• 제목/요약/키워드: aluminium complex

검색결과 43건 처리시간 0.027초

질소와 암모니아 분위기에서 알루미늄(III)의 호박산 및 아디프산 착물의 AlN으로의 변환 (Conversion of Succinate-and Adipate-Coordinated Al(III) Complexes to AlN in $N_2$ and $NH_3$ Atmospheres)

  • 안상경;오창우;정우식
    • 한국세라믹학회지
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    • 제33권4호
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    • pp.455-463
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    • 1996
  • Aluminium nitride (AlN) powder was prepared by using aluminium (III) complexes with dibasic carboxylate ligands(adipato)(hydroxo) aluminium(III) and (hydroxo)(succinato)aluminium (III) as a precursor. The AlN pow-der was obtained by calcining the complexes without mixing any carbon source under a flow of ammonia at 120$0^{\circ}C$ Contary to the conventional carbothermal reduction and nitridiation the process of decarboniza-tion of the residual carbon was not required because of the reaction of ammonia with carbon at temperature >100$0^{\circ}C$. Fine AlN powder was also prepared by calcining a mixture of an (adipato)(hydroxo)aluminium(III) complex and carbon under a flow of nitrogen at 140$0^{\circ}C$ The AlN powders prepared were ultrafine and their morphology was almost the same as that of powders of two precursors.

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흰쥐에서 제산제와 병용투여된 아세글루타미드 알루미늄의 약물동태 및 위장관 부착 (Pharmacokinetics And Gastric Adhesion Of Aceglutamide Aluminium On The Combination Of Antacid In Rats)

  • 조재열;남권호;유은숙;유영효;박명환;박정일
    • 약학회지
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    • 제39권6호
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    • pp.577-584
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    • 1995
  • On the combination of antacid, the pharmacokinetics and gastric adhesion of [$^{14}c$]aceglutamide aluminium complex([$^{14}C$]AGA) were examined in rats. Specially, this study was focused on the drug interaction that the co-administration of antacid may affect the oral absorption and gastric adhesion of aceglutamide aluminium complex(AGA). In the study of the oral co-administration of [$^{14}C$] AGA and antacid(aluminium hydroxide and magnesium hydroxide(AM)), the radioactivity of plasma and urinary recovery was lower than that of [$^{14}C$]AGA alone administered group. However, the cumulative recovery of radioactivity in feces was increased significantly. The comparative bioavailability of [$^{14}C$] AGA from the plasma concentration-time curve and urinary recovery was about 60%. In vitro, the effect of antacid on the gastric adhesion of AGA was not significatly different between AGA and AGA/antacid treatment. And it accorded well with the result of in vivo experiment. In conclusion, on the combination of antacid, the oral absorption of AGA was decreased by the gastric adhesion was not affected in respect of drug interaction.

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Aluminium Based Brazing Fillers for High Temperature Electronic Packaging Applications

  • Sharma, Ashutosh;Jung, Jae-Pil
    • 마이크로전자및패키징학회지
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    • 제22권4호
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    • pp.1-5
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    • 2015
  • In high temperature aircraft electronics, aluminium based brazing filler is the prime choice today. Aluminium and its alloys have compatible properties like weight minimization, thermal conductivity, heat dissipation, high temperature precipitation hardening etc. suitable for the aerospace industry. However, the selection of brazing filler for high temperature electronics requires high temperature joint strength properties which is crucial for the aerospace. Thus the selection of proper brazing alloy material, the composition and brazing method play an important role in deciding the final reliability of aircraft electronic components. The composition of these aluminium alloys dependent on the addition of the various elements in the aluminium matrix. The complex shapes of aluminium structures like enclosures, heat dissipaters, chassis for electronic circuitry, in avionics are designed from numerous individual components and joined thereafter. In various aircraft applications, the poor strength caused by the casting and shrinkage defects is undesirable. In this report the effect of various additional elements on Al based alloys and brazing fillers have been discussed.

로진 싸이즈에 미치는 溫度의 影響에 關하여 (Studies on the Temperature Effect to Rosin Size in Paper Making)

  • 지동범
    • 대한화학회지
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    • 제7권2호
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    • pp.133-139
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    • 1963
  • It is well-known that high temperature hurts the sizing effect of rosin size in paper making, mainly owing to the particle size of rosin-aluminium complex in paper stock. In this experiments, author find, when the temperature of stock rises up. the particle size of rosin-aluminium complex of neutral rosin size increases and the degree of sizing decreases finally. However, the behavior of Bewoid size is quite opposite to former. This result showed that, Bewoid size is suitable in hot summer and neutral rosin size in cold winter for better sizing effect.

