• 한국지열·수열에너지학회논문집
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• 제18권4호
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• pp.1-11
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• 2022

In this study, the thermal runaway of NCM and LFP batteries were compared and analyzed through numerical analysis under various conditions. Comparing the thermal runaway of the NCM622 (18650) battery cell and the LFP (18650) battery cell through oven test simulation, the LFP battery did not show thermal runaway, whereas the NCM622 battery temperature increased to 710℃ in 12 minutes. To observe the thermal runaway and propagation of the prismatic LFP battery cell, the internal temperature was set at 200℃ and the oven test simulation was conducted. It was found that thermal runaway occurred at 391℃ after 47 minutes. As a result of observing thermal runaway propagation by placing five NCM622 and LFP battery cells, the thermal runaway propagation was clearly observed in the case of the NCM622 battery, but in the case of the LFP battery, thermal runaway was not observed after the first cell. From the third battery cell, it was confirmed that the temperature change was very insignificant, and through this, it is considered that the LFP battery is relatively safe compared to the NCM battery in terms of the thermal runaway propagation of the battery.

• Design & Manufacturing
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• 제16권1호
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• pp.36-42
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• 2022

Globally, as population growth and economic development continue, resource consumption is increasing rapidly. As an alternative to electric vehicles was suggested as the environmental pollution problem emerged, the number of registered electric vehicles in Korea increased by more than 137 times compared to 2013. Secondary batteries are expected to expand into various markets such as small IT devices and electric vehicles, and the most important part of electric vehicles is the battery (secondary battery). Therefore, in this study, to analyze the stability of the CSM (Classifier Separator Mill) grinding disc that crushes secondary battery raw materials, structural analysis and vibration analysis of the 1st to 4th grinding discs and the final model were performed. The change of bending by the weight of the Grinding Disc is at least 0.065㎛ and maximum 0.075㎛, and the change by the standard gravity is judged to be very low. The strain is at least 0.00031㎛/㎛ and maximum 0.00078㎛/㎛, and even if the number of Hamer increases, the change by the weight is judged to be insignificant. When the Grinding Disc rotates at a maximum of 6000rpm, the deformation and deformation rate of the first to third models are similar, but the fourth model (Hamer 10EA) is more than three times and the final model (Hamer 12EA) is about four times. However, the maximum deformation is 28.21㎛, which is considered to be insignificant when the change is 6000rpm. Six modes of natural Frequency analysis of the 1st~4th order and final model of the grinding disc appeared to be bent or twisted.

• 한국산학기술학회논문지
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• 제21권12호
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• pp.339-345
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• 2020

국방 분야에서 유도무기와 같은 일회성 무기체계는 제작 후 오랜 기간 보관되어지기 때문에 수명 예측이 필수적이다. 본 연구에서는 유도무기에 사용되는 리튬 2차 전지에 대해 수명을 확인하기 위한 연구를 수행하였다. 연구를 위해 5년 이상 무기체계에 탑재되어 사용된 리튬 2차 전지를 확보하였으며, 비기능 검사를 수행하여 외적인 변화나 고장이 발생하였는지 확인하였다. 비기능 검사가 끝난 후 리튬 2차 전지의 성능 측정을 위한 방전 시험을 실시하였으며, 방전 시험 시 전지를 규격에 맞추어 충전한 후 방전 시험을 실시하였다. 방전 시험을 통해 초기 충전 전압, 방전 시간, 전지 온도 등을 측정하였으며, 이를 기존에 측정된 데이터와 비교하여 성능 변화 경향을 확인하였다. F-검정과 일원분산분석(One-way ANOVA, Analysis of Variance), 회귀 분석을 통해 노화가 발생하였는지 확인하였으며, 회귀 분석을 통해 측정된 근사식을 통해 리튬 전지의 수명을 추정하였다. 분산분석 결과 p-value 값이 기준값 0.05보다 작은 것을 알 수 있었으며, 일정 시간이 경과하였을 때에 전지의 성능이 15% 이상 감소하는 것을 확인할 수 있었다. 이러한 성능 변화는 리튬 폴리머 셀의 물성 변화로 인해 일어나는 것으로 추정된다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2001년도 하계학술대회 논문집 D
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• pp.2187-2189
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• 2001

The proposed algorithm has produced the rules of relationship between the load voltage, current, discharging electric power and ampere-hours, electric power capacity of battery on the basis of the data. Which were acquired through the battery discharging experiment that is defined by the battery's ambient temperature and various load conditions. Especially, by calculating the parameter of second order polynomial equation relation between the remaining capacity and the electric power, the algorithm is proposed adapting for the discharging pattern. And as the depth of discharging is increasing, the calculation-method of electric power is applied to decrease the accumulated error in the calculation method of capacity accumulation. Also, the proposed algorithm has compensated the temperature considering the capacity change of battery to the temperature.

• Bulletin of the Korean Chemical Society
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• 제29권10호
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• pp.1965-1968
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• 2008

The effects of carbon-coated silicon/graphite (Si/Gr.) composite anode on the electrochemical properties were investigated. The nanosized silicon particle shows a good cycling performance with a reasonable value of the first reversible capacity as compared with microsized silicon particle. The carbon-coated silicon/graphite composite powders have been prepared by pyrolysis method under argon/10 wt% propylene gas flow at $700{^{\circ}C}$ for 7 h. Transmission electron microscopy (TEM) analysis indicates that the carbon layer thickness of 5 nm was coated uniformly onto the surface silicon powder. It is confirmed that the insertion of lithium ions change the crystalline silicon phase into the amorphous phase by X-ray diffraction (XRD) analysis. The carbon-coated composite silicon/graphite anode shows excellent cycling performance with a reversible value of 700 mAh/g. The superior electrochemical characteristics are attributed to the enhanced electronic conductivity and low volume change of silicon powder during cycling by carbon coating.

