• Proceedings of the Korea Concrete Institute Conference
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• 2005.11a
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• pp.627-630
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• 2005

This paper examines degradation properties of alkali-activated alumino-silicate composite body by NAS solution exposed to high temperature. Activators include sodium hydroxides and sodium silicate solution. In the result of experiment, flexural and compressive strength of AAS base mortar exposed to high temperature ($400\~600^{\circ}C$) was higher than alumina cement base mortar. Particularly, In case of compressive strength, alumina cement base mortar was decreased by about $60\~70\%$. While, AAS base mortar exposed to high temperature ($400\~600^{\circ}C$) was higher than that curing by room temperature. The above results showed that AAS base inorganic binder has a good mechanical properties exposed to high temperature($400\~600$).

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.1
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• pp.63-71
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• 2011

Portland cement production is under critical review due to high amount of $CO_2$ gas released to the atmosphere. Attempts to increase the utilization of a by-products such as fly ash and ground granulated blast-furnace slag to partially replace the cement in concrete are gathering momentum. But most of by-products is currently dumped in landfills, thus creating a threat to the environment. Many researches on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. In this study, we investigated the influence of alkali activator and superplasticizer on the flowability and compressive strength of the alkali-activated mortar in oder to develop cementless alkali-activated concrete using blast furnace slag. In view of the results, we found out that the type and mixture ratio of alkali activator, the type and adding order of superplasticizer results to be significant factors. When cementless alkali-activated mortar using blast furnace slag manufactured with 1:1 the mass ratio of 9M NaOH and sodium silicate, and added superplasticizer before alkali activator in the mixer, we can be secured workability with 180 mm of flow during 1 hours and compressive strength of about 50 MPa under $20^{\circ}C$ curing condition at age of 28days.

• Journal of the Korea Institute of Building Construction
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• v.17 no.3
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• pp.261-268
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• 2017

Red mud is an inorganic by-product obtained from the mineral processing of alumina from Bauxite ores. A highly alkali inorganic waste product with a pH level over 11, red mud in its original state negatively impacts the ecosystem, so appropriate treatment is necessary. The development of alkali activated slag-red mud cement can be a representative study aimed at recycling the strong alkali of the red mud as a construction material. However, Alkali-activated binders that use sodium activators have been reported to be more vulnerable to efflorescence. Therefore, in this study, the compressive strength, pore characteristics, water absorption, elution characteristics, and efflorescence properties of alkali-activated slag cement mortar were assessed according to their red mud substitution ratio.

• Resources Recycling
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• v.18 no.2
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• pp.39-50
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• 2009

Portland cement production is under critical review due to high amount of $CO_2$ gas released to the atmosphere. Attempts to increase the utilization of fly ash, a by-products from thermal power plant to partially replace the cement in concrete are gathering momentum. But most of fly ash is currently dumped in landfills, thus creating a threat to the environment. Many researches on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. Instead, the source of material such as fly ash, that are rich in Silicon(Si) and Aluminium(Al), are activated by alkaline liquids to produce the binder. Hence concrete with no cement is effective in the reduction of $CO_2$ gas. In this study, we investigated the influence of the compressive strength of mortar on alkaline activator and curing condition in order to develop cementless fly ash based alkali-activated concrete. In view of the results, we found out that it was possible for us to make alkali-activated mortar with 70MPa at the age of 28days by using alkaline activator manufactured as 1:1 the mass ratio of 9M NaOH and sodium silicate and applying the atmospheric curing after high temperature at $60^{\circ}C$ for 48hours.

• Journal of the Korea Concrete Institute
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• v.23 no.4
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• pp.487-494
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• 2011

In this research, the possibility of using bottom ash as a binder for the alkali-activated cement mortar is studied. Several experiments were performed to investigate the variation of the material properties according to the mix proportion. In the experimental program, the flowability and compressive strength were evaluated for various values of water/ash ratio, activator/ash ratio, sodium silicate to sodium hydroxide ratio, curing temperature, and the fineness of bottom ash as the main variables. The experimental results showed that high strength of 40 MPa or greater could be achieved in $60^{\circ}C$ high temperature curing condition with proper flowability. For $20^{\circ}C$ ambient temperature curing, the 28 days compressive strength of approximately 30MPa could be obtained although the early-age strength development was very slow. Based on the results, the range of optimized mix design of bottom-ash based alkali-activated cement mortar was suggested. In addition, using the artificial neural network analysis, the flowability and compressive strength were predicted with the difference in the mix proportion of the bottom-ash based alkali-activated cement mortar.

