• Title/Summary/Keyword: anions contents

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Effects of Various Anions on Absorption and Toxicity of Lead in Plants (식물체의 연(Pb) 흡수 및 유해성에 미치는 음이온의 영향)

  • 성민웅
    • Journal of Plant Biology
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    • v.20 no.1
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    • pp.7-14
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    • 1977
  • The seeds of bean(Glycine max M.) and corn(Zea mays L.) soaked in 5000ppm lead solution for 24 hours were sowed in the flowerpots being placed sandy-clay soil under the field condition. The fixed concentrations of various anions and 2000 ppm lead were supplied alternately in the sandy-clay soi of the flowerpots at two days interval from May to July in 1976. After the plants were harvested prior to the flowering stage, the lead contents of plnat and soil were analyzed by atomic absorption spectrophotometer. The lead contents absorbed by the plant roots showed the highest in an weak acid soil of the best suitable condition of plant growth. The absorption of lead by the plant roots was inhibited by the various anions, especially divalent anions of the soil. Some phosphate anions inhibited lead absorption more than otehr various anions in the soil. The more various anions were in the soil, the more plants could be protected from the lead toxicity. In the case of lead supply in the soil, 99.5% of lead was accumulated in the upper layer of the soil(0-10cm), and 0.5% of lead accumulated in the lower layer (10-20cm). Therefore, the yellow-brown and white symptoms on the leaves and the inhibition of root growth by lead toxicity was increased in the early stage of the germination, however decreased in accordance with the progress of the growing stage becuase of the root growth toward beneath the lower layer of the soil. In spite of the contents of 3773ppm lead in the soil, the symptoms of lead toxicity was not found in the grown plants. At that time the lead contents of the plants absorbed from the soil were minimum 0.78ppm and maximum 3.64ppm through the growing stage.

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The Effects of Catalyst on the Hydrolysis and Polymerization of TEOS (Tetra Ethyl Ortho Silicate의 수화 및 중합에 미치는 촉매의 영향)

  • ;;S. Sakka
    • Journal of the Korean Ceramic Society
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    • v.27 no.1
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    • pp.86-90
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    • 1990
  • The shape and characteristics of polymers in hydrolzed and polymerized sol were affected by the types of catalysts. In our research, the contents of water and catalysts were constant and the types of catalyst were varied. In the case of acid catalysts, polymers in sol were linear and spinnable. The shapes of polymer were affected by the types of anions in acid catalysts. In the case of catalyst having anions, F, Cl, in the same period, the effects were similar. But in the case of base catalysts polymers were rigid rod like and not spinnable.

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Concentration and Size Distribution of Atmospheric Particulate Matters, Chloride, Nitrate, and Sulfate Salts in Urban Air (都市大氣중 浮遊粒子狀物質, 鹽化物, 窒酸鹽 및 黃酸鹽의 濃度와 粒經分布)

  • Sohn, Dong-Hun;Heo, Moon-Young
    • Journal of Korean Society for Atmospheric Environment
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    • v.2 no.3
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    • pp.27-33
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    • 1986
  • Atmospheric particulate matter (A. P. M.) was collected and size-fractionated by an Andersen high-volume air sampler over 15 month period from Jan. 1985 to Feb. 1986 in Seoul. The concentration of chloride, nitrate and sulfate were extracted in an ultrasonic bath and were analyzed by ion chromatography. The annual arithmetical mean of A. P. M. was 128.54 $\mug/m^3$. The concentration of anions were 2.88 $\mug/m^3$ for chloride, 3.86$\mug/m^3$ for nitrate, and 25.44$\mug/m^3$ for sulfate. The content of A. P. M. was lowest in the particle size range 1.1 $\sim 3.3\mum$ and increased as the particle size increased or decreased. And the anions exhibited a seasonal variation in the isize distribution. The contents of anions were higher in winter than summer. Ther ratio of fine particles to the total particles defined by F/T for chloride, nitrate and sulfate. The F\ulcornerT of these anion generally decrease with increasing air temperature. This tendency was prevalent in the chloride and nitrate.

