• Title/Summary/Keyword: aluminium complex

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Conversion of Succinate-and Adipate-Coordinated Al(III) Complexes to AlN in $N_2$ and $NH_3$ Atmospheres (질소와 암모니아 분위기에서 알루미늄(III)의 호박산 및 아디프산 착물의 AlN으로의 변환)

  • 안상경;오창우;정우식
    • Journal of the Korean Ceramic Society
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    • v.33 no.4
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    • pp.455-463
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    • 1996
  • Aluminium nitride (AlN) powder was prepared by using aluminium (III) complexes with dibasic carboxylate ligands(adipato)(hydroxo) aluminium(III) and (hydroxo)(succinato)aluminium (III) as a precursor. The AlN pow-der was obtained by calcining the complexes without mixing any carbon source under a flow of ammonia at 120$0^{\circ}C$ Contary to the conventional carbothermal reduction and nitridiation the process of decarboniza-tion of the residual carbon was not required because of the reaction of ammonia with carbon at temperature >100$0^{\circ}C$. Fine AlN powder was also prepared by calcining a mixture of an (adipato)(hydroxo)aluminium(III) complex and carbon under a flow of nitrogen at 140$0^{\circ}C$ The AlN powders prepared were ultrafine and their morphology was almost the same as that of powders of two precursors.

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Pharmacokinetics And Gastric Adhesion Of Aceglutamide Aluminium On The Combination Of Antacid In Rats (흰쥐에서 제산제와 병용투여된 아세글루타미드 알루미늄의 약물동태 및 위장관 부착)

  • 조재열;남권호;유은숙;유영효;박명환;박정일
    • YAKHAK HOEJI
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    • v.39 no.6
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    • pp.577-584
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    • 1995
  • On the combination of antacid, the pharmacokinetics and gastric adhesion of [$^{14}c$]aceglutamide aluminium complex([$^{14}C$]AGA) were examined in rats. Specially, this study was focused on the drug interaction that the co-administration of antacid may affect the oral absorption and gastric adhesion of aceglutamide aluminium complex(AGA). In the study of the oral co-administration of [$^{14}C$] AGA and antacid(aluminium hydroxide and magnesium hydroxide(AM)), the radioactivity of plasma and urinary recovery was lower than that of [$^{14}C$]AGA alone administered group. However, the cumulative recovery of radioactivity in feces was increased significantly. The comparative bioavailability of [$^{14}C$] AGA from the plasma concentration-time curve and urinary recovery was about 60%. In vitro, the effect of antacid on the gastric adhesion of AGA was not significatly different between AGA and AGA/antacid treatment. And it accorded well with the result of in vivo experiment. In conclusion, on the combination of antacid, the oral absorption of AGA was decreased by the gastric adhesion was not affected in respect of drug interaction.

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Aluminium Based Brazing Fillers for High Temperature Electronic Packaging Applications

  • Sharma, Ashutosh;Jung, Jae-Pil
    • Journal of the Microelectronics and Packaging Society
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    • v.22 no.4
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    • pp.1-5
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    • 2015
  • In high temperature aircraft electronics, aluminium based brazing filler is the prime choice today. Aluminium and its alloys have compatible properties like weight minimization, thermal conductivity, heat dissipation, high temperature precipitation hardening etc. suitable for the aerospace industry. However, the selection of brazing filler for high temperature electronics requires high temperature joint strength properties which is crucial for the aerospace. Thus the selection of proper brazing alloy material, the composition and brazing method play an important role in deciding the final reliability of aircraft electronic components. The composition of these aluminium alloys dependent on the addition of the various elements in the aluminium matrix. The complex shapes of aluminium structures like enclosures, heat dissipaters, chassis for electronic circuitry, in avionics are designed from numerous individual components and joined thereafter. In various aircraft applications, the poor strength caused by the casting and shrinkage defects is undesirable. In this report the effect of various additional elements on Al based alloys and brazing fillers have been discussed.

