• Title/Summary/Keyword: ammonia gas

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Thick-film ammonia gas sensor with high sensitivity and excellent selectivity

  • Lee, Kyuchung;Ryu, Kwang-Ryul;Hur, Chang-Wu
    • Journal of information and communication convergence engineering
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    • v.2 no.1
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    • pp.22-25
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    • 2004
  • A highly sensitive ammonia gas sensor using thick-film technology has been fabricated and examined. The sensing material of the gas sensor is FeOx-$WO_{3}-SnO_{2}$ oxide semiconductor. The sensor exhibits resistance increase upon exposure to low concentration of ammonia gas. The resistance of the sensor is decreased, on the other hand, for exposure to reducing gases such as ethyl alcohol, methane, propane and carbon monoxide. A novel method for detecting ammonia gas quite selectively utilizing a sensor array consisting of an ammonia gas sensor and a compensation element has been proposed and developed. The compensation element is a Pt-doped $WO_{3}-SnO_{2}$gas sensor which shows opposite direction of resistance change in comparison with the ammonia gas sensor upon exposure to ammonia gas. Excellent selectivity has been achieved using the sensor array having two sensing elements.

Development of a Measurement System for Ammonia Gas in Swine Housing (돈사내 암모니아가스 계측시스템 개발)

  • 방승훈;장동일;장홍희;임영일
    • Journal of Biosystems Engineering
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    • v.23 no.4
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    • pp.359-364
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    • 1998
  • A PC based measurement system was developed and it consisted of ammonia sensor(TS-1000), AMP & MUX Board, A/D Converter, and personal computer. The results obtained from the study are summarized as follows : 1. The relationship of outputs(V) of ammonia sensor(AS) and concentrations(ppm) of ammonia gas was analyzed by the linear regression analysis and the output values were very accurate when compared with standard ammonia gas. 2. The test results showed that the performance of ammonia gas sensor was not 31B3c1e4 by temperatures and humidities 3. The developed ammonia gas measurement system was proved to be practically uesful for measuring concentrations of ammonia gas in pig housing.

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Aqeous Neutralizer as Reactive Solvents for Odorous Ammonia Removal

  • Park, Young-G.
    • Environmental Engineering Research
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    • v.13 no.3
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    • pp.119-124
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    • 2008
  • Ammonia is an inorganic compound that may cause severe odor problem. In this study the effectiveness of applying natural neutralizer to destroy and remove the odor-causing compound from gas streams was studied. Experimental result evaluated with a bench-scale apparatus via the neutralization of gas phase. This indicates that the natural neutralization depends on the gas concentration, gas residence time, temperature and pH. Removal efficiency of ammonia from gas stream was achieved by 95% using theconvection in the packed bed. This study proved the chemical neutralization technology was effective for controlling inorganic odor-causing compound.

A Study on Ammonia Formation with Nitrogen Impurity at a Natural Gas Steam Reforming Catalytic Process (소량의 질소를 포함한 천연가스 수증기 개질 반응에서 GHSV 변화에 따른 암모니아 생성 반응에 관한 연구)

  • KIM, CHUL-MIN;PARK, SANG-HYOUN;LEE, JUHAN;LEE, SANGYONG
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.6
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    • pp.601-607
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    • 2019
  • Ammonia would be formed in natural gas containing small amount of nitrogen reforming process in the process natural gas, which might damage the Pt catalyst and Prox catalyst. In the article, the effect of nitrogen contents on the formation of ammonia in the reforming process has been studied. In the experiments, Ru based and Ni based catalysts were used and the concentration of ammonia in the reformate gas at various gas hourly space velocity was measured. Experimental result shows that relatively higher ammonia concentration was measured with Ru based catalyst than with Ni based catalyst. It also shows that the concentration of ammonia increased rapidly after most of the methane converted into hydrogen. Based on the experimental results to reduce ammonia concentration it might be better to finish methane conversion at the exit position of the reforming reactor to minimize the contact time of catalyst and nitrogen with high concentration of hydrogen.

Study of ammonia-gas removal′s characteristics using wood-material (침엽수를 이용한 암모니아 가스 제거효율 연구)

  • Park Young Gyu
    • Journal of environmental and Sanitary engineering
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    • v.19 no.2
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    • pp.7-14
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    • 2004
  • This paper was investigated to clarify the possibility of ammonia-gas removal by essential oil. First of all, the chemical analysis was performed to analyze the composition of an essential oil by GC-MS. The monoterpenes in an essential oil react with ammonia by neutralization and their reaction mechanism was elucidated. Based on their chemical neutralized reaction, the removal efficiencies of ammonia gas were studied to derive the optimal conditions in the scrubber tower such as optimal temperature and pH. The experimental result shows that the removal efficiency of ammonia gas was achieved over 80 % by the misty aerosol dispersion of scrubber tower.

Dried Bacillus subtilis Culture Reduced Ammonia Gas Release in Poultry House

  • Santoso, U.;Ohtani, S.;Tanaka, K.;Sakaida, M.
    • Asian-Australasian Journal of Animal Sciences
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    • v.12 no.5
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    • pp.806-809
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    • 1999
  • The present study showed the advantages of dried Bacillus subtilis culture (DBSC) supplementation on reducing ammonia gas release in the poultry house. In Experiment 1, 65-week-old Hyline W-36 hens were raised in individual wire-floor cages in a windowless house, and divided into two groups of 180 hens each. One group was fed diets without DBSC as the control and another group was fed a diet supplemented with 2% DBSC. In Experiment 2, 2-week-old broiler chicks were divided into 3 treatment groups of 20 chicks each and maintained in individual floor cages. One group was fed the diet without DBSC and other two groups were fed the diet supplemented with 1 or 2% DBSC, respectively. In experiment 1, DBSC consistently reduced ammonia gas release in the laying house (p<0.01) and manure storage facilities (p<0.01). incubation of feces for 1, 2, 3, 4, 5, 6, 24 or 48 hours showed that DBSC consistently reduced ammonia gas release. In Experiment 2, DBSC reduced ammonia gas release in the broiler house; however, DBSC had no effect on total N, urate-N and ammonia-N contents of feces, but it improved cumulative N utilization and decreased serum urea-N concentration when chicks when chicks were fed 1% DBSC.