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The Study on the Ion Water Characteristics of Raw Water in the Domestic Natural Mineral Water (국내 유통 중인 먹는샘물 원수의 이온류 수질 특성에 관한 연구)

  • Lee, Leenae;Ahn, Kyunghee;Min, Byungdae;Yang, Mihee;Choi, Incheol;Chung, Hyenmi;Park, Juhyun
    • Journal of Korean Society on Water Environment
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    • v.32 no.5
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    • pp.442-449
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    • 2016
  • The goal of this study is to provide basic data to establish a foundation for the provision of safe drinkable water. The raw water of natural mineral water was analyzed to determine the quantities of anions (F-, Cl-, NO3-N-, and SO42- ) and cations (Ca2+, K+, Mg2+, and Na+) during the former and latter half of 2016. Analysis of the current quality of the raw water of natural mineral water among domestic manufacturers showed average anions contents of 0.46mg/L of fluorine, 8mg/L of chlorine ion, 1.5mg/L of nitrate nitrogen, and 12mg/L of sulfate ion. While the fluorine content was greater than the water quality criterion of 2.0mg/L at four points, the fluorine level was overall stable. The average cations contents included 21.3mg/L of calcium, 1.0mg/L of potassium, 3.4mg/L of magnesium, and 9.6mg/L of sodium. The chemical characteristics were compared among the major ions, and the results are presented in a piper diagram. The content ratio of cations was in the order of Ca2+> Na+>Mg2+>K+, whereas that of anions was in the order of SO42->Cl->NO3-N->F-. While the cations were slightly scattered, the anions were generally concentrated except for at a few points. The Ca-Na-HCO3 type was dominant overall in water sources from diorite, gneiss, and granite, while the Na-Mg-Ca-HCO3-Cl type was dominant in basalt sources. Mineral water manufacturers source their water under various conditions, including in-hole casing, excavation depth, and contact state of bedrock; even within the same rocky area, some differences in the water quality type can occur. When the depth of the water source was taken into account, the mean anions contents of F-, Cl-, NO3-N-, and SO42- were similar, with no significant differences according to depth. Of the cations, K+ and Na+ showed no significant differences across all the tubular wells, whereas Ca2+ and Mg2+ decreased in content with depth.

Influence of N Forms to the Ionic Balance of Tobacco Plants (담배식물의 이온균형(均衡)에 미치는 형태별(形態別) 질소(窒素)의 영향)

  • Lee, Yun-Hwan
    • Korean Journal of Soil Science and Fertilizer
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    • v.19 no.2
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    • pp.139-145
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    • 1986
  • In order to study the influence of nitrate reduction to ionic balance in tissue of tobacco plant, differneces in amounts of those cations and anions were determined and these balances were compared with contents of organic acids and activities of nitrate reductase, while they were fertilized with different nitrogen sources ($NO_3-N$, $NH_4-N$, $NO_3+NH_4-N$) in water culture. The results of studies are summerized as follows; 1. Total uptake of inorganic cations was the highest in nitrate-fed plants, whereas that of inorganic anions showed the highest level in the plants grown with the mixture ($NO_3+NH_4$). The amounts of inorganic cations and anions were comparable in two treatments containing $NH_4-N$, but in plants treated with nitrate only had much higher level of inorganic cations than others. 2. Deficiency in the amount of inorganic anions in nitrate-fed plants was balanced with organic acids, dominantly with malic acid among them. But another two $NH_4-N$ fed plant sustained equilibrium between inorganic cations and anions. 3. Reduction of nitrate was raised in tissues of nitrate-fed plants. By the results of nitrate reduction, cations maintained equilibrium with nitrate ion were let loose. The replacement of inorganic anions with organic anions could be a compensation process for the loss of uptaken nitrate ions which must be reduced to be incorporated into organic N compounds.