Studies on the Temperature Effect to Rosin Size in Paper Making (로진 싸이즈에 미치는 溫度의 影響에 關하여)

  • Dong Bum Chi
    • Journal of the Korean Chemical Society
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    • v.7 no.2
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    • pp.133-139
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    • 1963
  • It is well-known that high temperature hurts the sizing effect of rosin size in paper making, mainly owing to the particle size of rosin-aluminium complex in paper stock. In this experiments, author find, when the temperature of stock rises up. the particle size of rosin-aluminium complex of neutral rosin size increases and the degree of sizing decreases finally. However, the behavior of Bewoid size is quite opposite to former. This result showed that, Bewoid size is suitable in hot summer and neutral rosin size in cold winter for better sizing effect.

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Chemical Coagulation Treatment Using Alum and PACl in Complex Wastewater (Alum과 PACl을 이용한 응집처리)

  • Sung, Il-Wha
    • Journal of Environmental Health Sciences
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    • v.35 no.1
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    • pp.53-57
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    • 2009
  • In order to treat the complex wastewater containing organic compound and solids, pre-treatment system associated with molecular separation process were investigated. The reductions of COD and turbidity were obtained after coagulation processes using Alum (Aluminium sulfate, $Al_2(SO_4)_2{\cdot}18H_{2}O$) and PACl (poly aluminium chloride as 17% $Al_{2}O_{3}$). The results of study were as follows: using variable dosage of Alum, COD removal was highest at 4,000 mg/l, and the reduction of COD and turbidity was 42% and 92%, respectively. The optimum coagulation would be effective at pH 7.3 than pH 9.0 by the addition of alum at a concentration of 6,000 mg/l and PACl was add at 4.25% in raw complex wastewater with 2,000 mg/l alum at pH 7.3, the reduction of COD was reduced by 32%. But coagulation aid experiments indicated that PACl would be more effective in sludge separation ability than COD removal efficiency.

Effects of the Addition of Metallic Salts and Polyhydric Alcohols on the Formation and the Triboelectric Charge of Zinc Complex-compound Particle (아연 착화합물의 입자형성 및 마찰대전량에 미치는 금속염 및 다가알코올 첨가의 영향)

  • In, Se-Jin
    • Clean Technology
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    • v.19 no.3
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    • pp.249-256
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    • 2013
  • The experiments have been performed to obtain zinc complex compound with smaller particle sizes, which is used as a charge control agent in manufacturing toner. Metallic salts and polyhydric alcohols have been studied to investigate their effects on the formation and the triboelectric charge of zinc complex-compound particle with different sizes. Reactants such as zinc chloride and 3,5-di-tert.-butyl salicylic acid have been used to form the complex compound. Polyethylene glycol (PEG-300), glycerin and ethylene glycol have been added into the zinc chloride solution beforehand to lower the reaction rate in the formation of zinc complex-compound. Aluminium(III) chloride has been mixed in the zinc chloride solution beforehand to restrain the particle size from growing. When PEG-300 and aluminium(III) chloride are used to lower the reaction rate and to restrain the particle size from growing, the average particle size of zinc complex compound decreases from $5.28{\mu}m$ to $2.33{\mu}m$, which was 44.1% of $5.28{\mu}m$.

A Study on the Fire Characteristics of Aluminum Composite Panel by Large Scale Calorimeter (라지스케일 칼로리미터에 의한 알루미늄 복합패널 외장재의 연소특성에 관한 연구)

  • Yun, Jung-Eun;Min, Se-Hong;Kim, Mi-Suck;Choi, Sung-Bok
    • Fire Science and Engineering
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    • v.24 no.2
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    • pp.89-96
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    • 2010
  • In this research, exterior material combustion experiment was really tested to evaluate fire risks of aluminium complex panel which is used a lot for building exterior material. As a result, We saw fast fire spreading of aluminium complex panel. The reason is polyethylene in aluminum complex panel combust spreading fast fire flame vertically. In this test, the highest heat release rate of aluminum complex panel was 1,144 kW and surface temperature which is measured by thermocouple went up to more than $903.3^{\circ}C$, that temperature is quite a higher than $660^{\circ}C$ which is aluminum melting temperature. So, fire of aluminum complex panel can be evaluated to give us severe damage both by fast fire spreading vertically and by fire spreading through openings internally. These results from real experiment will be able to use to predict fire spreading of aluminum complex panel by comparing to modeling materialization of aluminum complex panel in the future.