• 보건교육건강증진학회지
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• 제21권2호
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• pp.199-214
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• 2004

This study was aimed to assess the social functions of rural residents and to identify factors related with social function. This study conducted a survey using interview-type questionnaires with the Rand social health battery, and measured social function and the related factors between August 21th and August 23th, at 2001. The study subjects were 546 people (158 males, 388 females) living in Chungju-City. The social functions of the subjects were very weak. 20.7 % of respondents said they had no family in their neighbors and they were not well enough acquainted with neighborhood to visit each other. The 24.2 % of respondents said they had no mend that they felt at ease with and could talk frankly. Social function scores were significantly associated with economic status (p＝0.0494), having a vehicle (p＝0.0019), daily living activity (p＝0.0092) in multiple analysis. However, there was no association with age, education, smoking, alcohol consumption, and chronic disease. Our finding showed that social function was not associated with health behaviors definitely. However, It may be important to change existing social network and social function in order to change health behaviors.

• 전기전자학회논문지
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• 제27권1호
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• pp.85-92
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• 2023

최근 4차 산업혁명 시대가 다가오면서 휴대성을 강조한 IoT 기기가 늘고 있다. 동시에 배터리 사용량도 급증하고 있다. 배터리 사용량이 증가하면서 배터리 안전과 관련된 이슈는 피할 수 없는 문제가 되었고, 많은 연구가 이뤄졌다. 본 논문은 다양한 배터리 문제 중 팽창으로 인한 폭발 문제를 다루고 있으며, 저항 변화를 파악하여 배터리 팽창을 감지하는 시스템의 연구 및 개발을 포함하고 있다. 이번 연구의 핵심기술은 배터리가 팽창할 때 발생하는 부피 변화를 배터리에 그려진 전선의 저항 변화를 이용해 배터리 폭발을 방지하는 시스템을 개발하는 것이다. 또한 패턴분석을 통해 어떤 형태로 전선을 구성하여야 저항 변화가 많이 일어나는지 분석하였다.

• KIEE International Transactions on Electrophysics and Applications
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• 제3C권5호
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• pp.189-193
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• 2003

Initial irreversible capacity (IIC) can be defined by means of the initial intercalation Ah efficiency (IIE) and the initial irreversible specific capacity at the surface (IICs) with the linear-fit range of the intercalation so as to precisely express the irreversibility of an electrode-electrolyte system. Their relationship was IIC = Qc - Q$_{D}$ = (IIE$^{-1}$ - 1) Q$_{D}$ + IICs in the linear-fit range of IIE. Here, Qc and Qd signify charge and discharge capacity, respectively, based on a complete lithium ion battery cell. Charge indicates lithium insertion to carbon anode. Two terms of IIE and IICs depended on the types of active materials and compositions of the electrode and electrolyte but did not change with charging state. In an ideal electrode-electrolyte system, IIE and IICs would be 100%, 0 mAh/g for the electrode and mAh for the cell, respectively. These properties can be easily obtained by the Gradual Increasing of State of Charge (GISOC).OC).

• Journal of Power Electronics
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• 제15권1호
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• pp.31-38
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• 2015

In this paper, a buck-boost type battery charger is developed for charging battery set with a lower voltage. This battery charger is configured by a rectifier circuit, an integrated boost/buck power converter and a switched capacitors circuit. A boost power converter and a buck power converter sharing a common power electronic switch are integrated to form the integrated boost/buck power converter. By controlling the common power electronic switch, the battery charger performs a hybrid constant-current/constant-voltage charging method and gets a high input power factor. Accordingly, both the power circuit and the control circuit of the developed battery charger are simplified. The switched capacitors circuit is applied to be the output of the boost converter and the input of the buck converter. The switched capacitors circuit can change its voltage according to the utility voltage so as to reduce the step-up voltage gain of the boost converter when the utility voltage is small. Hence, the power efficiency of a buck-boost type battery charger can be improved. Moreover, the step-down voltage gain of the buck power converter is reduced to increase the controllable range of the duty ratio for the common power electronic switch. A prototype is developed and tested to verify the performance of the proposed battery charger.

• 전기전자학회논문지
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• 제24권4호
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• pp.1098-1103
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• 2020

본 논문은 리튬 이온 이차 전지의 전기적 실험 및 전기화학적 모델링을 통한 배터리 수명 상태(SOH)의 추정 방법을 다룬다. 배터리 전기적 노화 실험을 통하여 실제 배터리 수명 상태를 확인하기 위하여 전류 적산법을 사용한다. 전기적 실험에서 도출한 내부저항 값을 사용하여 SOH를 추정하며, 전기화학 모델링에서 사이클 수의 증가에 따른 SEI Layer의 변화를 통해 SOH를 추정한다. 실제 배터리 수명 상태를 포함한 세 가지 방법의 SOH 추정 방법에 가중치를 적용하여 새로운 SOH를 도출하며, 이는 전류적산법을 사용하여 구한 실제 값과의 오차를 줄여주어 추정 성능을 높인다.