• Title/Summary/Keyword: anisotropic condition

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Pressure-Temperature Diagram of Critical Condition for Disproportionation of Nd-Fe-B Alloy in Hydrogen

  • Kwon, H.W.;Kim, D.H.;Yu, J.H.
    • Journal of Magnetics
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    • v.15 no.4
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    • pp.155-158
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    • 2010
  • The HDDR (hydrogenation, disproportionation, desorption, and recombination) process can be used as an effective way of converting a no coercivity Nd-Fe-B ingot material, with a coarse $Nd_2Fe_{14}B$ grain structure, to a highly coercive one with a fine grain structure. Careful control of the HDDR process can lead to an anisotropic powder with good $Nd_2Fe_{14}B$ grain texture; the most critical step for inducing texture is disproportionation. The critical conditions (hydrogen pressure and temperature) for the disproportionation reaction of fully hydrogenated $Nd_{12.5}Fe_{81.1-(x+y)}B_{6.4}Ga_xNb_y$ (x = 0 or 0.3, y = 0 or 0.2) alloys, in different atmospheres of pure hydrogen and a mixed gas of hydrogen and argon, was investigated with TPA (thermopiezic analyser). From this, the hydrogen pressure-temperature diagram showing the critical conditions was established. The critical disproportionation temperature of the fully hydrogenated $Nd_{12.5}Fe_{81.1-(x+y)}B_{6.4}Ga_xNb_y$ alloys was slightly increased as the hydrogen pressure decreased in both pure hydrogen and mixed gas. The critical disproportionation temperature of the hydrogenated alloys was higher in the mixed gas than in pure hydrogen. Addition of Ga and Nb increased the critical disproportionation temperature of the fully hydrogenated Nd-Fe-B alloys.

The Development of Deep Silicon Etch Process with Conventional Inductively Coupled Plasma (ICP) Etcher (범용성 유도결합 플라즈마 식각장비를 이용한 깊은 실리콘 식각)

  • 조수범;박세근;오범환
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.7
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    • pp.701-707
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    • 2004
  • High aspect ratio silicon structure through deep silicon etching process have become indispensable for advanced MEMS applications. In this paper, we present the results of modified Bosch process to obtain anisotropic silicon structure with conventional Inductively Coupled Plasma (ICP) etcher instead of the expensive Bosch process systems. In modified Bosch process, etching step ($SFsub6$) / sidewall passivation ($Csub4Fsub8$) step time is much longer than commercialized Bosch scheme and process transition time is introduced between process steps to improve gas switching and RF power delivery efficiency. To optimize process parameters, etching ($SFsub6$) / sidewall passivation ($Csub4Fsub8$) time and ion energy effects on etching profile was investigated. Etch profile strongly depends on the period of etch / passivation and ion energy. Furthermore, substrate temperature during etching process was found to be an important parameter determining etching profile. Test structures with different pattern size have been etched for the comparison of the aspect ratio dependent etch rate and the formation of silicon grass. At optimized process condition, micropatterns etched with modified Bosch process showed nearly vertical sidewall and no silicon grass formation with etch rate of 1.2 ${\mu}{\textrm}{m}$/ min and the size of scallop of 250 nm.

Investigation of Surface Reflectance Reduction for Multicrystalline Silicon Solar Cells with Acid Texturing (Acid Texturing에 의한 다결정 실리콘 태양전지의 표면 반사율 감소에 대한 연구)

  • Kim, Ji-Sun;Kim, Bum-Ho;Lee, Eun-Joo;Lee, Soo-Hong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.16-17
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    • 2007
  • To improve efficiency of solar cells, it is important to make a light trapping structure to reduce surface reflectance for increasing absorption of sun light within the solar cells. One of the promising methods that can reduce surface reflectance is isotropic texturing with acid solution based on hydrofluoric acid(HF), nitric acid($HNO_3$), and organic additives. Anisotropic texturing with alkali solution is not suitable for multicrystalline silicon wafers because of its different grain orientation. Isotropic texturing with acid solution can uniformly etch multicrystalline silicon wafers unrelated with grain orientation, so we can get low surface reflectance. In this paper, the acid texturing solution is made up of only HF and $HNO_3$ for easy controling the concentration and low cost compared to acid solution with organic additives. $HNO_3$ concentration and dipping time were varied to find the condition of minimum surface reflectance. Textured surfaces were observed Scanning Electron Microscope(SEM) and surface reflectance were measured. The best result of arithmetic mean(wavelength from 400nm to 1000nm) reflectance with acid texturing is 4.64% less than alkali texturing.

