• Title/Summary/Keyword: barrier performance

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Over 8% efficient nanocrystal-derived Cu2ZnSnSe4 solar cells with molybdenum nitride barrier films in back contact structure

  • Pham, Hong Nhung;Jang, Yoon Hee;Park, Bo-In;Lee, Seung Yong;Lee, Doh-Kwon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.426.2-426.2
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    • 2016
  • Numerous of researches are being conducted to improve the efficiency of $Cu_2ZnSnSe_4$ (CZTSe)-based photovoltaic devices, which is one of the most promising candidates for low cost and environment-friendly solar cells. In this work, we concentrate on the back contact of the devices. A proper thickness of $MoSe_2$ in back contact structure is believed to enhance adhesion and ohmic contact between Mo back contact and absorber layer. Nevertheless, too thick $MoSe_2$ layers that are grown during high-temperature selenization process can impede the current collection, thus resulting in low cell performance. By applying molybdenum nitride as a barrier in back contact structure, we were able to control the thickness of $MoSe_2$ layer, which resulted in lower series resistance and higher fill factor of CZTSe devices. The phase transformation of Mo-N binary system was systematically studied by changing $N_2$ concentration during the sputtering process. With a proper phase of Mo-N fabricated by using an adequate partial pressure of $N_2$, the efficiency of CZTSe solar cells as high as 8.31% was achieved while the average efficiency was improved by about 2% with respect to that of the referent cells where no barrier layer was employed.

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A Study on the Structural Integrity of the First Stage Turbine Blade Caused by Thermal Barrier Coatings and the Cooling Design of the Nozzle (터빈 노즐 및 열차폐 코팅에 따른 고압 1 단 터빈 블레이드의 구조 건전성 영향에 대한 연구)

  • Huh, Jae Sung;Kang, Young Seok;Rhee, Dong Ho
    • Transactions of the KSME C: Technology and Education
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    • v.4 no.2
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    • pp.93-99
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    • 2016
  • High pressure nozzles and turbines of a gas turbine engine should be required to be operated under extreme operating conditions in order to maximize the performance. Engine manufactures have utilized nickel-base superalloys, enhanced cooling design, and thermal barrier coating techniques to overcome them and furthermore, material modeling, finite element analysis, optimization techniques, and etc. have been utilized widely for elaborate predictions. We aim to evaluate the effects on the low cycle fatigue life of the high pressure turbine blade caused by thermal barrier coatings and the cooling design of the endwall of the first stage turbine nozzle. To achieve it, the structural analysis, which utilized the results of conjugate heat transfer analysis as loading boundary conditions, was performed and then the results were the input for the assessment of low cycle fatigue life at several critical zones.

Health promoting behavior of adolescents (청소년의 건강증진 행위)

  • So Hee Young;Kim Hyun Li
    • Journal of Korean Public Health Nursing
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    • v.12 no.2
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    • pp.107-121
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    • 1998
  • The purpose of this study was to test the revised Health Promotion Model of Pender and to determine the factors to promote health behavior for adolescents' smoking behavior. The subjects of the study was 783 boys of 4 high school students. among 39. schools locating in Daejeon metropolitan city. The data was collected from July 1st to 15th. 1997 by school health nurse The research tool were HPLP of Walker. Pender. General self-efficacy scale of Sherer. control scale was measured by subconcept of hardiness scale of Pollock. and perceived barrier. perceived benefit. activity-related-affect tool were made by researcher via literature review The data were analyzed by SAS program using frequency. t-test. ANOVA. Schefee test. regression. The results were as follows 1. The mean of total health promoting behavior was $2.27\pm.35$. Among sub domain of health promoting behavior, the highest score was interpersonal support$(2.72\pm.60)$. and the lowest was health responsibility $(1.58\pm.44)$. 2. There were statistically significant difference in total health promoting behavior according to religion. parenting style. school performance. girl friend. father's smoking of individual characteristics. 3. The socioeconomic status. smoking, parent pattern. family structure of individual characteristics and experience domain associated with perceived benefit. perceived barrier. activity-related affect. interpersonal influence of behavior-specific cognition and affect domain. The perceived barrier. self-efficacy. girl friend and father's smoking of interpersonal influence. and control explained $25.8\%$ of variance of health promoting behavior. From above results school health nurse has to emphasize on health responsibility for health promotion of adolescent. But they couldn't intervene for parent pattern. socioeconomic status. family structure of individual characteristics and experience domain. it could be possible for school health nurse to promote health of adolescents through improving perceived barrier. also develop program to increase self-efficacy and through parent health class for fathers. Above results point to the importance of including parents in smoking prevention effort targeting adolescents. Because increasing control also promotes health of adolescents. it should be studied further about the specific measure. To verify the variables for increasing the fitness of health promoting model. it needs further replication of the research.

