• Title/Summary/Keyword: adhesion behavior

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Cytotoxicity and biocompatibility of high mol% yttria containing zirconia

  • Gulsan Ara Sathi Kazi;Ryo Yamagiwa
    • Restorative Dentistry and Endodontics
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    • v.45 no.4
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    • pp.52.1-52.11
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    • 2020
  • Objectives: Yttria-stabilized tetragonal phase zirconia has been used as a dental restorative material for over a decade. While it is still the strongest and toughest ceramic, its translucency remains as a significant drawback. To overcome this, stabilizing the translucency zirconia to a significant cubic crystalline phase by increasing the yttria content to more than 8 mol% (8YTZP). However, the biocompatibility of a high amount of yttria is still an important topic that needs to be investigated. Materials and Methods: Commercially available 8YTZP plates were used. To enhance cell adhesion, proliferation, and differentiation, the surface of the 8YTZP is sequentially polished with a SiC-coated abrasive paper and surface coating with type I collagen. Fibroblast-like cells L929 used for cell adherence and cell proliferation analysis, and mouse bone marrow-derived mesenchymal stem cells (BMSC) used for cell differentiation analysis. Results: The results revealed that all samples, regardless of the surface treatment, are hydrophilic and showed a strong affinity for water. Even the cell culture results indicate that simple surface polishing and coating can affect cellular behavior by enhancing cell adhesion and proliferation. Both L929 cells and BMSC were nicely adhered to and proliferated in all conditions. Conclusions: The results demonstrate the biocompatibility of the cubic phase zirconia with 8 mol% yttria and suggest that yttria with a higher zirconia content are not toxic to the cells, support a strong adhesion of cells on their surfaces, and promote cell proliferation and differentiation. All these confirm its potential use in tissue engineering.

A Study on Friction and Wear Behavior of Carbon Fiber Reinforced Polyetheretherketone (탄소 섬유 보강 폴리에테르에테르케톤의 마찰 및 마모 거동에 관한 연구)

  • Ryoo, Sung-Kuk;Kim, Kyung-Woong
    • Proceedings of the KSME Conference
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    • 2000.04a
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    • pp.772-779
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    • 2000
  • The friction and wear behavior of short carbon fiber reinforced polyetheretherketone was studied experimentally under dry sliding conditions against SCM440(AISI 4140) disks with a different surface roughness and hardness at the low sliding speeds and the high pressures on a pin-on-disk apparatus. Under the low disk surface roughness value the earsplitting noise and stick-slip were occurred. The increased adhesion friction and wear factor with stick-slip made the friction and wear behavior worse. Under the high disk surface hardness the break and falling-off of carbon fibers were accelerated. The carbon fibers fallen off from the matrix were ground into powder between two wear surfaces and this phenomenon caused a abrasive friction and wear factor to increase. So the friction and wear behavior became worse. With the transfer film made of wear particles formed on a disk, the carbon powder film formed on a pin lowered a friction coefficient.

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Comparison of the Tribological behaviors of Various Organic Molecular Films (다양한 유기분자막의 마찰특성 비교)

  • ;;;V. Tsukruk
    • Tribology and Lubricants
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    • v.17 no.5
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    • pp.386-390
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    • 2001
  • Monolayers such as self-assembled monolayer (SAM) have received considerable attention to reduce stiction and friction in micro-devices and microelectromechanical systems (MEMS). Various organic molecular films were investigated to obtain better understanding of their tribological behaviors and adhesion property. The organic molecular films studied in this work are: epoxysilane SAMs, octadecyltricholosilane (OST), multi-layers composed of epoxysilane SAMs, poly[styrene-b-(ethylene-co-butylene)-b-styrene](SEBS) and compound of epoxy resin and poly (paraphenylene)(EP/PPP). The pull-off forces of these films were also obtained from force-distance curves measured in static mode of operation of atomic force microscope(AFM). Tribological tests were conducted with a ball-on-flat reciprocating friction tester. The OST showed the lowest pull-off force, indicating its low adhesion property. It was revealed that, the OST, EP/PPP and the multi-layer of epoxysilane SAMs, SEBS and EP/PPP exhibited good tribological properties at the lower load (0.3 N) whereas the OST showed best performance at the higher load (1.8 N).

Application of DEM to Simulate Interaction between Soil and Tire Lug

  • Oida, A.;Ohkubo, S.
    • Agricultural and Biosystems Engineering
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    • v.1 no.1
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    • pp.1-6
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    • 2000
  • Using the modified DEM (Distinct Element Model), which we proposed, the effect of cross section of tire lug on the tire performance was simulated. Though the DEM has an advantage over the FEM when it is applied to simulate the behavior of discrete assembly of particles such as soil, there was still a problem in the case of conventional DEM, that the simulated movement of particles was too free. We constructed a new mechanical model (modified DEM) which can take account of the effect of adhesion between particles. It is shown that the soil deformation is simulated by the modified DEM better than the conventional DEM. Comparing the simulated soil reaction to the tire lug with the experimental results, the adequate DEM parameters were found. It is also indicated possible to find the effect of lug cross section shape on the tractive performance of tire by the DEM simulation.

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Curing Characteristics of Low Molar Ratio Urea-Formaldehyde Resins

  • Fan, Dongbin;Li, Jianzhang;Mao, An
    • Journal of Adhesion and Interface
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    • v.7 no.4
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    • pp.45-52
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    • 2006
  • Five low molar ratio urea-formaldehyde (LUF) resins were synthesized in this study. The effects of molar ratio, free formaldehyde content, and catalysts on the curing characteristics of LUF resins were studied by measuring its free formaldehyde content, pH value change after catalysts added, curing rate, and pot life, observing its cured appearance, and analyzing its thermal behavior. The results indicate that: 1) The LUF resin with lower molar ratio than 1.0 can still cure; 2) Free formaldehyde content is not the main factor in affecting curing rate of LUF resin; 3) Compared with ammonium chloride as a traditional catalyst, persulfate salts markedly accelerate the curing rate of LUF resin, and result in the different appearance; 4) the addition of sodium chloride to catalysts can accelerate the curing rate of LUF resin, but the effect is moderate.

