• Title/Summary/Keyword: alcohol decomposition

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Enzyme Production Related to Alcohol Metabolism from Thermophilic Fungus Thermoascus aurantiacus (호열성 사상균 Thermoascus aurantiacus의 알코올분해대사 관련 효소학적 특성)

  • Ko Hee-Sun;Kim Hyun-Soo
    • Microbiology and Biotechnology Letters
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    • v.34 no.3
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    • pp.216-220
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    • 2006
  • Thermophillic fungus Thermoascus aurantiacus showed excellent growth and produced high amount of alcohol oxidase and catalase in a pectin medium. Besides, the strain produced enzymes which related with pectin or alcohol decomposition. We detected extracellular pectin esterase (EC 3.1.1.11) activity and, both intracellular and extracellular pectinase (EC 4.2.2.10) activity, as pectinolytic enzymes produced by T. aurantiacus. The production of methanol decomposition enzymes, such as alcohol oxidase (AOD, EC 1.1.3.13), alcohol dehydrogenase (ADH, EC 1.1.1.1), formaldehyde dehydrogenase (FADH, EC 1.2.1.1) and formate dehydrogenase (FDH, EC 1.2.1.2) follows by pectin esterase reaction which is converted to methanol. We concluded that T. aurantiacus has pectinolytic and alcohol - oxidative enzymological mechanism which produced carbon dioxide as a final material, started from pectin.

A Study on the Treatment of Organic Wastewater by Ozone Electrolysis (유기성 폐수의 오존전해처리에 관한 연구)

  • 정홍기;이태호
    • Journal of environmental and Sanitary engineering
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    • v.11 no.2
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    • pp.59-63
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    • 1996
  • To treat certain wastewater that has alcohol and phenol, we performed the ozone electrolysis by using the titanium electrode. In this experiment, we examined decomposition voltage of organics, time for electrolysis, and removal efficiency of organics. In addition we compared the ozone oxidation electrolysis. The followings are results; 1. When it comes to the alcohol treatment in wastewater, ozone electrolysis showed higher removal efficiency than ozone oxidation or electrolysis. 2. After comparing the decomposition rate of methylalcohol, ethylalcohol, and prophylalcohol in ozone electrolysis, we knew the fact that increasing carbon number made the decomposition rate slow. 3. According to the treatment of alcohol by ozone electrolysis, decomposition voltage was 50V, time for electrolysis was three hours, and treatment acidity was neutral (pH 6.5 - 8.1). 4. Ozone electrolysis was effective to the phenol treatment. When we treated phenol by using ozone electrolysis for three hours, TOC treatment efficiency was 95%. However, ozone oxidation just showed 45% treatment efficiency.

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Reaction and Characterization of Silylene and its Precusor (Silylene과 Silylene 전구체의 반응 특성 연구)

  • Kong, Young Kun;Ahn, Young Man
    • Analytical Science and Technology
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    • v.7 no.3
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    • pp.321-327
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    • 1994
  • The mild thermal decomposition of 7, 7-dimethyl-1, 2, 3, 4, 5-pentaphenyl-7-silanorbornadiene with excess methyl alcohol proceeds to give 1-methoxydimethylsilyl-1, 2, 3, 4, 6-pentaphenylcyclohexa-2, 5-diene which is colorless needle crystal. The cophotolysis of the solution of 7-silanorbornadiene in the excess ethyl alcohol proceeds with loss of silylenes to give ethoxydimethylsilane which is insertion reaction product of silylene with O-H bond of ethyl alcohol. According to above results, it is presumed that the mechanism of photochemical decomposition and that of mild thermochemical decomposition of 7-silanorbornadiene are different.

