• 제목/요약/키워드: alkali-activated

검색결과 256건 처리시간 0.026초

플라이애시와 슬래그 혼합 알칼리 활성 시멘트의 미세구조 특성 (Microstructural Characteristics of Alkali-Activated Cements Incorporating Fly Ash and Slag)

  • 장정국
    • 도시과학
    • /
    • 제7권1호
    • /
    • pp.39-43
    • /
    • 2018
  • This study investigates microstructural characteristics of alkali-activated cements incorporating slag and fly ash. Samples were prepared with four fly ash:slag ratios, i.e., 100:0, 90:10, 70:30 and 50:50, and they were synthesized by using an alkali activator. Microstructural characteristics of the alkali-activated cements were determined by XRD, TGA, SEM, N2 gas adsorption/desorption methods, and compressive strength test. The results showed that properties of alkali-activated fly ash/slag were significantly affected by slag contents. Alkali-activated fly ash/slag with slag content of 30-50% showed higher compressive strength than ordinary Portland cement paste. An increase in slag content resulted in a denser microstructure, which composed of amorphous gel, therefore contributed to strength development of the material.

알칼리활성화 슬래그-레드머드 흙포장재의 레드머드 대체율에 따른 기공특성 (Porosity of Alkali-Activated Slag-Red Mud Soil Mixed Pavement of Red Mud Substitution Rate)

  • 강혜주;김병기;김재환;강석표
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2016년도 추계 학술논문 발표대회
    • /
    • pp.91-92
    • /
    • 2016
  • Red mud is an inorganic by-product produced from the mineral processing of alumina from Bauxite ores. the development of alkali-activated slag-red mud cement can be a representative study aimed at recycling the strong alkali of the red mud as a construction material. This study is to investigate the pore characteristics of alkali-activated slag-red mud soil pavement according to the red mud content. The results showed that the porosity of alkali-activated slag-red mud soil pavement increased but the compressive strength of that decreased as the red mud content increased.

  • PDF

A Preliminary Study on Alkali Activation of Waste Concrete Powder

  • 사수이;김규용;유하민;이예찬;편수정;남정수
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2023년도 봄 학술논문 발표대회
    • /
    • pp.303-304
    • /
    • 2023
  • In this study, the effects of NaOH and KOH alkali activators of various concentrations on the performance of alkali activated waste concrete powder (WCP) was discussed. The samples activated by alkaline solutions were cured for up to 28 days and then compressive strength test was performed. These samples were also characterized using various techniques to explore the phase evolution, and microstructural changes. Results showed superior performance of NaOH-activated WCP. Additionally, activation of WCP by 8M concentrated alkali solutions improved the strength, reactivity and microstructure of alkali activated WCP binder sample.

  • PDF

알칼리활성화 슬래그-레드머드 흙포장재의 레드머드 대체율에 따른 백화 특성 (Efflorescence Characteristics of Alkali-Activated Slag-Red Mud Soil Mixed Pavement of Red Mud Substitution Rate)

  • 강혜주;이영원;오두연;이규영;강석표
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2015년도 추계 학술논문 발표대회
    • /
    • pp.153-154
    • /
    • 2015
  • This study is alkali-activated slag-red mud soil mixed pavement of efflorescence characteristics analysis of mitigation measures is drawn to the red mud substitution rate in accordance with the alkali-activated slag-red mud soil mixed pavement of efflorescence characteristics were exhibited. As a result of alkali-activated slag-red mud soil mixed pavement is more substitution rate increases appeared to efflorescence is increased.

  • PDF

PVA 섬유와 실리카흄 첨가가 알칼리 활성 슬래그의 염화물 침투 저항성에 미치는 영향 (Effect of PVA Fiber and Silica Fume Addition on Chloride Penetration Resistance of Alkali-Activated Slag)

  • 윤현노
    • 도시과학
    • /
    • 제12권2호
    • /
    • pp.13-18
    • /
    • 2023
  • This study investigates the effect of polyvinyl alcohol (PVA) fiber and silica fume addition on the chloride penetration resistance of alkali-activated slag. Silica fume was added to replace slag at the dosage of 0, 5, 10, and 20% by weight of the binder, while PVA fiber was added at the dosage of 0, 1, and 2% by volume of the mixture. Samples were synthesized via alkali activator with 1.0 of silicate modulus and cured at room temperature for 28 days. Compressive strength test, permeable voids volume test, water absorprtion test, and rapid chloride penetration test were conducted for measuring the charaterisitics of alkali-activaed slag. The results showed that increasing silica fume content up to 10% in alkali-activated slag improved compressive strength and chloride penetration resistance. Addition of PVA fibers up to 1% by volume enhanced strength and chloride penetration resistance, but exceeding this led to reduced strength and durability due to increased void formation in the matrix.

