• Title/Summary/Keyword: amorphous and crystalline

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Formation of Nb2O5 Microcone Structure in NaF Electrolyte by Anodization (NaF 전해질 양극산화에 의한 마이크로콘 구조 니오븀 산화물 제조)

  • Jeong, Bong-Yong;Jung, Eun-Hye
    • Journal of the Korean Ceramic Society
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    • v.48 no.6
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    • pp.625-629
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    • 2011
  • In this study, we show that by anodization of Nb in NaF electrolytes microcone niobium oxide layers can be formed under a range of experimental conditions. It is found that a single NaF electrolyte leads to the formation of microcones. At 1 M NaF, 40 V, 1 h, well-ordered microcones were generated on Nb discs. XRD results show that the initially formed anodic oxide is amorphous, but an amorphous to crystalline transition occurs during anodization. For the formation of favorable microcones, it is considered that proper parameters such as electrolyte concentration, voltage, anodizing time are necessary according to the kind of electrolytes.

Current Status of Solar Cell Research and Development (태양전지(太陽電池)의 최근(最近) 연구(硏究) 개발(開發) 동향(動向))

  • Choi, Byung-Ho;Yoon, Kyung-Hoon;Song, Jin-Soo
    • Solar Energy
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    • v.8 no.2
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    • pp.73-76
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    • 1988
  • Thick films based on the mature crystalline silicon technology are expected to exhibit eversmaller cost reduction. The thin-film-based technology is, however, expected to exhibit a much sharper drop in cost as it develops. In this report, technology and recent R & D of thin film solar cell, such as amorphous silicon, cadnium telluride, copper indium diselenide and gallium arsenide, are described. Perspectives of world photovoltaic market and solar cell price are also described.

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Purification of Trichoderma viride Cellobiohydrolase by Immunoaffinity Chromatography (면역친화 크로마토그라피에 의한 Tricholderma viride의 Cellobiohydrolase 분리)

  • 오태광
    • Microbiology and Biotechnology Letters
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    • v.18 no.4
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    • pp.390-393
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    • 1990
  • A cellobiohydrolase was purified from the culture broth of Trichoderma uiride by using immunoaffinity chromatography. A single protein band in polyacylamide gel electrophoresis and isoelectrofocusing after immunoaffinity purification corresponded to cellobiohydrolase activity. A immunoaffinity purified cellobiohydrolase is more effective in the hydrolysis of highly crystalline cellulose than amorphous cellulose.

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Atomically sculptured heart in oxide film using convergent electron beam

  • Gwangyeob Lee;Seung-Hyub Baek;Hye Jung Chang
    • Applied Microscopy
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    • v.51
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    • pp.1.1-1.2
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    • 2021
  • We demonstrate a fabrication of an atomically controlled single-crystal heart-shaped nanostructure using a convergent electron beam in a scanning transmission electron microscope. The delicately controlled e-beam enable epitaxial crystallization of perovskite oxide LaAlO3 grown out of the relative conductive interface (i.e. 2 dimensional electron gas) between amorphous LaAlO3/crystalline SrTiO3.

Relationship Between Voltage-time Characteristics and Microstructures of Tantalum Oxide Thin Films Prepared by Anodic Oxidation (양극 산화법으로 제조된 Tantalum Oxide 박막의 전압-시간 특성과 미세구조와의 연관성)

  • 정형진;윤상옥;이동헌
    • Journal of the Korean Ceramic Society
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    • v.28 no.6
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    • pp.443-450
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    • 1991
  • Microstructures of tantalum oxide, anodic-oxidized in oxalic acid, are shown to be related to voltage-time characteristics during formation reaction. It is observed that a crystalline phase transformed from an amorphous phase is recrystallized in the presence of the high electric field within the film, and this recrystallized film has a very porous microstructure. From the results of the XRD, the nonlinearity observed after the first spark voltage is recognized to be due to the local crystallization.

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Reduction of reflection from PET (polyethylene terephthalate) film surface by natural plasma etching

  • Oh, Hoon;Song, Yu-Jin;Whang, Ki-Woong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1419-1424
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    • 2006
  • We could reduce the reflection from PET(polyethylene terephthalate) film surface by natural plasma etching which does not use etch masks. The plasma etched PET film showed lower reflectance and higher transmittance which is resulted by making subwavelength structure(SWS) on the film surface by the plasma etch rate difference between the amorphous and crystalline region in the surface of PET film.

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THE EFFECTS OF Sm ON THE MICROSTRUCTURE AND MAGNETOSTRICTION OF Fe-Co ALLOYS

  • Shima, Toshiyuki;Aoyagi, Eiji;Fujimori, Hiroyasu
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.726-729
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    • 1995
  • We investigated the effects of Sm on the microstructure and magnetic properties of Fe-Co Alloy films prepared by a DC triode sputtering. The magnetostriction was found to be changed with the Sm content from positive to negative values, taking a zero magnetostriction was at about 3 at% Sm. The Sm content dependence of magnetostriction was explained by the formation of Sm enriched amorphous phase surrounding the main bcc (Fe,Co) crystalline phase, which was observed by a high resolution transmission electron microscopy.

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Fabrication and Characterization of New Glass Wasteforms for Radioactive Iodine Immobilization

  • Kang, Min-Ji;Kim, Miae;Hong, Kyong-Soo
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2019.05a
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    • pp.229-230
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    • 2019
  • We fabricated three $AgI-Ag_2O-B_2O_3$ glasses with different compositions. As a result, two specimens appeared in amorphous phases and one in a crystalline phase. The prepared glasses in this study are considered as one candidate of immobilizing matrices for $^{129}I$.

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Fabrication of Plasma Resistant Y2O3-Al2O3-SiO2 Coating Ceramics by Melt-Coating Method (용융코팅법에 의한 내플라즈마성 Y2O3-Al2O3-SiO2계 코팅 세라믹스 제조)

  • Park, Eui Keun;Lee, Hyun-Kwuon
    • Korean Journal of Materials Research
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    • v.30 no.7
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    • pp.359-368
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    • 2020
  • This study is aimed at improving the plasma resistance of Al2O3 ceramics on which plasma resistant YAS(Y2O3-Al2O3-SiO2) frit is melt-coated using a simple heat-treatment process. For this purpose, the results of phase analysis and microstructural observations of the prepared YAS frits and the coating layers on the Al2O3 ceramics according to the batch compositions are compared and discussed with regard to the results of plasma resistance test. The prepared YAS frits consist of crystalline or amorphous or co-existing crystalline and amorphous phases according to the batch compositions, depending on the role and content of each raw material. The prepared YAS frit is melt-coated on the densely sintered Al2O3 ceramics, resulting in a dense coating layer with a thickness of at least ~ 80 ㎛. The YAS coating layer consists of crystalline YAG(Y3Al5O12), Y2Si2O7, and Al2O3 phases, and YAS glass phase. Plasma resistance of YAS coated Al2O3 ceramics is strongly dependent on the content of the YAG(Y3Al5O12) and Y2Si2O7 crystalline phases in the coating layer, especially on the content of the YAG phase. Comparing the weight loss of YAS coating ceramics with values obtained for commercial Y2O3, Al2O3, and quartz ceramics, the plasma resistance of the YAS coating ceramics is 6 times higher than that of quartz, 2 times higher than that of Al2O3, and 50 % of the resistance of Y2O3.