• 제목/요약/키워드: anions contents

검색결과 59건 처리시간 0.04초

식물체의 연(Pb) 흡수 및 유해성에 미치는 음이온의 영향 (Effects of Various Anions on Absorption and Toxicity of Lead in Plants)

  • 성민웅
    • Journal of Plant Biology
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    • 제20권1호
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    • pp.7-14
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    • 1977
  • The seeds of bean(Glycine max M.) and corn(Zea mays L.) soaked in 5000ppm lead solution for 24 hours were sowed in the flowerpots being placed sandy-clay soil under the field condition. The fixed concentrations of various anions and 2000 ppm lead were supplied alternately in the sandy-clay soi of the flowerpots at two days interval from May to July in 1976. After the plants were harvested prior to the flowering stage, the lead contents of plnat and soil were analyzed by atomic absorption spectrophotometer. The lead contents absorbed by the plant roots showed the highest in an weak acid soil of the best suitable condition of plant growth. The absorption of lead by the plant roots was inhibited by the various anions, especially divalent anions of the soil. Some phosphate anions inhibited lead absorption more than otehr various anions in the soil. The more various anions were in the soil, the more plants could be protected from the lead toxicity. In the case of lead supply in the soil, 99.5% of lead was accumulated in the upper layer of the soil(0-10cm), and 0.5% of lead accumulated in the lower layer (10-20cm). Therefore, the yellow-brown and white symptoms on the leaves and the inhibition of root growth by lead toxicity was increased in the early stage of the germination, however decreased in accordance with the progress of the growing stage becuase of the root growth toward beneath the lower layer of the soil. In spite of the contents of 3773ppm lead in the soil, the symptoms of lead toxicity was not found in the grown plants. At that time the lead contents of the plants absorbed from the soil were minimum 0.78ppm and maximum 3.64ppm through the growing stage.

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Tetra Ethyl Ortho Silicate의 수화 및 중합에 미치는 촉매의 영향 (The Effects of Catalyst on the Hydrolysis and Polymerization of TEOS)

  • 정형진;이전국
    • 한국세라믹학회지
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    • 제27권1호
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    • pp.86-90
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    • 1990
  • The shape and characteristics of polymers in hydrolzed and polymerized sol were affected by the types of catalysts. In our research, the contents of water and catalysts were constant and the types of catalyst were varied. In the case of acid catalysts, polymers in sol were linear and spinnable. The shapes of polymer were affected by the types of anions in acid catalysts. In the case of catalyst having anions, F, Cl, in the same period, the effects were similar. But in the case of base catalysts polymers were rigid rod like and not spinnable.

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都市大氣중 浮遊粒子狀物質, 鹽化物, 窒酸鹽 및 黃酸鹽의 濃度와 粒經分布 (Concentration and Size Distribution of Atmospheric Particulate Matters, Chloride, Nitrate, and Sulfate Salts in Urban Air)

  • 손동헌;허문영
    • 한국대기환경학회지
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    • 제2권3호
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    • pp.27-33
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    • 1986
  • Atmospheric particulate matter (A. P. M.) was collected and size-fractionated by an Andersen high-volume air sampler over 15 month period from Jan. 1985 to Feb. 1986 in Seoul. The concentration of chloride, nitrate and sulfate were extracted in an ultrasonic bath and were analyzed by ion chromatography. The annual arithmetical mean of A. P. M. was 128.54 $\mug/m^3$. The concentration of anions were 2.88 $\mug/m^3$ for chloride, 3.86$\mug/m^3$ for nitrate, and 25.44$\mug/m^3$ for sulfate. The content of A. P. M. was lowest in the particle size range 1.1 $\sim 3.3\mum$ and increased as the particle size increased or decreased. And the anions exhibited a seasonal variation in the isize distribution. The contents of anions were higher in winter than summer. Ther ratio of fine particles to the total particles defined by F/T for chloride, nitrate and sulfate. The F\ulcornerT of these anion generally decrease with increasing air temperature. This tendency was prevalent in the chloride and nitrate.

