• Polymer(Korea)
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• v.31 no.1
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• pp.37-46
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• 2007

Fully or nearly fully 6- [4- (4'- (nitrophenylazo)phenoxycarbonyl)]pentanoated polysaccharide derivatives were synthesized by reacting cellulose, amylose, chitosan, chitin, alginic acid, pullulan or amylopectin with 6- [4- (4'- (nitrophenylazo)phenoxy) ] pentanoyl chloride (NA6C) and their thermotropic liquid crystalline behaviors were investigated. Like in the case of NA6C, all the polysaccharide derivatives formed monotropic nematic phases, suggesting that the mesophase structure of the polysaccharide derivatives is dertermined by the mesogenic side groups and not by the polysaccharide backbone. This is the first report of polysaccharide derivatives, except cellulose derivative, that form thermotropic nematic phases. The thermal stability and degree of order of the nematic phases observed for poly saccharide derivatives were significantly different from those reported for the polymers in which the azobenzene groups are attached to flexible or rigid backbones through flexible spacers. The results were discussed in terms of the difference in the arrangement of the main and side chains and the flexibility of the main chain.

• Wind and Structures
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• v.27 no.6
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• pp.381-397
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• 2018

Nonlinear behavior in fluid-structure interaction (FSI) of bridge decks becomes increasingly significant for modern bridges with increasing spans, larger flexibility and new aerodynamic deck configurations. Better understanding of the nonlinear aeroelasticity of bridge decks and further development of reduced-order nonlinear models for the aeroelastic forces become necessary. In this paper, the amplitude-dependent and neutral angle dependent nonlinearities of the motion-induced loads are further highlighted by series of computational fluid dynamics (CFD) simulations. An effort has been made to investigate a semi-analytical time-domain model of the nonlinear motion induced loads on the deck, which enables nonlinear time domain simulations of the aeroelastic responses of the bridge deck. First, the computational schemes used here are validated through theoretically well-known cases. Then, static aerodynamic coefficients of the Great Belt East Bridge (GBEB) cross section are evaluated at various angles of attack, leading to the so-called nonlinear backbone curves. Flutter derivatives of the bridge are identified by CFD simulations using forced harmonic motion of the cross-section with various frequencies. By varying the amplitude of the forced motion, it is observed that the identified flutter derivatives are amplitude-dependent, especially for $A^*_2$ and $H^*_2$ parameters. Another nonlinear feature is observed from the change of hysteresis loop (between angle of attack and lift/moment) when the neutral angles of the cross-section are changed. Based on the CFD results, a semi-analytical time-domain model for describing the nonlinear motion-induced loads is proposed and calibrated. This model is based on accounting for the delay effect with respect to the nonlinear backbone curve and is established in the state-space form. Reasonable agreement between the results from the semi-analytical model and CFD demonstrates the potential application of the proposed model for nonlinear aeroelastic analysis of bridge decks.

• KSII Transactions on Internet and Information Systems (TIIS)
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• v.15 no.12
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• pp.4439-4455
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• 2021

Compared with two-stage object detection algorithms, one-stage algorithms provide a better trade-off between real-time performance and accuracy. However, these methods treat the intermediate features equally, which lacks the flexibility to emphasize meaningful information for classification and location. Besides, they ignore the interaction of contextual information from different scales, which is important for medium and small objects detection. To tackle these problems, we propose an image pyramid network based on dual attention mechanism (DAIPNet), which builds an image pyramid to enrich the spatial information while emphasizing multi-scale informative features based on dual attention mechanisms for one-stage object detection. Our framework utilizes a pre-trained backbone as standard detection network, where the designed image pyramid network (IPN) is used as auxiliary network to provide complementary information. Here, the dual attention mechanism is composed of the adaptive feature fusion module (AFFM) and the progressive attention fusion module (PAFM). AFFM is designed to automatically pay attention to the feature maps with different importance from the backbone and auxiliary network, while PAFM is utilized to adaptively learn the channel attentive information in the context transfer process. Furthermore, in the IPN, we build an image pyramid to extract scale-wise features from downsampled images of different scales, where the features are further fused at different states to enrich scale-wise information and learn more comprehensive feature representations. Experimental results are shown on MS COCO dataset. Our proposed detector with a 300 × 300 input achieves superior performance of 32.6% mAP on the MS COCO test-dev compared with state-of-the-art methods.

