• Title/Summary/Keyword: ambient air

Search Result 1,458, Processing Time 0.044 seconds

Large-Area Synthesis of High-Quality Graphene Films with Controllable Thickness by Rapid Thermal Annealing

  • Chu, Jae Hwan;Kwak, Jinsung;Kwon, Tae-Yang;Park, Soon-Dong;Go, Heungseok;Kim, Sung Youb;Park, Kibog;Kang, Seoktae;Kwon, Soon-Yong
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2013.08a
    • /
    • pp.130.2-130.2
    • /
    • 2013
  • Today, chemical vapor deposition (CVD) of hydrocarbon gases has been demonstrated as an attractive method to synthesize large-area graphene layers. However, special care should be taken to precisely control the resulting graphene layers in CVD due to its sensitivity to various process parameters. Therefore, a facile synthesis to grow graphene layers with high controllability will have great advantages for scalable practical applications. In order to simplify and create efficiency in graphene synthesis, the graphene growth by thermal annealing process has been discussed by several groups. However, the study on growth mechanism and the detailed structural and optoelectronic properties in the resulting graphene films have not been reported yet, which will be of particular interest to explore for the practical application of graphene. In this study, we report the growth of few-layer, large-area graphene films using rapid thermal annealing (RTA) without the use of intentional carbon-containing precursor. The instability of nickel films in air facilitates the spontaneous formation of ultrathin (<2~3 nm) carbon- and oxygen-containing compounds on a nickel surface and high-temperature annealing of the nickel samples results in the formation of few-layer graphene films with high crystallinity. From annealing temperature and ambient studies during RTA, it was found that the evaporation of oxygen atoms from the surface is the dominant factor affecting the formation of graphene films. The thickness of the graphene layers is strongly dependent on the RTA temperature and time and the resulting films have a limited thickness less than 2 nm even for an extended RTA time. The transferred films have a low sheet resistance of ~380 ${\Omega}/sq$, with ~93% optical transparency. This simple and potentially inexpensive method of synthesizing novel 2-dimensional carbon films offers a wide choice of graphene films for various potential applications.

  • PDF

Variation of Indoor Average Ozone Concentration within the Radiation Therapy Room by High Energy Radiation (고 에너지 방사선에 기인된 방사선치료실 내 평균 오존 농도의 변화)

  • Lee, Jin-kook;Lee, Hyo-Yeong;Im, In-Chul;Yu, Yun-Sik
    • Journal of the Korean Society of Radiology
    • /
    • v.10 no.3
    • /
    • pp.171-180
    • /
    • 2016
  • This study was to evaluate the change in characteristics of concentration of ozone after exposure to high energy radiation in linac room. Background ozone concentration of linac room was measured and compared to ozone concentration around linac room. Background ozone concentration of linac room was mean $17.4{\pm}7.9ppb$. It was 50% of the ozone concentration($36.8{\pm}22.3ppb$) around linac room(p<0.05). The concentration of ozone after exposure to high energy radiation in linac room was elevated to double of background ozone level, intensity after exposure. with exposure time concentration of ozone increased proportionally. It showed maximum level at 130~180seconds and slowed a tendency to saturate. It required more than 10 minutes for ozone concentration in linac room to drop to ozone concentration around linac room. The concentration of ozone after exposure to high energy radiation is high enough to cause specific physical symptoms, such as acute dyspnea or chest pain due to dry cough. Exposure to high concentration of ozone in sealed linac room can aggravate pulmonary disease, so special attention is needed.

