• Title/Summary/Keyword: additive concentration

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Influence of the MgO-TiO2 Co-Additive Content on the Phase Formation, Microstructure and Fracture Toughness of MgO-TiO2-Reinforced Dental Porcelain Nanocomposites

  • Waiwong, Ranida;Ananta, Supon;Pisitanusorn, Attavit
    • Journal of the Korean Ceramic Society
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    • v.54 no.2
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    • pp.141-149
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    • 2017
  • The influence of the co-additive concentration (0 - 45 wt% with an interval of 5 wt%) of MgO-$TiO_2$ on the phase formation, microstructure and fracture toughness of MgO-$TiO_2$-reinforced dental porcelain nanocomposites derived from a one-step sintering technique were examined using a combination of X-ray diffraction, scanning electron microscopy and Vickers indentation. It was found that MgO-$TiO_2$-reinforced dental porcelain nanocomposites exhibited significantly higher fracture toughness values than those observed in single-additive (MgO or $TiO_2$)-reinforced dental porcelain composites at any given sintering temperature. The amount of MgO-$TiO_2$ as a co-additive was found to be one of the key factors controlling the phase formation, microstructure and fracture toughness of these nanocomposites. It is likely that 30 wt% of MgO-$TiO_2$ as a co-additive is the optimal amount for $MgTi_2O_5$ and $Mg_2SiO_4$ crystalline phase formation to obtain the maximum relative density (96.80%) and fracture toughness ($2.60{\pm}0.07MPa{\cdot}m^{1/2}$) at a sintering temperature of $1000^{\circ}C$.

Permeation Properties of Surface Modified Nanofiltration Membrane (표면 개질된 나노복합막의 투과 특성)

  • Tak Tae-Moon;Park Hyung-Kiu;Jang Gyung-Gug
    • Membrane Journal
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    • v.14 no.3
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    • pp.207-217
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    • 2004
  • In this study, we prepared nanofiltration membrane by applying the interfacial polymerization method as a way of manufacturing composite membranes. We have examined the effects of various preparation factors such as monomer concentration and composition, thermal curing condition, post treatment condition. In addition to preparation conditions, we also monitored the effects of operation conditions such as feed solution concentration and operation pressure on the permeation properties of the resulting nanofiltration membrane. We intended to increase the permeation rate of nanofiltration membrane by the enlargement of effective surface area using additives during interfacial polymerization step. With increasing the monomer concentration, membrane permeation rate are decreased with maintaining almost constant rejection. With respect to curing condition, with increasing the curing temperature both permeation rate and rejection are decreased. With increasing the ratio of MPD in amino monomer composition, permeation rate decreased drastically with high rejection. With increasing the feed solution concentration, both permeation rate and rejection decreased. Both permeation rates and rejection increased with increasing the operating pressure. Nanofiltration membrane have higher surface roughness with increasing additive concentration in the case of using MPD contained amine composition than using piperazine alone. Permeation rates are much lower than the nanofiltration membrane prepared by piperazine.

Use of Fraxnius rhynchophylla H.ance bark as antioxidant (물푸레나무 수피의 항산화 효과)

  • 김대구;이병근;김현용
    • Journal of Korea Foresty Energy
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    • v.22 no.2
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    • pp.69-77
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    • 2003
  • This study reviewed antioxidants and various enzymic physiological functions of Korean ash tree extractives that contains coumarine and ester component in order to examine the practical possibility of those materials as pharmaceutical and cosmetic additive applications. first, in the experiment of enzymic physiological activity, the electron donating ability showed 62.00% at 1ppm and over 90% at 10ppm or higher concentration, and the pseudo SOD ability showed 39% at the concentration of 2000ppm and 84.73% at the concentration of 5000ppm. Second, the inhibition activity of xanthine oxidase showed a relatively low inhibition effect of 45.57% at 200ppm, and the inhibition effect of tyrosinase showed 57.51% at 2000ppm. However, it showed a very low inhibition effect at the concentration of 500ppm or less. Third, the lipid oxidation, when Cu$\^$2+/ion was used as an oxidation accelerator, showed the inhibition effect of 82% at the concentration of 10ppm, and when Fe$\^$2+/ion was used also as the oxidation accelerator, it showed a very outstanding effect of 60% and more at 100ppm. Conclusively it is clear that the extracts of Korean ash tree bark can be used as cosmetic and pharmaceutical additive agents due to their excellent activities as antioxidant and enzymic physiological functions of it.