• Bulletin of the Korean Chemical Society
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• v.32 no.2
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• pp.651-655
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• 2011

We synthesized a novel cationic dendrimer consisting of a poly(amidoamine) dendrimer (PAMAM, generation 4) backbone with both L-arginine (Arg) at the termini and 6-aminohexanoic acid (Ahx) between the original core polymer and the peripheral Arg units. The sequential chemical modification of PAMAM G4 with Ahx and Arg resulted in higher transfection efficiency with much less cytotoxicity. PAMAM G4-Ahx-Arg formed stable polyplexes at weight ratios of 8:1 or higher (polymer: plasmid DNA), and the mean polyplex diameter was $180{\pm}20nm$. PAMAM G4-Ahx-Arg showed much higher transfection ability than PAMAM G4 or PAMAM G4-Ahx. Furthermore, PAMAM G4-Ahx-Arg was much less cytotoxic than PEI25KD and PAMAM G4-Arg. In addition to Arg grafting of the PAMAM dendrimer, which endows a higher transfection capability, the addition of Ahx spacer increased dendrimer hydrophobicity, introduced flexibility into the conjugated amino acids, and reduced cytotoxicity. Overall, it appears that the concomitant modification of PAMAM with Ahx and Arg could lead to new PAMAM conjugates with better performances.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.35 no.2A
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• pp.165-173
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• 2010

WMN(Wireless Mesh Network) is an wireless backbone network technology that is an easily configurable network in the low cost compared to the wireless LAN(Local Area Network). Most of the previous researches have evaluated their algorithms by the simulations rather than by the implementation. There exist some implementation papers, however, they have the limitations of the flexibility on the link establishment and the link quality utilization. Consequently, the benefit of the WMN - configuration flexibility is degraded and the performance deterioration occurs in the multi-hop wireless environment. In this paper, we introduce a Linux-based link layer Wireless Mesh Routing System - WBMR. The design and implementation of WBMR provides the dynamic link establishment and the effective multi-channel usage. We have modified the ntroof the original WLAN operation for the dynamic link establishment, and the Linux bridge for the link layer routing. The result of performance evaluation verifies that our WBMR supports fast self-configuration and increases data transmission throughput compared to the other researches of the wireless multi-hop environment.

• 한국정보디스플레이학회:학술대회논문집
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• 2005.07b
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• pp.1518-1522
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• 2005

A cinnamate group is a well-known compound group used in the dimerization reaction by ultraviolet irradiation, and cinnamate polymers are studied as photoalignment materials. In this study, the radical reaction of cinnamate side groups attached to a flexible polymer backbone is considered feasible using thermal energy. To induce the thermal reaction of cinnamate side groups, we modified the flexibility of poly(vinyl cinnamate) by introducing a plasticizer into the polymers and investigated the thermal reaction behavior of cinnamate side groups. The plasticization of poly(vinyl cinnamate) makes the induction of the thermal reaction of cinnamate side groups easier than that of unmodified poly(vinyl cinnamate). The thermal reaction of cinnamate side groups is closely related to the enhancement of the thermal stability of the liquid crystal orientation of polymer films with polarized UV irradiation.

