• 대한원격탐사학회지
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• 제28권4호
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• pp.421-434
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• 2012

동해에서 CDOM의 광학적 특성과 순환을 이해하기 위하여 MODIS의 원격탐사반사도($R_{rs}$)를 이용한 기존의 CDOM 흡광계수 추정 알고리즘들(Semi-Algorithms (3개), Empirical-Algorithms (3개))을 현장관측 자료와 비교 평가하였다. 2009년부터 2011년까지 총 7번의 현장 관측 자료는 연안 해역에서부터 외양의 다양한 해양환경을 포함하고 있다. 본 연구 결과, 동해에서 Quasi-Analytical Algorithm (QAA_v5) 이 현장 $a_{CDOM}$(412) 값을 가장 유사하게 추정하였다. Quasi-Analytical Algorithm (QAA_v5) 알고리즘을 기준으로 Semi-analytical 알고리즘은 과소추정하는 경향을 보였다. 그러나 Empirical 알고리즘은 과대추정하는 경향을 보였다. $a_{CDOM}$(412)의 값이 높은 곳에서 위성관측 엽록소-a (Chlorophyll-a)의 값도 높았다. 이 결과는 CDOM이 엽록소-a의 함량 추정에 영향을 줄 수 있다는 가능성을 제시한다. 본 연구 결과는 세계최초 정지궤도 해색위성인 GOCI의 CDOM 알고리즘을 개선하는데 기초자료로 활용될 것이다.

• 한국환경농학회지
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• 제34권2호
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• pp.111-119
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• 2015

BACKGROUND: Ethychlozate (ECZ) is a plant growth regulator of synthetic auxin for agricultural commodities (ACs). Accurate and sensitive method to determine ECZ in diverse ACs on global official purpose is required to legal residue regulation. As the current official method is confined to the limited type of crops with poor validation, this study was conducted to improve and extend the ECZ method using high-performance liquid chromatography (HPLC) in all the registered crops with method verification. METHODS AND RESULTS: ECZ and its acidic metabolite (ECZA) were both extracted from acidified samples with acetone and briefly purified by dichloromethane partition. ECZ was hydrolyzed to form ECZA and the combined ECZA was finally purified by ion-associated partition including hexane-washing. The instrumental quantitation was performed using HPLC/ FLD under ion-suppression of ECZA with no interference by sample co-extractives. The average recoveries of intra- and inter-day experiment ranged from 82.0 to 105.2% and 81.7 to 102.8%, respectively. The repeatability and reproducibility for intra- and inter-day measurements expressed as a relative standard deviation was less than 8.7% and 7.4%, respectively. CONCLUSION: Established analytical method for ECZ residue in ACs was applicable to the nation-wide pesticide residues monitoring program with the acceptable level of sensitivity, repeatability and reproducibility.

• 한국동물위생학회지
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• 제40권4호
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• pp.253-258
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• 2017

The aim of this study is to develop an optimal analytical method for gonadorelin, progesterone, oxytocin and estradiol, the major components of hormones. A relatively simple and reproducible method using high performance liquid chromatography was developed and as a result of the measurement of specificity, linearity, repeatability, accuracy and intermediated precision, the validity of the developed method was verified with the result of meeting the verification criteria of analytical method validation. Using this newly developed method, 12 post-market veterinary products were tested and the ingredient content were 91.9~116.4%, which satisfied the 90~120% condition of the administrative measure standard. Therefore, if the newly developed method is used for the collection examination of hormone in veterinary medicine, it can be useful as an approved test method.

• 분석과학
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• 제8권4호
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• pp.759-770
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• 1995

By extensive studies with the quantitative status of the mineral constituents of thousands of water samples, it was found that almost in all natural waters irrespective of the surface or sub-surface sources, minimum 99.5% of the total amount of the cationic constituents are generally the contributions of 3 commonly present parameters viz. Ca, Mg and Na and that of the anionic species are same and contributed by $HCO_3$, Cl and $SO_4$ only. In the field of water works, all these major mineral substances are conventionally measured as their individual ions. But till now, no reliable and generalised methods or rules have been developed for the determination of the exact kinds of the individual salt components and their amounts from these ionic constituents normally present in water. As salt content, only the TDS (Total Dissolved Solids) parameter is frequently measured by evaporation of the water sample. But TDS can tell nothing about the kinds and amounts of the individual salts present in it. Considering the analytical importance of the estimation of the mineral substances as their individual salts, some generalised mathematical models have been developed by this research which are based on the 'hypothetical order of chemical combinations' as may occur among the ionic constituents. With the help of these models, one can easily assume the most probable salts with approximate quantities derived from the ionic constituents. In addition, approximate amount of Na content can also be estimated mathematically with simultaneous verification of the correctness of the water analysis results. The models are stated in this paper with practical illustrations and descriptions of the method of applications.

• 한국구조물진단유지관리공학회 논문집
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• 제18권2호
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• pp.74-81
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• 2014

본 연구에서는 휨모멘트를 받는 SC 벽체 스터드의 성능을 최적화시키기 위해 비선형 유한요소법을 사용한 해석적 연구를 수행하였다. SC 벽체에 대한 유한요소모형에서는 접촉, 연결, 그리고 재료에 대한 비선형성을 고려하였다. 그리고 해석모형의 검증을 위해 선행된 실내 실험을 모사하여 계측결과와 해석결과를 비교하였고, 제안된 해석방법의 타당성을 검증하였다. 문헌조사를 통해 해석 대상물의 크기를 결정하였고, 다양한 스터드의 형식과 배치간격을 고려한 해석을 수행하였다. 또한, KEPIC SNG를 만족하는지에 대한 추가적인 검토를 수행하였다. 최종적으로 수치해석과 기준의 검토를 통하여 개선된 스터드의 최적 형식 및 배치안을 제시하였다.

