• Title/Summary/Keyword: alcohol gas

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Marketing of cleaned fresh ginseng and pre-packaging fumigation of 2-phenylethyl alcohol on ginseng storability (세척인삼 유통 현황과 포장전 2-phenylethyl Alcohol 훈증이 저장성에 미치는 영향)

  • Kim, Sun-Ik;Sung, Bong-Jae;Kim, Hyeon-Ho;Hwang, Yong-Soo
    • Korean Journal of Agricultural Science
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    • v.38 no.2
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    • pp.205-212
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    • 2011
  • The potential factors for quality loss of cleaned fresh ginseng and technology to be associated with the improvement of marketability through pre-packaging fumigation were examined. Major microorganisms isolated from fresh ginseng included Botrytis cinerea, and Erwinia sp. Others such as Cylindrocarpon sp., Fusarium spp., Pennicilium spp., Bacillus spp. were also found at relatively low frequency. The bacterial density of vacuum packaged fresh ginseng rapidly increased during simulated marketing. Little correlation between bacterial growth and package swelling was found. In order to improve packaging method of fresh ginseng, pre-packaging treatment of 2-phenylethyl alcohol (PE, 100 uL/L, 4 hr) was examined. The fumigation treatment effectively inhibited the growth of bacteria density and also effective on keeping firmness of ginseng root, especially in cortical portion. The internal gas compositions of plastic container packaged for ginseng were approximately ranged between 6 to 8% $O_2$and 3 to 4% $CO_2$. The $O_2$ level of fumigation treatment was lower than control whereas $CO_2$ level was higher. The upsurge of ethylene evolution I day after simulated marketing was found only in fumigation treatment but it returned to ordinary level at day 2. The sucrose content of 2-PE treatment was significantly reduced at 5 days after simulated marketing but reducing sugars like glucose and fructose remained at higher level. The difference in sugar levels was reduced after 10 days of simulated marketing. The decay of fresh ginseng began at the lateral or fine root, which is weak to physical damage, in general. The epidermis was more damaged. Plastic container packaging with PE fumigation could be an alternative to vacuum packaging, which allows an aerobic environment and prevents anaerobic respiration. Further study of pre-package fumigation is required to improve technology of fresh ginseng marketing.

Performance Investigation of Water Vapor Permeation Using PVA/PSSA-MA Membranes (PVA/PSSA-MA막을 이용한 수증기 투과 성능에 관한 연구)

  • Rhim Ji-Won;Yun Tae-Il;Seo Moo-Young;Cho Hyun-Il;Ha Seong-Yong;Nam Sang-Yong
    • Membrane Journal
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    • v.16 no.2
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    • pp.153-158
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    • 2006
  • The crosslinked poly(vinyl alcohol) (PVA) mwmbranes with poly(styrene sulfonic acid-co-maleic acid) (PSSA-MA) were used to measure the water vapor and air permeabilities at 25 and $35^{\circ}C$. In addition, the contact angles of crosslinked PVA membranes were observed and increased with PSSA-MA contents. The water vapor permeability of 15300 Baller (1 Baller=$10^{-10}cm^3(STP){\cdot}cm/cm^2{\cdot}s{\cdot}cmHg$) was shown the maximum value at $35^{\circ}C$ when PSSA-MA=7 wt% membrane was used. The gas permeability of 146 Barrer was indicated the maximum at PSSA-MA=7 wt% at $35^{\circ}C$ and $P(H_2O)/P(Air)$ was the highest value 109.2 at $25^{\circ}C$.

Volatile Flavor Components in Watermelon(Citrullus vulgaris S.) and Oriental Melon(Cucumis melo L.) (국내산 수박(Citrullus vulgaris S.) 과 참외(Cucumis melo L.) 의 휘발성 향기성분)

  • Kim, Kyong-Su;Lee, Hae-Jung;Kim, Sun-Min
    • Korean Journal of Food Science and Technology
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    • v.31 no.2
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    • pp.322-328
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    • 1999
  • Volatile flavor components of watermelon (Citrullus vulgaris S.) and oriental melon (Cucumis melo L.) obtained by simultaneous steam distillation and extraction apparatus were separated by gas chromatography (GC) and gas chromatography-mass spectrometry (GC/MS). Thirty seven and fifty five volatile flavor components were identified in watermelon and oriental melon, respectively. (Z)-3-Nonen-1-ol, (Z,Z)-3,6-nonadien-1-ol, (E,Z)-2,6-nonadienal and (E)-2-nonenal containing unsaturated nine carbon atoms were the characteristic flavor components of watermelon. $C_{9}-Unsaturated$ esters including (Z)-3-nonenyl acetate, (Z)-6-nonenyl acetate, (Z,Z)-3,6-nonadienyl acetate and thioester were important components in the flavor profile of oriental melon.