Measurement of Ammonia Emission Rate and Environmental Parameters from Growing-Finishing and Farrowing House during Hot Season (하절기 육성$\cdot$비육돈사와 분만돈사의 암모니아 발생특성 및 환경변화)

  • Lee S. H;Cho H. K.;Choi K. J.;Oh K. Y.;Yu B. K.;Lee I. B.;Kim K. W.
    • Journal of Animal Environmental Science
    • /
    • v.11 no.1
    • /
    • pp.1-10
    • /
    • 2005
  • This study was carried out to measure the environmental related parameters from two types of swine houses. Indoor temperature, relative humidity, carbon dioxide level, ammonia concentration and emission were measures every 2 minutes from each house with portable monitoring units. Carbon dioxide concentration balance was used to estimate the ventilation rates of the different houses. Daily ammonia concentrations in the growing-finishing and farrowing houses ranged from 2 to 17 ppm and 6 to 15 ppm respectively. The daily ammonia emission rate from the manure averaged 4.37 g/h$\cdot$500 kg from growing-finishing house and 4.82 g/h$\cdot$500 kg from the farrowing house. The above findings proved that summer season was associated with higher ammonia emission rates due to higher ventilation rate and ambient air temperature.

  • PDF

A multiphase flow modeling of gravity currents in a rectangular channel (사각형 수로에서 중력류의 다상흐름 수치모의)

  • Kim, Byungjoo;Paik, Joongcheol
    • Journal of Korea Water Resources Association
    • /
    • v.52 no.10
    • /
    • pp.697-706
    • /
    • 2019
  • A multiphase flow modeling approach equipped with a hybrid turbulence modeling method is applied to compute the gravity currents in a rectangular channel. The present multiphase solver considers the dense fluid, the less-dense ambient fluid and the air above free surface as three phases with separate flow equations for each phase. The turbulent effect is simulated by the IDDES (improved delayed detach eddy simulation), a hybrid RANS/LES, approach which resolves the turbulent flow away from the wall in the LES mode and models the near wall flow in RANS mode on moderately fine computational meshes. The numerical results show that the present model can successfully reproduce the gravity currents in terms of the propagation speed of the current heads and the emergence of large-scale Kelvin-Helmholtz type interfacial billows and their three dimensional break down into smaller turbulent structures, even on the relatively coarse mesh for wall-modeled RANS computation with low-Reynolds number turbulence model. The present solutions reveal that the modeling approach can capture the large-scale three dimensional behaviors of gravity current head accompanied by the lobe-and-cleft instability at affordable computational resources, which is comparable to the LES results obtained on much fine meshes. It demonstrates that the multiphase modeling method using the hybrid turbulence model can be a promising engineering solver for predicting the physical behaviors of gravity currents in natural environmental configurations.

Investigation of Plant Injury under Ambient Air Pollutants (대기오염물질에 의한 농작물 피해원인 조사)

  • Lee, Jong-Sik;Shin, Joung-Du;Kim, Jin-Ho;Jung, Goo-Bok;Kim, Won-Il;Kim, Gun-Yeob
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.40 no.1
    • /
    • pp.31-35
    • /
    • 2007
  • In order to find out the cause of plant injury, the symptom of plant injury, and contents of element concerned in the plant were analysed. Also, a case study was conducted to find out the factor of plant injury at a agriculture and industry complex in Gyeongsang province in 2004. The distribution of isomeric curve was made with meteorological data, toxic gas concentration exhausted from pollution source. The general symptom of plant injury by ammonia gas was dry and dead of leaves with white color. At low concentration of ammonia gas, plant leaf showed spots of reddish brown. The characteristic of plant injury symptom by hydrogen fluoride gas was that the symptom was appeared at the edge of leaf. The isomeric curve of sulfur dioxide at the region, where the plant was damaged, showed that the area was affected by exhausted gas from the pollution source. Especially, this area was affected more deeply at summer than any other season.

