• Title/Summary/Keyword: anode water

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Removal of Rhodamine B in Water by Ultraviolet Radiation Combined with Electrolysis(I) (전기분해와 UV 조사에 의한 수중의 Rhodamine B의 제거(I))

  • Park, Young-Seek
    • Journal of Environmental Health Sciences
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    • v.34 no.6
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    • pp.439-445
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    • 2008
  • The feasibility study for the application of the removal and mineralization of Rhodamine B (RhB) was performed in a batch electrochemical reactor. The electro/UV process was consisted of DSA (dimensionally stable anode) electrode and UV-C or ozone lamp. The experimental results showed that RhB removal by the ozone lamp was higher than that of the UV-C lamp. Optimum current of the electro/UV process was 1 A. The electrochemical, UV and electro/UV process could completely degrade RhB, while a prolonged treatment was necessary to reach a high level RhB mineralization. It was observed that RhB removal in electro/UV process is similar to the sum of the UV and electrolytic decolorization. However, it was found that the COD of RhB could be degraded more efficiently by the electro/UV process (90.2 %) than the sum of the two individual oxidation processes [UV (19.7%) and electrolytic process (50.8%)]. A synergetic effect was demonstrated between the UV and electrolysis.

Structure and field emission properties of carbon-nitrogen (CN) nanofibers obtained by hot isostatic pressure (Hot isostatic pressure을 이용한 CN nanofiber의 구조 및 전계방출 특성)

  • Lee, Yang-Doo;Blank, V.D.;Batov, D.V.;Buga, S.G;Nahm, Sahn;Lee, Yun-Hi;Ju, Byeong-Kwon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.04a
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    • pp.84-87
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    • 2003
  • Carbon-nitrogen (CN) nanofibers have been produced using a water cooled hot isostatic pressure (HIP) apparatus. The CN nanofibers were grown in random with the diameter of about 100-150nm and length over $10{\mu}m$. Emission properties of CN nanofibers were investigated for spacing, between anode and cathode, variation. Then turn-on fields about $1.4V/{\mu}m$. The time reliability and light emission test were carried out for above 100 hours. We suggest that CN nanofibers can be possibly applied to high brightness flat lamp because of low turn-on field and time reliability.

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2차원 토양 실험장치에서 동전기-펜턴 공정의 이해

  • 양지원;박지연;김상준;이유진;기대정
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.04a
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    • pp.310-313
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    • 2003
  • Removal of phenanthrene by electrokinetic method combined with Fenton-like process was studied in a model system. The scale of reactor was 120 cm in length, 10 cm in width, and 50 cm in height. Sand was selected as a model soil. Bentonite was filled in the space between reservoir and contaminated soil to control the flow rate of water. When constant voltage of 100 V was applied to this system, current varied from 1000 mA to 290 mA for 28 days. pH of anode and cathode reservoirs became to 2 and 13, respectively. Removal efficiency of phenanthrene was more than 60 %.

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Electrochemical Regeneration of FAD by Catalytic Electrode Without Electron Mediator and Biochemical Reducing Power

  • JEON SUNG JIN;SHIN IN HO;SANG BYUNG IN;PARK DOO HYUN
    • Journal of Microbiology and Biotechnology
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    • v.15 no.2
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    • pp.281-286
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    • 2005
  • We created a new graphite-Cu(II) electrode and found that the electrode could catalyze FADH$_2$ oxidation and FAD reduction coupled to electricity production and consumption, respectively. In a fuel cell with graphite-Cu(II) anode and graphite-Fe(III) cathode, the electricity was produced by coupling to the spontaneous oxidation of FADH$_2$ Fumarate and xylose were not produced from the enzymatic oxidation of succinate and xylitol without FAD, respectively, but produced with FAD. The production of fumarate and xylose in the reactor with FAD electrochemically regenerated was maximally 2- 5 times higher than that in the reactor with FAD. By using this new electrode with catalytic function, a bioelectrocatalysts can be engineered; namely, oxidoreductase (e.g., lactate dehydrogenase) and FAD can function for biotransformation without an electron mediator and second oxidoreductase for cofactors recycling.

An Electrochemical Evaluation on the Corrosion of Weld Zone in Cold Arc Welding Process of the Cast Iron (주철의 냉간 아크용접시 용접부의 부식에 관한 전기화학적 평가)

  • Kim, Jin-Gyeong;Mun, Gyeong-Man
    • Proceedings of the KWS Conference
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    • 2005.06a
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    • pp.273-275
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    • 2005
  • Variation of hardness and corrosion potential of welding zone was investigated when cold arc welding of cast iron was carried out with a parameter of Ni electrode. Hardness of HAZ was the highest compared to other welding zone. And corrosion potential of HAZ was also more negative value than other welding zone. However there was not a proportional relation between hardness and corrosion potential. Local corrosion of HAZ was clearly appeared than other welding zone by small anode and large cathode in seal water solution.