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Characterizations of Flexible Clay-PVA Hybrid Films: Thermo-optical Properties, Morphology, and Gas Permeability (유연한 점토-폴리(비닐 알코올) 하이브리드 필름의 특성 연구: 열적.광학적 성질, 모폴로지, 및 가스 투과성)

  • Shin, Ji-Eun;Ham, Mi-Ran;Kim, Jeong-Cheol;Chang, Jin-Hae
    • Polymer(Korea)
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    • v.35 no.5
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    • pp.402-408
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    • 2011
  • To improve $Na^+$-saponite(SPT) film flexibility, we prepared SPT hybrid clay films with various poly(vinyl alcohol) (PVA) concentrations(0~10 wt%) using the solution intercalation method. In this study, we investigated the thermo-optical properties, morphology, and gas permeability of the SPT hybrid films. We also examined the relationship between the film properties and PVA content using wide angle X-ray diffraction measurements(XRD), field emission scanning electron microscopy(FESEM), differential scanning calorimetry(DSC), thermogravimetric analysis(TGA), thermomechanical analysis(TMA), ultraviolet-visible(UV-vis) spectroscopy, and oxygen transmission rate($O_2$TR) testing. The properties of the clay hybrid films were strongly affected by PVA filler content. The presence of a small amount of PVA was sufficient to improve the flexibility of SPT hybrid films.

Factors Affecting HETP in Capillary Gas Chromatography (모세관 기체 크로마토그래미에서 HETP에 영향을 미치는 인자)

  • 노경호;나영진;정용안
    • KSBB Journal
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    • v.17 no.1
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    • pp.88-92
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    • 2002
  • The election profiles with different flow rates of motile phase were experimentally measured to investigate the effects on HETP in capillary gas chromatography. Based on the correlation coefficient ($r^2$), the first and second moments as well as HETP were determined from the elution cuties, and the parameters used in empirical equations were estimated. The empirical equations were expressed in terms of mobile phase velocity, and the theoretical Golay equation was considered. The samples were d-limonene and perillyl alcohol, potential anticancer agent mainly was contained in the peel of orange. From the experimental results, HETP of the samples were increased with mobile phase velocities. The correlation coefficient of d-limonene was in the range between 0.8265 and 0.8465, while that of perillyl alcohol was between 0.9353 and 0.9374. The total HETP was composed of $H_{g}$, $H_{l}$ and Hc, and Hg had the greatest effect on HETP, but HI showed a negligible effect. In terms of HETP, the optimum velocity of mobile phase was present.

Improvement of Long-term Stability in $SnO_2$ Based Gas Sensor for Monitoring Offensive Odor

  • Park, Jong-Hun;Kim, Kwang-Ho
    • The Korean Journal of Ceramics
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    • v.6 no.3
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    • pp.304-308
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    • 2000
  • WO$_3$/SnO$_2$ceramics has been suggested as an effective sensing material for monitoring offensive odor or pollutant gases. This work was focussed on improving long-term stability, which has been a principal problem generally taking place in SnO$_2$semiconductor gas sensor. Miniaturized thick film gas sensors were fabricated by screen printing technique. Two types of sensor materials, W doped SnO$_2$and WO$_3$mixed SnO$_2$, were comparatively investigated on those long-term stability and sensitivites to several gases. Small amount of W doping(0.1 mol%) into SnO$_2$largely improved the long-term stability. The W(0.1 mol%) doped SnO$_2$gas sensor had higher sensitivities to both acetone and alcohol compared with WO$_3$(5 wt%) mixed SnO$_2$gas sensor. On the contrary, WO$_3$(5 wt%) mixed SnO$_2$gas sensor showed more superior sensitivity to cigarette smoke due to larger W content.

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Effect of irradiation on the oxidation kinetics of TODGA-based extraction mixtures at atmospheric pressure

  • Skvortsov, I.V.;Belova, E.V.;Yudintsev, S.V.
    • Nuclear Engineering and Technology
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    • v.52 no.9
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    • pp.2034-2040
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    • 2020
  • The gas evolution from mixtures consisting of 0.2 M solution of N,N,N',N'-tetra-n-octyldiglycolamide (TODGA) in n-alcohol (n-decanol or n-nonanol) with Isopar-M diluent was investigated during thermal oxidation. The effect of ionizing radiation on their thermal stability has been studied. It has been determined that the volume of gaseous thermolysis products increases by 260% in the case of n-nonanol and 80% in the case of n-decanol compared to non-irradiated solutions. It has been shown that the gas evolution rate and gas volume increase when the irradiated mixture saturated with nitric acid is heated. However, there are no prerequisites for the development of autocatalytic oxidation.