Modeling of Ammonia Mass Transfer Using a Hollow Fiber Membrane Contactor (중공사막 접촉기를 이용한 암모니아 물질전달 모델링)

  • Oh, Dae-Yang;Jeong, Joo-Young;Choi, Won-Ho;Park, Joo-Yang
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.4
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    • pp.503-510
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    • 2011
  • Ammonia in water which is toxic to human, its concentration is regulated below 0.5 mg/L in drinking water. Current study aimed to develop appropriate models for ammonia stripping using hollow fiber membrane contactor. Two different models were developed during the study. Model 1 was assumed only free ammonia ($NH_3$) transfer in stripping process, whereas the Model 2 was assumed with total ammonia ($NH_3+{NH_4}^+$) transfer. Ammonium chloride ($NH_4CI$), sodium hydroxide(NaOH) were used to make ammonia solution, which was concentration of 25 mg as N/L at a pH of 10.5. The experimental conditions were such that, the liquid flow was in tube-side in upward direction and t he gas flow was on shell-side in downward direction a t room temperature. The experimental and modeling results showed that marginal difference were observed at low gas flux. However the difference between the both models and experimental value were increased when the gas flux was increased. The study concludes that the Model 1 with free ammonia is more appropriate when both models were compared and useful in ammonia stripping process at low gas flux.

Improvement in ammonia gas sensing behavior by polypyrrole/multi-walled carbon nanotubes composites

  • Jang, Woo-Kyung;Yun, Ju-Mi;Kim, Hyung-Il;Lee, Young-Seak
    • Carbon letters
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    • v.13 no.2
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    • pp.88-93
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    • 2012
  • Polypyrrole (PPy)/multi-walled carbon nanotubes (MWCNTs) composites were prepared by in situ polymerization of pyrrole on the surface of MWCNTs templates to improve the ammonia gas sensing properties. PPy morphologies, formed on the surface of MWCNTs, were investigated by field emission scanning electron microscopy. The thermal stabilities of the PPy/MWCNTs composites were improved as the content of MWCNTs increased due to the higher thermal stability of the MWCNTs. PPy/MWCNTs composites showed synergistic effects in improving the ammonia gas sensing properties, attributed to the combination of efficient electron transfer between PPy/MWCNTs composites and ammonia gas, and the reproducible electrical resistance variation on PPy during the gas sensing process.

Fabrication and Characterization of Thick Film Ammonia Gas Sensor (후막형 암모니아 가스 센서의 제조 및 가스 감응 특성)

  • Yun, Dong-Hyun;Kwon, Chul-Han;Hong, Hyung-Ki;Kim, Seung-Ryeol;Lee, Kyu-Chung
    • Journal of Sensor Science and Technology
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    • v.6 no.6
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    • pp.445-450
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    • 1997
  • An ammonia gas sensor with high sensitivity using thick-film technology were fabricated and examined. The material for sensing the ammonia gas was the mixture of oxide semiconductor, $FeO_{x}-WO_{3}-SnO_{2}$. The sensor exhibits resistance increase upon exposure to low concentration of ammonia gas. The resistance of the sensor is decreased, on the other hand, for exposure to reducing gases such as ethyl alcohol, methane, propane and carbon monoxide. A novel method for detecting ammonia gas quite selectively utilizing a sensor array consisting of an ammonia gas sensor and a compensation element were proposed and developed. The compensation element is a Pt-doped $WO_{3}-SnO_{2}$ gas sensor which shows opposite direction of resistance change in comparison with that of the ammonia gas sensor upon exposure to ammonia gas. Excellent selectivity has been achieved using the sensor array having two sensing elements.

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Recovery of Ammonia Nitrogen using Gas-permeable Membranes (기체투과막을 이용한 암모니아성 질소 회수방안)

  • Lee, Sang-hun;Chae, Sang Yeop
    • Membrane Journal
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    • v.32 no.3
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    • pp.191-197
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    • 2022
  • Ammonia nitrogen can be effectively recovered from livestock manure waste, etc. by using the gas permeable membrane technology. In this case, ammonia gas in the waste passes through the pores in one-side of membrane, impregnated in waste, and then reach the opposite side of the membrane. The permeated ammonia gas molecules are captured and recovered by acid (such as sulfuric acid) in the solution existing on the opposite side of the membrane. In order to improve ammonia nitrogen removals in the inlet part, high pH should be maintained in the feed waste including ammonia nitrogen to recover, which requires the cost of the chemical. To resolve this issue, previous studies tested various methods, for example, utilization of cheap calcium hydroxide or aeration together with inhibition of unwanted nitrification. The gas permeable membranes used for the recovery of ammonia nitrogen may be characterized, not only by proper heat and chemical resistance, but also by hydrophobicity, allowing selective ammonia gas permeation through the hydrophobic membrane pores. Future research should consider the relevant pilot or upscale processes using on-site wastes with various properties, and identify the optimal design/operation conditions as well as economic feasibility improvement plans.