• 제목/요약/키워드: atmospheric influences

검색결과 135건 처리시간 0.022초

헤드스페이스-SPME 방법을 이용한 트리메틸아민의 분석방법 연구 (The Analysis of Airborne Trimethylamine Using a Headspace (HS)-SPME Method)

  • 안지원;김기현
    • 한국대기환경학회지
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    • 제24권3호
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    • pp.357-366
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    • 2008
  • In this study, the analytical performance of trimethylamine (TMA) were investigated with respect to headspace-solid phase microextraction (HS-SPME) method. In order to induce the elution of aqueous TMA to headspace, NaOH was added as a decomposition reagent to aqueous TMA standard. By controlling the combination of three major variables for TMA extraction, the extent of extraction was compared between the two contrasting conditions for each variable (i.e., reaction time (long (L) vs short (S)), exposure temperature (30 vs $50^{\circ}C$), and exposure time (10 vs 30 min)). The results of this comparative analysis showed that the extraction efficiency for all eight types of HS-SPME combinations decreased on the order: L-30-30>L-50-10>L-30-10>L-50-30>S-30-30>S-50-30>S-50-10>S-30-10. The effect of reaction time appeared to exert significant influences on the relative recovery rate of HS-SPME at 90% confidence level. However, the effects of exposure temperature or exposure time were not so significant as reaction time. When the recovery rate of HS-SPME is compared against the direct injection of liquid standard into GC injector, it recorded as 2%. According to this comparative study, the reaction conditions for HS-SPME application can exert significant influences on the analysis of TMA.

Measurement and Interpretation of Time Variations of Particulate Matter Observed in the Busan Coastal Area in Korea

  • Kim, Cheol-Hee;Son, Hye-Young
    • Asian Journal of Atmospheric Environment
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    • 제5권2호
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    • pp.105-112
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    • 2011
  • In order to investigate the effects of local and synoptic meteorological conditions on urban scale particulate air pollutants observed over the Busan coastal area, power spectrum analysis was applied to observed particulate matter with an aerodynamic diameter $\leq10\;{\mu}m$ ($PM_{10}$) for the period from 1 October, 1993 to 31 December, 2004. Fast Fourier Transform (FFT) analysis was used to obtain the hourly mean observed $PM_{10}$ concentrations to identify different periodicity scales of $PM_{10}$ concentrations. The results showed that, aside from the typical and well-known periodicities such as diurnal and annual variations caused by anthropogenic influences, three other significant power spectral density peaks were identified: 7-day, 21-day and 2.25-year periodicities. Cospectrum analysis indicated that the seven-day variations were closely related to the synoptic meteorological conditions such as weak wind speed, which are relevant to the stagnant high pressure system slowly passing through the Korean Peninsula. The intra-seasonal 21-day variation was negatively correlated with wind speed but was consistently positively correlated with relative humidity, which is related to aerosol formation that can be achieved as a result of the hygroscopic characteristics of aerosols. However, the quasibiennial 2.25-year variation was correlated with the frequency of Asian dust occurrence, the periodicities of which have been recorded inter-annually over the Korean Peninsula.

Factors Defining Store Atmospherics in Convenience Stores: An Analytical Study of Delhi Malls in India

  • Prashar, Sanjeev;Verma, Pranay;Parsad, Chandan;Vijay, T. Sai
    • The Journal of Asian Finance, Economics and Business
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    • 제2권3호
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    • pp.5-15
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    • 2015
  • This research paper has been attempted to inventory the atmospheric factors, contributing to better sales. Exploratory study was undertaken to identify various signs of store atmospherics variables that influence the buying behaviour of buyers. Thirty-four variables identified from this study were used to create a structured questionnaire. This questionnaire was then administered among shoppers in NCR Delhi using non-probability convenience sampling. To determine the atmospheric factors, Principal Component Analysis (PCA) along with Varimax Rotation was attempted. Using principal component factor analysis on the data collected, nine factors were identified to have impact on the store atmospheric. These were Querulous, Music, Sensitive, Budget Seeker, Sensuous, Light, Idler, Space seeker and Comfort Seeker. Contrary to the various earlier studies where music, space seeker and comfort seeker were considered to be most significant factors, light and querulous have emerged out to be the major factor that influences the store atmospheric. This study shows that customers are sensitive, space seekers and sensuous. Constituents of these factors reveal distinct patterns. This research may be used as guidelines for development and management of shopping malls in emerging countries. Retail marketers in India can take this cue in designing their strategies to attract consumers.