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Alum과 PACl을 이용한 응집처리 (Chemical Coagulation Treatment Using Alum and PACl in Complex Wastewater)

  • 성일화
    • 한국환경보건학회지
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    • 제35권1호
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    • pp.53-57
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    • 2009
  • In order to treat the complex wastewater containing organic compound and solids, pre-treatment system associated with molecular separation process were investigated. The reductions of COD and turbidity were obtained after coagulation processes using Alum (Aluminium sulfate, $Al_2(SO_4)_2{\cdot}18H_{2}O$) and PACl (poly aluminium chloride as 17% $Al_{2}O_{3}$). The results of study were as follows: using variable dosage of Alum, COD removal was highest at 4,000 mg/l, and the reduction of COD and turbidity was 42% and 92%, respectively. The optimum coagulation would be effective at pH 7.3 than pH 9.0 by the addition of alum at a concentration of 6,000 mg/l and PACl was add at 4.25% in raw complex wastewater with 2,000 mg/l alum at pH 7.3, the reduction of COD was reduced by 32%. But coagulation aid experiments indicated that PACl would be more effective in sludge separation ability than COD removal efficiency.

아연 착화합물의 입자형성 및 마찰대전량에 미치는 금속염 및 다가알코올 첨가의 영향 (Effects of the Addition of Metallic Salts and Polyhydric Alcohols on the Formation and the Triboelectric Charge of Zinc Complex-compound Particle)

  • 인세진
    • 청정기술
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    • 제19권3호
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    • pp.249-256
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    • 2013
  • 본 연구에서는 프린터 토너의 대전량 제어제로 사용되는 아연 착화합물 제조시 금속염과 다가알코올을 첨가함에 따라 변화되는 입자 형태, 평균 입도 및 마찰대전량에 대해 고찰하였다. 아연 착화합물을 제조하기 위해 염화아연과 3,5-di-tert-butyl salicylic acid를 사용하였다. 다가알코올을 첨가함에 따른 입자 형태 변화를 확인하기 위해 아연 착화합물 제조시 폴리에틸렌 글리콜(PEG-300), 글리세린 및 에틸렌글리콜을 첨가하였고, 금속염인 염화알루미늄을 첨가함으로써 변화되는 입자크기를 확인하였다. 또한 금속염과 다가알코올을 동시에 첨가하여 입도 변화를 확인한 결과, 각각 단독으로 첨가 했을 때보다 아연착화합물의 평균 입도가 더 많이 감소하는 것을 확인할 수 있었다. 특히, 알루미늄 착화합물의 함유량이 30 wt%이고 염화아연에 대한 PEG-300의 몰비를 3으로 하였을 때 아연 착화합물의 평균 입도가 $2.33{\mu}m$로 순수한 아연 착화합물의 평균 입도인 $5.28{\mu}m$의 44.1%로 가장 많이 감소한 것을 알 수 있었다.

라지스케일 칼로리미터에 의한 알루미늄 복합패널 외장재의 연소특성에 관한 연구 (A Study on the Fire Characteristics of Aluminum Composite Panel by Large Scale Calorimeter)

  • 윤정은;민세홍;김미숙;최승복
    • 한국화재소방학회논문지
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    • 제24권2호
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    • pp.89-96
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    • 2010
  • 본 연구에서는 건축외장재로 많이 사용되고 있는 알루미늄복합패널의 화재위험성을 평가하기 위하여 외장재 실물 연소실험을 실시하였다. 그 결과 알루미늄복합패널의 빠른 화재확산을 보였으며, 이는 알루미늄 복합패널에 내장된 폴리에틸렌이 연소되면서 화염의 수직확산이 급격히 일어난 것이다. 본 실험에서 알루미늄복합패널의 최고 열방출률은 1,144kW로 나타났으며, 열전대에 의해 측정된 표면온도는 알루미늄의 용융점인 $660^{\circ}C$를 넘는 최고 $903.3^{\circ}C$ 이상 상승하였다. 그러므로 알루미늄복합패널의 화재는 상층으로의 급격한 연소확대나 개구부를 통한 내부로의 화재확산에 의한 큰 피해를 줄 수 있을 것으로 판단된다. 이러한 실물실험에서 얻어낸 결과는 향후 알루미늄복합패널의 모델링 구현과 비교함으로써 알루미늄복합패널의 화재 확산 예측에 적용 될 수 있을 것이다.