Dynamic numerical simulation of plastic deformation and residual stress in shot peening of aluminium alloy

  • Ullah, Himayat;Ullah, Baseer;Muhammad, Riaz
    • Structural Engineering and Mechanics
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    • v.63 no.1
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    • pp.1-9
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    • 2017
  • Shot peening is a cold surface treatment employed to induce residual stress field in a metallic component beneficial for increasing its fatigue strength. The experimental investigation of parameters involved in shot peening process is very complex as well as costly. The most attractive alternative is the explicit dynamics finite element (FE) analysis capable of determining the shot peening process parameters subject to the selection of a proper material's constitutive model and numerical technique. In this study, Ansys / LS-Dyna software was used to simulate the impact of steel shots of various sizes on an aluminium alloy plate described with strain rate dependent elasto-plastic material model. The impacts were carried out at various incident velocities. The influence of shot velocity and size on the plastic deformation, compressive residual stress and force-time response were investigated. The results exhibited that increasing the shot velocity and size resulted in an increase in plastic deformation of the aluminium target. However, a little effect of the shot velocity and size was observed on the magnitude of target's subsurface compressive residual stress. The obtained results were close to the published ones, and the numerical models demonstrated the capability of the method to capture the pattern of residual stress and plastic deformation observed experimentally in aluminium alloys. The study can be quite helpful in determining and selecting the optimal shot peening parameters to achieve specific level of plastic deformation and compressive residual stress in the aluminium alloy parts especially compressor blades.

Prediction of crack trajectory by the boundary element method

  • Bush, M.B.
    • Structural Engineering and Mechanics
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    • v.7 no.6
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    • pp.575-588
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    • 1999
  • A boundary element method is applied to the analysis of crack trajectory in materials with complex microstructure, such as discontinuously reinforced composite materials, and systems subjected to complex loading, such as indentation. The path followed by the crack(s) has non-trivial geometry. A study of the stress intensity factors and fracture toughness of such systems must therefore be accompanied by an analysis of crack trajectory. The simulation is achieved using a dual boundary integral method in planar problems, and a single boundary integral method coupled with substructuring in axisymmetric problems. The direction of crack propagation is determined using the maximum mechanical energy release rate criterion. The method is demonstrated by application to (i) a composite material composed of components having the elastic properties of aluminium (matrix) and silicon carbide (reinforcement), and (ii) analysis of contact damage induced by the action of an indenter on brittle materials. The chief advantage of the method is the ease with which problems having complex geometry or loading (giving rise to complex crack trajectories) can be treated.

Synergistic Effect of Azadirachta Indica Extract and Iodide Ions on the Corrosion Inhibition of Aluminium in Acid Media (Azadirachta Indica엑스와 요드화이온이 산성매체에서 Al 부식방지에 대한 Synergistic 효과)

  • Arab, S.T.;Al-Turkustani, A.M.;Al-Dhahiri, R.H.
    • Journal of the Korean Chemical Society
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    • v.52 no.3
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    • pp.281-294
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    • 2008
  • synergistic action caused by iodide ions on the corrosion inhibition of aluminium (Al) in 0.5 M HCl in the presence of Azadirachta Indica (AZI) plant extract has been investigated using potintiodynamic polarization and impedance techniques. It is found that AZI extract inhibits the corrosion of aluminium in 0.5 M HCl. The inhibition efficiency increases with the increase in AZI extract concentration, until 24% v/v of AZI extract, then Inh.% is decreased with father increase in AZI extract concentration. The adsorption of this extract in the studied concentration is found to obey Frewendlish adsorption isotherm. The addition of iodide ions enhances the inhibition efficiency to a considerable extent. The increase in Inh.% values in presence of fixed concentration of iodide ions indicates that AZI extract forms an insoluble complex at lower AZI extract concentrations by undergoing a joint adsorption. But at higher concentrations of AZI extract, competitive adsorption is found between iodide ions and the formed complex leading to less Inh.%.The Inh.% decreased in presence of iodide ions with AZI extract than in presence of AZI extract alone at all studied iodide concentrations. The synergism parameter Sq is defined and calculated from surface coverage values. This parameter in the case of AZI extract is found to be more than unity, indicating that the enhanced inhibition efficiency caused by the addition of iodide ions.