• BMB Reports
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• v.42 no.6
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• pp.387-392
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• 2009

Here, we report the first biochemical and structural characterization of the hypothetical protein HP0902 from Helicobacter pylori, in terms of structural genomics. Gel-permeation chromatography and dynamic light scattering indicated that the protein behaves as a dimer in solution. Circular dichroism spectroscopy showed that HP0902 primarily adopts a $\beta$-structure and the protein was highly thermostable with a denaturing temperature higher than $70^{\circ}C$. Finally, the backbone NMR assignments were obtained on the [$^{13}C,^{15}N$]HP0902 and the secondary structure was determined using the chemical shift data. Additionally, the local flexibility was assessed via a heteronuclear $^1H-^{15}N$ steady state NOE experiment. The results revealed that HP0902 would adopt a compactly folded, all-$\beta$ topology with 11 $\beta$-strands. All of the results clearly support the notion that HP0902 belongs to the cupin superfamily of proteins.

• Journal of Communications and Networks
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• v.14 no.6
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• pp.629-639
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• 2012

A challenge faced by smart grid systems is providing highly reliable transmissions to better serve different types of electrical applications and improve the energy efficiency of the system. Although wireless networking technologies can provide high-speed and cost-effective solutions, their performance may be impaired by various factors that affect the reliability of smart grid networks. Here, we first suggest the use of IEEE 802.11s-based wireless LAN mesh networks as high-speed wireless backbone networks for smart grid infrastructure to provide high scalability and flexibility while ensuring low installation and management costs. Thereafter, we analyze some vital problems of the IEEE 802.11s default routing protocol (named hybrid wireless mesh protocol; HWMP) from the perspective of transfer reliability, and propose appropriate solutions with a new routing method called HWMP-reliability enhancement to improve the routing reliability of 802.11s-based smart grid mesh networking. A simulation study using ns-3 was conducted to demonstrate the superiority of the proposed schemes.

• Proceedings of the IEEK Conference
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• 2002.07c
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• pp.1936-1939
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• 2002

Much recent attention on wireless technologies s put on topology-less wireless network, in which all nodes an be mobile and can communicate over wireless links, due to its ease of deployment, high flexibility and low expenses. One key in topology-less wireless network is mobile base stations (MBSs), which provides access points or mobile terminals (MTs) to wireless backbone network. MBSs can move to anywhere in accordance with changes in geographical distribution of MTs. They serve as dynamic odes. However, in order to utilize network resources and take full advantage of this topology-less network, MBSs must move to suitable position according to the current tate of network use. Moreover, MBSs have to consider the distance among them to avoid the crash and gap area of MBSs. Therefore, this paper proposes MBS movement algorithm by implementing push-pull method to fulfill the corporation of MBSs and considering the center of covered MTs or centroid to satisfy the MT coverage. From the simulation results, the proposed algorithm increases the performance of system when comparing with the centroid-based algoriom〔7〕, such as coverage area, MT coverage and call drops rate.

• Macromolecular Research
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• v.17 no.11
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• pp.870-873
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• 2009

In this study, 2-diglycidylether of benzotrifluoride (2-DGEBTF) and 4-diglycidylether of benzotrifluoride (4-DGEBTF) epoxy resins, which contained fluorine groups in the main chain, were synthesized. The resins were characterized by FTIR, $^1H$ NMR, $^{13}C$ NMR and $^{19}F$ NMR spectroscopy. The 2-DGEBTF and 4-DGEBTF epoxy resins were cured with triethylene tetramine (TETA), and the effect of the fluorine group on the synthesized epoxy resin on the cure behavior, thermal, and mechanical properties was investigated. The 2-DGEBTF/TETA system was more reactive than the 4-DGEBTF/TETA system, whereas the thermal stability factor i.e., the decomposition activation energy ($E_d$), of 4-DGEBTF/TETA was higher than that of 2-DGEBTF/TETA. These results can be explained by the decrease in cross-linking density and decomposition of the short side chains, resulting in the $CF_3$ group at the para position. However, the $K_{IC}$ value of 4-DGEBTF/TETA was higher than that of 2-DGEBTF/TETA. This was attributed to the increase in flexibility in the epoxy backbone, resulting in a difference in steric hindrance and polarlizability.