• 제목/요약/키워드: additive effects

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적층공법을 적용한 시멘트계 복합재료의 수축특성 (Shrinkage Characteristic of Cementitious Composite Materials for Additive Manufacturing)

  • 이호재;김기훈;유병현;김원우;문재흠
    • 한국구조물진단유지관리공학회 논문집
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    • 제23권6호
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    • pp.99-104
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    • 2019
  • 본 연구의 목적은 시멘트계 복합재료의 적층을 위해 증점제를 적용하여 개발한 출력배합의 수축 특성을 평가하고, 프린팅 기법을 이용해 제작한 적층시험체와의 수축 특성을 비교하는 데 있다. 증점제 적용 시 수축이 기준배합과 비교하여 평균 25% 저감(56일 기준)되는 것을 확인하였다. 수축이 저감되는 긍정적인 효과에 반해 압축강도는 약 15% 감소(28일 기준)되는 부정적인 효과도 확인되었다. 출력배합을 이용해 제작한 적층시험체와 몰드시험체를 이용하여 수축을 평가한 결과, 적층시험체의 수축변형률이 약 25% 감소(28일 기준)되는 것을 확인하였다. 본 연구결과를 통해 3D 프린팅을 이용한 시멘트계 복합재료의 출력 시 수축의 진전속도와 수축으로 인한 균열의 발생시점을 예측할 수 있을 것으로 판단된다.

Semi-additive 방법을 이용한 폴리이미드 필름 상의 미세 구리배선 제작 시 도금액의 영향 (The Effects of Copper Electroplating Bath on Fabrication of Fine Copper Lines on Polyimide Film Using Semi-additive Method)

  • 변성섭;이재호
    • 마이크로전자및패키징학회지
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    • 제13권2호
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    • pp.9-13
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    • 2006
  • COF에 사용되는 구리배선은 폴리이미드 필름에 subtractive 방법을 이용하여 만들어지고 있으나 선폭이 작아짐에 따라 subtractive 방법은 폭방향으로 에칭 현상으로 인하여 사용에 제한이 되고 있다. Semi-additive 방법은 리소그래피 공정과 전기도금범을 사용하여 구리배선을 만드는 방법으로 $10-40{\mu}m$의 좁은 선폭에 대한 연구를 하였다. AZ4620과 PMER900의 두꺼운 PR을 사용하였으며 전기도금법을 이용하여 구리 배선을 형성하였다. 기존의 용액은 높은 잔류응력으로 인하여 구리도금층에 crack이 발생하였으며 via filling에 사용된 도금액을 사용한 경우 잔류응력이 낮아서 crack이 없는 구리배선을 얻을 수 있었다. 기지층의 에칭시 배선의 폭방향으로의 에칭 현상은 관찰되지 않았다.

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Effect of MgO-P2O5 Sintering Additive on Microstructure of Sintered Hydroxyapatite (HAp) Bodies and Their In-Vitro Study

  • Lee, Byong-Taek;Youn, Hyeong-Chul;Lee, Chi-Woo;Song, Ho-Yeon
    • 한국재료학회지
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    • 제17권2호
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    • pp.100-106
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    • 2007
  • The effects of $MgO-P_2O_5$ based sintering additive on the microstructure and material and biological properties of hydroxyapatite $(HAp,\;Ca_{10}(PO_4)_6(OH)_2)$ ceramic were investigated using XRD, SEM and TEM techniques. The $MgO-P_2O_5$ sintering additive improved the material properties and increased the grain size in the sintered HAp bodies. As the content of sintering additive increased over 4 wt%, a small amount of the HAp phase was decomposed and transformed to ${\beta}-TCP$. In the 2 wt% $MgO-P_2O_5$ content HAp sintered body, the maximum values of density and hardness were respectively about 3.10 gm/cc and 657 HV. However, the maximum fracture toughness in the HAp body containing 8 wt% $MgO-P_{2}O_{5}$ was about $1.02MPa{\cdot}m^{1/2}$ due to the crack deflection effect. Human osteoblast like MG-63 cells and osteoclast like raw 264.7 cells were well grown and fully covered all of the HAp sintered bodies. The osteoblast cells were grown with spindle-shaped and the osteoclast cells had a grape-like round shape.

