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검색결과 73건 처리시간 0.029초

A Study on the Properties of Silk and Nylon 6 Fabrics by Tannic Acid Treatment

  • Yoa, Soojin;Kim, Jongjun
    • 패션비즈니스
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    • 제20권3호
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    • pp.119-132
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    • 2016
  • Weighting of silk fabrics have long been practiced in silk fabric trading based on the primary consideration of price-weight, and secondary one of quality improvement in handle, luster, and drape properties. Recent trend of practicing weighting of silk fabrics is, however, focused on the improvement of the handle, luster, drape, and other properties. During the finishing processes of synthetic fiber, nylon, comprising amide structure, include the use of tannic acid, especially in the dyeing. A multitude of studies are being implemented in terms of improving fastness to washing, fastness to light of dyed nylon product, or the light fastness of nylon 6 itself. In this study, the effects of various tannic acid treatments on the physical properties related to the handle of nylon 6 and silk fabrics are examined and reviewed. The effects of treatment condition of the tannic acid, e.g., the concentration of the aqueous tannic acid solution, treatment time, and temperature were investigated. As the concentration of the aqueous solution of tannic acid increased, the bending rigidity values of the silk and nylon 6 fabrics increased. The treated fabrics felt stiff to the touch. Within the mild conditions of bending employed in the bending measurement of KES, nylon 6 treated fabric specimen exhibited a trend of improvement of bending resiliency within the range of small bending deformation. The weight of treated fabrics have all increased. The air-permeability values decreased as the treatment concentration increased. However, the decrease tendency of air permeability values may be alleviated by adjusting the fabric count during the tentering or expanding processes, either by tension adjustment or heat treatment. Optimum conditions of the treatment for nylon 6 are 1.25% tannic acid concentration, bath temperature of $85^{\circ}C$, pH 3.1, and those for silk fabric treatment are 1.25% tannic acid concentration, bath temperature of $85^{\circ}C$, pH 3.1. The treatment conditions will lead to the improvement in the properties of fabrics for summer.

정어리 염건품의 제조 조건과 저장중의 성분변화 (Condition of Processing and Change of Chemical Composition on the Salted-dried Sardine during the Storage)

  • 정혜경;박영호
    • 한국수산과학회지
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    • 제16권3호
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    • pp.231-238
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    • 1983
  • 정어리 염건품의 제조에 있어서 제조 조건과 제품품질과의 관계를 조사하여 적정한 제조 조건을 규명하고자 실험하였다. 시료 정어리를 $9{\sim}10^{\circ}C$$5\%,\;10\%$$15\%$의 식염용액에 각각 12시간, 24시간 및 36시간 염지한 후 72시간 송풍건조(온도; $24{\sim}25^{\circ}C$, 풍속; 3m/sec)하여 성분 변화 및 관능검사를 하여 적정 조건을 결정하였다. 그 결과, 염건 정어리의 제조 조건은 염분농도 $15\%$, 염지시간 36시간이 가장 적합한 조건이었다. 이 조건으로 만들어진 염건품을 상온에 저장하면서 성분 변화를 검토하고, 무염 송풍 건조한 정어리의 저장 중의 성분 변화와 비교한 결과는 다음과 같이 요약할 수 있었다. $15\%$, 36시간 염지 처리 염건품의 경우 저장 기간에 따른 histamine, VBN, TMA-N 함량변화를 보면 VBN 함량은 건조 직후 29.5mg/100g, 저장 10일째는 초기 부패점을 지난 47.8mg/100g에 달했으며, histamine은 건조 직후 50mg/100g으로 다소 증가한 값으로 나타났고 그 후 약간의 증가를 보였으며, TMA도 histamine과 비슷한 증가 경향을 나타내었다. 지질의 산가 및 과산화물가의 변화를 보면 산가는 염건품의 경우, 건조 직후 12.6에서 저장 30일째 30.5까지 증가하였으며, POV는 저장 20일째에 최고치 142.7meq/kg을 나타낸 후 감소하였단. 정어리 지질의 지방산 조성에 있어서는 $C_{16:0}$$25.9\%$로 가장 많고, 다음이 $C_{22:6}$$13.3\%$, $C_{18:0}$$13.2\%$의 순이었다. 지방산 조성의 변화를 보면 염건품의 경우 저장 기간에 따라 $C_{22:6}$$C_{20:5}$가 감소하는 경향을 나타내었다.