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Characteristics of metal contact for silicon solar cells (실리콘 태양전지의 금속전극 특성)

  • Cho, Eun-Chel;Kim, Dong-Seop;Min, Yo-Sep;Cho, Young-Hyun;Ebong, A.U.;Lee, Soo-Hong
    • Solar Energy
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    • v.17 no.1
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    • pp.59-66
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    • 1997
  • The solar cell electrical output parameters such as the open circuit voltage($V_{oc}$) and short circuit current density($V_{sc}$) are intrinsic characteristics depending on junction depth, doping concentration, metal contacts barriers and cell structure. As a role of thumb for solar cell design, the metal contact barriers for phosphorus doped emitter should have lower work function in order to provide lower series resistance. The fabrication of PESC(passivated emitter solar cell) structure usually involves the use of titanium as a metal contact barrier. Chromium, which work function is similar to titanium but conductance is higher than titanium is being investigated as the new metal contact barrier. Although titanium has lower work function difference than chromium, the electric performances of chromium as contact barrier are higher than titanium. This better performance is attributed to the lower resistivity from chromium. This paper, therefore, compares the attributes of metal barrier contacts using titanium and chromium.

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Evaluation of Optimal Performance of Hydraulic Barriers in Offshore Landfill using Seepage-Advection-Dispersion Analysis under Steady State Flow (정상류하 침투·이류 분산 해석을 이용한 폐기물 해상최종처리장 차수시스템의 최적 성능 평가)

  • Hwang, Woong-Ki;Oh, Myoung-Hak;Kim, Tae-Hyung;Kim, Hyang Eun
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.30 no.2
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    • pp.61-68
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    • 2018
  • This study was conducted to propose the optimum minimum requirement of cutoff system composed of the impermeable soil layer and vertical barrier in offshore landfill for prevention pollution leakage by seepage, advection, and dispersion numerical analyses under steady state. According to the study results, the minimum requirement of impermeable soil layer is below $1{\times}10^{-6}cm/s$ of hydraulic conductivity with more than 500 cm thickness or a system with equivalent cutoff effect. The minimum requirement of vertical barrier is below $1{\times}10^{-6}cm/s$ of hydraulic conductivity with more than 50 cm thickness or a system with equivalent cutoff effect. In addition, the vertical barrier should be embedded enough to seal securely with the impermeable soil layer for working cutoff effect.

Optimal Transducer Positions of an Active Noise Control System with an Opening in an Enclosure (능동방음벽 시스템에서의 제어음원 위치에 관한 고찰)

  • 백광현
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.14 no.2
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    • pp.164-171
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    • 2004
  • Active control techniques have been used in wide areas of noise and nitration control engineering and a noise barrier is one of them. Omoto's work in 1993 would be one of the fundamental and systematic studies on the actively controlled noise barrier, in which he used equal number of control sources and error sensors. The error sensors were placed uniformly along the top edge of the noise barrier with equal distance apart and the control sources were placed in the exactly same way some distance apart from the error sensors. Since then, a couple of studies were made on the secondary sources'arrangement rather than the optimality of secondary source positions. Shao's results showed that arc shaped arrangement for secondary sources is better than the straight line one, and later work of Yang showed that the more important factor is the average distance between the primary source and secondary sources. However, since these studies were all executed with a simple uniform distribution of the secondary sources along the straight line or arc, it is difficult to conclude which arrangement is superior In order for the fare comparison. the optimality of the source positions in each arrangement must be given in prior. The primary goal of this study is focused on this aspect and some major factors were investigated and compared. The computer simulation results showed that the arc shaped arrangement is marginally better than the straight line one, and more importantly slightly tuned position can greatly improve the performance of the control system.

