• Journal of Korean Society of Environmental Engineers
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• v.30 no.3
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• pp.345-351
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• 2008

Fe-impregnated activated carbon(Fe-AC) was prepared by Fe(III) loading on activated carbon(AC) in various preparation pH. In order to evaluate the stability of Fe-AC, dissolution of iron from Fe-AC in acidic conditions was measured. In addition, batch experiments were conducted to monitor the removal efficiency of copper by Fe-AC. Results of stability test for Fe-AC showed that the amount of extracted iron increased with contact time but decreased with increasing solution pH. The dissolved amount of iron gradually increased at solution pH 2 and finally 13% of the total iron loaded on activated carbon was extracted after 12 hr. However dissolution of iron was negligible over solution pH 3. Removal of Cu(II) by Fe-AC was greatly affected by solution pH and was decreased as solution pH increased as well as initial Cu(II) concentration decreased. Surface complexation modeling was performed by considering inner-sphere complexation reaction and using the diffuse layer model with MINTEQA2 program.

• Journal of Korean Society of Environmental Engineers
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• v.37 no.10
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• pp.583-589
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• 2015

This study was performed to evaluate the feasibility of anaerobic pretreatment for the leachate solubilized from thermal hydrolysis of sewage sludge cake. Overall process for the treatment of sludge cake consists of thermal hydrolysis, crystallization of magnesium, ammonium, and phosphate (MAP) for the leachate and anaerobic digestion of supernatant from MAP crystallization. The experimental evidence showed that the optimum ratio of Mg : P for the struvite crystallization of leachate solubilized from thermal hydrolysis of sludge cake was 1.5 to 1.0 as weight basis at the pH of 9.5. With this operational condition, the removal efficiencies of ammonia nitrogen and phosphorous achieved 50% and 97%, respectively. The mesophilic batch test showed that the ultimate biodegradability of the supernatant from MAP crystallization reached 63% at S/I ratio of 0.5. The readily biodegradable fraction of 90% ($S_1$) of the MAP supernatant BVS (Biodegradable Volatile Solids, $S_0$) degraded with $k_1$ of $0.207day^{-1}$ for the initial 17 days where as the rest slowly biodegradable fraction ($S_2$) of 10% of BVS degraded with $k_2$ of $0.02day^{-1}$ for the rest of the operational period. Semi-Continuously Fed and Mixed Reactor (SCFMR) was chosen as one of the best candidates to treat the MAP supernatant because of its total solids content over 6%. Maximum average biogas production rates reached 0.45 v/v-d and TVS removal efficiency of 37~41% was achieved at an hydraulic retention time (HRT) of 20 days and its corresponding organic loading rate (OLR) of 1.43 g VS/L-d.

• Journal of Korean Society of Environmental Engineers
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• v.35 no.8
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• pp.564-570
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• 2013

Domestic treatment facilities for acid mine drainage (AMD) mostly used a passive treatment process. But some passive treatment facility discharged high manganese concentrations because it is required high pH (>9) for abiotic oxidation of Mn(II) to Mn(IV). This study was focused on the feasibility of biological manganese treatment using the manganese-oxidizing bacteria (Pseudomonas sp. MN5) from AMD and economical application method of it. To investigate the various conditions of water quality the most part of the experiments were based on batch test. And result of it showed that maximum manganese oxidation rate were $10.4mg/L{\cdot}h$ at the pH7. We also performed small column tests in which MOB were attached to the functional polyurethane (FPU) media containing alkaline chemicals. Manganese concentration decreased 42 mg/L to below 6 mg/L. But anaerobic condition formed by excessive bacterial respiration in column resulted in increasing effluent manganese concentration.

• Journal of Korean Society of Environmental Engineers
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• v.39 no.1
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• pp.26-33
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• 2017

The objective of this study was to evaluate the characteristic of adsorption by using a meso-porous adsorbent (MPA), and investigate the removal efficiency of geosmin which taste and odor causing compounds in drinking water supplies through batch test. The results for the adsorption isotherm was analyzed by using the Langmuir equation and Freundlich equation, generally being applied. And the study showed that the both Langmuir and Freundlich equation explains the results better. Both of pseudo-first-order model and pseudo-second-order model were respectively applied for evaluation of kinetic sorption property of geosmin onto MPA. The adsorption experiment results using MPA showed that maximum adsorption capacity of MPA was lower 7 times than that of GAC, and adsorption rate of MPA was faster 11 times than that of GAC, on the basis of pseudo-first-order model. Therefore, it was determined that MPA was effectively able to remove geosmin in drinking water supplies in short EBCT condition, but regeneration cycle in MAP process was shorter than that in conventional process.

• Journal of the Korea Concrete Institute
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• v.24 no.3
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• pp.333-340
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• 2012

The current study prepared 9 laboratorial concrete mixes and 3 ready-mixed concrete batches to examine the size and shape effects in compression failure of lightweight aggregate concrete (LWC). The concrete mixes were classified into three groups: normal-weight, all-lightweight and sand-lightweight concrete groups. For each concrete mix, the aspect ratio of circular or square specimens was 1.0 and 2.0. The lateral dimension of specimens varied between 50 and 150 mm for each laboratorial concrete mix, whereas it ranged from 50 to 400 mm with an incremental variation of 50 mm for each ready-mixed concrete batch. Test observations revealed that the crack propagation and width of the localized failure zone developed in lightweight concrete specimens were considerably different than those of normal-weight concrete (NWC). In LWC specimens, the cracks mainly passed through the coarse aggregate particles and the crack distribution performance was very poor. As a result, a stronger size effect was developed in LWC than in NWC. Especially, this trend was more notable in specimens with aspect ratio of 2.0 than in specimens with that of 1.0. The prediction model derived by Kim et al. overestimated the size effect of LWC when lateral dimension of specimen is above 150 mm. On the other hand, the modification factors specified in ASTM and CEB-FIP provisions, which are used to compensate for the shape effect of specimen on compressive strength, were still conservative in LWC.

