• Transactions of the Korean hydrogen and new energy society
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• v.16 no.3
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• pp.244-252
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• 2005

It is very interesting and important in the academic point of view and in practical use the hydrogen-induced phase separation(HIPS) which appears during hydrogen heat treatment. Since hydrogen can be removed very fast by pumping it out the hydrogen-induced new lattice phase which can not be obtained without hydrogen can be preserved as meta-stable state. In this study it has been investigated whether the HIPS appear in Pd-Al, Pd-Co, Pd-Cr, Pd-Ti, Pd-V and Pd-Zr alloys and discussed thermodynamic representation of the HIPS. The Pd alloys were arc-melted under argon atmosphere and remelted 4 or 5 times for homogenization. The alloys were annealed at 600$^{\circ}C$ under vacuum for 24 hrs and then subjected to pressure-composition isotherm measurements at 100$^{\circ}C$. The hydrogen heat treatment(HHT) of samples was carried out at 600$^{\circ}C$ under hydrogen pressure of 70 bar for 6 days and PC isotherms at 100$^{\circ}C$ were measured. By comparing the PC isotherms measured before and after HHT, occurrence of phase separation was determined. The experimental results showed that the HIPS appeared only in Pd-0.05Co alloy. For Pd-Co alloys with various composition the PC isotherms were measured. By adopting Park-Flanagan model for ternary thermodynamics the Gibbs free energy change for Pd-Co-H solid solution was calculated and subsequently with this the HIPS in Pd-Co alloy was explained fairly.

• Journal of Welding and Joining
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• v.32 no.4
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• pp.26-33
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• 2014

The metallurgical and mechanical characteristics, toughness and corrosion resistance of dissimilar welds between super duplex stainless steel UNS S32750 and carbon steel ASTM A516Gr.70 have been evaluated. Three heat inputs of 21.12, 24.00, 26.88kJ/cm were employed to make joints of dissimilar metals with flux cored arc welding(FCAW). Based on microstructural examination, vermicular ferrite was formed in the first layer of weld at low heat input(21.12kJ/cm) and $Cr_{eq}/Ni_{eq}$ of 1.61 while acicular ferrite was formed in last layer of weld at high heat input(26.88kJ/cm) and $Cr_{eq}/Ni_{eq}$ of 1.72. Ferrite percentage in dissimilar welds was lowest in the first layer of weld regardless of heat inputs and it gradually increased in the second and third layers of weld. Heat affected zone showed higher hardness than the weld metal although reheated zone showed lower hardness than weld metal due to the formation of secondary austenite. Tensile strengths of dissimilar welds increased with heat input and there was 100MPa difference. The corrosion test by ferric chloride solution showed that carbon steel had poor corrosion resistance and pitting corrosion occurred in the first layer(root pass) of weld due to the presence of reheated zone where secondary austenite was formed. The salt spray test of carbon steel showed that the surface only corroded but the amount of weight loss was extremely low.

• Transactions of the Korean hydrogen and new energy society
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• v.17 no.4
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• pp.362-370
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• 2006

The purpose of this paper was to investigate the reforming characteristics and optimum operating condition of the plasmatron assisted $CH_4$ reforming reaction for the hydrogen-rich gas production. Also, in order to increase the hydrogen production and the methane conversion rate, parametric screening studies were conducted, in which there were the variations of the $CH_4$ flow ratio, $CO_2$ flow ratio, vapor flow ratio, mixing flow ratio and catalyst addition in reactor. High temperature plasma flame was generated by air and arc discharge. The air flow rate and input electric power were fixed 5.1 l/min and 6.4 kW, respectively. When the $CH_4$ flow ratio was 38.5%, the production of hydrogen was maximized and optimal methane conversion rate was 99.2%. Under these optimal conditions, the following synthesis gas concentrations were determined: $H_2$, 45.4%; CO, 6.9%; $CO_2$, 1.5%; and $C_2H_2$, 1.1%. The $H_2/CO$ ratio was 6.6, hydrogen yield was 78.8% and energy conversion rate was 63.6%.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.21 no.2
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• pp.349-353
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• 2012

