• Title/Summary/Keyword: alkali material

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Consideration of Alkali-Silica Reaction of Mortar Containing Glass Abrasive Sludge (유리 연마슬러지를 혼합한 모르타르의 알칼리-실리카 반응에 관한 고찰)

  • Lee, Seung-Heun;Hwang, Hae-Jeong;Lee, Seung-Tae;Kim, Ki-Dong
    • Journal of the Korean Ceramic Society
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    • v.44 no.9
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    • pp.510-516
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    • 2007
  • After observing the alkali-silica reaction of the mortar that contains glass abrasive sludge, when evaluating it by a mineral or chemical point of view, it contained reactive silica $(59{\sim}67%)$ and $R_20$ elements $(4.3{\sim}9.8%)$. Also, when evaluated by the mortar bar method, an addition of 5 wt% of CRT glass abrasive sludge is judged harmless. However when adding more, there appear severe contractions, thus carefulness is needed while using. Less than 0.10% of expansion was measured when adding up to 30wt% of flat glass abrasive sludge. However, after 30 days of the measurement, more than 0.1% rate of expansion was measured when adding more than 5 wt%. Therefore, more detailed experiments are needed in case of more than 5 wt%.

Properties of Alkali-activated Slag-Red Mud Soil Pavement Using Recycled Aggregate (순환골재를 사용한 알칼리활성화 슬래그-레드머드 흙포장재의 특성)

  • Kang, Suk-Pyo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.3
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    • pp.276-283
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    • 2016
  • Red mud is an inorganic by-product produced from the mineral processing of alumina from Bauxite ores. the development of alkali-activated slag-red mud cement can be a representative study aimed at recycling the strong alkali of the red mud as a construction material. This study is to investigate the optimum water content, compressive strength, moisture absorption coefficient and efflorescence of alkali-activated slag-red mud soil pavement according to the recycling fine aggregate content. The results showed that the optimum water content, moisture absorption coefficient and efflorescence area of alkali-activated slag-red mud soil pavement increased but the compressive strength of that decreased as the recycled fine aggregate content increased.

Quantitative Variation of Alkali-soluble Extracts from Coniferous Barks for Tannin-based Adhesives (타닌접착제를 위한 침엽수 수피의 알칼리성 추출물의 양적 변이)

  • Cho, Nam-Seok;Kim, Young-Sin;Han, Gyu-Seong
    • Journal of the Korean Wood Science and Technology
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    • v.25 no.1
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    • pp.23-27
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    • 1997
  • Alkali-soluble extracts were prepared from barks of Japanese larch(Larix leptolepis). Siberian larch(Larix gmelineii) and Radiata pine(Pinus radiata) The effect of various factors, such as particle size, liquor ratio, extraction temperature, and reaction time, on the extracts yield was investigated. Particle sizes affected the alkali-soluble extracts; the finer the particle size, the higher extracts and extract efficiency. High temperature and high liquor ratio were more effective. In the range of 0.25% to 1% NaOH concentration, alkali extracts were increased with the increasing alkali concentration. However, extract yields were leveled off above 0.5% alkali concentration. Extractions with NaHCO3 were almost equivalent to those of NaOH extraction. 1% NaOH and 1% NaHCO3 resulted in the highest yields of alkaline extracts. Extracts from Japanese larch were lower than those from Siberian larch and Radiata pine barks. Siberian larch bark was the best raw material for tannin adhesives, because its extractive yield was higher than those of the other barks. Concerning pH of alkaline media during extraction, small increases of the extract yields were resulted at range of pH 7 to pH 9, while a large increases from pH 9.0 to pH 12. This phenomenon is attributed to higher alkalinity.