SiC 소결에 미치는 Al2O3-RE2O3 첨가제의 영향과 SiCf/SiC 복합체의 제조 (Effects of Al2O3-RE2O3 Additive for the Sintering of SiC and the Fabrication of SiCf/SiC Composites)

  • 유현우;카티 라주;박지연;윤당혁
    • 한국세라믹학회지
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    • 제50권6호
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    • pp.364-371
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    • 2013
  • The sintering behavior of monolithic SiC is examined using the binary sintering additive of $Al_2O_3$-rare earth oxide ($RE_2O_3$, where RE = Sc, Nd, Dy, Ho, or Yb). Through hot pressing at 20 MPa and $1750^{\circ}C$ for 1 h in an Ar atmosphere for 52 nm fine ${\beta}$-SiC powder added with 5 wt% sintering additive, a SiC density of > 97% is achieved, which indicates the effectiveness of $Al_2O_3-RE_2O_3$ system as a sintering of additive for SiC. Based on this result, 7 wt% of $Al_2O_3-Sc_2O_3$ is tested as an additive system for the fabrication of a continuous SiC fiber-reinforced SiC-matrix composite ($SiC_f$/SiC). Electrophoretic deposition combined with the application of ultrasonic pulses is used to efficiently infiltrate the matrix phase into the voids of $Tyranno^{TM}$-SA3 fabric. After hot pressing, a composite density of > 97% is obtained, along with a maximum flexural strength of 443 MPa.

천연물 유래 항생제 대체 사료첨가제의 육계 임상 효능에 대한 연구 (The Clinical Effects of an Herbal Antimicrobial Feed Additive in Growing Chickens)

  • 오홍근;박현;김윤철;이현아;김옥진
    • 한국임상수의학회지
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    • 제27권1호
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    • pp.17-22
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    • 2010
  • 천연물 유래 항생제 대체 사료첨가제 Flavo-$SK^{TM}$은 원광대학교 인수공통감염병연구센터에서 1,000종 이상의 천연물로부터 효능평가를 거쳐 개발되었다. 본 연구는 육계 농장에서 대규모 임상 효능평가를 통한 Flavo-$SK^{TM}$의 항균 효과 규명과 항생제 대체 효과를 알아보고자 수행되었다. 20,000 마리의 병아리를 Flavo-$SK^{TM}$ 투여군과 비투여군 2 그룹으로 나누어 31일 동안 육계농장에서 연구가 수행되었다. Flavo-$SK^{TM}$ 투여군에는 항생제가 없는 사료에 Flavo-$SK^{TM}$를 0.29% 배합하여 급여하였고 비투여군은 항생제 포함된 일반 사료를 급여하였다. 연구기간 동안 사료섭취량, 체중, 임상증상을 분석하고 시험종료일에 부검하여 육안검사와 미생물학적 검사 및 병리조직학적 검사를 수행하였다. 연구결과 천연물 유래 항생제 대체 사료첨가제 Flavo-$SK^{TM}$은 육계에 항균효과를 가진 항생제 대체 사료첨가제로서 효과적인 것을 확인할 수 있었다.

난류 관유동에서 마찰저항감소 첨가제에 대한 펌프와 온도의 영향 (Pump and Temperature Effects on Drag Reducing Additives in Turbulent Pipe Flows)