• 한국수산과학회지
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• 제55권2호
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• pp.218-223
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• 2022

Cholesterol is an essential component for maintaining health; however, excessive consumption can lead to diseases. Thus, continuous monitoring of cholesterol content is important in food research. The cholesterol analysis method used in Korea follows the Korean Food Standards Codex. As this method uses gas chromatography, derivatization of the sample is required, and analysis time is more than 30 min. Kim developed a new method using liquid chromatography; however saponification by the non-heat saponification method is insufficient. To address these limitations, a new cholesterol analysis method was developed and verified. The correlation coefficients for the cholesterol standard (STD) were maintained above 0.99. The limit of detection and limit of quantitation of cholesterol STD were 2.41 ㎍/mL and 7.31 ㎍/mL, respectively. The accuracies for cholesterol were 92.21-99.02%. The developed analytical method was also verified using three standard reference materials, and their accuracies were 93.71-97.09%. In addition, the cholesterol content of fishes was analyzed, and the values were compared with those recorded by the United States Department of Agriculture. Our results suggest that this method could be used as a new analytical method for cholesterol in seafood.

• 한국근적외분광분석학회:학술대회논문집
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• 한국근적외분광분석학회 2001년도 NIR-2001
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• pp.1516-1516
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• 2001

During the recent years, wine analysis has played an increasing role due the health benefits of phenolic ingredients in red wine [1]. On the other hand there is the need to be able to distinguish between different wine varieties. Consumers want to know if a wine is an adulterated one or if it is based on the pure grape. Producers need to certificate their wines in order to ensure compliance with legal regulations. Up to now, the attempts to investigate the origin of wines were based on high-performance liquid chromatography (HPLC), gas chromatography (GC) and pyrolysis mass spectrometry (PMS) [l,2,3]. These methods need sample pretreatment, long analysis times and therefore lack of high sample throughput. In contradiction to these techniques using near infrared spectroscopy (NIRS), no sample pretreatment is necessary and the analysis time for one sample is only about 10 seconds. Hence, a near infrared spectroscopic method is presented that allows a fast classification of wine varieties in bottled red wines. For this, the spectra of 50 bottles of Cabernet Sauvignon, Lagrein and Sangiovese (Chianti) were recorded without any sample pretreatment over a wavelength range from 1000 to 2500 nm with a resolution of 12 cm$\^$-1/. 10 scans were used for an average spectrum. In order to yield best reproducibility, wines were thermostated at 23$^{\circ}C$ and a optical layer thickness of 3 mm was used. All recorded spectra were partitioned into a calibration and validation set (70% and 30%). Finally, a 3d scatter plot of the different investigated varieties allowed to distinguish between Cabernet Sauvignon, Lagrein and Sangiovese (Chianti). Considering the short analysis times this NRS-method will be an interesting tool for the quality control of wine verification and also for experienced sommeliers.

• 한국응용곤충학회지
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• 제61권4호
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• pp.659-664
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• 2022

Putrescine은 일반적으로 미생물의 활동에 의해 발생되며, 신선함의 척도로서 사용된다. 그러나 동결건조된 로열젤리에 대한 putrescine의 분석법은 아직 확립되지 않은 실정이다. 본 연구에서는 C18 컬럼을 이용하여 동결건조 로열젤리 내 putrescine을 분석하기 위한 UPLC 분석법을 확립하고자 하였다. 새롭게 확립된 분석법은 7분 이내에 putrescine을 분석 가능하였으며, 이러한 분석법을 검증하기 위해 특이성, 직선성, 정밀성, 정확성, 정량한계, 정성한계 등을 평가하였다. 본 연구를 통해 동결건조 로열젤리의 신선한 정도를 평가하기 위한 분석법을 제공하였으며, 추후 안전성의 척도에 대한 자료로서 활용 가능할 것으로 기대되어진다.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2011년도 정기총회 및 추계학술대회 논문집
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• pp.649-655
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• 2011

In this paper, the content to carry out the modal testing and to analyze the data as the target of the main transformer installed on KTX is mentioned. The main transformer for KTX is a structure which is over 10 Ton. For the possibility to occur a stress concentration phenomenon exists, the dynamic durability of the system is experimentally needed to understand. To do this, we obtained the vibration data using an accelerometer, an impact hammer, a measuring instrument and gained the frequency response function of the main transformer based on the acquisition data. In this content, when the theoretical model for structural analysis should be established, we think it will be used for the property verification of analytical model. Also, we expect that the measured and analysed data will offer basic research material to maintain the system and diagnose the condition by monitoring the natural frequency of the main transformer for KTX periodically.

• 한국지진공학회논문집
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• 제18권1호
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• pp.1-8
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• 2014

The purpose of this study was to investigate the performance of hollow reinforced concrete bridge column systems with reinforcement details for material quantity reduction. The proposed reinforcement details have economic feasibility and rationality and make construction periods shorter. A model of hollow reinforced concrete bridge columns was tested under a constant axial load and a quasi-static cyclically reversed horizontal load. As a result, proposed reinforcement details for material quantity reduction were equal to existing reinforcement details in terms of required performance. The companion paper presents the experimental and analytical study for the performance assessment of hollow reinforced concrete bridge column systems with reinforcement details for material quantity reduction.