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The Optimal Combination of Major Nutrients Computed by The Homès Systematic Variation Technique I. Determination of the Optimal Combination of Anions N: S: P in Fertilization on the Various Grassland Soils (Homès 방법(方法)에 의(依)한 다량요소(多量要素)의 적정시용(適正施用) 비율(比率) 결정(決定)에 관(關)한 연구(硏究) I. 초지(草地) 토양별(土壤別) 음(陰)이온 N : S : P 적정시용(適正施用) 비율(比率))

  • Jung, Yeun-Kyu;Yoon, Sang-Gi;Weinberger, P.
    • Korean Journal of Soil Science and Fertilizer
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    • v.14 no.1
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    • pp.31-36
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    • 1981
  • This pot experiment was conducted to find out the optimal fertilization ratio of the anions (N : S : P) in various soil conditions. Soil samples were collected from uncultivated mountains and hills where development for grasslands is under consideration. The optimum ratios were computed by the $Hom{\grave{e}}s$ systematic variation technique. The results were summarized as follows : 1. The optimum fertilization ratios of the anions (N : S : P) for the high yields of grass - clover mixed sward at various areas were obtained (Table 5). 2. The grass yields in mixed sward were increased by the increase of specific soil characteristics, CEC, OM, T-N, avail-$P_2O_5$. However. it was not recognizable by the contents of the cations, the base saturation, and the pH. 3. The relatively high yields of clover were positively related to the Ca and Mg contents in soils, and it was a factor of the increased total yields of mixed sward. 4. The relatively high optimum fertilization ratios of S in volcanic ash soil in the Cheju district and P in sediment lithosol in Daegu should be taken into account in determing the fertilization rate for high yield of clover in mixed sward.

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Effect of Basic Oxygen Furnace Slag used as Structural Filling Materials on the Subsurface Environment (성·복토용으로 사용된 전로제강슬래그가 주변 토양환경에 미치는 영향)

  • Lee, Hosub;Nam, Taekwoo;Jho, Eun Hea;Nam, Kyoungphile
    • Journal of Soil and Groundwater Environment
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    • v.21 no.3
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    • pp.6-13
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    • 2016
  • The effect of blast oxygen furnace (BOF) slag used as filling materials on the soil environment was studied using column tests that simulated the flow of the BOF slag leachate through the soil layer. The Cu, Mn, Zn, Ni, and F contents of the leachate affected soil were similar to that of the controls (i.e., soils that were not affected by the leachate). The As, Cd, and Pb contents were lower in the leachate affected soils than the controls. The changes in these contaminants contents can be attributed to the interactions between anions such as alkalinity generating anions (e.g., CO32−, HCO3, OH) or calcium ions with heavy metals or F, which consequently affected the fate of heavy metals and F in the leachate affected soils. The germination and growth of Spinapis alba in the soils affected by the leachate and the controls were also similar. However, the proportion of alkalophilic bacteria in the soils affected by the leachate significantly increased, and this can be explained by the increased soil pH due to the alkaline leachate. Overall, this study shows that the alkalinity of the BOF slag leachate, rather than the presence of heavy metals and F in the leachate, needs to be considered when the BOF slag is to be reused as structural filling materials.

Study on precipitate formation and the change of cations and anions in domestic bottled water (국내 시판 먹는샘물의 물성에 따른 이온성분의 변화 및 침전물 생성)

  • Lee, Eun-Kyeong;Jang, Seong-Il;Jung, Yeon-Wook;Jeon, Seong-Sook;Ju, Myeong-Hui;Lee, Soon-Ae;Park, Jong-Sook
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.5
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    • pp.561-569
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    • 2008
  • We analyzed contents of cations and anions for the domestic bottled drinking water. Results showed that total cation content was 45.81 mg/L and contained 40% of Ca. The content of cations were decreased in the order of Ca>Si>Na>Mg>K. Total anion content was 12.20 mg/L and contained 90% of ${SO_4}^{2-}$ and $Cl^-$. $F^-$ and $NO_{3-}N$ were a little contained. While Si content was reduced 2.3~75.7%(mean value:38.5%) after freezing, Ca content was reduced 45.2% after boiling. It showed that water containing higher Ca content was significantly decreased after boiling. Precipitates formed by freezing and boiling is composed of minerals such as Si and Ca. Compared to minerals from food intake, concentrations of minerals from water intake are expected to be less influenced. It is recommended Bottled Water that contains more than 20 mg/L of Ca(exceeding water-quality standard for turbidity) is safe to drink without thawing and boiling.

