• 제목/요약/키워드: aluminum polymer

검색결과 201건 처리시간 0.024초

Preparation of Solventless UV Curable Thermally Conductive Pressure Sensitive Adhesives and Their Adhesion Performance

  • Baek, Seung-Suk;Park, Jinhwan;Jang, Su-Hee;Hong, Seheum;Hwang, Seok-Ho
    • Elastomers and Composites
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    • 제52권2호
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    • pp.136-142
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    • 2017
  • Using various compositions of thermally conductive inorganic fillers with boron nitride (BN) and aluminum oxide ($Al_2O_3$), solventless UV-curable thermally conductive acrylic pressure sensitive adhesives (PSAs) were prepared. The base of the PSAs consists of 2-ethylhexyl acrylate, 2-hydroxyethyl acrylate, and isobornyl acrylate.The compositions of the thermally conductive inorganic fillers were 10, 15, 20, and 25 phr in case of BN, and 20:0, 15:5, 10:10, 5:15, and 0:20 phr in case of $BN/Al_2O_3$. The adhesion properties like peel strength, shear strength, and probe tack, and the thermal conductivity of the prepared PSAs were investigated with different thermally conductive inorganic filler contents. There were no significant changes in photo-polymerization behavior with increasing BN or $BN/Al_2O_3$ content. Meanwhile, the conversion rate and transmittance of the PSAs decreased and their thermal stabilities increased with increasing BN content. Their adhesion properties were also independent of the BN or $BN/Al_2O_3$ content. The dispersibility of BN in the acrylic PSAs was better than that of $Al_2O_3$ and it ranked the thermal conductivity in the following order: BN > $BN/Al_2O_3$ > $Al_2O_3$.

다공막 주형에 의한 전도성 고분자 나노와이어의 합성 (Synthesis of Conductive Polymer Nano-wires by Porous Membrane Template)

  • 신화섭;염경호
    • 멤브레인
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    • 제22권1호
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    • pp.35-45
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    • 2012
  • 양극산화 알루미나(AAO)막의 나노 사이즈 미세공(세공 크기 20 nm, 10 nm 및 200 nm)을 주형으로 사용하여 전도성 고분자인 폴리피롤, 폴리아닐린 중합체 및 폴리피롤/폴리아닐린 공중합체 나노와이어를 제조하였다. 미세공 주형 내에서 전도성 고분자의 성장은 세공의 벽면을 따라 튜브 형태로서 성장하였으며, 3시간 이후에는 내부가 완전히 채워진 나노와이어가 형성되었다. AAO 막을 수산화나트륨 용액으로 퍼리하여 세공 내에 형성된 전도성 고분자 나노와이어를 회수 하였으며. 회수된 나노와이어�l 직경과 길이는 주형 막의 세공 형상과 일치하였다. 통상의 용액 중합법으로 제조된 전도성 고분자 분말과 비교하여 주형 합성법으로 제조된 전도성 고분자 나노와이어는 결정성과 열적 안정성이 향상되었으며, 전기 저항은 4~60% 감소하였다.

산소 플라즈마 처리된 그래핀 산화물이 PMMA/수산화알루미늄 컴포지트의 기계적 물성에 미치는 영향 (Effects of Oxygen Plasma-treated Graphene Oxide on Mechanical Properties of PMMA/Aluminum Hydroxide Composites)

  • 김효철;전소녀;김형일;최호석;홍민혁;최기섭
    • 폴리머
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    • 제35권6호
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    • pp.565-573
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    • 2011
  • Poly(methyl methacrylate)/aluminum hydroxide(PMMA/AH) 컴포지트의 기계적 강도를 향상시키기 위해 그래핀 산화물(GO)을 충전제로 사용하여 나노컴포지트를 제조하였다. GO는 흑연을 Hummers법으로 산화한 후 열처리에 의해 박리시켜 제조하였다. PMMA/AH 컴포지트 매트릭스와의 계면혼화성을 향상시키기 위해 산소 플라즈마를 사용하여 노출 시간을 0분에서 70분까지 변화를 주어가며 GO 표면을 개질시켰다. 노출 시간이 50분까지 증가함에 따라 산소 플라즈마 처리한 GO를 충전제로 사용한 나노컴포지트는 PMMA/AH 컴포지트에 비해 굴곡강도, 굴곡탄성률, Rockwell 경도, Barcol 경도, Izod 충격강도 모두 현저히 증가하였다. 적절한 조건에서 산소 플라즈마 처리된 GO는 PMMA/AH 컴포지트 매트릭스와의 계면접착력이 매우 우수함을 파단면 모폴로지로부터 확인하였다. 하지만 GO의 함량이 0.07 phr 이상으로 증가하면 충전제의 분산이 균일하지 못하여 나노컴포지트의 기계적 강도는 오히려 감소하는 경향을 나타내었다.