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국내 유통 중인 먹는샘물 원수의 이온류 수질 특성에 관한 연구 (The Study on the Ion Water Characteristics of Raw Water in the Domestic Natural Mineral Water)

  • 이이내;안경희;민병대;양미희;최인철;정현미;박주현
    • 한국물환경학회지
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    • 제32권5호
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    • pp.442-449
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    • 2016
  • The goal of this study is to provide basic data to establish a foundation for the provision of safe drinkable water. The raw water of natural mineral water was analyzed to determine the quantities of anions (F-, Cl-, NO3-N-, and SO42- ) and cations (Ca2+, K+, Mg2+, and Na+) during the former and latter half of 2016. Analysis of the current quality of the raw water of natural mineral water among domestic manufacturers showed average anions contents of 0.46mg/L of fluorine, 8mg/L of chlorine ion, 1.5mg/L of nitrate nitrogen, and 12mg/L of sulfate ion. While the fluorine content was greater than the water quality criterion of 2.0mg/L at four points, the fluorine level was overall stable. The average cations contents included 21.3mg/L of calcium, 1.0mg/L of potassium, 3.4mg/L of magnesium, and 9.6mg/L of sodium. The chemical characteristics were compared among the major ions, and the results are presented in a piper diagram. The content ratio of cations was in the order of Ca2+> Na+>Mg2+>K+, whereas that of anions was in the order of SO42->Cl->NO3-N->F-. While the cations were slightly scattered, the anions were generally concentrated except for at a few points. The Ca-Na-HCO3 type was dominant overall in water sources from diorite, gneiss, and granite, while the Na-Mg-Ca-HCO3-Cl type was dominant in basalt sources. Mineral water manufacturers source their water under various conditions, including in-hole casing, excavation depth, and contact state of bedrock; even within the same rocky area, some differences in the water quality type can occur. When the depth of the water source was taken into account, the mean anions contents of F-, Cl-, NO3-N-, and SO42- were similar, with no significant differences according to depth. Of the cations, K+ and Na+ showed no significant differences across all the tubular wells, whereas Ca2+ and Mg2+ decreased in content with depth.

담배식물의 이온균형(均衡)에 미치는 형태별(形態別) 질소(窒素)의 영향 (Influence of N Forms to the Ionic Balance of Tobacco Plants)

  • 이윤환
    • 한국토양비료학회지
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    • 제19권2호
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    • pp.139-145
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    • 1986
  • 담배식물이 흡수한 질산태질소가 조직중(組織中)에서 환원 되므로서 양(陽)이온과 음(陰)이온성분간(成分間)의 평형(平衡)에 미치는 영향을 구명하기 위하여 질소원(窒素源)을 달리한 배양액(培養液)으로 재배(栽培)하면서 무기(無機) 양음(陽陰)이온총량차이(總量差異)를 조사하고 질소환원(窒素還元) 및 유기산함량(有機酸含量)의 변화(變化)와 이온총량차이(總量差異)와의 관계(關係)를 검토(檢討)한 결과(結果) 1. $NO_3-N$ 배양액에서 자란 식물은 $NH_4-N$ 배양액의 것보다 양(陽)이온총량(總量)이 높았다. 무기음(無機陰)이온총량(總量)은 $NO_3+NH_4$혼합배양액(混合培養液)에서 가장 높게 나타났으나 $NO_3-N$ 배양액에서 가장 낮아서 무기 양음(陽陰)이온총량차이(總量差異)가 가장 컸고 $NH_4{^+}$가 함유된 배양액에서는 무기양음이온 총량차이가 비슷하여 무기이온으로서 거의 이온균형(均衡)이 유지(維持)되었다. 2. 식물체중(植物體中) 유기산(有機酸)은 malic acid의 분포가 가장 컸으며 $NO_3-N$ 배양액식물은 유기산(有機酸)이 다량함유(多量含有)되어 있으나 $NH_4-N$ 또는 혼합배양액(混合培養液)의 것은 거의 검출(檢出)되지 않았다. $NO_3-N$ 배양액식물(培養液植物)은 유기산총량(有機酸總量)이 무기음(無機陰)이온 총량(總量)보다 초과(超過)되어 유기산(有機酸)에 의한 이온균형(均衡)비율이 크나 $NH_4-N$ 배양액식물은 이온균형(均衡)에 차지하는 유기산(有機酸)비율이 극히 소량이었다. 3. $NO_3-N$식물(植物)은 질산환원(窒酸還元)이 왕성하게 진행되므로서 유리(遊離)된 양(陽)이온과의 이온균형(均衡)을 위하여 유기산(有機酸)이 다량(多量) 함유(含有)되었다.