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Influence of WIP conditions on dimensional change of LTCC sheet (온간 정수압 공정 조건에 따른 LTCC sheet의 수축률)

  • Jeong, M.S.;Yoon, Y.H.;Rhim, S.H.;Yoon, S.M.;Oh, S.I.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.05a
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    • pp.507-511
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    • 2008
  • LTCC (Low Temperature Co-fired Ceramic) has been successfully applied to ceramic substrates for circuits and micro-fluidic systems and has proven its superior performance in a variety of applications. The prediction of shrinkage in LTCC process is an important for dimensional control of micro LTCC products which has influences on electronic characteristics. For avoiding the unpredictable shrinkage of LTCC during the sintering which makes accurate placement of the circuit devices difficult, pre-processes such as WIP (Warm Isostatic Pressing) and lamination must be modified. The objective of the present investigation is to establish a proper WIP conditions for near net shape fabrication of LTCC products. This paper discusses the influence of WIP conditions on the dimensional change of LTCC sheet. In the investigation, it is shown that the shrinkage values of sheets depend on WIP conditions and sheet directions. This work is a quantitative evaluation of the effect of WIP pressure on shrinkage of LTCC sheet. Additionally, the results show anisotropic shrinkage behaviour of sheet during LTCC process.

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Performance Analysis of a Vibrating Microgyroscope using Angular Rate Dynamic Model (진동형 마이크로 자이로스코프의 각속도 주파수 동역학적 모델의 도출 및 성능 해석)

  • Hong, Yoon-Shik;Lee, Jong-Hyun;Kim, Soo-Hyun
    • Journal of the Korean Society for Precision Engineering
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    • v.18 no.1
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    • pp.89-97
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    • 2001
  • A microgyroscope, which vibrates in two orthogonal axes on the substrate plane, is designed and fabricated. The shuttle mass of the vibrating gyroscope consists of two parts. The one is outer shuttle mass which vibrates in driving mode guided by four folded springs attached to anchors. And the other is inner shuttle mass which vibrates in driving mode as the outer frame does and also can vibrate in sensing mode guided by four folded springs attached to the outer shuttle mass. Due to the directions of vibrating mode, it is possible to fabricate the gyroscope with simplified process by using polysilicon on insulator structure. Fabrication processes of the microgyroscope are composed of anisotropic silicon etching by RIE, gas-phase etching (GPE) of the buried sacrificial oxide layer, metal electrode formation. An eletromechanical model of the vibrating microgyroscope was modeled and bandwidth characteristics of the gyroscope operates at DC 4V and AC 0.1V in a vacuum chamber of 100mtorr. The detection circuit consists of a discrete sense amplifier and a noise canceling circuit. Using the evaluated electromechanical model, an operating condition for high performance of the gyroscope is obtained.

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Active Vibration Control of Underwater Hull Structure Using Macro-Fiber Composite Actuators (MFC 작동기를 이용한 수중 Hull 구조물의 능동 진동 제어)

  • Kwon, Oh-Cheol;Sohn, Jung-Woo;Choi, Seung-Bok
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.19 no.2
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    • pp.138-145
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    • 2009
  • Structural vibration and noise are hot issues in underwater vehicles such as submarines for their survivability. Therefore, active vibration and noise control of submarine, which can be modeled as hull structure, have been conducted by the use of piezoelectric materials. Traditional piezoelectric materials are too brittle and not suitable to curved geometry such as hull structures. Therefore, advanced anisotropic piezocomposite actuator named as Macro-Fiber Composite(MFC), which can provide great flexibility, large induced strain and directional actuating force is adopted for this research. In this study, dynamic model of the smart hull structure is established and active vibration control performance of the smart hull structure is evaluated using optimally placed MFC. Actuating performance of MFC is evaluated by finite element analysis and dynamic modeling of the smart hull structure is derived by finite element method considering underwater condition. In order to suppress the vibration of hull structure, Linear Quadratic Gaussian(LQG) algorithm is adopted. After then active vibration control performance of the proposed smart hull structure is evaluated with computer simulation and experimental investigation in underwater. Structural vibration of the hull structure is decreased effectively by applying proper control voltages to the MFC actuators.

A Study on a New Concept for the Structural Strength Assessment to Development of Membrane LNG Cargo Container System under Static Load (멤브레인형 LNG 화물창 개발을 위한 정적 구조 안전성 평가 모델 연구)

  • Hwang, Se Yun;Kim, Yooil;Kang, Joong Kyoo;Lee, Jang Hyun
    • Journal of the Society of Naval Architects of Korea
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    • v.53 no.2
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    • pp.162-169
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    • 2016
  • A new concept of membrane type LNG CCS was proposed. Also, its static behavior was numerically analyzed considering the interaction between primary and secondary barrier together with securing device. Hull deflection was taken into account as an external load, together with temperature distribution across the barriers. The suggested numerical model considers both sliding and contact between the two mating surfaces of both the primary and secondary barrier, and anisotropic material behavior of plywood, R-PUF was also taken into account. Furthermore, detailed local strength was evaluated for the securing device, which is arranged between two barriers to hold the primary barrier. It was confirmed through the numerical analysis that the new concept of membrane type CCS was structurally safe under static loading condition and securing concept was structurally reliable.