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Activity of Glutathione S-transferase and Effect of Alcohol Decomposition on the Fruit of Hovenia dulcis Thunb (지구자의 Glutathione S-transferase 활성과 알코올 분해효과)

  • Cha, Bae-Cheon;Lee, Eun-Hee;Lee, Eun;Park, Hang-Ho
    • YAKHAK HOEJI
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    • v.48 no.3
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    • pp.213-217
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    • 2004
  • For the determination of glutathione S-transferase activity, a new method was established by using HPLC system. Moreover, amount of enzyme for a optimum reaction was determined by a comparative study with a variety concentration of enzyme. Using a established method, activity of glutathione S-transferase that is alcohol metabolizing enzyme was investigated on the fruit of Hovenia dulcis Thunb. As the result of experiment, EtOH and $H_2O$ extracts of the fruit of Hovenia dulcis Thunb showed visible a synergistic effect of glutathione S-transferase activity. On a continuous experiment, EtOH and $H_2O$ extracts of the fruit of Hovenia dulcis Thunb showed alcohol decomposition activity on the in vivo test using rat. These results suggest that the fruit of Hovenia dulcis Thunb may be useful in the prevention of hangover.

Increased Alcohol Decomposition Efficacy of Hoveina dulcis Extract by Carbohydrate-Hydrolyzing Enzymes (당 분해 효소를 이용한 헛개나무 열매 추출물이 알코올 분해에 미치는 영향)

  • Lee, Kyung-Seok;Kim, Ae-Jung;Lee, Ki-Young
    • Journal of the East Asian Society of Dietary Life
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    • v.22 no.4
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    • pp.473-479
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    • 2012
  • In this study, increased alcohol decomposition efficacy (ADH) of Hoveina dulcis extract by Carbohydrate-Hydrolyzing Enzymes was investigated. Carbohydrate decomposition enzymes such as Maxinvert (Invertase), Optidex L-400 (Glucoamylase) and Rohament CL (Cellulase & Pectinase) were added to Hoveina dulcis extract at different concentrations (0.01, 0.05, 0.1, 0.5 and 1%) for 48 hrs, after which samples were taken every 6 hrs for determination of ADH activity. As the enzyme concentration became higher, ADH activity also increased. Especially, the addition of 1% Rohament CL increased enzyme activity to 76% at 30 hrs incubation, after which the increase in activity stopped. In the rat and human body experiment, enzymatic decomposition of Hovenia dulcis extract by addition of 1% Rohament CL was also effective in decreasing serum alcohol concentration and respiration. Especially, in the early stage after alcohol consumption, the efficacy of enzyme treatment of Hovenia dulcis extract was more effective. These results show that if the glycoside forms of active compounds such as flavonols in Hovenia dulcis extract are converted into aglycone forms, alcohol decomposition capability can be enhanced.

Decomposition of Organic Compound by Photo-Chemical Reaction on Ilmenite (일메나이트 상에서 광화학반응에 의한 유기물의 분해)

  • Choi, Im-Kyu;Ha, Baik-Hyon
    • Solar Energy
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    • v.8 no.2
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    • pp.39-45
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    • 1988
  • Photo-decomposition experiments to produce hydrogen from organic compound such as alcohols and organic acids were investigated using the Korean natural ilmenite, which was used as ore itself as well as the calcined in vacuum. The decomposition activities of alcohol on ore (30-60 mesh) which was not calcined did not decrease even if it was repeatedly used. But crushed ore which had newly formed ilmenite surface revealed enhanced activities. The ilmenite powder calcined in vacuum showed 3-8 times higher activies than the ore powder itself and also the decomposition activity of formic acid was much higher than that of alcohols.

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폴리프로필렌의 친수화 개질 -Polypropylene-poly(vinyl alcohol-co-ethylene) 블렌드의 특성-

  • 임상규;손태원
    • Proceedings of the Korean Fiber Society Conference
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    • 1996.04a
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    • pp.64-68
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    • 1996
  • PP-EVOH(poly(vinyl alchol-co-ethylene)) blends were prepared by the mixing of polypropylene and poly(vinyl alcohol-co-ethylene) containing 38mol% of ethylene units (EVOH38) at melt state above PP melting temperature. The materials were characterized by using dynamic mechanical thermal analysis (DMTA), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and contact angle measurement to detemine the glass transition, meltin, decomposition temperatures, and wettability respectively. From the results, PP-EVOH(poly(vinyl alcohol-co-ethylene)) blends exgibits partial miscibility.