  • 박성룡;서항석;윤형기
    • 설비공학논문집
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    • 제8권3호
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    • pp.330-337
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    • 1996
  • The effects of pump and temperature on drag reducing characteristics were investigated with a polymer(PAAM : Polyacrylamide) and three kinds of surfactants(CTAC, STAC, Habon-G) in fully developed turbulent pipe flows with various experimental parameters such as additive concentration(30~500ppm), pipe diameter(4.65mm, 10.85mm), Reynolds number($4{\times}10^4{\sim}10^5$) and working fluid temperature($20{\sim}80^{\circ}C$). The pump effect on PAAM was severe such that the drag reduction rates obtained with pump were decreased upto 30% as compared with those obtained with compressed air in 4.65mm test section. The temperature effect on PAAM was noticeably considerable, that is, the higher temperaute, the less drag reduction rate. On the other hand, no significant pump effect on the surfactants was observed. The drag reducing effectiveness of CTAC was totally lost in the temperature ragne of 60 to $80^{\circ}C$, whereas STAC and Habon-G kept their distinct drag reducing capability at a temperature of $80^{\circ}C$. This study clearly elucidated that for DHC application of drag reducing additives, the pump and temperature effects as well as additive concentration and pipe diameter should be carefully taken into consideration.

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Statistical Genetic Studies on Cattle Breeding for Dairy Productivity in Bangladesh: II. Estimation of Reciprocal and Heterosis Effects and Optimum Crossbreeding System between the Local Breeds and Exotic Breeds for Milk Performance

  • Hossain, K.B.;Takayanagi, S.;Miyake, T.;Bhuiyan, A.K.F.H.;Sasaki, Y.
    • Asian-Australasian Journal of Animal Sciences
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    • 제15권6호
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    • pp.777-782
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    • 2002
  • Reciprocal effects among local breeds and additive and heterosis effects were estimated for total milk production per lactation (TLP), lactation length (LL) and daily milk yield (DMY). Procedures for an optimum crossbreeding system were examined by comparing various crossbred combinations. Three data sets were chosen from the total records collected from 1962 to 1997. Data set I with a total of 5,938 records composed of 9 breed groups for reciprocal crosses, data set II with a total of 6,064 records composed of 5 breed groups for additive and heterosis effects and data set III with a total of 10,319 records composed of 42 breed groups for optimum crossbreeding system were analyzed. The least squares ANOVA was used. The reciprocal crosses between Red Sindhi and the Bangladeshi Local showed significant difference. When the Red Sindhi was used as cow, the cross was superior to the opposite in terms of the three performance traits. The results showed that additive breed effects on both TLP and DMY were positive and highly significant between Bos indicus and Bos taurus, whereas the individual heterosis effects were not significant. In general, any local breeds were improved two to three times by crossing with the Friesian once or twice. However, the effect was reduced when the grading up with the Friesian was repeated more than twice. On the other hand, when the local breed was crossed with the other breeds such as Holstein and Jersey, the improvement of TLP was less. Crossing the F1 cows with the Friesian bull gave further improvement. Almost the same trends were found also for LL and DMY. The local breeds and their crosses are raised mainly for draft animals, then it is recommended that the crossbreds between the local cows and Friesian are used for dairy purposes and more than 75% Friesian blood is used for beef.

Evaluation of Crossbreeding Effects for Wool Traits in Sheep

  • Malik, B.S.;Singh, R.P.
    • Asian-Australasian Journal of Animal Sciences
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    • 제19권11호
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    • pp.1536-1540
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    • 2006
  • Crossbreeding effects for wool quality traits viz. greasy fleece weight (kg), staple length (cm), average fibre diameter (${\mu}$) and medulation percentage were estimated using the Dickerson's and Kinghorn's models. The data analyzed involved 15 genetic groups including Nali purebred, $F_1$'s of two and three breeds, $F_2$'s and reciprocal crossbred obtained from the crossing of Nali (N), Merino (M) and Corriedale (C) breeds during 1980-96. Nali and Corriedale breeds had non-significant negative additive genetic effects (Dickerson's model) on greasy fleece weight, while effects of Corriedale were negative for staple length only from both models. In general additive genetic effects of all three breeds were non-significant for all the wool traits except medulation percentage. Non significant heterotic and recombination effects (epistatic loss) were estimated from both models. However, the estimates of crossbreeding effects varied between the models both in magnitude as well as in direction barring few exceptions. Undesirable positive heterosis was found on medulation percentage for all types of combinations involving three breeds. Comparison of least squares means of various genetic groups revealed that both two breed and three breed crosses were superior to the Nali breed for all wool quality traits. Fibre diameter of MN crossbreds was significantly less than CN crossbreds. Results also indicated that as the inheritance of Nali breed in a cross is decreased, the medulation percentage decreases which is desirable. Inter se mating of crossbreds (two breed, three breed) has not resulted in a decline in the wool quality traits. These results indicate that the synthetic population derived from three breeds can be stabilized easily for wool traits as there may not be epistatic loss on subsequent inter se mating of crossbreds.