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Effects of Microbial Additive Supplementation on Meat Quality and Fatty Acid Profiles of Growing-Finishing Pigs

  • Hyuk Jun Lee;Myeong Ji Seo;Young Ho Joo;Ji Yoon Kim;Chang Hyun Baeg;Dong Hyeon Kim;Seong Shin Lee;Sam Churl Kim
    • Journal of Environmental Science International
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    • v.32 no.12
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    • pp.925-932
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    • 2023
  • The objective of this study was to investigate the effects of microbial additive on the meat quality and fatty acid (FA) profiles of growing-finishing pigs. A total of 180 growing-finishing pigs (Landrace × Yorkshire × Duroc; mixed sex; 14 weeks of age; 58.0 ± 1.00 kg) were randomly distributed into three treatments with three pens consisting of 20 growing-finishing pigs per pen for 60 days. The experimental treatments were as follows: 0, 0.5, and 1.0% microbial additive. The crude protein, cooking loss, drip loss, water holding capacity, and shear force in loin muscle were no significant differences among treatments (p>0.05), except for the moisture and crude fat contents. The pH and TBARS of loin muscle shown no significant differences among treatments (p>0.05). However, the L* and a* values of loin muscle were the highest in the 1.0% supplementation group compared with the other treatments (p<0.05). The b* value of loin muscle was the highest in the control group compared with the other treatments (p<0.05). Linolenic acid, eicosapentaenoic acid, docosapentaenoic acid, docosahexaenoic acid, and n-3 FAs contents of loin muscle were the highest in 1.0% supplementation group compared with the other treatments (p<0.05). In conclusion, using 1.0% microbial additive supplementation can improve meat quality by increasing polyunsaturated FA concentration and meat color in pig loins.

Extinguishing Concentration of Inert Gases in Heptane Pool Fires (헵탄 풀화재에서 불활성기체 소화농도)

  • Jung, Tae-Hee;Lee, Eui-Ju
    • Journal of the Korean Society of Safety
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    • v.27 no.3
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    • pp.71-76
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    • 2012
  • The coflow velocity effect on the minimum extinguishing concentration(MEC) was investigated experimentally in heptane cup-burner flames. Various inert gases($N_2$, Ar, $CO_2$, He) were added into the oxidizer to find the critical concentration and the effectiveness of the agents on flame extinction. The experimental results showed that the MECs were increased with increasing coflow velocity for most inert gases except helium, but the higher coflow velocity induced the lower burning rates of heptane. This indicated that the increase of coflow velocity resulted in the decrease of fuel velocity evaporated from fuel surface, and hence the stain rate on the reaction zone was also decreased. In the case of helium as a additive, the extinguishing concentration was independent of the coflow velocity because the heat conductivity was ten times larger than the other inert gases and flow effect by a strain rate might be compensated for heat loss to the surroundings.

The Effect of Electroplating Parameters on the Compositions and Morphologies of Sn-Ag Bumps (Sn-Ag 범프의 조성과 표면 형상에 영향을 미치는 도금 인자들에 관한 연구)

  • Kim, Jong-Yeon;Yoo, Jin;Bae, Jin-Soo;Lee, Jae-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.10 no.4
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    • pp.73-79
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    • 2003
  • With the variation of Ag concentration in bath, current density, duty cycle, additive and agitation for electroplating of Sn-Ag solder, the compositions and the morphologies of solder were studied. It was possible to controll Ag content in Sn-Ag solder by varying Ag concentration in bath and current density. The microstructure size of Sn-Ag solder decreased with increasing current density. Duty cycle of pulse electroplating and quantity of additive affected on Ag content of deposit and surface roughness. In this work eutectic Sn-Ag solder bumps with fine pitch of 30 $\mu\textrm{m}$ and height of 15 $\mu\textrm{m}$ was formed successfully. The Ag content of electrodeposited solder was confirmed by EDS and WDS analyses and the surface morphologies was analyzed by SEM and 3D surface analyzer.

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Surface Characteristics and Photocatalytic Propertiy of B Doped TiO2 Layer Synthesized by Plasma Electrolytic Oxidation Process (Plasma Electrolytic Oxidation 방식으로 제조된 B Doped TiO2의 표면특성과 광촉매 특성)

  • Lee, Jong-Ho;Lee, Young-Ki;Kim, Young-Jig;Oh, Han-Jun
    • Korean Journal of Materials Research
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    • v.31 no.10
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    • pp.552-561
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    • 2021
  • For the purpose of manufacturing a high efficiency TiO2 photocatalyst, B-doped TiO2 photocatalysts are synthesized using a plasma electrolytic oxidation method in 0.5 M H2SO4 electrolyte with different concentrations of H3BO3 as additive. For the B doped TiO2 layer fabricated from sulfuric electrolyte having a higher concentration of H3BO3 additive, the main XRD peaks of (101) and (200) anatase phase shift gradually toward the lower angle direction, indicating volume expansion of the TiO2 anatase lattice by incorporation of boron, when compared with TiO2 layers formed in sulfuric acid with lower concentration of additive. Moreover, XPS results indicate that the center of the binding energy peak of B1s increases from 191.45 eV to 191.98 eV, which suggests that most of boron atoms are doped interstitially in the TiO2 layer rather than substitutionally. The B doped TiO2 catalyst fabricated in sulfuric electrolyte with 1.0 M H3BO3 exhibits enhanced photocurrent response, and high efficiency and rate constant for dye degradation, which is ascribed to the synergistic effect of the new impurity energy band induced by introducing boron to the interstitial site and the improvement of charge transfer reaction.

