• 자원리싸이클링
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• 제9권2호
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• pp.18-25
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• 2000

등방성 영구자석의 제조과정에서 발생되고 있는 barium hexaferrite 폐 자석으로 소결체를 제조하여 물리적, 자기적 특성을 조사하였다. 소결체는 XRD, XRF, SEM 및 자기적 성질을 측정하였다 폐 영구자석을 분쇄하고 조립화하여 폐 영구자석 분말 과립과 시판용 과립을 일정비율로 혼합. 성형하고 소결하였다. 폐 영구자석 분쇄분말의 함량에 따라 자기적 특성은 점차 감소하지만 소결 온도 $1150~1200^{\circ}C$ 에서 영구자석으로서 요구되는 자기적 특성값을 나타내었다.

• Journal of Magnetics
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• 제21권4호
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• pp.496-502
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• 2016

Doped and undoped barium hexaferrite powders ($BaFe_{12}O_{19}$, $Ba_{0.7}Ti_{0.3}Fe_{12}O_{19}$ and $Ba_{0.7}La_{0.3}Fe_{12}O_{19}$) were produced by the sol-gel method. The effects of substituting elements were studied in terms of the magnetic properties of barium hexaferrite powders. The magnetic properties were remarkably changed by the substitution of $La^{3+}$ and $Ti^{4+}$ ions for the $Ba^{2+}$ ion and were accompanied by oxygen deficiency in the $BaFe_{12}O_{19}$. Coercivities ($H_C$) from 4200 to 5100 Oe, remanences ($M_R$) from 22 to 49 emu/g and saturation magnetizations ($M_S$) from 41 to 73 emu/g were obtained for different samples. The obtained results were discussed in detail.

• 한국자기학회지
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• 제24권1호
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• pp.1-10
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• 2014

$Co_2Z$-type hexaferrite 시편을 다양한 합성법을 이용하여 제조하였다. 수열합성법을 이용하여 M-type, $Co_2Y$-type, $Co_2Z$-type을 제조하였으며, 제조된 M-type과 $Co_2Y$-type을 출발물질로 하여 고상반응법(ball milling)과 수열합성법(hydrothermal)으로 $Co_2Z$-type을 제조하였다. 제조된 시편의 결정구조와 미세구조 자기적 성질은 XRD, FESEM, VSM, impedance analyzer를 이용하여 조사하였다. M-type과 $Co_2Y$-type은 단일상의 결정구조를 얻을 수 있었다. 여러 합성법 중에 M+Y ball milling, M+Y hydrothermal에서 제조한 시편이 $Co_2Z$-type hexaferrite의 단일상과 대체로 일치하는 것을 알 수 있었으며, $Co_2Z$-type의 모든 시편들은 이론적인 포화 자화값(50 emu/g)과 비슷한 값을 나타내었다. 소결한 시편들의 투자율은 시약을 precusor로 하여 제조한 $Co_2Z$-type의 투자율이 가장 높았으며, 열처리 온도가 증가함에 따라 투자율은 낮아졌다. 다른 합성법에서는 열처리 온도에 따른 변화가 거의 나타나지 않는 것을 확인할 수 있었다.

• 한국분말재료학회지
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• 제21권4호
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• pp.256-259
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• 2014

A magnetic powder, M-type barium hexaferrite (BaFe12O19), was consolidated with the spark plasma sintering process. Three different holding temperatures, $850^{\circ}C$, $875^{\circ}C$ and $900^{\circ}C$ were applied to the spark plasma sintering process with the same holding times, heating rates and compaction pressure of 30 MPa. The relative density was measured simultaneously with spark plasma sintering and the convergent relative density after cooling was found to be proportional to the holding temperature. The full relative density was obtained at $900^{\circ}C$ and the total sintering time was only 33.3 min, which was much less than the conventional furnace sintering method. The higher holding temperature also led to the higher saturation magnetic moment (${\sigma}_s$) and the higher coercivity ($H_c$) in the vibrating sample magnetometer measurement. The saturation magnetic moment (${\sigma}_s$) and the coercivity ($H_c$) obtained at $900^{\circ}C$ were 56.3 emu/g and 541.5 Oe for each.

• 한국세라믹학회:학술대회논문집
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• 한국세라믹학회 2003년도 춘계총회 및 연구발표회 초록집
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• pp.182.1-182
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• 2003

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2000년도 International Symposium on Magnetics The 2000 Fall Conference
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• pp.455-456
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• 2000

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2000년도 International Symposium on Magnetics The 2000 Fall Conference
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• pp.433-440
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• 2000

Barium ferrite particles were synthesized from Ba(NO$_3$)$_2$, Fe(NO$_3$)$_3$ and KOH mixed solutions using hydrothermal crystallization in supercritical water. The experimental apparatus for production of barium ferrite is a flow-type apparatus. Fine barium ferrite particles were produced because supercritical water causes the metal hydroxides to be rapidly dehydrated before significant growth takes place. The effects of Fe/Ba ratio and reaction time on the formation, particle size, and magnetic properties of barium ferrite were studied. When Fe/Ba ratio were varied from 0.5 to 12, single-phase barium ferrite powder was only produced in the range of 0.5〈Fe/Ba〈2. Also, with elevating reaction time, the BaO.6Fe$_2$O$_3$ particle size grew smaller. Especially, uniform barium hexaferrite particles of size 100-200nm were obtained at 80sec. In this study, therefore, single-phase barium ferrite particles are highly stable and can be produced continuously in a reaction time of less then 2min.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2007년도 The 1st International Symposium on Advanced Magnetic Materials
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• pp.286.2-286.2
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• 2007

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2008년도 Asian Magnetics Conference
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• pp.175.2-175.2
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• 2008

• Journal of Magnetics
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• 제6권1호
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• pp.23-26
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• 2001

Nano-crystalline hexaferrite $BaFe_{12}O_{19}$(BaM) thin films have been prepared by the sol-gel method. A solution of Ba-nitrate and Fe-nitrates was dissolved in solvent with the stoichiometric ratio Ba/Fe=1/10. Films were spin-coated onto $SiO_2$Si substrates, dried and then heated in air at various temperatures. In films prepared at a drying temperature $T_d=250^{\circ}C$ and a crystallizing temperature 650${\circ}C$, single-phase BaM was obtained. High coercivities were obtained in these nano-crystalline thin films, 4~5.5 kOe for hexaferrite. Polycrystalline BaM/$SiO_2$/Si(100) thin films were characterized by Rutherford backscattering (RBS), thermogravimetry (TGA), differential thermal analysis (DTA), x-ray diffraction (XRD), and vibrating sample magnetometry (VSM), as well as Fourier transform infrared spectroscopy (FTIR). The perpendicular coercivity $H_{C\bot}$ and in-plane coercivity $H_{CII}$ after annealing at 650${\circ}C$ for 2 hours were 4766 Oe and 4480 Oe, respectively, at room temperature, under a maximum applied field of 10 kOe.