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The Observation of Scattering Patterns During Membrane Formation: Spinodal Decomposition and Nucleation Growth (스피노달 분해와 기핵성장에 따른 상분리 과정의 광산란 패턴의 관찰)

  • Kang, Jong-Seok;Huh, Hoon;Lee, Young-Moo
    • Membrane Journal
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    • v.12 no.2
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    • pp.97-106
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    • 2002
  • Small angle light scattering (SALS) and field emission scanning electron microscope (FE-SEM) have been used to investigate the light scattering patterns with time evolved during water vapor quenching (relative humidity of 53 (${\pm}3)%$ at $26^{\circ}C$ of polysulfone (PSf)/NMP/Alcohol and chlorinated poly(vinyl chloride) (CPVC)/THF/Alcohol, respective1y. Time dependence of the position of the light scattering maximum was observed at PSf dope solutions, confirming spinodal decomposition (SD), while CPVC dope solutions showed a decreased scattered light intensity with an increased q-value, indicating nucleation & growth (NG). For the each system, domain growth rate in the intermediate and late stage of phase separation decreased with increasing the number of carbon of alcohol used as additive (non-solvent). Also, in the early stage for SD, the scattering intensity with time was in accordance with Cahn's linear theory of spinodal decomposition, regardless of types of non-solvent additive. Also, the size scales obtained by SALS were mutually compared to domain sizes gained by FE-SEM measurement. These observations of scattering pattern were much clearly observed for the 20PSf/70NMP/10n-butanol (w/w%) and agreed with the theoretical predictions for scattering patterns of each stage like the early, the intermediate, and the late stage of SD type phase separation. As the scattering maximum was observed at the larger angles (larger q) in the order of n-butanol > n-propanol > methanol > no alcohol, the pore size of final morphology decreased.

A Study on the Thermal Stability of Polymer Mixtures using Air Bags (에어백용 고분자 혼합물의 열안정성에 관한 연구)

  • Oh, Yang-Hwan;Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.20 no.4
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    • pp.353-357
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    • 2003
  • Sodium azide (SA) is commonly used as propellant for inflating automatic safety bags and other chemical manufacturing purposes. The investigation of potentially thermal hazard of sodium azide and its mixture with polymers are very important because it can occur an expected traffic accident so we took a experiment s using different scanning calorimeter (DSC) in nitrogen atmosphere. The decomposition temperature were about $350{\sim}450^{\circ}C$. We could find not only exothermic reaction was remarkably decreased in mixture s of acrylonitrile-butadiene-styrene (ABS) and polyvinyl chloride (PVC), but also increasing mixed rate of ABS, polyvinyl alcohol (PVA) and polymethyl methacrylate (PMMA) decreased thermal decomposition heat.

Studies on microbial population affecting the decomposition of fir litter. (전나무낙엽의 분해에 따른 Microbial population의 변화에 관한 연구)

  • Jang, Nam Gi;Im, Yeong Deuk
    • Korean Journal of Microbiology
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    • v.6 no.3
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    • pp.92-92
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    • 1968
  • 1) The aim of present investigation is to elucidate the relation of the balance of the production and decomposition of the fir litter. in Kwangnung plantation stands. 2) The decay constant, K, of litters was 0. 185 for the fir stand at Kwangnung. 3) The mode for the accumulation of organic carbon ($C_a$) is $c_a$= $610(1-e^{-0.185t})$), and for the decay of organic carbon (C) C = $610(1-e^{-0.185t})$. 4) The time required for the decay of half of the accumulated organic carbon in the fir stand is 3. 74 years and for 99% of elimination 27.02 years. 5) The litters of Abies holophylla killed by heat and washed with alcohol-benzol, with hot water, or with both alcohol-benzol and hot water were incubated after inoculated with suspension of firwood soil. Plate counts were made of fungi and bacteria from time to time. 6) Removal of the alcohol-benzol soluble substance stimulates at the beginning of the decay the growth of fungi and also of bacteria. 7) Removal of the water soluble fraction is detrimental to the growth of fungi in particular. 8) The distribution of soil microbial population is higher in both F and H horizon of the fir plantation soil in Kwangnung. However, the number of soil microorganisms decreases with the depth in forest soil.