• 제목/요약/키워드: amorphous alloys

검색결과 256건 처리시간 0.028초

벌크 아몰퍼스 성형의 유한요소 해석 (Finite Element Analysis for forming of bulk amorphous materials)

  • 윤상헌;고헌권;김용일;이용신
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 추계학술대회
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    • pp.1804-1809
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    • 2003
  • The purpose of this study is to clarify the bulk/sheet forming characteristics of bulk amorphous alloys in the supercooled liquid state. The temperature dependences of Newtonian viscosities of amorphous materials are obtained based on the previous experimental works. Finite element analyses for compression forming and sheet deep drawing of amorphous materials are performed. Effects of friction coefficients and temperature are examined and formability of amorphous material is explained in detail.

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동기지 동계 Bulk Amorphous 복합재의 압축 변형거동 (Deformation behavior in Cu-based bulk amorphous alloys composite during compression)

  • 이창호;김지수;박은수;허무영
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2004년도 추계학술대회논문집
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    • pp.203-206
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    • 2004
  • Copper-based bulk amorphous alloy composite was synthesized by using the copper-coated $Cu_{54}Ni_{6}Zr_{22}Ti_{18}$ amorphous powder which was obtained by argon gas atomization. The amorphous powder having a super-cooled liquid region of 53 K was coated by crystalline copper by electroless coating. The consolidation was carried out by manufacturing performs and by the subsequent warm extrusion at 743 K. During the compression test at the room temperature, the composite containing a large fraction of crystalline copper displayed a larger plastic strain after yielding. FEM simulation revealed change in fracture modes in the composites depending on the amount of crystalline copper in the composites.

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Characterization and Formation Mechanism of Zr-Cu and Zr-Cu-Al Metallic Glass Thin Film by Sputtering Process

  • Lee, Chang-Hun;Sun, Ju-Hyun;Moon, Kyoung-Il;Shin, Seung-Yong
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.271-272
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    • 2012
  • Bulk Metallic Glasses (BMGs or amorphous alloy) exhibit high strength and good corrosion resistance. Applications of thin films and micro parts of BMGs have been used a lot since its inception in the research of BMGs. However, Application and fabrication of BMGs are limited to make structural materials. Thin films of BMGs which is sputtered on the surface of structural materials by sputtering process is used to improve limits about application of BMGs. In order to investigate the difference of properties between designed alloys and thin films, we identified that thin films deposited on the surface that have the characteristic of the amorphous films and the composition of designed alloys. Zr-Cu (Cu=30, 35, 38, 40, 50 at.%) and Zr-Cu-Al (Al=10 at.% fixed, Cu=26, 30, 34, 38 at.%) alloys were fabricated with Zr (99.7% purity), Cu (99.997% purity), and Al (99.99% purity) as melting 5 times by arc melting method before rods 2mm in diameter was manufactured. In order to analyze GFA (Glass Forming Ability), rods were observed by Optical Microscopy and SEM and $T_g$, $T_x$, ($T_x$ is crystallization temperature and $T_g$ is the glass transition temperature) and Tm were measured by DTA and DSC. Powder was manufactured by Gas Atomizer and target was sintered using powder in large supercooled liquid region ($=T_x-T_g$) by SPS(Spark Plasma Sintering). Amorphous foil was prepared by RSP process with 5 gram alloy button. The composition of the foil and sputtered thin film was analyzed by EDS and EPMA. In the result of DSC curve, binary alloys ($Zr_{62}Cu_{38}$, $Zr_{60}Cu_{40}$, $Zr_{50}Cu_{50}$) and ternary alloys ($Zr_{64}Al_{10}Cu_{26}$, $Zr_{56}Al_{10}Cu_{34}$, $Zr_{52}Al_{10}Cu_{38}$) have $T_g$ except for $Zr_{70}Cu_{30}$ and $Zr_{60}Al_{10}Cu_{30}$. The compositions with $T_g$ made into powders. Figure shows XRD data of thin film showed similar hollow peak.

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$SiO_2$위에 증착된 $Si_{1-X}Ge_X$합금의 증착온도 변화에 따른 결정성 및 미세구조에 관한 연구 (A study of the crystallinity and microstructure of the $Si_{1-X}Ge_X$ alloys deposited on the $SiO_2$at various temperatures)

  • 김홍승;이정용;이승창;강상원
    • 한국재료학회지
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    • 제4권4호
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    • pp.416-427
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    • 1994
  • 비정질 $SiO_{2}$위에서 증착시킨 $Si_{1-x}Ge_x$합금의 증착온도에 따른 결정성, 미세구조와 조성의 균일성을 X선 회절법과 투과 전자현미겨으로 조사하였고, $Si_{1-x}Ge_x/Sio_2$계면을 고분해능 투과 전자현미경을 이용하여 원자단위로 관찰하였다. Ge의 몰분율을 0.3으로 놓고 증착온도를 $300^{\circ}C,400^{\circ}C,500^{\circ}C,600^{\circ}C,700^{\circ}C$로 변화시키며 Si-MBE로 증착된 박막은 , 분석 결과 $300^{\circ}C$에서는 비정질상만이 존재하였고 $400^{\circ}C$에서는 결정상과 비정질상이 공존하고 있었다. 두상은 $SiO_2$위에 함께 증착되었으나 초기 성장에서는 비정질상이 주로 성장되었으며 박막의 두께가 비정질층이 관찰되었다. $600^{\circ}C$이상에서는 결정상으로만 증착되었다. 증착된 다결정상은 주상성장을 하였다. 증착된 박막의 조성은 중착온도에 관계없이 균일하였으며, $Si_{1-x}Ge_x/Sio_2$계면은 다결정상이나 비정질상에 관계없이 평탄하였다.

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비정질 Zr-V-Ti 합금분말의 결정화에 따른 게터 특성 변화 (Changes of Getter properties by Crystallization of Amorphous Zr-V-Ti alloy Powders)

  • 박제신;김원백;백진선
    • 한국분말재료학회지
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    • 제14권1호
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    • pp.50-55
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    • 2007
  • The hydrogen sorption speeds of $Zr_{57}V_{36}Ti_7$ amorphous alloy and its crystallized alloys were evaluated at room temperature. $Zr_{57}V_{36}Ti_7$ amorphous alloy was prepared by ball milling. The hydrogen sorption rate of the partially crystallized alloy was higher than that of amorphous. The enhanced sorption rate of partially crystallized alloy was explained in terms of grain refinement that has been known to promote the diffusion into metallic bulk of the gases. The grain refinement could be obtained by crystallization of amorphous phase resulting in the observed increase in sorption property.

Soft-magnetic Characteristics of Co-based Amorphous Powder Produced by Spinning Water Atomization Process (SWAP)

  • Otsuka, I.;Wada, K.;Watanabe, A.;Kadomura, T.;Yagi, M.
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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    • pp.784-785
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    • 2006
  • Co-based amorphous powder was produced by a new atomization process "Spinning Water Atomization Process (SWAP)", having rapid super-cooling rate. The composition of the alloys was ($(Co_{0.95}Fe_{0.05})_{1-x}Cr_x$)$_{75}Si_{15}B_{10}$ (x=0, 0.025, 0.05, 0.075). The powders became the amorphous state even if particle size was up to about $500{\mu}m$. The coercive force of powders was about 0.35 - 0.7 Oe. Furthermore, Co-based amorphous powder cores with glass binders were made by cold-pressing and sintering methods. The initial permeability of the core in the frequency range up to 100 kHz was about 110, and the core loss at 100 kHz for Bm = 0.1 T was $350kW/m^3$.

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