Interaction between Brassinolide and Auxins on Bioassays (Brassinolide와 Auxin과의 상호작용의 생물검정에 의한 평가)

  • Choi, Chung-Don;Kim, Soon-Chul;Lee, Soo-Kwan
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.35 no.1
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    • pp.58-64
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    • 1990
  • This study was conducted to investigate the interaction effect of a new plant growth regulator brassinolide and auxins using several bioassay methods such as rice lamina inclination test, oat coleoptile segment growth test and radish hypocotyl elongation test. For rice lamina inclination test, the antagonistic response showed at low concentration combinations of homobrassinolide and auxins (IAA and 2,4-D), while the combinations of high concentration responsed mostly synergistic or additive effects, IAA was generally higher than 2,4-D for combination effect with homobrassinolide. For oat coleoptile segment growth test, the synergistic effect showed at IAA concentrations less than 0.1ppm while additive response exhibited above 0.3ppm regardless of homobrassinolide concentrations. In radish hypocotyl elongation test, the interaction response varied with cotyledon. The sections removed cotyledon showed mostly antagonistic effects, except for combination of homobrassinolide with IAA 3ppm. Interaction responses were Quite different from bioassay methods, particularly using experimental materials: antagonistic responses were usually shown at the section that attached growing point while these for sections that removed growing point were responded synergistic or additive effect due to unstable endogenous hormones.

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Effect of Nonsolvent and Metal Salt Concentration on Oxygen Separation Performances of Polycarbonate/Metal Salt Membrane (Polycarbonate/Metal Salt 막의 산소분리특성에 미치는 비용매와 금속염 농도의 영향)

  • Seo, Sang-Hun;Lee, Woo-Tai
    • Journal of the Korean Society of Industry Convergence
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    • v.4 no.1
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    • pp.61-69
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    • 2001
  • Polycarbonate(PC) membranes for oxygen enrichment from air were prepared by the wet phase inversion method. In order to improve oxygen separation performances of the PC membrane, the effect of the added ethanol(nonsolvent) and $CuCl_2$(metal salt) concentration in the casting solution on morphology, oxygen permeability ami $O_2/N_2$ separation factor of the membrane was studied. In addition, tensile strength and elongation at break of the membrane were investigated. An asymmetric membrane with a dense top layer and a porous sublayer was obtained. The thickness of the dense top layer decreased with increasing amount of nonsolvent additive. Compared with pure PC membrane without additive(metal salt), the oxygen permeability and $O_2/N_2$ separation factor of the $PC/CuCl_2$ membrane are significantly improved. The oxygen permeability and $O_2/N_2$ separation factor is $5.25{\times}10^{-9}cm^3(STP){\cdot}cm/cm^2{\cdot}sec{\cdot}cmHg$ and 4.5, respectively. This improvement might be due to good interaction between metal salt and oxygen.

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The Effect of Hydrogen Chloride on the $NO_x$ Production in $H_2/HCl/Air$ Premixed Flame ($H_2/HCl/Air$ 예혼합 화염의 질소산화물 생성에서 염화수소의 영향)

  • Kwon, Young-Suk;Lee, Ki-Yong
    • Journal of the Korean Society of Combustion
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    • v.9 no.4
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    • pp.28-34
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    • 2004
  • Numerical simulations of freely propagating flames burning $H_2/HCl/Air$ Air mixtures were performed at atmospheric pressure in order to understand the effect of hydrogen chloride on flame structures. The chemical and physical effects of hydrogen chloride on flame structures were observed. A chemical kinetic mechanism was developed, which involved 26 gas-phase species and 198 forward elementary reactions. Under several equivalence ratios the flame speeds were calculated and compared with those obtained from the experiments, the results of which were in good agreement. As hydrogen chloride as additive was added into $H_2/Air$ flame, the flame speed, radical concentration and NO production rate were decreased. The chemical effect of hydrogen chloride caused the reduction of radical concentration, and then the decrease of the net rate of NO production. It was found that the influence in the reduction of $EI_{NO}$ with the addition of hydrogen chloride was attributed more due to the chemical effect than the physical effect.

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