• Title/Summary/Keyword: aromatic components

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Expert System Approach for Vapor-Phase Infrared Spectra of Aromatic Compounds

  • Pyo Dongjin;Hwang Hoon;Lee Junyeoun
    • Bulletin of the Korean Chemical Society
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    • v.13 no.2
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    • pp.148-155
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    • 1992
  • Computerized interpretation of vapor phase infrared spectra using a novel expert system approach for spectra/structure correlation for vapor phase spectra is introduced. Rapid identification of aromatic functional groups of components in gaseous mixture can be achieved using this expert system.

Analysis of Essential Oils from Korean Aromatic Tobacco Varieties by GC/MS and data system. (GC/MS와 data system을 이용한 한국산 향끽미종 잎담배의 정유성분 분석)

  • Park, Jeen-Woo;Lee, Un-Chul;Kim, Yong-Tae;Heu, Il
    • Journal of the Korean Society of Tobacco Science
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    • v.4 no.1
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    • pp.61-66
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    • 1982
  • Essential oil components were isolated from Korean aromatic tobaccos by using a simultaneous distillation and extraction apparatus. The essential oils were analyzed by GC/M S and date system. Forty-two volatile components were identified on the basis of their mass spectra. Determination of contents of essential oil components from Hyangcho and Sohyang was achieved by pseudo-multiple ion selection (Ml S) technique. Varietal differences were detected from the quantitative comparison of the MIS data.

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INFLUENCE OF HARVEST TIME ON CHARACTERISTICS OF AROMATIC-TYPE TOBACCO (향끽미종 연초의 수확시기가 건조엽의 특성에 미치는 영향)

  • 류명현;김용옥;정형진;김신일;손현주;추홍구
    • Journal of the Korean Society of Tobacco Science
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    • v.7 no.1
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    • pp.39-47
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    • 1985
  • Normally cultured aromatic tobaccos, KA 101 and KA 103, were primed progressively in three-leaf segments, either 7 days before bud, bud, or early flower stage with 7 days interval, respectively, The cured leaves were weighed for yield, graded, analyzed for quality-related constituents including volatile aroma components. Also the cured leaves were manufactured and smoked by panelists. Yield and quality by price decreased with advancing ripeness. Reducing sugar, total nitrogen, protein nitrogen decreased with successive ripeness, but reverse in this trends with nicotine, petroleum ether extracts and volatile acids components. Among volatile neutral components, furfural, furfuryl alcohol, benzyl alcohol, penethyl alcohol and p-cresol decreased, but solanone increased with delayed harvest. Neophytadiene, oxysolanone, furfuryl aceton was highest at mid harvest, which was judged to be best by panelists. Mid harvest, first primed at bud stage when leaf color comes to pale green to yellow green, seems to be highly recommendable.

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Analysis of Constituents Related to Five Sensory Test in Peony Root (작약근의 오관평가와 관련된 성분 검정)

  • Choung Myoung-Gun
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.50 no.spc1
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    • pp.191-195
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    • 2005
  • Experiment was conducted to establish the standard of quality evaluation in Korean cultivated peony roots. free sugars, free amino acids, organic acids and aromatic components, which were generally considered to be information components of five sensory test in peony roots, were examined. As free sugars, sucrose, glucose and fructose were identified in peony roots. $\gamma-aminoisobuturic$ acid, arginine and other 16 kinds of free amino acids were found in peony roots. The major organic acids of peony roots were oxalic acid, citric acid and malic acid. Eugenol and other 10 aromatic components were identified in peony roots by GC/MSD.

Review of Functional Volatile Component in Essential Oil of Medicinal and Aromatic Plants (자원식물의 기능성 정유성분 이용 고찰)

  • 정해곤;방진기;성낙술;김성민
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.48
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    • pp.41-48
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    • 2003
  • The number of natural products obtained from plants has now reached over 100,000 and new chemical compounds are being discovered ever year. Medicinal and Aromatic plants and their extracts have been used for centuries to relieve pain, aid healing, kill bacteria and insects are important as the antifungal and anti-herbivore agents with further compounds being involved in the symbiotic associations. Although their functions in plants have not been fully established, it is Known that some substances have growth regulatory properties while others are involved in pollination and seed dispersal. The complex nature of these chemicals are usually produced in various types of secretory structures which is an important character of a plant family and also influenced and controlled by genetic and ecological factors. Detailed anatomical description of these structures ave relevant to the market value of the plants, the verification of authenticity of a given species and for the detection of substitution or adulteration. Volatile oils are used for their therapeutic action for flavoring of lemon, in perfumery of rose or as starting materials for the synthesis of other compounds of turpentine. For therapeutic purposes they are administered as inhalations of eucalyptus oil, peppermint oil, as gargles and mouthwashes of thymol and transdermally many essential oils including those of lavender, etc. With these current trend for using volatile components in essential oil will be increasing in the future in Korea and in the world as well.