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A Study on the Effects of Fire-Resistant Coating Materials for Prevention of Concrete Spalling (콘크리트 폭렬 저감에 대한 내화 피복재의 영향에 관한 연구)

  • Jeong, Eui-Dam;Song, Myong-Shin;Kang, Hyun-Ju;Kang, Seung-Min
    • Journal of the Korean Society of Hazard Mitigation
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    • v.10 no.5
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    • pp.9-15
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    • 2010
  • Recently, the high-compressive strength concrete where the use is extending was weak in fire because of spalling that was occurring with rise of internal vapor pressure by high temperature. For preventing spalling of high-strength concrete in fire, Organic fibers have been using in concrete generally. By melting of organic fibers in concrete in fire, the internal moistures of concrete moves quickly to the outside, and so, preventing of spalling of high-strength concrete. But this method will be able to prevent the spalling of high-strength concrete, but makes the decrease of the concrete strength after fire. This study make a comparison between properties of preventing of spalling and remaining compressive strength of concrete using intumescence Alkali-Silicates fire-resistant material and that of concrete with organic fibers. Using organic fibers for preventing of spalling of concrete are P.P and Nylon fibers, and anti-fire intumescence material for protection of concrete surface is alkali-silicate materials. Fire resistance test executed as long as 3 hr under the flame temperature $1,200^{\circ}C$ over. In the case of concrete with P.P fibers, don't occurred the spalling, but the remaining compressive strength will not be able to measure, the concrete using intumescence Alkali-Silicates system fire-resistant material is not only preventing of the spalling but also the remaining compressive strength maintained until the maximum 96%.

A Fundamental study on the Characteristics of Zeolite Cement Mortar (제올라이트 시멘트 모르타르의 재료적 특성에 관한 기초 연구)

  • Jo, Byung-Wan;Kang, Suk-Won;Park, Seung-Kook;Choi, Ji-Sun
    • Journal of the Korea Concrete Institute
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    • v.23 no.2
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    • pp.203-209
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    • 2011
  • The cement industry is expected to face a major set-back in the near future due to its large energy consumption and $CO_2$ production, causing global warming. In order to overcome these environmental problems, this research has bee carried out to find a cement substitute material. One possible cement substitute material is Zeolite cement. In this study, the materialistic characteristics of Zeolite cement mortar were evaluated. Natural Zeolite cement mortar was prepared using alkali activation (NaOH) instead of water ($H_2O$) to determine achievable strength and appropriate mixing ratio. Based on the mixing ratio, functional material was added to alkali active agent to harden Zeolite mortar to develop a highly functional construction material. The study result showed that pure Zeolite cement mortar achieved compressive strength of 42 MPa in 7 days depending on the mixing amount of alkaline catalyst and the hardening temperature, showing high efficiency and possibility as a new construction material.

Studies on the Enzymatic Hydrolysis of Lignocellulosic Materials for the Alternative Fuels (II) - The Effect of Delignification Treatment on the Enzymatic Hydrolysis of Steam - Exploded Woods - (대체연료(代替燃料) 생산(生産)을 위한 목질재료(木質材料)의 가수분해(加水分解)에 관한 연구(硏究)(II) - 탈(脫)리그닌처리가 폭쇄처리재(爆碎處理材)의 효소적(酵素的) 당화(糖化)에 미치는 영향(影響) -)

  • Cho, Nam-Seok
    • Journal of the Korean Wood Science and Technology
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    • v.18 no.4
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    • pp.18-25
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    • 1990
  • As polysaccharides in lignocellulosic materials are encrusted with aromatic lignin molecules and have high crystallinity, these require pretreatment to improve their digestability by cellulolytic enzymes. Though a number of pretreatment methods have been proposed, the steam explosion process is evaluated as a promising method. This study was performed to investigate the effect of delignification treatment by alkali, methanol and the others on the enzymatic hydrolysis. Delignification treatment resulted in great increase rate in enzymatic hydrolysis. Concerning to the effect of delignication reagents on the enzymatic hydrolysis, methanol treatment was more effective than alkali in the case of oak wood. In pine wood, the delignification did not showed any significant enhancement of hydrolysis rate. Complete delignification by Alkali-Oxygen. Alkali treatment showed high saccharification rate of 99.5%.

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Flowability Properties of Alkali Activated Mortar (알칼리 활성 모르타르의 유동특성)

  • Lee, Gun-Young;Lee, Gun-Cheol;Park, Ji-Woong
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.05a
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    • pp.205-206
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    • 2016
  • This study examines the effect of binding material and alkali activator on the rheology characteristics of alkali active mortar quantitatively, and a result is as follows. In the 1/2 slump flow, the higher mixing ratio of the fly ash has been shown to increase the table flow. the reason is that fly ash ball bearing action. When viewed in the consistency curve, the higher mixing ratio of the blast furnace slag powder was higher shear stress.