As the world wind energy market grows rapidly, the productions of wind power generation equipment have recently increased, but manufacturers are not able meet this requirement. Particularly offshore wind energy industry is one of the most popular renewable energy sectors. To generalize welding processes, the welding automation is considered for steel structure manufacturing in offshore wind energy to get high quality and productivity. Welding technology in construction of the wind towers is depended on progress productivity. In addition, the life of wind tower structures should be considered by taking account of the natural weathering and the load it endures. The root passes are typically deposited using Gas Tungsten Arc Welding(GTAW) with a specialized backing gas shield. Not only the validation consists of welders experienced in determining the welding productivity of the baseline welding procedure, but also the standard testing required by the ASME section IX and API1104 codes, toughness testing was performed on the completed field welds. This paper presents the welding characteristics of the root-pass welding of high tensile steel in manufacturing of offshore wind tower. Based on the result from welding experiments, optimal welding conditions were selected after analyzing correlation between welding parameters(peak current, background current and wire feed rate) and back-bead geometry such as back-bead width(mm) and back-bead height performing root-pass welding experiment under various conditions. Furthermore, a response surface approach has been applied to provide an algorithm to predict an optimal welding quality.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.27 no.6
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• pp.328-336
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• 2015

Currently, 22% of the total energy consumption of buildings in Korea is used for lighting. Light-shelves have garnered attention as a way to reduce consumption, but there are few studies on the types of curve and curvature, which limits the improvement of light-shelf performance and its design. This study constructed a test bed of actual residential types to evaluate the performance. Outcomes of light usage, according to variables of light-shelves, were used as indicators of performance evaluation. The results are as follows:1) Performance evaluation was conducted on flat-type light-shelves to verify performance of curvature-shelves, which are movable with a width of 200 mm, and the most ideal angle and specification per solar term are calculated. 2) The (-) shaped curvature contributed to a reduction in energy consumption and an improvement of evenness. 3) In case of light-shelves with (-) shaped curvature, an increased angle not exceeding $80^{\circ}$ of the arc contributed to an improvement of light penetration. 4) Appropriate specifications of curved light-shelves include movable types with widths of 200 mm, and angle ranges of $20^{\circ}{\sim}60^{\circ}$. 5) Light energy consumption of a movable light-shelf with curvature and width of 200 mm were reduced by 17% and 7.8% compared to a $0^{\circ}$ fixed and a movable light-shelf, respectively.

• Transactions of the Korean hydrogen and new energy society
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• v.11 no.4
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• pp.189-202
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• 2000

$AB_2$ type Zr-based Laves phases alloys have been studied for potential application as a negative electrode in a Ni-MH battery. The $AB_2$-type electrodes have a much higher energy density than $AB_5$-type electrodes per weight, however they have some disadvantages such as poor activation behavior and cycle life etc. Nonetheless, the $AB_2$-type electrodes have been studied very extensively due to their high energy density. In this study, in order to develop the cycle life, the Mn of $AB_2$ alloy composition was substituted partially by Mo. The alloys were melted by arc furnace and remelted 4-5 times for homogeneity. The alloy powder was used below 200-325 mesh for experiments. The structures and phases of the alloys were analyzed by XRD, SEM and EDS, and measured the curve of a pressure-composition isotherms. The electrodes were prepared by cold pressing of the copper-coated(25 wt%) alloy powders, and tested by a half cell. The results are summarized as follows. The cycle life was improved with the increase of Mo amount in $Zr_{1-x}Ti_xV_{0.4}Ni_{1.2}Mn_{0.4}Mo_y$(x=0.3, 0.4) and the activation was faster, whereas the discharge capacity decreased.

• Progress in Medical Physics
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• v.25 no.2
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• pp.65-71
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• 2014