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Formation Fe2O3 Nanowalls through Solvent-Assisted Hydrothermal Process and Their Application for Titan Yellow GR Dye Degradation

  • Ahmed, Khalid Abdelazez Mohamed
    • 대한화학회지
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    • 제58권2호
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    • pp.205-209
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    • 2014
  • Hematite iron oxide (${\alpha}$-$Fe_2O_3$) nanowalls were fabricated on aluminum substrate by a facile solvent-assisted hydrothermal oxidation process. The XRD and EDS patterns indicate that the sample has a rhombohedral phase of hematite $Fe_2O_3$. FE-SEM, TEM, HR-TEM, SA-ED were employed to characterize the resulting materials. $N_2$ adsorption-desorption isotherms was used to study a BET surface area. Their capability of catalytic degradation of titan yellow GR azo dye with air oxygen in aqueous solution over $Fe_2O_3$ catalysts was studied. The result indicates that the as-prepared product has a high catalytic activity, because it has a larger surface area. Langmuir and Freundlich isotherms of adsorption dye on the catalysts surface were investigated and the decomposition of titan yellow GR follows pseudo-first order kinetic.

VIRTUAL TELEMATICS SERVICE PROVIDER SYSTEM

  • Jang, In-Sung;Lee, Jun-Wook
    • 대한원격탐사학회:학술대회논문집
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    • 대한원격탐사학회 2006년도 Proceedings of ISRS 2006 PORSEC Volume II
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    • pp.836-839
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    • 2006
  • Telematics, one of the so-called New Growth Engine of IT839, is a leading IT service where wireless internet service represented by information and mobility is extended to the area of transportation. To provide telematics service, Telematics service provider have to connect with various Contents Provider or Service Provide server - for example - LBSS(Location Based Service Server), ASPS(Application Service Provider Server), TELICS(TELematics Information Center Server), GMS(Geo-mobility Server), WTPS(World Telematics Protocol Server) and MAUS(Map Air Update Server). Presently, It is nearly impossible or very difficult for the company that are manufacturing and testing telematics device to develop and test telematics solution without connecting Telematics Service Provider, Service Provider, Contents Provider. And, it is very difficult to connect in TSP, CP, SP having the product to be developed. In this paper, we proposed virtual telematics service provider. The proposed Virtual Telematics Service Provider is to provide telematics services and functionalities by integrating telematics servers into TSP gateway virtually. In other words, VTSP is performs with the role of TSP, CP, SP. And the VTSP support integration of telematics servers, interfacing and monitoring between terminal and the integrated servers.

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Agar 그래프트 폴리아크릴산 겔의 흡수능 최적화 (Optimization of the Water Absorption by Crosslinked Agar-g-Poly(acrylic acid))

  • Wuttisela, Karntarat;Panijpan, Bhinyo;Triampo, Wannapong;Triampo, Darapond
    • 폴리머
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    • 제32권6호
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    • pp.537-543
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    • 2008
  • Crosslinked agar-g-poly(acrylic acid) (x-agar-g-PAA) super absorbent with a water absorbency ($Q_{H2O}$) of approximately 660 g/g was synthesized by the copolymerization of agar with an acrylic acid monomer. KPS and MBA were used as the initiator and crosslinker, respectively. Grafting was performed in air. Infrared spectroscopy was used to identify the product of copolymerization. The optimum conditions to synthesize the x-agar-g-PAA superabsorbent were 0.1 g of agar, 0.1 g of the KPS initiator, for 15 min; 50% AA monomer, 0.005 g of the MBA crosslinker, for a propagation time of 5 min; and 1 M NaOH for 15 min to allow for saponification. The reaction temperature was $80{^\circ}C$.