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Homès 방법(方法)에 의(依)한 다량요소(多量要素)의 적정시용(適正施用) 비율(比率) 결정(決定)에 관(關)한 연구(硏究) I. 초지(草地) 토양별(土壤別) 음(陰)이온 N : S : P 적정시용(適正施用) 비율(比率) (The Optimal Combination of Major Nutrients Computed by The Homès Systematic Variation Technique I. Determination of the Optimal Combination of Anions N: S: P in Fertilization on the Various Grassland Soils)

  • 정연규;윤상기
    • 한국토양비료학회지
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    • 제14권1호
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    • pp.31-36
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    • 1981
  • 초지개발(草地開發)이 유망시(有望視)되는 전국각지(全國各地)의 미개간(未開墾) 산지(山地)의 표토토양(表土土壤)을 채취(採取)하여 $Hom{\grave{e}}s$의 Systematic Variation방법(方法)에 의(依)한 다량요소(多量要素) Anions N: S: P 적정시용비율(適正施用比率) 결정(決定)을 위(爲)한 pot시험(試驗)을 에서 수행(遂行)한 결과(結果)는 1. 안양등(安養等) 6개(個) 지역(地域)의 토양(土壤)에 대(對)한 혼파목초재배시(混播牧草栽培時) 각(各) 토양(土壤) 및 초종별(草種別) 다수확(多收穫)을 위(爲)한 당량비 기준(基準) N: S: P적정시용비율(適正施用比率)이 계산(計算)되었다(표(表)5). 2. 혼파목초(混播牧草)에서 화목과목초(禾木科牧草)의 수량증수(收量增收)는 각토양(各土壤)이 C.E.C, OM, T-N, Avl $P_2O_5$ 특성(特性)들과 정상관관계(正相關關系)가 있고 무기(無機)Cation 함량(含量), 염기포화도 및 pH와의 관계(關係)는 뚜렷하지 않았다. 3. 각토양중(各土壤中) Ca, Mg함량(含量)과 정상관(正相關)을 보인 두과목초(荳科牧草)의 수량증가(收量增加)는 혼파목초(混播牧草) 총수량증가(總收量增加)의 요인(要因)이 되었다. 4. 두과목초(荳科牧草)의 수량증수(收量增收)를 위(爲)하여 제주(濟州)의 화산회토(火山灰土)에서 S, 대구(大邱)의 수성암(水成岩) 암쇄토(岩碎土)에서 P시비비율(施肥比率)이 높게 나온것은 초지조성(草地造成) 및 비배관리(肥培管理)에 유의(留意)되어져야 할 것이다.

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성·복토용으로 사용된 전로제강슬래그가 주변 토양환경에 미치는 영향 (Effect of Basic Oxygen Furnace Slag used as Structural Filling Materials on the Subsurface Environment)

  • 이호섭;남택우;조은혜;남경필
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제21권3호
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    • pp.6-13
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    • 2016
  • The effect of blast oxygen furnace (BOF) slag used as filling materials on the soil environment was studied using column tests that simulated the flow of the BOF slag leachate through the soil layer. The Cu, Mn, Zn, Ni, and F contents of the leachate affected soil were similar to that of the controls (i.e., soils that were not affected by the leachate). The As, Cd, and Pb contents were lower in the leachate affected soils than the controls. The changes in these contaminants contents can be attributed to the interactions between anions such as alkalinity generating anions (e.g., CO32−, HCO3, OH) or calcium ions with heavy metals or F, which consequently affected the fate of heavy metals and F in the leachate affected soils. The germination and growth of Spinapis alba in the soils affected by the leachate and the controls were also similar. However, the proportion of alkalophilic bacteria in the soils affected by the leachate significantly increased, and this can be explained by the increased soil pH due to the alkaline leachate. Overall, this study shows that the alkalinity of the BOF slag leachate, rather than the presence of heavy metals and F in the leachate, needs to be considered when the BOF slag is to be reused as structural filling materials.