A Varian Portal Dosimetry system was compared to an isocentrically mounted MapCHECK 2 diode array for volumetric modulated arc therapy (VMAT) QA. A Varian TrueBeam STx with an aS-1000 digital imaging panel was used to acquire VMAT QA images for 13 plans using four photon energies (6, 8, 10 and 15 MV). The EPID-based QA images were compared to the Portal Dose Image Prediction calculated in the Varian Eclipse treatment planning system (TPS). An isocentrically mounted Sun Nuclear MapCHECK 2 diode array with 5 cm water-equivalent buildup was also used for the VMAT QAs and the measurements were compared to a composite dose plane from the Eclipse TPS. A ${\gamma}$ test was implemented in the Sun Nuclear Patient software with 10% threshold and absolute comparison at 1%/1 mm (dose difference/distance-to-agreement), 2%/2 mm, and 3%/3 mm criteria for both QA methods. The two-tailed paired Student's t-test was employed to analyze the statistical significance at 95% confidence level. The average ${\gamma}$ passing rates were greater than 95% at 3%/3 mm using both methods for all four energies. The differences in the average passing rates between the two methods were within 1.7% and 1.6% of each other when analyzed at 2%/2 mm and 3%/3 mm, respectively. The EPID passing rates were somewhat better than the MapCHECK 2 when analyzed at 1%/1 mm; the difference was lower for 8 MV and 10 MV. However, the differences were not statistically significant for all criteria and energies (p-values >0.05). The EPID-based QA showed large off-axis over-response and dependence of ${\gamma}$ passing rate on energy, while the MapCHECK 2 was susceptible to the MLC tongue-and-groove effect. The two fluence-based QA techniques can be an alternative tool of VMAT QA to each other, if the limitations of each QA method (mechanical sag, detector response, and detector alignment) are carefully considered.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.27 no.11
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• pp.574-580
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• 2015

Climatic zone in building code is an administrative district classification reflecting regional climatic characteristics. Use of Degree-Days is a fundamental method that can be used in various building design codes, analysis of building energy performance, and establishment of minimum thermal transmittance of building envelopes. Many foreign countries, such as the USA, the EU, Australia, Italy, India, China, etc., have already adapted climatic zone classification with degree-days, precipitation or amount of water vapor based on the characteristics of their own country's climate. In Korea, however, the minimum requirements for regional thermal transmittance are classified separately for the Jungbu area, Nambu area and Jeju Island with no definite criterion. In this study, degree-days of 255 Korean cities were used for climatic zone classification. Outdoor dry-bulb temperature data from the Korea Meteorological Administration for 1981~2010 was used to calculate degree-days. ArcGIS and the calculated degree-days were utilized to analyze and visualize climatic zone classification. As a result, depending on the distribution and distinctive differences in degree-days, four climatic zones were derived : 1) Central area, 2) Mountain area of Gyeonggi and Gangwon provinces, 3) Southern area, and 4) Jeju Island. The climatic zones were suggested per administrative district for easy public understanding and utilization.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.22 no.1
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• pp.22-28
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• 2013

Robotic GMA (Gas Metal Arc) welding process is one of widely acceptable metal joining process. The heat and mass inputs are coupled and transferred by the weld arc to the molten weld pool and by the molten metal that is being transferred to the weld pool. The amount and distribution of the input energy are basically controlled by the obvious and careful choices of welding process parameters in order to accomplish the optimal bead geometry and the desired quality of the weldment. To make effective use of automated and robotic GMA welding, it is imperative to predict online faults for bead geometry and welding quality with respect to welding parameters, applicable to all welding positions and covering a wide range of material thickness. MD (Mahalanobis Distance) technique was employed for investigating and modeling the GMA welding process and significance test techniques were applied for the interpretation of the experimental data. To successfully accomplish this objective, two sets of experiment were performed with different welding parameters; the welded samples from SM 490A steel flats. First, a set of weldments without any faults were generated in a number of repeated sessions in order to be used as references. The experimental results of current and voltage waveforms were used to predict the magnitude of bead geometry and welding quality, and to establish the relationships between weld process parameters and online welding faults. Statistical models developed from experimental results which can be used to quantify the welding quality with respect to process parameters in order to achieve the desired bead geometry based on weld quality criteria.

• Journal of Ocean Engineering and Technology
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• v.21 no.3 s.76
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• pp.71-76
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• 2007

Recently, many industries have been employing the application of laser beam welding, due to the resulting high welding quality, such as smaller width of melting and heat affective zone, smaller welding deformation, and fine grains of weldment, compared to arc welding. However, in order to appropriately utilize this welding process with steel structure, the characteristics of welding residual stresses and fracture toughness in welded joints are to be investigated for reliability. Therefore, in this study, the mechanical properties of weldments by arc and laser welding are investigated using FEM to confirm the weldability of laser welding to the general structural steel (HT50). The Charpy impact test and 3-points bending CTOD test are carried out in the range of temperatures between $-60^{\circ}C\;and\;20^{\circ}C$, in order to understand the effect on the fracture toughness of weldments. From the research results, it has been found that the maximum residual stress appears at the center of plate thickness, and that the fracture toughness is influenced by strength mis-match.