characteristics of ultra high-strength concrete is basically brittle, but due to the steel fiber reinforcement behaviour of this structure member became ductile after the peak load. As a result of the test, the stress block of compressive zone could be defined. The proposed analytical calculation of internal force capacity based by plastic analysis gave a good prediction for the shear and flexural strength of specimens. The numerical verification of the finite element model which constitutive law developed for Mode I fracture of fiber reinforced concrete correctly captured the overall behaviour of the specimens tested.

• Smart Structures and Systems
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• v.11 no.4
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• pp.411-433
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• 2013

Due to its easy operation and wide applicability, the ambient vibration method is commonly adopted to determine the cable force by first identifying the cable frequencies from the vibration signals. With given vibration length and flexural rigidity, an analytical or empirical formula is then used with these cable frequencies to calculate the cable force. It is, however, usually difficult to decide the two required parameters, especially the vibration length due to uncertain boundary constraints. To tackle this problem, a new concept of combining the modal frequencies and mode shape ratios is fully explored in this study for developing an accurate method merely based on ambient vibration measurements. A simply supported beam model with an axial tension is adopted and the effective vibration length of cable is then independently determined based on the mode shape ratios identified from the synchronized measurements. With the effective vibration length obtained and the identified modal frequencies, the cable force and flexural rigidity can then be solved using simple linear regression techniques. The feasibility and accuracy of the proposed method is extensively verified with demonstrative numerical examples and actual applications to different cable-stayed bridges. Furthermore, several important issues in engineering practice such as the number of sensors and selection of modes are also thoroughly investigated.