Probabilistic Q-system for rock classification considering shear wave propagation in jointed rock mass

  • Kim, Ji-Won;Chong, Song-Hun;Cho, Gye-Chun
    • Geomechanics and Engineering
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    • v.30 no.5
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    • pp.449-460
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    • 2022
  • Safe underground construction in a rock mass requires adequate ground investigation and effective determination of rock conditions. The estimation of rock mass behavior is difficult, because rock masses are innately anisotropic and heterogeneous at different scales and are affected by various environmental factors. Quantitative rock mass classification systems, such as the Q-system and rock mass rating, are widely used for characterization and engineering design. The measurement of rock classification parameters is subjective and can vary among observers, resulting in questionable accuracy. Geophysical investigation methods, such as seismic surveys, have also been used for ground characterization. Torsional shear wave propagation characteristics in cylindrical rods are equal to that in an infinite media. A probabilistic quantitative relationship between the Q-value and shear wave velocity is thus investigated considering long-wavelength wave propagation in equivalent continuum jointed rock masses. Individual Q-system parameters are correlated with stress-dependent shear wave velocities in jointed rocks using experimental and numerical methods. The relationship between the Q-value and the shear wave velocity is normalized using a defined reference condition. This relationship is further improved using probabilistic analysis to remove unrealistic data and to suggest a range of Q-values for a given wave velocity. The proposed probabilistic Q-value estimation is then compared with field measurements and cross-hole seismic test data to verify its applicability.

Factors affecting hydraulic anisotropy of soil

  • Nurly Gofar;Alfrendo Satyanaga;Gerarldo D. Aventian;Gulnur Pernebekova;Zhanat Argimbayeva;Sung-Woo Moon;Jong Kim
    • Geomechanics and Engineering
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    • v.36 no.4
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    • pp.343-353
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    • 2024
  • The hydraulic anisotropic behavior of unsaturated soil has not been fully explored in relation to the grain-size distribution. The present study conducted laboratory assessments to examine the hydraulic anisotropy condition of statically compacted specimens in various initial states. The investigation incorporated the concept of hydraulic anisotropy by employing two discrete forms of soil stratification: horizontal-layering (HL) and vertical-layering (VL). The examined soils comprised sandy silt and silty sand, exhibiting either unimodal or bimodal soil-water characteristic curve (SWCC). This study aimed to investigate the potential correlation between the hydraulic anisotropy ratio and soil properties. The present study established a correlation between the hydraulic anisotropy ratio and several soil parameters, including fine content, dry density, plastic limit, and liquid limit. The study results indicate a non-linear relationship between the percentage of fine and dry density in soils with unimodal and bimodal soil-water characteristic curve (SWCC) and hydraulic anisotropy ratio.

An Experimental Study on Depositional Environments and Consolidation Properties of Shihwa Deposits (시화지역 퇴적층의 퇴적환경과 압밀특성에 관한 연구)

  • 원정윤;장병욱;김동범;손영환
    • Journal of the Korean Geotechnical Society
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    • v.20 no.5
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    • pp.49-58
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    • 2004
  • Consolidation properties of Shihwa deposits were analysed by means of depositional environments. Depositional environments including particle size distributions, sediment structures, geochemical properties, porewater chemistries and carbon age dating were analysed using undisturbed samples retrieved successively from a boring hole in the study area. Laboratory oedometer tests and anisotropic consolidated triaxial tests (CKoUC) for undisturbed samples were performed to examine the overconsolidation phenomena. Based on the results of analysis of depositional environments, it was found that the upper silt/clay mixed layer was deposited under marine condition while underlying sand and clay layers were deposited under fluvial condition. Planar laminated structures of silts and clays were dominant in marine deposits. Although there was no clear evidences that geological erosion had occurred in marine deposits, overconsolidation ratios of the upper marine samples were greater than unity Stress Paths of the upper marine samples behaved similarly to those of normally consolidated clays. Data plotted in stress state charts showed that the marine deposits were normally consolidated in geological meaning. These apparent overconsolidation of the marine deposits can be explained by the structures i.e. chemical bonding due to the difference of the rate of deposition, not by geological erosions and ground water fluctuations.