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Composite Ni-TiO2 nanotube arrays electrode for photo-assisted electrolysis

  • Pozio, Alfonso;Masci, Amedeo;Pasquali, Mauro
    • Advances in Energy Research
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    • v.3 no.1
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    • pp.45-57
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    • 2015
  • This article is addressed to define a new composite electrode constituted by porous nickel and an array of highly ordered $TiO_2$ nanotubes obtained by a previous galvanostatic anodization treatment in an ethylene glycol solution. The electrochemical performances of the composite anode were evaluated in a photo-electrolyser, which showed good solar conversion efficiency with respect to the UV irradiance together with a reduction of energy consumption. Such a combination of materials makes our system simple and able to work both in dark and under solar light exposure, thus opening new perspectives for industrial-scale applications.

A review on electrically debonding Adhesives (전기해체 접착제)

  • Jeong, Jongkoo
    • Journal of Adhesion and Interface
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    • v.19 no.2
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    • pp.84-94
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    • 2018
  • Electrically debonding adhesives[EDA], one of the controlled delamination materials[CDM] is reviewed. CDM can be defined as the ability to separate adhesive bonded assemblies without causing damage to the substrates. Its application includes electronics, medical surgery, dentistry, building and general manufacturing where the opportunity to separate assemblies is important. There are several important mechanisms of EDAs; faradaic reaction, phase separation and anode detachment, cathodic debonding, gas emission mechanism, and mechanical stresses. These mechanisms are reviewed with various research results. Since the mechanism behind the electrochemical debonding of adhesives is not well understood, this review aims to help the research scientists in the industries. Finally, new applications of EDA are introduced as new business opportunity.

Enhancement of Catalytic Activity of Pt/Alumina by a Novel Pretreatment Method for the CO Oxidation for Fuel Cell Applications (연료전지용 CO의 산화를 위한 백금/알루미나 촉매의 성능향상에 관한 연구)

  • Jo, Myung-Chan
    • Journal of Environmental Science International
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    • v.17 no.12
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    • pp.1307-1314
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    • 2008
  • Hydrogen gas is used as a fuel for the proton exchange membrane fuel cell (PEMFC). Trace amount of carbon monoxide present in the reformate $H_2$ gas can poison the anode of the PEMFC. Therefore, preferential oxidation (PROX) of CO is essential for reducing the concentration of CO from a hydrogen-rich reformate gas. In this study, conventional Pt/$Al_2O_3$ catalyst was prepared for the preferential oxidation of CO. The effects of catalyst preparation method, additive, and hydrogen on the performances of PROX reaction of CO were investigated. Water treatment and addition of Ce enhanced catalytic activity of the Pt/$Al_2O_3$ catalyst at low temperature below $100^{\circ}C$.

A Study of Electrolytic Ozone Generator for Ozone Asher (Ozone Asher용(用) Ozone Generator 개발연구(開發硏究))

  • Moon, Jae-Duk;Woo, Jung-Wook
    • Proceedings of the KIEE Conference
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    • 1993.07b
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    • pp.648-651
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    • 1993
  • A parallel plate type electrolytic ozone generator for ozone asher has been fabricated and studied, and 4 kinds of ozone generation anode electrode having different slits have also been investigated. It is found that there were optimum conditions for the slits of electrode, which, however, controls the field in the interelectrode spacing, and allows sideflow waterpaths through the slits in the electrode. As a result, the generated ozone concentrations of A, B, C and D type electrode showed 2.2, 1.3, 1.5 and 3.0 ppm for 400 ml/min flowrate tap water test, and, ozone yields of 11, 13, 15 and 30 $mg/kWhcm^2$ respectively.

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The Study on the the P3HT:PCBM Bulk Heterojunction Solar Cells Utilizing $WO_3$ Nano-particle As a Hole Transporting Layer

  • Choe, Ha-Na;Kim, Seong-Hyeon;Kim, Gyeong-Gon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.321-321
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    • 2010
  • The PEDOT:PSS layer is usually used as hole transporting layer for the polymer bulk heterojunction solar cells. However, the interface between ITO and PEDOT:PSS is not stable and the chemical reaction between ITO and PEDOT can result in degraded device performance. We used the tungsten oxides as a hole transport layer by spin-coating. The $WO_3$ nanoparticles were well dispersed in ammonium hydroxide and deionized water and formed thin layer on the ITO anode. We found that $WO_3$ surface is more hydrophobic than the bare ITO or PEDOT:PSS-coated surfaces. The hydrophobic surfaces promote an ordered growth of P3HT films. A higher degree of P3HT ordering is expected to improve the hole mobility and the lifetime of the device using the tungsten oxide showed better stability compared to the device using the PEDOT:PSS.

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