알칼리 활성화 슬래그 시멘트 모르타르의 내황산성 (Resistance of Alkali Activated Slag Cement Mortar to Sulfuric Acid Attack)

  • 민경산;이승헌
    • 한국세라믹학회지
    • /
    • 제44권11호
    • /
    • pp.633-638
    • /
    • 2007
  • The setting time of alkali activated slag cement tends to be much faster than ordinary Portland cement, and its compressive strength had been higher from the 1 day but became lower than that of the cement on the 28 days. According to the results of the surface observation, weight loss, compressed strength, and erosion depth tests on the sulphuric acid solution. It has been drawn that alkali activated slag cement has a higher sulphate resistance than ordinary Portland cement, and in particular, the alkali activated slag cement added 5 wt% alumina cement has little deterioration on the sulphuric acid solution. The reason why the alkali activated slag cement has higher sulphate resistance than other hardened cement pastes is that it has no $Ca(OH)_2$ reactive to sulphate ion, and there is little $CaSO_4{\cdot}2H_2O$ production causing volume expansion, unlike other pastes. And it is supposed that $Al(OH)_3$ hydrates with high sulphate resistance, which is produced by adding the alumina cement increases the sulfate resistance.

고온에서의 알칼리 활성화 내화성 결합재의 강도 및 공극구조 평가 (Estimation of Strength and Pore Structure of Alkali-Activated Fire Protection Materials at High Temperature)

  • 송훈;김영호;김완기;소형석
    • 한국디지털건축인테리어학회논문집
    • /
    • 제12권4호
    • /
    • pp.59-66
    • /
    • 2012
  • This study is interested in identifying the effectiveness of alkali-activated fire protection material compounds including the alkali-activator such as potassium hydroxide, sodium silicate and fly ash as the fire resistant finishing materials. Also, this paper is concerned with change in compressive strength and pore structure of the alkali-activated fire protection material at high temperatures. The testing methods of fire protection materials in high temperature properties are make use of TG-DSC and mercury intrusion porosimetry measurements. This study results show that compressive strength is rapidly degraded depending on a rise of heating temperature. Porosity showed a tendency to increase irrespective of specimen types. This is due to both the outbreak of collapse of gel comprising the cement and a micro crack by heating. However, alkali-activated fire protection material composed of potassium hydroxide, sodium silicate and fly ash has the thermal stability of the slight decrease of compressive strength and porosity at high temperature. These thermal stability is caused by the ceramic binding capacity induced by alkali activation reaction by the reason of the thermal analysis result not showing the decomposition of calcium hydrate.

Hydration Mechanism of Alkali Activated Slag Cement

  • Jong Cheol Kim;Keun Ho Auh;Sung Yun Hong
    • The Korean Journal of Ceramics
    • /
    • 제5권1호
    • /
    • pp.35-39
    • /
    • 1999
  • For many years, alkali activated blast furnace slag cement containing no ordinary portland cement has received much attention in the view of energy saving and its many excellent properties. We examined the structural change of slag glass which was activated by alkali metal compounds using IR spectroscopy. The properties of hydrated products and unhydrated slag grains was characterized by XRD and micro-conduction calorimeter. Ion concentration change in the liquid during the hydration of blast furnace slag was also studied to investigated the hydration mechanism.

  • PDF

순환골재를 사용한 알칼리활성화 슬래그-레드머드 흙포장재의 특성 (Properties of Alkali-activated Slag-Red Mud Soil Pavement Using Recycled Aggregate)

  • 강석표
    • 한국건설순환자원학회논문집
    • /
    • 제4권3호
    • /
    • pp.276-283
    • /
    • 2016
  • 레드머드는 보오크사이트 원광석에서 생산되는 알루미나의 선광과정에서 발생되는 무기질 부산물이다. 인 레드머드를 활용하고자 하는 연구가 국내에서 이루어지고 있다. 강알카리성의 레드머드를 건설산업용 촉진제로서 활용하고자 하는 연구로서 알칼리활성화 슬래그-레드머드 시멘트가 국내외적으로 발표되고 있다. 본 논문은 순환골재 대체율에 따른 알칼리활성화 슬래그-레드머드 건식 흙포장재의 최적함수율, 압축강도, 흡수율, 백화발생 특성에 대하여 비교 검토하였다. 그 결과 순환골재 대체율이 증가할수록 알칼리활성화 슬래그-레드머드 흙포장재의 최적 함수비, 물흡수계수, 백화면적은 증가하고 압축강도는 감소하였다.

알칼리 자극제를 혼입한 고로슬래그 모르타르의 건조수축 특성에 관한 실험적 연구 (An Experimental Study on the Properties of Drying Shrinkage for Alkali-Activated Slag Mortar)

  • 천정환;김재훈;지남용
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2006년도 춘계학술논문 발표대회 제6권1호
    • /
    • pp.97-100
    • /
    • 2006
  • This paper report the result of the investigation on the properties of drying shrinkage for alkali-activated slag mortar in different relative humidity Commonly we know that drying shrinkage means lost more moisture but the mechanism of drying shrinkage of alkali activated slag mortar is not entirely due to the quantity of weight loss of water from mortar. pore size distribution and the calcium silicate hydrate gel characteristics have a critical influence on the magnitude of drying shringkage to alkali activated slag mortar. For this investigation, Ca(OH)2, Na2SiO4 were as alkali activator with 5 dosages(6%, 9%, 12%, 15%, 20%) and curing condition were three different relative humidity(35%, 65%, 95%) at $20{\pm}3^{\circ}C$

  • PDF