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Pore size effects of adhesion and friction for nanohoneycomb structures in AFM (원자현미경에서 나노허니컴 구조물의 홀 사이즈에 따른 점착 및 마찰 거동 분석)

  • Choi, Duk-Hyun;Lee, Pyung-So;Lee, Kun-Hong;Park, Hyun-Chul;Hwang, Woon-Bong
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.11a
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    • pp.129-132
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    • 2005
  • This study analyzes the behavior of adhesion and friction according to the pore size of nanohoneycomb structures in atomic force microscope (AFM). Anodic aluminum oxide (AAO) films are fabricated as nanohoneycomb structures. According to the pore diameters of the nanohoneycomb structures, the adhesive forces and the frictional coefficients arc obtained in AFM, and the behaviors are analyzed in the view of the contact area between the sphere particle and nanohoneycomb substrate. The effective Young's moduli of the nanohoneycomb structures are measured from the nanoindentation tests, and the contact areas at zero applied load are calculated by combining the porosity of the nanohoneycomb structures and the contact radius determined from JKR and DMT theory.

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Fabrication of Metal Nanohoneycomb Structures and Their Tribological Behavior

  • Kim, Sung-Han;Lee, Sang-Min;Choi, Duk-Hyun;Lee, Kun-Hong;Park, Hyun-Chul;Hwang, Woon-Bong
    • Advanced Composite Materials
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    • v.17 no.2
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    • pp.101-110
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    • 2008
  • Metal nanohoneycomb structures were fabricated by E-beam evaporation and a two-step anodization process in phosphoric acid. Their tribological properties of adhesion and friction were investigated by AFM in relation to the pore size of the nanohoneycomb structures. Variations of the adhesive force are not found with pore size, but formation of the pore greatly reduces the adhesive force compared to the absence of pore structure. The coefficient of friction increased nonlinearly with pore size, due to surface undulation around the pore. Tribological properties do not differ greatly between the original nanohoneycomb structure and the metal nanohoneycomb structure.

Quantitative Analysis of Growth of Cells on Physicochemically Modified Surfaces

  • Chandra, Prakash;Kim, Jihee;Rhee, Seog Woo
    • Bulletin of the Korean Chemical Society
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    • v.34 no.2
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    • pp.524-530
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    • 2013
  • In this study, we describe the most expected behavior of cells on the modified surface and the correlation between the modified substrates and the response of cells. The physicochemical characteristics of substrates played an essential role in the adhesion and proliferation of cells. Glass and polymer substrates were modified using air plasma oxidation, and the surfaces were coated with self-assembled monolayer molecules of silanes. The PDMS substrates embedded with parallel micropatterns were used for evaluation of the effect of topologically modified substrate on cellular behaviour. BALB/3T3 fibroblast cells were cultured on different surfaces with distinct wettability and topology, and the growth rates and morphological change of cells were analyzed. Finally, we found the optimum conditions for the adhesion and proliferation of cells on the modified surface. This study will provide insight into the cell-surface interaction and contribute to tissue engineering applications.

Comparison of the tribological behaviors of various organic molecular films (다양한 유기분자막의 마찰특성 비교)

  • ;;;V. Tsukruk
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2001.06a
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    • pp.49-54
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    • 2001
  • Monolayers such as self-assembled monolayer (SAM) have received considerable attention to reduce stiction and friction in micro-devices and microelectromechanical systems (MEMS). Various organic molecular films were investigated to obtain better understanding of their tribological behaviors and adhesion property. The organic molecular films studied in this work are: epoxysilane SAMs, octadecyltricholosilane (OST), multi-layers composed of epoxysilane SAMs, poly〔styrene-b-(ethylene-co-butylene)-b-styrene〕(SEBS) and compound of epoxy resin and poly (paraphenylene) (EP/PPP). The pull-off forces of these films were also obtained from force-distance curves measured in static mode of operation of atomic force microscope (AFM). Tribological tests were conducted with a ball-on-flat reciprocating friction tester. The OST showed the lowest pull-off force, indicating its low adhesion property. It was revealed that, the OST, EP/PPP and the multi-layer of epoxysilane SAMs, SEBS and EP/PPP exhibited good tribological properties at the lower load (0.3 N) whereas the OST showed best performance at the higher load (1.8 N).

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A Study on Coating Adhesion of Hot Rolled Galvanized Iron Manufactured without pickling process (산세생략형 열연 용융아연도금강판의 특성)

  • 최진원;전선호
    • Journal of the Korean institute of surface engineering
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    • v.32 no.1
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    • pp.21-30
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    • 1999
  • Coating adherance behavior of low carbon steels, produced by POSCO, Korea, was studied in order to study the characteristics of hot rolled galvanized iron(HGI) manufactured without pickling line and the development of its process. Galvanizing experiments were carried out in zinc pot with 0.2wt% Al after hot rolled plates with scale were reduced at $550~750^{\circ}C$ in 10~30% hydrogen gas atmosphere during 60~400seconds. The reduced plates and coated products were examined by SST, XRD, SEM and EPMA on their surfaces and cross sections. Coating layer of HGI manufactured with pickling line was composed of retained scale, Fe-Zn-Al compound, Fe-Zn compound ($\delta_1\;and\;\zeta$ Phase) and pure zinc. It was superior to HGI in coating adhesion. It seems to be due to forming of Fe-Zn-Al compound in interface of matrix and retained porous scale.

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