Analysis of Lattice constants change for study of W-C-N Diffusion (W-C-N 확산방지막의 격자상수 변화 분석을 통한 특성 연구)

  • Kim, Soo-In;Lee, Chang-Woo
    • Journal of the Korean Vacuum Society
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    • v.17 no.2
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    • pp.109-112
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    • 2008
  • The miniaturization of device size and submicron process causes serious problems in conventional metallization due to the solubility of silicon and metal at the interface, such as an increasing contact resistance in the contact hole and interdiffusion between metal and silicon. Moreover, the interaction between Cu and Si is so strong and detrimental to the electrical performance of Si even at temperatures below $200^{\circ}C$. Therefore it is necessary to implement a barrier layer between Cu and Si. So we study W-C-N diffusion barrier for prevent Cu diffusion as a function of $N_2$ gas flow and thermal stability. Especially, we also study the W-C-N diffusion barrier for analyzing the change of lattice constants.

Additional Impurity Roles of Nitrogen and Carbon for Ternary compound W-C-N Diffusion Barrier for Cu interconnect (Cu 금속 배선에 적용되는 질소와 탄소를 첨가한 W-C-N 확산방지막의 질소불순물 거동 연구)

  • Kim, Soo-In;Lee, Chang-Woo
    • Journal of the Korean Vacuum Society
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    • v.16 no.5
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    • pp.348-352
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    • 2007
  • In submicron processes, the feature size of ULSI devices is critical, and it is necessary both to reduce the RC time delay for device speed performance and to enable higher current densities without electromigration. In case of contacts between semiconductor and metal in semiconductor devices, it may be very unstable during the thermal annealing process. To prevent these problems, we deposited tungsten carbon nitride (W-C-N) ternary compound thin film as a diffusion barrier for preventing the interdiffusion between metal and semiconductor. The thickness of W-C-N thin film is $1,000{\AA}$ and the process pressure is 7mTorr during the deposition of thin film. In this work we studied the interface effects W-C-N diffusion barrier using the XRD and 4-point probe.

Current Status of the Numerical Models for the Analysis of Coupled Thermal-Hydrological-Mechanical Behavior of the Engineered Barrier System in a High-level Waste Repository (고준위폐기물처분장 공학적방벽시스템의 열-수리-역학적 복합거동 해석 모델 개발 현황)

  • Cho, Won-Jin;Kim, Jin Seop;Lee, Changsoo;Choi, Heui-Joo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.10 no.4
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    • pp.281-294
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    • 2012
  • The current status of the computer codes for the analysis of coupled thermal-hydrological-mechanical behavior occurred in a high-level waste repository was investigated. Based on the reported results on the comparison between the predictions using the computer codes and the experimental data from the in-situ tests, the reliability of the existing computer codes was analyzed. The presented codes simulated considerably well the coupled thermal-hydrological-mechanical behavior in the near-field rock of the repository without buffer, but the predictions for the engineered barrier system of the repository located at saturated hard rock were not satisfactory. To apply the current thermal-hydrological-mechanical models to the assessment of the performance of engineered barrier system, a major improvement on the mathematical models which analyze the distribution of water content and total pressure in the buffer is required.

Interfacial Properties of Atomic Layer Deposited Al2O3/AlN Bilayer on GaN

  • Kim, Hogyoung;Kim, Dong Ha;Choi, Byung Joon
    • Korean Journal of Materials Research
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    • v.28 no.5
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    • pp.268-272
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    • 2018
  • An $Al_2O_3/AlN$ bilayer deposited on GaN by atomic layer deposition (ALD) is employed to prepare $Al_2O_3/AlN/GaN$ metal-insulator-semiconductor (MIS) diodes, and their interfacial properties are investigated using X-ray photoelectron spectroscopy (XPS) with sputter etch treatment and current-voltage (I-V) measurements. XPS analyses reveal that the native oxides on the GaN surface are reduced significantly during the early ALD stage, indicating that AlN deposition effectively clelans up the GaN surface. In addition, the suppression of Al-OH bonds is observed through the ALD process. This result may be related to the improved device performance because Al-OH bonds act as interface defects. Finally, temperature dependent I-V analyses show that the barrier height increases and the ideality factor decreases with an increase in temperature, which is associated with the barrier inhomogeneity. A Modified Richardson plot produces the Richardson constant of $A^{**}$ as $30.45Acm^{-2}K^{-2}$, which is similar to the theoretical value of $26.4Acm^{-2}K^{-2}$ for n-GaN. This indicates that the barrier inhomogeneity appropriately explains the forward current transport across the $Au/Al_2O_3/AlN/GaN$ interface.