Affecting Factors on the Variation of Atmospheric Concentration of Polycyclic Aromatic Hydrocarbons in Central London

  • Baek, Sung-Ok;Roger Perry
    • Journal of Korean Society for Atmospheric Environment
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    • v.10 no.E
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    • pp.343-356
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    • 1994
  • In this study, a statistical investigation was carried out for the evaluation of any relationship between polycyclic aromatic hydrocarbons (PAHss) associated with ambient aerosols and other air quality parameters under varying meteorological conditions. Daily measurements for PAHs and air quality/meteorological parameters were selected from a data-base constructed by a comprehensive air monitoring in London during 1985-1987. Correlation coefficients were calculated to examine any significant relationship between the PAHs and other individual variables. Statistical analysis was further Performed for the air quality/meteorological data set using a principal component analysis to derive important factors inherent in the interactions among the variables. A total of six components were identified, representing vehicle emission, photochemical activity/volatilization, space heating, atmospheric humidity, atmospheric stability, and wet deposition. It was found from a stepwise multiple regression analysis that the vehicle emission component is overall the most important factor contributing to the variability of PAHs concentrations at the monitoring site. The photochemical activity/volatilzation component appeared to be also an important factor particularly for the lower molecular weight PAHs. In general, the space heating component was found to be next important factor, while the contributions of other three components to the variance of each PAHs did not appear to be as much important as the first three components in most cases. However, a consistency for these components in their negative correlations with PAHs data was found, indicating their roles in the depletion of PAHs concentrations in the urban atmosphere.

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Studies on Smoke Composition of Korean Tobacco Leaves 1.On the Non-Volatile Phase (국내산 잎담배의 연기성분 연구 1. 비휘발성 성분을 중심으로)

  • 오세열;황건중
    • Journal of the Korean Society of Tobacco Science
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    • v.5 no.2
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    • pp.71-75
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    • 1983
  • The relative proportion of the major smoke components in the nonvolatile phase from some varieties of tobacco, 1. e. flue- cured, burley, and aromatic tobacco, were determined. In flue- cured tobacco smoke, hydroquinone and glycerol we re exhibited higher concentrations than in the smoke from the other tobaccos. In aromatic tobacco smoke, the contents of non-volatile phase were present in lower concentrations.

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Organic Compounds in Condensable Particulate Matter Emitted from Coal Combustion (석탄 연소 시 배출되는 응축성 미세먼지의 유기 성분)

  • Jin Park;Sang-Sup Lee
    • Clean Technology
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    • v.29 no.4
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    • pp.279-287
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    • 2023
  • Fine dust emitted from coal combustion is classified into filterable particulate matter (FPM) and condensable particulate matter (CPM). CPM is difficult to control with existing air pollution control devices, so research is being conducted to understand the characteristics of CPM. Components constituting condensable particulate matter (CPM) are divided into inorganic and organic components. There are many quantitative analysis results for the ionic components, which account for a significant proportion of the CPM inorganic components, but little is known about the organic components. Thus, there is a need for a quantitative analysis of CPM organic components. In this study, aromatic hydrocarbons (toluene, ethyl benzene, m,p-xylene, and o-xylene) and n-alkanes with 10 to 30 carbon atoms were quantitatively analyzed to understand the organic components of CPM emitted from a lab-scale coal combustor. Of the aromatic hydrocarbons, toluene accounted for 1.03% of the CPM organic components. On the other hand, the contents of ethyl benzene, m,p-xylene, and o-xylene showed low values of 0.11%, 0.18%, and 0.51% on average, respectively. Among the n-alkanes, triacontane (C30) showed a high content of 2.64% and decane (C10) showed a content of 2.05%. The next highest contents were shown with dodecane (C12), tetradecane (C14), and heptacosane (C27), all of which were higher than that of toluene. The n-alkane substances that had detectable concentrations showed higher contents than ethyl benzene, m,p-xylene, and o-xylene except for tetracosane (C24).

The Fluorescence Behavior of the Responsive Macrocycle by Aromatic Imine Molecules

  • Choi, Chang-Shik;Jeon, Ki-Seok;Lee, Ki-Hwan
    • Journal of Photoscience
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    • v.11 no.32
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    • pp.71-74
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    • 2004
  • The macrocycle L exhibited a switch on-off behavior through the fluorescent responses by aromatic imine molecule 1 (X=H) / trifluoroacetic acid (TFA). In the 'switch on' state, it was supposed that the aromatic imine molecule 1 is in the cavity of macrocycle L and a photoinduced electron transfer (PET) from the nitrogen of azacrown part to the anthryl group is inhibited by the interaction between the aromatic imine molecule 1 and the azacrown part of macrocycle L. In the 'switch off' state, it was supposed that the protonated imine molecule 1 is induced by the continuous addition of TFA and a repulsion between the protonated azacrown part and the protonated imine molecule 1 is occurred. It was considered that this process induces the intermolecular PET from the protonated imine molecule 1 to the anthryl group of macrocycle L because of a proximity effect between the anthryl group and the protonated imine molecule 1. From the investigation of the transient emission decay curve, the macrocycle L showed three components (3.45 ns (79.72%), 0.61 ns (14.53%), and 0.10 ns (5.75%). When the imine molecule 1 was added in the macrocycle L as molar ratio=1:1, the first main component showed a little longer lifetime as 3.68 ns (82.75%) although the other two components were similar as 0.64 ns (14.28%) and 0.08 ns (2.96%). On the contrary, when the imine molecule 3 (X=C1) was added in the macrocycle L as molar ratio=l:1, all the three components were decreased such as 3.27 ns (69.83%), 0.44 ns (13.24%), and 0.06 ns (16.93%). The fluorescent pH titration of macrocycle L was carried out from pH=3 to pH=9. The macrocycle L and C $U^{2+}$- macrocycle L complex were intersected at about pH=5, while the E $u^{3+}$ -macrocycle L complex was intersected at about pH=5.5. In addtion, we investigated the fluorescence change of macrocycle L as a function of the substituent constant ($\sigma$$_{p}$$^{o}$) showing in the para-substituent with electron withdrawing groups (X=F, Cl) and electron donating groups (X=C $H_3$, OC $H_3$, N(C $H_3$)$_2$), respectively, as well as non-substituent (X=H).).ctively, as well as non-substituent (X=H).

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