Fabrication of Cr$_2$O$_3$powder from waste MgO-Cr refractory

  • Lee, Hoon-Ha;Sohn, Jin-Gun;Lee, Jae-Young;Kim, Dae-Young
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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    • pp.357-361
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    • 2001
  • The possibility of producing Cr$_2$O$_3$powder from waste magnesia-chromium refractory was investigated by sulfuric acid reaction, alkali fusion, water leaching & purification and heat treatment. The effects of temperature, the amount of NaOH added and the flow rate of air on chromium extraction efficiency in an alkali fusion step were investigated. The fusion product was leached with methanol to solve free-NaOH, and then leached with water to produce a Na$_2$CrO$_4$solution. The purity of chrome(Ⅵ) oxides, prepared both from monochromate with an impurity content and monochromate purified with $CO_2$were also examined. The purified monochromate solution was reduced from Cr(Ⅵ) to Cr(III) with NaHSO$_3$solution. The reduced solution was neutralized with NaOH to produce Cr(OH)$_3$. Water washing was treated to eliminate Na$_2$SO$_4$from neutralized Cr(OH)$_3$slurry. The washed Cr(OH)$_3$was dried and thermally treated to produce Cr$_2$O$_3$powder. The properties like lightness and hue of Cr$_2$O$_3$fabricated in this study were L=47.47, a=-14.40 and b=17.21.

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건축설비의 단열 보온을 위한 발포세라믹 개발 (A Foaming Ceramics for Insulation of Building Equipment)

  • 이주영;송영환;신해중;최재호;장성철;윤강로;이용희
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2008년도 동계학술발표대회 논문집
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    • pp.369-374
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    • 2008
  • This study is an inorganic foaming ceramic by sol-gel reaction in order to overcome weak point of insulator using in construction equipment. We shall be able to confirm as the existing product substitute is possible result of this study. The solution where the silicate, the ceramic powder and the additive are included which makes foaming ceramic slurry, then the insulator made by used $CO_2$ Sol-Gel reaction. There being will be able to manufacture the insulator where the economical efficiency is excellent confirmed at the start product which is completed. The recording gel time decreases when the silicate will increase. Uses the hydrogen peroxide and fe make foam, when additionally surface preparation the fluorine resin, the water tolerance increases and will be able to complement the weak point of the silicate which omits in the water. The case which will use the loess powder with the research method which sees specially was environment-friendly product and according to appearing, the physical properties of nonflammability.

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기름담금 염장발효 굴의 품질특성 (Quality Characteristics of the Salt-Fermented Oysters in Olive Oil)

  • 김석무;공청식;김종태;강정구;김남우;김정배;오광수
    • 한국식품영양과학회지
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    • 제33권8호
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    • pp.1398-1406
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    • 2004
  • 우리나라 남해안에서 대량 양식하고 있는 굴의 효율적인 이용을 위한 연구로서, 상온에서 장기간 저장이 가능하며 생굴의 풍미를 지닌 기름담금 염장발효 굴 시제품을 가공하였고, 이들의 성분특성, 저장안정성 및 관능적 특성 등에 대하여 살펴보았다. 기름담금 염장발효 굴의 일반성분 조성은 수분이 61.6%, 조단백질 12.0%, 조회분이 16.3% 및 휘발성 염기질소량은 34.3 mg/100 g이었고, 총아미노산의 함량은 11,496.0 mg/100 g으로 Asp, Glu, Pro, Gly, Cys, Leu, Phe 및 Lys 등이 주요 구성아미노산이었다. 구성지방산은 18:1n-9의 조성비가 높았고, 20:5n-3와 22:6n-3 등의 고도불포화지방산도 많이 함유되어 있었다. 정미성분으로는 Tau, Glu, Pro, Gly, Ala, $\beta$-Ala, Lys 등의 유리 아미노산과 betaine 및 Na, K이온의 함량이 많았다. 기름담금 염장발효 굴을 가온 검사 및 실온에 저장하면서 품질안정성을 살펴본 결과, 저장중 품질이 안정하게 유지되고 있음을 보여주었고, 저장기간이 경과할수록 관능적 특성이 좋아지는 것으로 나타났다. 그리고 본 시제품을 굴 젓갈과 굴 훈제기름담금 통조림, 앤초비필레 등 시판 관련제품들과 관능적 기호도를 비교하였을 때, 기호적 측면에서 조금도 손색이 없었다.