합류식 하수관거 월류수의 인제거를 위한 응집제 투여 (Addition of Coagulants for Phosphorus Removal from Combined Sewer Overflows (CSOs))

  • 손상미;주티담롱판;박기영
    • 상하수도학회지
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    • 제26권2호
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    • pp.295-302
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    • 2012
  • The coagulation of combined sewer overflows ($CSO_{s}$) was investigated by jar-testing with several commercial coagulants. $CSO_{s}$ sample showed different characteristics of coagulation from secondary wastewater with three common coagulants, aluminum sulfate, ferric chloride and polyaluminum chloride (PACl). Jar-tests showed that relatively wide range of optimal SS and T-P removal yielded with alum and ferric chloride compared with cationic polymers, though efficient SS and T-P removal can be achieved with all three coagulants. The decrease of pH was caused by the increase in dosage of aluminum sulfate, ferric chloride and PACl as coagulants. The pH was changed from 7.0 to 4.7 with the dosages of ferric chloride 25 mL/L. Aluminum sulfate revealed pH of 5.0 and PACl was highest pH of 5.4 after dosing of coagulants. The optimal pH to treat $CSO_{s}$ with aluminum sulfate were 6-6.5; with PACl 6-7, and with ferric chloride higher than 7.

소형 정찰 UAV를 위한 고분자 전해질막 연료전지의 경량의 금속 분리판 (Lightweight Metallic Bipolar Plates of PEMFC for a Small Reconnaissance UAV)

  • 김기인;이종광;장보선;권세진
    • 한국항공우주학회지
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    • 제38권10호
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    • pp.1031-1037
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    • 2010
  • 이 논문에서는 소형 정찰 UAV의 동력원으로 연료전지 시스템을 적용하기 위해, 기존의 흑연 분리판을 대체할 수 있는 가벼운 알루미늄 분리판을 제시하였다. 분리판은 연료전지 시스템 전체 무게의 80% 이상을 점유하므로, 경량의 알루미늄 분리판은 연료전지 UAV의 유효 탑재량과 항속 시간을 증가시킬 수 있다. 일반적으로 사용되고 있는 흑연 재질의 분리판과 성능을 비교 및 평가하기 위해 알루미늄과 흑연 분리판을 제작하였으며, 알루미늄 분리판의 성능이 흑연 분리판에 비해 약 15% 이상 증가하였음을 확인하였다. 또한, 실제 소형 정찰 UAV에 적용하기 위한 기초 연구로써 알루미늄 분리판을 이용한 단전지의 성능을 다양한 운전조건에서 측정하였다.

구조용 경량 알루미늄 발포금속의 기계적 특성 연구 분석 (Mechanical Characteristics Analysis of Structural Light-weight Aluminum Foam)

  • 마정범;이정익
    • 한국융합학회논문지
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    • 제2권3호
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    • pp.1-6
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    • 2011
  • 대표적인 경량금속 중의 하나인 알루미늄 폼재의 연구동향을 기계적인 측면에서 고찰하여 보았다. 특히 기공(pore)을 가진 알루미늄재료는 난연성, 감쇠특성, 에너지흡수 성능 등 여러 측면에서 기존의 폴리머 폼재보다 우수한 기계적 성능을 가지고 있고, 더욱이 재활용이 가능하다는 면에서 환경보호에 관심이 집중되고 있는 현 시점에서 연구가 활발히 진행되고 있다. 폼재의 일반적 특성, 에너지 흡수 및 소음흡수 특성에 대해 살펴보고 폼재가 적용된 사례들에 대한 분석을 통해 향후 폼재와 외곽 구조재의 접합문제 등에 대한 제언을 하였다.