Analytic study on thermal management operating conditions of balance of 100kW fuel cell power plant for a fuel cell electric vehicle (100kW급 연료전지 열관리 시스템 실도로 운전조건 해석적 연구)

  • Lee, Ho-Seong;Lee, Moo-Yeon;Cho, Choong-Won
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.20 no.2
    • /
    • pp.1-6
    • /
    • 2019
  • The objective of this study was to investigate performance characteristics of thermal management system(TMS) in a fuel cell electric vehicle with 100kW Fuel Cell(FC) system. In order to build up analytic modelling for TMS, each component was installed and tested under various operating conditions, such as water pump, radiator, 3-Way valve, COD heater, and FC stack etc. and as the results of them, correlations reflecting component's characteristics with flow rate, air velocity were developed. Developed analytic modelling was carried out under various operating conditions on the road. To verify modelling's accuracy, after prediction for optimum coolant flow rate was fulfilled under certain operating conditions, such as FC system, water pump speed, opening of 3-way valve, and pipe resistance, analytic and experimental values were compared and good agreement was shown. In order to predict cold-start operating performance for analytic modelling, coolant temperature variation was analyzed with $-20^{\circ}C$ ambient temperature and duration was predicted to rise in optimum temperature for FC. Because there is appropriate temperature difference between inlet and outlet of FC stack to operate FC system properly, related analysis was performed with respect to power consumption for TMS and heat rejection rate and performance map was depicted along with FC operating conditions.

Comparison of Airborne Lead Concentration in and Around Lead Production Plant (재생 납 생산 공장과 인근 지역의 공기 중 납 농도 수준 비교)

  • Park, Changhwan;Park, Yunkyung;Oh, Younhee;Choi, Inja;Cha, Wonseok;Choi, Sangjun
    • Journal of Korean Society of Occupational and Environmental Hygiene
    • /
    • v.29 no.1
    • /
    • pp.34-41
    • /
    • 2019
  • Objective: This study is conducted to evaluate airborne lead concentration in and around lead production plant. Methods: Airborne lead concentration was monitored simultaneously inside of the processes of lead recycling factory and outside of factory which include stack, boundary of factory and residential area 1 km and 7.5 km from factory, respectively. All samples were measured three times at 1.5 m from the ground and analyzed using inductively coupled plasma mass spectrometer, inductively coupled plasma optical emission spectrometer or flame atomic absorption spectrometer. Results: All airborne lead concentrations measured inside of factory($13.9{\mu}g/m^3-252.9{\mu}g/m^3$) and outside of factory($0.001{\mu}g/m^3-54.97{\mu}g/m^3$) showed log-normal distribution. Geometric mean lead concentration, $54.81{\mu}g/m^3$, measured inside of factory was significantly higher than outside of factory, $0.20{\mu}g/m^3$(p<0.01). Among the samples measured inside the factory, lead concentration was the highest in the refining process($59.02{\mu}g/m^3-252.9{\mu}g/m^3$). In the case of the samples outside the factory, the nearest chimney was the highest($3.84{\mu}g/m^3-54.97{\mu}g/m^3$), and the lead concentration at the farthest place, 7.5 km from the factory was the lowest($0.001{\mu}g/m^3-1.7{\mu}g/m^3$). The arithmetic lead concentration, $0.45{\mu}g/m^3$ in the residential area near the factory was below the atmospheric environment standard of $0.5{\mu}g/m^3$, but the maximum concentration of $3.4{\mu}g/m^3$ was exceeded. Conclusions: Airborne lead concentration in residential area, 1 km away from lead recycling plant, may exceed ambient air standard of $0.5{\mu}g/m^3$.

Preparation and characterization of Environmental Functional Nanofibers by electrospun nanofibers-Dry sorption material for indoor CO2 capture (정전방사를 통한 환경기능성 미세섬유 제조 및 특성분석 - 실내환경 CO2 포집용 건식흡착소재)