대기 혼합층 발달 과정의 모형 실험과 수치 해석 (Laboratory Experimentals and Numerical Analysis for Development of a Atmospheric Mixed Layer)

  • 이화운
    • 한국환경과학회지
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    • 제2권1호
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    • pp.17-26
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    • 1993
  • The layer that is directly influenced by ground surface is called the atmospheric boutsdary layer in comparison with the free atmosphere of higher layer. In the boundary layer, the changes of wind, temperature and coefficient of turbulent diffusion in altitude are large and have great influences an atmospheric diffusion. The purpose of this paper is to express the structure and characteristics of development of mixed layer by using laboratory experiment and numerical simulation. Laboratory experiment using water tank are performed that closely simulate the process of break up of nocturnal surface inversion above heated surface and its phenomena are analyzed by the use of horizontally averaged temperature which is observed. The result obtained from the laboratory experiment is compared with theoretical ones from ; \textsc{k}-\varepsilon numerical model. The results are summarized as follows. 1) The horizontally averaged temperature was found to vary smoothly with height and the mixed layer developed obviously being affected by the convection. 2) The mean height of mixed layer may be predicted as a function of time, knowing the mean initial temperature gradient. The experimental values are associated well with the theoretical values computed for value of the universal constant $C_r$= 0.16, our $C_r$ value is little smaller than the value found by Townsend and Deardoru et al.

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제주 동복·북촌 풍력발전단지의 바람환경 특성분석 (Characteristics of Wind Environment in Dongbok·Bukchon Wind Farm on Jeju)

  • 정형세;김연희;최희욱
    • 신재생에너지
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    • 제18권1호
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    • pp.1-16
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    • 2022
  • Climatic characteristics were described using the LiDAR (Light Detection and Ranging) and the met-mast on Dongbok·Bukchon region. The influences of meteorological conditions on the power performance of wind turbines were presented using the data of Supervisory Control And Data Acquisition (SCADA) and met-mast of the Dongbok·Bukchon Wind Farm (DBWF) located in Jeju Island. The stability was categorized into three parameters (Richardson number, Turbulence intensity, and Wind shear exponent). DBWF was dominant in unstable atmospheric conditions. At wind speeds of 14 m/s or more, the proportion of slightly unstable conditions accounted for more than 50%. A clear difference in the power output of the wind turbine was exhibited in the category of atmospheric stability and turbulence intensity (TI). Particularly, a more sensitive difference in power performance was showed in the rated wind speeds of the wind turbine and wind regime with high TI. When the flow had a high turbulence at low wind speeds and a low turbulence at rated wind speeds, a higher wind energy potential was produced than that in other conditions. Finally, the high-efficiency of the wind farm was confirmed in the slightly unstable atmospheric stability. However, when the unstable state become stronger, the wind farm efficiency was lower than that in the stable state.

The Numerical Prediction of the Micro Climate Change by a Residential Development Region

  • Oh, Eun-Joo;Lee, Hwa Woon;Kondo, Akira;Kaga, Akikazu;Yamaguchi, Katsuhito
    • 한국환경과학회지
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    • 제12권5호
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    • pp.529-539
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    • 2003
  • We developed a numerical model that considered the influences on the thermal environment of vegetation, water surfaces and buildings to predict micro climatic changes in a few $\textrm{km}^2$ scales; and applied this model to the Mino residential development region in Osaka Prefecture by using a nested technique. The calculated temperatures and winds in the residential development region reasonably agreed with the observed ones. We then investigated the influences on the thermal environment of the construction of a dam, the change of the green coverage rate. The results obtained from the numerical simulations were qualitatively reasonable.