• Proceedings of the Korea Concrete Institute Conference
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• 2009.05a
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• pp.393-394
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• 2009

Recently, various researchers have studied alkali-activated concrete that do cementless as the binder. This study analyzed the effect on alkali-activated mortar by fineness of blast slag as the binder with no use of cement, by observing workability and compressive strength.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.4
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• pp.114-121
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• 2010

Portland cement production is under critical review due to high amount of CO2 gas released to the atmosphere. Attempts to increase the utilization of a by-products such as fly ash and ground granulated blast-furnace slag to partially replace the cement in concrete are gathering momentum. But most of by-products is currently dumped in landfills, thus creating a threat to the environment. Many researches on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. However, most study deal only with alkali-activated ground granulated blast furnace slag or fly ash, as for the combined use of the both, little information is reported. In this study, we investigated the influence of mixture ratio of fly ash/ blast furnace slag tand curing condition on the flowability and compressive strength of mortar in oder to develop cementless alkali-activated concrete. In view of the results, we found out that the mixture ratio of fly ash/blast furnace slag always results to be significant factors. But the influence of curing temperature in the strength development of mortar is lower than the contribution due to other factors. At the age of 28days, the mixture 50% fly ash and 50% ground granulated blast furnace slag activated with 1:1 the mass ratio of 9M NaOH and sodium silicate, develop compressive strength of about 65 MPa under $20^{\circ}C$ curing.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2018.05a
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• pp.240-241
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• 2018

In this paper, we tried to find the proper ratio of industrial byproducts which can express mechanical characteristics similar to ordinary portland cement by varying the ratio of industrial byproducts. as a result, the activated slag binder produced by the industrial byproduct in this study increased in compressive strength as the ratio of blast furnace slag increased and the fly ash ratio decreased.

• Journal of the Korea Concrete Institute
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• v.25 no.3
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• pp.305-312
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• 2013

This paper reports the results of an investigation into the effects of silica fume on strength properties of alkali-activated slag cement (AASC) with water-binder (W/B) ratio and replacement ratio of silica fume content. The W/B ratio varied between 0.50 and 0.60 at a constant increment of 0.05. The silica fume content varied from 0% to 50% by weight of slag. The activators was used sodium hydroxide (NaOH) and the dosage of activator was 3M. The strength development with W/B ratio has been studied at different ages of 1, 3, 7 and 28 days. For mixes of AASC mortars with varying silica fume content, the flow values were lower than the control mixes (without silica fume). The flow value was decrease as the content of silica fume increase. This is because the higher surface areas of silica fume particles increase the water requirement. The analysis of these results indicates that, increasing the silica fume content in AASC mortar also increased the compressive strength. Moreover, the strength decreases with the W/B ratios increases. This is because the particle sizes of silica fume are smaller than slag. The high compressive strength of blended slag-silica fume mortars was due to both the filler effect and the activated reaction of silica fume evidently giving the mortar matrix a denser microstructure, thereby resulting in a significant gain in strength.

• Resources Recycling
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• v.19 no.4
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• pp.19-28
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• 2010

Attempts to increase the utilization of a by-products such as fly ash and blast furnace slag to partially replace the cement in concrete are gathering momentum. But most of by-products is currently dumped in landfills, thus creating a threat to the environment. Many researches on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. However, most study deal only with alkali-activated blast furnace slag or fly ash, as for the combined use of the both, little information is reported. In this study, we investigated the influence of mixture ratio of fly ash/slag, type of alkaline activator and curing condition on the workability and compressive strength of mortar in oder to develop cementless alkali-activated concrete. In view of the results, we found out that the mixture ratio of fly ash/slag and the type of alkaline activator always results to be significant factors. But the influence of curing temperature in the strength development of mortar is lower than the contribution due to other factors. At the age of 28days, the mixture 50% fly ash and 50% slag activated with 1:1 the mass ratio of 9M NaOH and sodium silicate, develop compressive strength of about 65 MPa under $20^{\circ}C$ curing.