  • Kim, Eun Joo;Park, Kyung-Ryul
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.19 no.12
    • /
    • pp.938-943
    • /
    • 2018
  • Thin nano-sized fibres were prepared by an electrospinning method. The spinning appratus consisted of pump for polymer injection, nozzle and nozzle rotus, and an aluminum plate collected the polymer fibers. Its surface was chemically modified for selective improved adsorption of carbon monoxide at indoor level. The chemical activation enabled to form the fibres 250-350 nm in thickness with pore sizes distributed between 0.6 and 0.7 nm and an average specific surface area of $569m^2/g$. The adsorption capacities of pure (100%) and indoor (0.3%) $CO_2$, of which level frequently appears, at the ambient condition were improved from 1.08 and 0.013 to 2.2 and 0.144 mmol/g, respectively. It was found that the adsorption amount of $CO_2$ adsorbed by the chemically activated carbon nanofiber prepared through chemical activation would vary depending on the ratio of specific surface area and micropores. In particular, chemical interaction between adsorbent surface and gas molecules could enhance the selective capture of weak acidic $CO_2$.

Protective Effects of Novel Tripeptide Against Particulate Matter-induced Damage in HaCaT Keratinocytes (미세먼지에 의해 유발되는 인간각질형성세포 손상에 대한 신규 트리펩타이드의 보호 효과)

  • Lee, Eung Ji;Kang, Hana;Hwang, Bo Byeol;Lee, Young Min;Chung, Yong Ji;Kim, Eun Mi
    • Journal of the Society of Cosmetic Scientists of Korea
    • /
    • v.47 no.1
    • /
    • pp.75-84
    • /
    • 2021
  • In this study, we investigated inhibitory effect of Tripeptide against particulate matter (PM)-induced damage in human keratinocytes. PM-induced cell death was inhibited by Tripeptide and the activity of aryl hydrocarbon receptor (AhR) also inhibited by Tripeptide resulting in reduced expression of its downstream targets, cytochrome P450 family 1 subfamily A member 1 (CYP1A1) and cyclooxygenase-2 (COX-2), which are responsible for toxic metabolites production and inflammation. Furthermore, PM-induced expressions of pro-inflammatory cytokines, matrix metalloproteinase-1 (MMP-1) and apoptosis-related factors were decreased by anti-oxidant activity of Tripeptide. From these results, it has been shown that the Tripeptide has protective effect against PM-induced skin damage not only through the inhibiting of keratinocyte death but also through the inhibiting the secretion of several damage-inducing factors to adjacent skin tissue. And the results suggested that Tripeptide with anti-pollution effect could be applied as a new functional cosmetic material.

Indoor and Outdoor Levels of Particulate Matter with a Focus on I/O Ratio Observations: Based on Literature Review in Various Environments and Observations at Two Elementary Schools in Busan and Pyeongtaek, South Korea (실내 외 농도 비(I/O ratio)에 기반한 주변환경과 실내 미세먼지 농도분포 특성: 선행연구 리뷰와 여름철 부산과 평택 초등학교에서의 측정 결과를 중심으로)

  • Kang, Jiwon;An, ChanJung;Choi, Wonsik
    • Korean Journal of Remote Sensing
    • /
    • v.36 no.6_3
    • /
    • pp.1691-1710
    • /
    • 2020
  • We measured PM2.5 and PM10 (particulate matter less than 2.5 ㎛ and 10 ㎛ in diameter, respectively) simultaneously at 16 locations around an elementary school and classrooms in Busan and Pyeongtaek, South Korea. In this study, we compared the results of this field intensive with those in the literature (144 cases of 30 studies), focusing on I/O (Indoor/Outdoor) ratios. We also reviewed the results of previous studies, categorizing them into related sub-categories for indoor-activities, seasons, building-uses, and the surrounding environment. We conclude that indoor PM10 is affected more by indoor-sources (e.g., physical activities) than PM2.5 in the absence of combustion sources like smoking and cooking. Additionally, PM10 and PM2.5 likely have different indoor-outdoor infiltration efficiencies. Conclusively, PM10 in classrooms can be more sensitively affected by both indoor activities and ambient concentrations, and mechanical ventilation can be more efficient in reducing PM concentrations than natural ventilation.