Dynamic numerical simulation of plastic deformation and residual stress in shot peening of aluminium alloy

  • Ullah, Himayat;Ullah, Baseer;Muhammad, Riaz
    • Structural Engineering and Mechanics
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    • 제63권1호
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    • pp.1-9
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    • 2017
  • Shot peening is a cold surface treatment employed to induce residual stress field in a metallic component beneficial for increasing its fatigue strength. The experimental investigation of parameters involved in shot peening process is very complex as well as costly. The most attractive alternative is the explicit dynamics finite element (FE) analysis capable of determining the shot peening process parameters subject to the selection of a proper material's constitutive model and numerical technique. In this study, Ansys / LS-Dyna software was used to simulate the impact of steel shots of various sizes on an aluminium alloy plate described with strain rate dependent elasto-plastic material model. The impacts were carried out at various incident velocities. The influence of shot velocity and size on the plastic deformation, compressive residual stress and force-time response were investigated. The results exhibited that increasing the shot velocity and size resulted in an increase in plastic deformation of the aluminium target. However, a little effect of the shot velocity and size was observed on the magnitude of target's subsurface compressive residual stress. The obtained results were close to the published ones, and the numerical models demonstrated the capability of the method to capture the pattern of residual stress and plastic deformation observed experimentally in aluminium alloys. The study can be quite helpful in determining and selecting the optimal shot peening parameters to achieve specific level of plastic deformation and compressive residual stress in the aluminium alloy parts especially compressor blades.

Prediction of crack trajectory by the boundary element method

  • Bush, M.B.
    • Structural Engineering and Mechanics
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    • 제7권6호
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    • pp.575-588
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    • 1999
  • A boundary element method is applied to the analysis of crack trajectory in materials with complex microstructure, such as discontinuously reinforced composite materials, and systems subjected to complex loading, such as indentation. The path followed by the crack(s) has non-trivial geometry. A study of the stress intensity factors and fracture toughness of such systems must therefore be accompanied by an analysis of crack trajectory. The simulation is achieved using a dual boundary integral method in planar problems, and a single boundary integral method coupled with substructuring in axisymmetric problems. The direction of crack propagation is determined using the maximum mechanical energy release rate criterion. The method is demonstrated by application to (i) a composite material composed of components having the elastic properties of aluminium (matrix) and silicon carbide (reinforcement), and (ii) analysis of contact damage induced by the action of an indenter on brittle materials. The chief advantage of the method is the ease with which problems having complex geometry or loading (giving rise to complex crack trajectories) can be treated.

Azadirachta Indica엑스와 요드화이온이 산성매체에서 Al 부식방지에 대한 Synergistic 효과 (Synergistic Effect of Azadirachta Indica Extract and Iodide Ions on the Corrosion Inhibition of Aluminium in Acid Media)

  • Arab, S.T.;Al-Turkustani, A.M.;Al-Dhahiri, R.H.
    • 대한화학회지
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    • 제52권3호
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    • pp.281-294
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    • 2008
  • Potintiodynamic 분광작용과 임피던스 기술을 이용하여 요드화 이온으로 Azadirachta Indica 엑스가 존재하는 0.5 M HCI용액 속의 Al 에 대한 부식 방지 작용을 상승시켰다. 이는 0.5 M HCI 용액에서 AZI 엑스가 Al의 부식을 방지함을 발견하였다. AZI 엑스 농도가 24% v/v이전에는 농도가 커짐에 따라 방지효율도 따라서 커진다. 하지만 AZI 엑스 농도가 더 커지면 Inh. %는 오히려 작아진다. 요드화 이온의 증가는 방지효율을 상당한 양으로 강화시킨다. 요드화 이온이 혼합적으로 존재할 때 Inh. %값은 증가한다. 이는 낮은 AZI 엑스 농도에서 AZI 엑스는 joint adsorption을 통하여 insoluble complex을 형성한다. 하지만 높은 AZI 엑스 농도에서는 요드화 이온과 형성한 complex사이에 competitive adsorption이 나타나 낮은 Inh. %를 초래한다. At all studied요드화 이온의 농도에서 요드화 이온과 AZI 엑스가 동시에 존재할 때의 Inh. %값은 AZI 엑스만 존재할 때보다 감소된다. Synergism parameter Sq는 표면 Coverage 값으로 계산된다. 이 Parameter는 AZI 엑스경우 unity 보다 더 큼을 알 수 있다. 이는 요드화 이온의 증가로 인하여 방지효율이 강화 되였음을 제시한다.