자기 조립 반응에 의한 그래핀이 코팅된 알루미늄 입자의 합성 방법 (Synthesis of Graphene Coated Aluminum Powders by Self-assemble Reaction)

  • 황진욱;탁우성;남상용;김우식
    • 한국분말재료학회지
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    • 제26권5호
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    • pp.383-388
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    • 2019
  • To improve the mechanical properties of aluminum, graphene has been used as a reinforcing material, yielding graphene-reinforced aluminum matrix composites (GRAMCs). Dispersion of graphene materials is an important factor that affects the properties of GRAMCs, which are mainly manufactured by mechanical mixing methods such as ball milling. However, the use of only mechanical mixing process is limited to achieve homogeneous dispersion of graphene. To overcome this problem, in this study, we have prepared composite materials by coating aluminum particles with graphene by a self-assembly reaction using poly vinylalcohol and ethylene diamine as coupling agents. The scanning electron microscopy and Fourier-transform infrared spectroscopy results confirm the coating of graphene on the Al surface. Bulk density of the sintered composites by spark plasma sintering achieved a relative density of over 99% up to 0.5 wt.% graphene oxide content.

응집제를 이용한 양돈폐수의 침감성 및 슬러지의 탈수성 증대 (Enhancement of Dewatering and Settling Characteristics for Swine Wastewater Using Coagulants)

  • 강선홍;민경석
    • 한국물환경학회지
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    • 제18권3호
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    • pp.313-319
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    • 2002
  • Laboratory experiments using metal coagulants[alum, PAC(Poly Aluminum Chloride)] and polymer were conducted in this study to enhance dewatering and settling characteristics for swine wastewater. In this study, application of mixture of metal coagulants and polymer improved settling and dewatering characteristics for swine wastewater compared to using only metal coagulants. Also sludge volume was decreased when the mixture was applied. About 80-90% of settling velocity was increased and thickening ratio was increased as much as two times when adding 100mg/L of cationic polymers. Polymer was excellent for enhancing dewatering property among coagulants.

$A\;\ell\;(OH)_3$를 첨가(添加)한 PVC의 내(耐)Tracking성(性)과 열분석(熱分析)에 관한 연구(硏究) (A Study on Thermegravimetry and Tracking Resistance of PVC Doped with $A\;\ell\;(OH)_3$)

  • 강성화;임기조;신용덕;박대희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1995년도 추계학술대회 논문집 학회본부
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    • pp.389-391
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    • 1995
  • Using as an alternate of insulating material for outdoor and cable, however, it has still many problems to be solved in the field of material such as resistances of environment and tracking. In this paper, Tracking property of PVC filled with aluminum hydroxide have been investigated by ASTM D 2303 method. It was found that time to track of PVC filled aluminum hydroxide was longer than that of unfilled PVC. Tensile strength and elongation of PVC were decreases increased with aluminum hydroxide contents. On the other hand, Thermegravimetry of PVC decreased. Therefore, the increase of time to tracking breakdown by antitracking additive can be explained by increased degradation temperature of polymer.

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Preparation and Analysis of High Functional Silicone Hydrogel Lens Containing Metal Oxide Nanoparticles by Photopolymerizaion

  • Heo, Ji-Won;Sung, A-Young
    • 한국재료학회지
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    • 제32권4호
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    • pp.193-199
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    • 2022
  • In this study, lenses are fabricated using various nanomaterials as additives to a silicone polymer made with an optimum mixing ratio and short polymerization time. In addition, PVP is added at a ratio of 1 % to investigate the physical properties according to the degree of dispersion, and the compatibility with hydrophobic silicone and the possibility of application as a functional lens material are confirmed. The main materials are SIU as a silicone monomer, DMA, a hydrophilic copolymer, EGDMA as a crosslinking agent, and 2H2M as a photoinitiator. Holmium (III) oxide, Europium (III) oxide, aluminum oxide, and PVP are used. When Holmium (III) oxide and Europium (III) oxide are added based on the Ref sample, the characteristics of the lens tend to be similar overall, and the aluminum oxide shows a tendency slightly different from the previous two oxides. This material can be used as a silicone lens material with various nano oxides and polyvinylpyrrolidone (PVP) acting as a dispersant.