Effect of Moisture Content of Biocatalyst on the Gas Phase Continuous Bioreaction (생촉매의 수분함유량이 기상의 연속반응에 미치는 영향)

  • ;Deb
    • KSBB Journal
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    • v.8 no.5
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    • pp.417-423
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    • 1993
  • The effect of moisture content of biocatalyst on the performance of a gas phase continuous bioreactor was investigated along with study on the mass transfer limitation. The biocatalysts whose moisture contents are 46.2% and 37.2%, respectively were prepared by immobilization of alcohol oxidase on Amberlite IRA-400, following by slow dehydration method, and packed into a column. Relative production rate (RPR), acetaldehyde composition ($X_p$) and conversion (X) of biocatalysts (37.2%) are better than those of biocatalysls (46.2%), and it was considered that these are attributed to the mass transfer enhancement in the gas phase compared with the aqueous phase.

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Changes of Volatile Flavor Compounds of Seibel Grape Must during Alcohol Fermentation and Aging (Seibel 포도즙 알코올 발효 및 저장 중 휘발성 향기성분의 변화)

  • 고경희;장우영
    • Microbiology and Biotechnology Letters
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    • v.27 no.6
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    • pp.491-499
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    • 1999
  • A great variety of the volatile metabolic by-products was formed in yeast cell during alcohol fermentation. The seibel grape (Vitis labrasca) which was grown in the Southern Korea used for wines. The objective of this research was to identify the volatile flavor compounds during alcohol fermentation and aging at 12$^{\circ}C$. saccharomyces cerevisiae and Schizosaccharomyces pombe were inoculated and fermented in seibel grape must. The volatile flavor compounds of logarithmic, stationary and death phases were extracted, concentrated and identified by gas chromatography/mass spectrometer (GC/MS). The volatile flavor compounds were determined by a Hewlett-Packard 5890 II Plus GC which was equipped with Supelcowax 10 fused silica capillary column (60m$\times$0.32mm$\times$0.25${\mu}{\textrm}{m}$ film thickness) wall coated with polyethyleneglycerol. The scan detection method allowed the comparison of the spectrum from the chromatogram of volatile flavor compounds to those in data Wileynbs base library. Among the volatile compounds collected by ether-hexane extraction method, the evolution of 20 main compounds, such as 9 esters (ethyl butyrate, isoamyl acetate, ethyl caproate, n-hexyl acetate, ethl caprylate, ethyl caprate, diethy succinate, ethyl hexadecanoate, 2-pheneethyl acetate), 4 alcohols (3-methyl-1-butanol, 1-hexanol, 1-heptanol, benzoethanol), 4 ketones and acids (2-octanone, caproic acid, caprylic acid, capric acid), 2 furan and phenol (2,6-bis(1,1-dimethyl ethyl)phenol, 2,3-dihydrobenzofuran) were observed during alcohol fermentation and aging. The production of the esters during alcohol fermentation with S. cerevisiae was higher than those of Sch. pombe. The sensory scores of the aged wine samples in aroma, taste and overall acceptability were not significantly different(p<0.05).

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Study on Facilitated Olefin Transport Phenomena of Poly(vinyl alcohol)/AgCF3SO3/Al(NO3)3 Electrolyte (Poly(vinyl alcohol)/AgCF3SO3/Al(NO3)3 전해질의 올레핀 촉진수송 현상 연구)

  • Park, Young Sung;Kang, Sang Wook
    • Membrane Journal
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    • v.26 no.1
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    • pp.32-37
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    • 2016
  • The poly(vinyl alcohol) $(PVA)/AgCF_3SO_3/Al(NO_3)_3$ electrolyte membrane was fabricated to prepare for highly permeable facilitated olefin transport membrane, compared with poly(vinylpyrrolidone) $(PVP)/AgCF_3SO_3/Al(NO_3)_3$ complex. In order to examine the characteristics of $PVA/AgCF_3SO_3/Al(NO_3)_3$ membrane, we used the analytical methods such as SEM, FT-IR, and FT-Raman. The best separation performance was observed at the mole ratio of 1 : 1 : 0.01 $PVA/AgCF_3SO_3/Al(NO_3)_3$ among various $Al(NO_3)_3$ concentration. As a result, the selectivity was 12 and mixed-gas permeability was 3.5 Barrer. Furthermore, the selectivity and permeability remained constant for up to 115 h.