도시지역의 국지순환과 침적현상에 관한 수치모의 (Numerical Simulation for Local Circulation of Urban Area and Deposition Phenomenon)

  • 이화운;오은주;노순아;반수진
    • 한국대기환경학회지
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    • 제19권6호
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    • pp.773-787
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    • 2003
  • There are variations in the temperature Held due to urban heat island and anthropogenic heating so that regional scale meteorological field is changed. Therefore we simulate and predict the regional climate change according to surface characteristics through regional meteorological model. This study investigates the regional meteorological field by urbanization that influences in local circulation system using CSU-RAMS and simulates dry deposition velocity (V$_{d}$) using PNU/DEM which includes surface characteristics (such as albedo, surface hydrology and rough-ness length etc.) with calculated meteorological field. During the summer, horizontal distributions of V$_{d}$ were simulated using CSU-RAMS and PNU/DEM at Busan metropolitan area. The estimated values of V$_{d}$ were larger in forest and agricultural areas than water areas since ozone with low water solubility is destroyed slowly at wet surface or water.water.

무성방전내에서 톨루엔 제거에 미치는 운전변수의 영향 (Effects of Operating Parameters on Toluene Removal in Dielectric Barrier Discharge Process)

  • 정재우;이용환;박경렬
    • 한국대기환경학회지
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    • 제18권3호
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    • pp.173-182
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    • 2002
  • We investigated the effects of operating variables, such as electrical. reactor and gas parameters on toluene removal and discharge property in the dielectric barrier discharge (DBD) process. The toluene removal was initiated with the energy transfer to the reactor by loading of voltages higher than the discharge onset value. The energy transfer and toluene removal increased with the applied voltage. Higher removal rate was observed with smooth surface electrode despite of lower energy transfer compared with the coarse electrode, because more uniform discharge can be obtained on smooth surface state. The decrease of dielectric material thickness enhanced the removal efficiency by increasing the discharge potential. The toluene removal efficiency decreased with the increase of the inlet concentration. The increase of gas retention time enhanced the removal efficiency by the increase of energy density. The oxygen and humidity contents seem to exert significant influences on the toluene removal by dominating the generation of electrons, ions, and radicals which are key factors in the removal mechanism.

산화촉매에 의한 소형디젤엔진의 배출가스 저감특성 (Characteristics of Exhaust Emissions Reduction by Oxidation Catalyst for Light-duty Diesel Engine)

  • 김선문;임철수;엄명도;정일래
    • 한국대기환경학회지
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    • 제18권5호
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    • pp.411-417
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    • 2002
  • The purpose of this study is to evaluate the emission reduction characteristics depending on the formation of the catalyst which influences the development of the diesel oxidation catalyst (DOC) suitable for small-sized diesel engines. We also attempted to suggest the feasibility of it as an after-treatment device. The reduction efficiency of DOC for CO and HC was proportional to the contents of precious metals, and the particulate matter (PM) has been reduced as much as 53∼59%. The reduction rate of soluble organic fraction (SOF) by DOC attachment revealed 100%. The composition of sulfate in PM increased from 3%, 7∼11% by installation of DOC. It is described that increase of sulfate contributed to the production of PM. This result also showed that the SOF and sulfate have trade-off relationship.

A FRAMEWORK TO UNDERSTAND THE ASYMPTOTIC PROPERTIES OF KRIGING AND SPLINES

  • Furrer Eva M.;Nychka Douglas W.
    • Journal of the Korean Statistical Society
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    • 제36권1호
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    • pp.57-76
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    • 2007
  • Kriging is a nonparametric regression method used in geostatistics for estimating curves and surfaces for spatial data. It may come as a surprise that the Kriging estimator, normally derived as the best linear unbiased estimator, is also the solution of a particular variational problem. Thus, Kriging estimators can also be interpreted as generalized smoothing splines where the roughness penalty is determined by the covariance function of a spatial process. We build off the early work by Silverman (1982, 1984) and the analysis by Cox (1983, 1984), Messer (1991), Messer and Goldstein (1993) and others and develop an equivalent kernel interpretation of geostatistical estimators. Given this connection we show how a given covariance function influences the bias and variance of the Kriging estimate as well as the mean squared prediction error. Some specific asymptotic results are given in one dimension for Matern covariances that have as their limit cubic smoothing splines.