Investigation on soil contamination and its remediation system in the vicinity of abandoned Au-Ag mine in Korea (휴/폐광 금은광산 주변의 토양오염조사와 복구시스템 연구)

  • 정명채
    • Economic and Environmental Geology
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    • v.32 no.1
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    • pp.73-82
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    • 1999
  • The objectives of this study are to investigate soil contamination in the vicinity of abandoned Au-Ag mine and to apply a remediation technique of liming to tailings. In the study area of the Imcheon Au-Ag mine, soils were sampled in and around the mine the analyzed by Atomic Absorption Spectrometry extracted by both 0.1N HCl and aqua regia. Elevated levels of Cd, Cu, Pb and Zn concentrations extracted by 0.1N HCl were found in soils taken from tailings site. These high contents directly influenced metal concentrations in soils taken in the vicinity of the site. This is mainly due to clastic movement by wind and effluent of mine waste water. In addition, relatively enriched concentrations of the metals were found in soils extrated by aqua regia due to strong decomposition of the samples compared with 0.1N HCl extration. According to the statistical approach, metal concentrations in soils by 0.1N HCl had a positive correlation with those by aqua regia extraction. Mine waste waters and stream waters were also sampled around the mine in spring and summer and analyzed by AAS for Cd, Cu, Pb and Zn, and by Ion Chromatography for anions. Like soils developed over tailings, significant levels of metals and sulphates were found in the mine waste waters ranging of 0.2~0.3, 0.5~2.0, 0.2~2.8, 30~50 and 1,240~4,700 mg/l of Cd, Cu, Pb, Zn and $SO_4^{2-}$, respectively. These elevated levels influenced in the stream waters in the vicinity of the tailings site. In seasonal variation of metal and anion contents, relatively high levels were found in waters sampled on summer due to leaching the metals and anions from tailings by rain. This study also examined the possibility of lime treatment for remediation of acid mine tailings and assumed to be 46 tones of pulverized lime for neutralization of the tailings.

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금산지역 토양별 화학적 특성과 주요 용존성분

  • 송석환;이용규
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.09a
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    • pp.195-199
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    • 2002
  • This study is for know chemistry of the representative soils from Keumsan, its relationships with dissolved compositions, and its absorption relationships within the flora. It has been done for two comparisons: 1) phyllite, shale and granite(PSG), and 2) granite and coal bearing shale(GC). Among the soil leachate of the PSG, cations are mainly low in the phyllite area while anions are mainly low in the granite area. In the soil compositions, Ca and Mg of the beans are high and Na is high in the granite area while Ca and Na of the perilla are high in the granite area and Mg is high in the phyllite area. In th both species, Na for the granite area and Mg for the phyllite area are high while Ca for the shale area is low. Among the flora, shale area shows low Ca and Mg contents while granite area shows slightly high Na contents, regardless the species. Compared with beans, perilla is low in the Mg and high in the Na contents. These relationships show that the contents of the soil leachate do not reflect absorption within the flora. Among the soil leachate of the GC, shale area is high in the most of the elements. Especially, SO$_4$ is over 15 times high In the phyllite area. In the soil, granite area shows high Ca, Na and low Mg contents. In the flora, the Miscanthus sinensis shows high Ca and Mg contents in the granite area while the Artemisia vulgaris shows high Ca, Ca and Mg contents in the shale area. These relationships for contents of the flora and soil leachate suggest that the flora has a different absorption according different species.

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