국내 시판 먹는샘물의 물성에 따른 이온성분의 변화 및 침전물 생성 (Study on precipitate formation and the change of cations and anions in domestic bottled water)

  • 이은경;장성일;정연욱;전성숙;주명희;이순애;박종숙
    • 상하수도학회지
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    • 제22권5호
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    • pp.561-569
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    • 2008
  • We analyzed contents of cations and anions for the domestic bottled drinking water. Results showed that total cation content was 45.81 mg/L and contained 40% of Ca. The content of cations were decreased in the order of Ca>Si>Na>Mg>K. Total anion content was 12.20 mg/L and contained 90% of ${SO_4}^{2-}$ and $Cl^-$. $F^-$ and $NO_{3-}N$ were a little contained. While Si content was reduced 2.3~75.7%(mean value:38.5%) after freezing, Ca content was reduced 45.2% after boiling. It showed that water containing higher Ca content was significantly decreased after boiling. Precipitates formed by freezing and boiling is composed of minerals such as Si and Ca. Compared to minerals from food intake, concentrations of minerals from water intake are expected to be less influenced. It is recommended Bottled Water that contains more than 20 mg/L of Ca(exceeding water-quality standard for turbidity) is safe to drink without thawing and boiling.

휴/폐광 금은광산 주변의 토양오염조사와 복구시스템 연구 (Investigation on soil contamination and its remediation system in the vicinity of abandoned Au-Ag mine in Korea)

  • 정명채
    • 자원환경지질
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    • 제32권1호
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    • pp.73-82
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    • 1999
  • The objectives of this study are to investigate soil contamination in the vicinity of abandoned Au-Ag mine and to apply a remediation technique of liming to tailings. In the study area of the Imcheon Au-Ag mine, soils were sampled in and around the mine the analyzed by Atomic Absorption Spectrometry extracted by both 0.1N HCl and aqua regia. Elevated levels of Cd, Cu, Pb and Zn concentrations extracted by 0.1N HCl were found in soils taken from tailings site. These high contents directly influenced metal concentrations in soils taken in the vicinity of the site. This is mainly due to clastic movement by wind and effluent of mine waste water. In addition, relatively enriched concentrations of the metals were found in soils extrated by aqua regia due to strong decomposition of the samples compared with 0.1N HCl extration. According to the statistical approach, metal concentrations in soils by 0.1N HCl had a positive correlation with those by aqua regia extraction. Mine waste waters and stream waters were also sampled around the mine in spring and summer and analyzed by AAS for Cd, Cu, Pb and Zn, and by Ion Chromatography for anions. Like soils developed over tailings, significant levels of metals and sulphates were found in the mine waste waters ranging of 0.2~0.3, 0.5~2.0, 0.2~2.8, 30~50 and 1,240~4,700 mg/l of Cd, Cu, Pb, Zn and $SO_4^{2-}$, respectively. These elevated levels influenced in the stream waters in the vicinity of the tailings site. In seasonal variation of metal and anion contents, relatively high levels were found in waters sampled on summer due to leaching the metals and anions from tailings by rain. This study also examined the possibility of lime treatment for remediation of acid mine tailings and assumed to be 46 tones of pulverized lime for neutralization of the tailings.

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금산지역 토양별 화학적 특성과 주요 용존성분

  • 송석환;이용규
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2002년도 추계학술발표회
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    • pp.195-199
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    • 2002
  • This study is for know chemistry of the representative soils from Keumsan, its relationships with dissolved compositions, and its absorption relationships within the flora. It has been done for two comparisons: 1) phyllite, shale and granite(PSG), and 2) granite and coal bearing shale(GC). Among the soil leachate of the PSG, cations are mainly low in the phyllite area while anions are mainly low in the granite area. In the soil compositions, Ca and Mg of the beans are high and Na is high in the granite area while Ca and Na of the perilla are high in the granite area and Mg is high in the phyllite area. In th both species, Na for the granite area and Mg for the phyllite area are high while Ca for the shale area is low. Among the flora, shale area shows low Ca and Mg contents while granite area shows slightly high Na contents, regardless the species. Compared with beans, perilla is low in the Mg and high in the Na contents. These relationships show that the contents of the soil leachate do not reflect absorption within the flora. Among the soil leachate of the GC, shale area is high in the most of the elements. Especially, SO$_4$ is over 15 times high In the phyllite area. In the soil, granite area shows high Ca, Na and low Mg contents. In the flora, the Miscanthus sinensis shows high Ca and Mg contents in the granite area while the Artemisia vulgaris shows high Ca, Ca and Mg contents in the shale area. These relationships for contents of the flora and soil leachate suggest that the flora has a different absorption according different species.

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