• Clean Technology
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• v.22 no.2
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• pp.96-105
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• 2016

VOCs emissions from industries cause the air pollution and odor. In the industrial facilities, the existing odor treatment techniques have limits and problems. In this study, the optimum essential oil and metal oxide selected by screening test. lavender oil, cypress oil and TiO₂ were determined by deodorant materials and those were blended by 5%, 45%, 10%, respectively. In addition, the result of batch type experiments depending on the dilution rate, injection, rate, temperature showed that the optimum condition of deodorant is 6 mL of injection rate, and 200 times of dilution rate and the removal efficiency increased in proportion with temperature. In addition, the activation energy was calculated from the rate equation, which appeared in the 3-4 times lower than conventional deodorants.

• Korean Journal of Microbiology
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• v.54 no.2
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• pp.105-112
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• 2018

To compare the denitrification efficiency, this study used molasses and methanol were used as external carbon sources. Specific experimental conditions were classified according to C/N ratio conditions. The batch test showed that the denitrification efficiency increased as C/N ratios of molasses and methanol rose. The most suitable C/N ratio of molasses turned out 4:1 considering the concentration of the residue chemical oxygen demand (COD) and the denitrification efficiency, which was 91.4%. Specific denitrification rate (SDNR) drawn as a kinetic factor demonstrated that molasses and methanol showed similar SDNR values as C/N ratios of molasses and methanol increased. Under the condition of C/N ratio 4:1, 0.0292 g $NO_3{^-}-N$ removal/g mixed liquor volatile suspended solid (MLVSS)/day (molasses), 0.0299 g $NO_3{^-}-N$ removal/g MLVSS/day (methanol) were found. Sludge adapted to molasses showed that Bacterium Pseudomonas sp. and Bergeylla sp. dominated through an analysis of microbial community. In addition, some bacteria were high convergences than the variety of microbial community. Accordingly, it was assumed that molasses focus on growing microorganisms specialized in denitrification and applied as a replaceable external carbon source that can enhance denitrification performance.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.11
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• pp.1192-1197
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• 2006

Adsorbability of ionic and nonionic pharmaceuticals was studied using granular activated carbon(GAC). In a batch adsorption test of muticomponent solution, 500 mg/L of GAC dose removed all target compounds between 94 and 98% at initial concentration of 10 ${\mu}g/L$. Adsorption of ionic pharmaceuticals increased as pH was lowered toward to pKa, however adsorption capacity of nonionic pharmaceuticals showed insignificant variation with the changing pH. The enhanced adsorption capacity of ionic pharmaceuticals at lower pH was attributed to the corresponding increase in the molecular form of ionic pharmaceuticals with carboxylic group at low pH. In addition, decrease of pH increased hydrogen ion concentration in the bulk solution and the protons bound to the available sites on the carbon enhanced the removal of the ionic pharmaceuticals from solution. After 40 days of continuous operation, GAC column showed the removal of target compounds were removed by $93{\sim}99%$ at 15 min of EBCT mainly due to adsorption mechanism of GAC. At shorter EBCT than 15 min, breakthrough of CA, IBP and GFZ occurred earlier than the other ionic and nonionic pharmaceuticals. effect of EBCT on adsorption of nonionic pharmaceuticals was greater than ionic ones. This study showed that persitent pharmaceuticals found in drinking water treatment could be effectively controlled by adsorption in GAC process.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.6
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• pp.1083-1091
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• 2000

The objective of this study is to develop effective and economical treatment processes for the removal of non-biodegradable organics by reusing the sludge generated from Fenton's Oxidation Process. It was found that about 50% of coagulants and 50% of catalyst can be reduced by reusing the sludge generated from Fenton's Oxidation Process. It was also found that the amount of sludge generation can be reduced in coagulation process and Fenton's Oxidation Process. From the results of bench-scale test, it was found that the average removal efficiency increased to 8.5% and the amount of sludge generation was reduced up to 35% by reusing the sludge as coagulant. The average organic removal efficiency increased to 5.3% and the amount of sludge generation was reduced up to 14% by reusing the sludge as catalyst in Fenton's Oxidation. It can be concluded that the reuse of sludge generated from Fenton's Oxidation Process would be reduced cost of chemical consumption and Fenton's sludge treatment.

• Journal of Korean Society of Environmental Engineers
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• v.38 no.6
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• pp.329-333
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• 2016

Disinfection by electrolysis would be useful for small wastewater treatment plant, combined sewer overflow, ballast water, swimming pool, and fish farming, where the transport, storage, and the use of chlorine gas is limited. This study investigated the feasibility of the electrolysis of dilute hydrochloric acid (HCl) for disinfection. The effects of HCl concentration, voltage and reaction time on the generation of oxidizing agents, HOCl, $O_3$, and $H_2O_2$, were examined in a series of batch test. The highest current efficiency was 99.3% which was found at 2.2%, 3 V, and 5 min of HCl concentration, voltage, and reaction time, respectively. Continuous electrolysis at 2.2% HCl, 3 V, and 5 min of the hydraulic retention time showed 97.4% of the current efficiency. Addition of sodium chloride up to 20 g/L linearly increased the oxidizing agents production. 92.2% of total coliforms were removed by the contact with the electrolyzed water.