에트링가이트-석탄 복합계 팽장재의 수화반응 모델에 관한 연구 (A Study on the Hydration Reaction Model of Expansive Additive of Ettringite-Gypsum Type)

  • 박선규;야구귀문;김무한
    • 콘크리트학회논문집
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    • 제17권4호
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    • pp.581-586
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    • 2005
  • 고성능 콘크리트는 단위 시멘트량이 많기 때문에 초기재령에 있어서 시멘트의 급속한 수화반응으로 인해 시멘트 경화체는 자기수축이 발생하게 된다. 이러한 자기수축 변형이 발생한 부재가 외부 또는 내부 구속 상태에 있을 경우에는 수축균열이 발생하게 되며, 이러한 초기재령에 발생한 수축균열은 콘크리트 구조물의 미관 및 내구성 저하를 초래하기 때문에 이를 억제하는 것은 매우 중요하다. 한편, 이러한 고성능 콘크리트의 자기수축을 저감시키는 방법으로서 팽창재의 혼입에 의한 수축보상이 있는데 자기수축 저감에 유효한 것으로 알려져 있다. 그러나 지금까지의 팽창재에 의한 고성능 콘크리트의 자기수축에 관한 연구는 실험에 근거한 연구로서 정량적인 연구가 아닌 정성적인 연구가 대부분 이었다. 이러한 팽창재에 의한 고성능 콘크리트의 자기수축 저감량을 정량적으로 평가하기 위해서는 팽창재의 수화반응 모델부터 시작하여 팽창재에 의한 시멘트 경화체의 팽창 모델을 구축할 필요가 있다. 따라서, 본 연구에서는 초기 재령의 자기수축 저감을 목적으로 초기재령에서 빠른 팽창력을 발휘하도록 재료 설계된 에트링가이트-석회 복합계를 대상으로하여, 팽창재의 입도분포 및 수화의 진행에 따른 인접겔과의 접촉을 고려한 팽창재의 수화반응모델을 제안하였다. 또한, 제안된 팽창재의 수화반응모델을 실험적으로 모델의 타당성에 대해서 검토한 결과, 본 연구에서 제안한 팽창재의 수화반응 모델은 실험치를 양호하게 평가할 수 있을 것으로 판단된다.

수축저감제와 팽창재를 병용 치환한 콘크리트의 수축 특성 (Properties of Shrinkage in Concrete Incorporating Shrinkage Reducing Agent and Expansive Additive)

  • 김광화;문학룡;심영태;이병상;정용희;한천구
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2004년도 학술.기술논문발표회
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    • pp.61-64
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    • 2004
  • This study is to investigate the engineering and shrinkage properties of concrete incorporating shrinkage reducing agent(SRA) and expansive additive(EA) in order to reduce shrinkage of concrete. According to results, as for the properties of fresh concrete, increase in, SRA and EA content leads to reduce the fluidity but to increase the air content, and as for setting time, there is little difference. For strength properties, it decreased with an increase in SRA dosage and increased up to 5% of EA content. For the properties of drying shrinkage, it shows decline tendency with an increase in SRA and EA content reiteratively. It alto reduces significantly with the combination of SRA-EA systems due to the combined effect of the admixture. In the scope of this paper, it is found that the use of SRA with 0.5% and EA with 5% has optimum effects on the various properties of concrete. And under the combination of SRA and EA, it can reduce drying shrinkage about 37%.

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