활석을 이용한 사포나이트의 수열합성 (Hydrothermal Synthesis of Saponite from Talc)

  • 배인국;장영남;채수천;류경원;최상훈
    • 한국광물학회지
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    • 제16권2호
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    • pp.125-133
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    • 2003
  • 삼팔면체형의 스멕타이트계 사포나이트(saponite)를 천연 광물질인 활석을 이용하여 수열법에 의해 합성하였다. 출발물질은 활석에 $Na_2$$CO_3$를 첨가하여 공기중에서 $800^{\circ}C$로 가열한 후, 화학양론적 조성에 맞게 Al($NO_3$)$_3$$.$$9H_2$O 및 Mg($NO_3$)$_2$$.$ $6H_2$O 금속염 수용액를 첨가하였고, pH는 7∼12 범위내로 $NH_4$OH 수용액에 의해 조절하여 제조하였다. 수열반응 조건은 약 1리터의 수열반응 용기에서 $230^{\circ}C$, 압력은 25∼75 kgf/$\textrm{cm}^2$의 범위 내에서 10∼60시간이었다. 실험결과, 반응온도 및 회전속도를 230 $^{\circ}C$와 180 rpm으로 고정시킨 수열조건 하에서 반응시간, 반응압력, pH 조건을 각각 40시간, 25kgf/$\textrm{cm}^2$, 약 10으로 하였을 때, 그리고, 화학조성을 화학양론적 조성에 필요한 $Na_2$O의 양보다 200% 과량 추가하였을 때, 양호한 사포나이트가 합성되었다. 또한 압력을 75 kgf/$\textrm{cm}^2$까지 증가시켜도 결정도에 미치는 영향은 미미하였으며, 반응시간이 길수록 더 좋은 결정도를 나타냈다.

방사능 계측법에 의한 티탄산 바륨의 특성화 연구 (I). 옥살산염법에 의한 티탄산 바륨의 합성 (A Study on the Characterization of Barium Titanate by a Radiometric Method (I). Synthesis of Barium Titanate by an Oxalate Method)

  • 이철;신용균;정구순
    • 대한화학회지
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    • 제33권1호
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    • pp.65-69
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    • 1989
  • 방사성 바륨 또는 방사성 란탄 추적자를 함유하고 있는 Ba(NO$_3)_2$ 와 TiO(NO$-3)_2$의 무기혼합용액을 옥살산의 에탄올 용액으로 적정하므로써 바륨티탄닐의 옥살산 염을 합성하였고, 이를 1000$^{\circ}$C에서 하소시켜 BaTiO$_3$를 만들었다. 옥살산염의 분석결과는 BaTiO(C$_2O_4)_2{\cdot}4H_2O$이며, 무기혼합용액중 Ba/Ti의 몰비가 0.950∼1.05 범위 내에서 화학양론적 결합으로 합성됨을 방사성 바륨 추적자의 도움으로 쉽게 확인하였고, Perovskite형의 구조임을 XRD로 확인하였다. 그리고 란탄 첨가제가 침전에 화학적으로 균일하게 혼입됨은 방사성 란탄의 추적자 실험으로 발견하였다. 이와 같은 실험적 사실로부터 침전물의 구성 성분의 결합이 분자준위에서 일어나고 또 티탄산바륨이 단일상의 결정임을 설명하였다.

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