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Effect of the Combined Using of Fly Ash and Blast Furnace Slag as Cementitious Materials on Properties of Alkali-Activated Mortar (결합재(結合材)로 플라이애시와 고로(高爐)슬래그의 혼합사용(混合使用)이 알칼리 활성(活性) 모르타르의 특성(特性)에 미치는 영향(影響))

  • Koh, Kyung-Taek;Kang, Su-Tae;Park, Jung-Jun;Ryu, Gum-Sung;Lee, Jang-Hwa;Kang, Hyun-Jin
    • Resources Recycling
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    • v.19 no.4
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    • pp.19-28
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    • 2010
  • Attempts to increase the utilization of a by-products such as fly ash and blast furnace slag to partially replace the cement in concrete are gathering momentum. But most of by-products is currently dumped in landfills, thus creating a threat to the environment. Many researches on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. However, most study deal only with alkali-activated blast furnace slag or fly ash, as for the combined use of the both, little information is reported. In this study, we investigated the influence of mixture ratio of fly ash/slag, type of alkaline activator and curing condition on the workability and compressive strength of mortar in oder to develop cementless alkali-activated concrete. In view of the results, we found out that the mixture ratio of fly ash/slag and the type of alkaline activator always results to be significant factors. But the influence of curing temperature in the strength development of mortar is lower than the contribution due to other factors. At the age of 28days, the mixture 50% fly ash and 50% slag activated with 1:1 the mass ratio of 9M NaOH and sodium silicate, develop compressive strength of about 65 MPa under $20^{\circ}C$ curing.

Properties of Intumescence Alkali Silicates for Building Fire-Resistant (건축용 내화 재료로서의 포비성 알칼리 규산염의 특성에 관한 연구)

  • Kang, Hyun Ju;Kang, Seung Min;Song, Myong Shin;Kim, Young Sik;Park, Jong Hun
    • Applied Chemistry for Engineering
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    • v.20 no.4
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    • pp.416-422
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    • 2009
  • The buildings constructed with steel structure are coated with certified fire resistive material to resist from fire. All the building materials lose their initial performances as time passes by, so they need some maintenance. The Sprayed Fire Resistive Material (SFRM) also loses its performance and this performance loss of the SFRM is very important because fire resistance of buildings depends on SFRM. So this study was aimed to synthesis of alkali-silicates for SFRM and to evaluate the effect of alkali-silicates, K-silicates, Na-silicates and Li-silicates, by exchange of mole ratios as basic factors, tested solubility, intumescence ratios, thermal analysis, powder X-ray diffraction, fire-resistant and heat-resistant.

Fundamental Study of Alkali-Activated Concrete Properties based on Modified Slag (개질 슬래그 기반 알칼리 활성 콘크리트의 기본 물성 연구)

  • An, Ji-Hwan;Jeon, Sung-Il;Kwon, Soo-Ahn
    • International Journal of Highway Engineering
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    • v.17 no.2
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    • pp.1-11
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    • 2015
  • PURPOSES : This study set out to investigate the fundamental properties of alkali-activated concrete (AAC) using modified slag as the pavement maintenance material. METHODS: The material properties of modified slag based alkali-activated concrete (MSAAC) were analyzed and evaluated against those of alkali-activated slag concrete (AASC). Several mix formulations were considered, including one MSACC and four AASCs. The main variables considered in the study were slump, air content, compressive strength, rapid chloride permeability test, scaling resistance, freeze-thaw test, XRD, SEM, and EDS. RESULTS: MSAAC exhibits a compressive strength in excess of 21 MPa six hours after curing. Also, the charge passed of the MSACC was found to be less than 2000 coulombs after seven days and about 1000 coulombs after 28 days. The weight loss determined from a scaling test did not exceed $1kg/cm^2$ in the case of the MSACC, but that of the AASCs had already exceeded $1kg/cm^2$ at the 10th cycle. Based on the results of the freeze-thaw test, the relative dynamic modulus of every mix was found to be in excess of 90%. An energy dispersive spectroscopy(EDS) analysis found that the weight rate percentage of the calcium and aluminum in the MSAAC mix is twice that of the AASC mixes. CONCLUSIONS : It was found that the MSAAC mix exhibits significantly better performance than AASC mixes, based on various fundamental properties.